ATE187703T1 - MICRO-MESOPOROUS GEL AND METHOD FOR THE PRODUCTION THEREOF - Google Patents

MICRO-MESOPOROUS GEL AND METHOD FOR THE PRODUCTION THEREOF

Info

Publication number
ATE187703T1
ATE187703T1 AT95200093T AT95200093T ATE187703T1 AT E187703 T1 ATE187703 T1 AT E187703T1 AT 95200093 T AT95200093 T AT 95200093T AT 95200093 T AT95200093 T AT 95200093T AT E187703 T1 ATE187703 T1 AT E187703T1
Authority
AT
Austria
Prior art keywords
micro
production
mesoporous gel
mesoporous
gel
Prior art date
Application number
AT95200093T
Other languages
German (de)
Inventor
Giannino Pazzuconi
Gianluca Bassi
Roberto Millini
Carlo Perego
Giovanni Perego
Original Assignee
Enitecnologie Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enitecnologie Spa filed Critical Enitecnologie Spa
Application granted granted Critical
Publication of ATE187703T1 publication Critical patent/ATE187703T1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28026—Particles within, immobilised, dispersed, entrapped in or on a matrix, e.g. a resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28047—Gels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28088—Pore-size distribution
    • B01J20/2809—Monomodal or narrow distribution, uniform pores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/80—Catalysts, in general, characterised by their form or physical properties characterised by their amorphous structures

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Silicon Compounds (AREA)
  • Medicinal Preparation (AREA)
  • Colloid Chemistry (AREA)

Abstract

Micro-mesoporous gel consisting of a silica matrix possibly wherein one or more metal oxides selected from transition metals or metals belonging to groups IIIA, IVA and VA are uniformly dispersed, characterized by a monomodal porosity distribution.
AT95200093T 1994-07-06 1995-01-14 MICRO-MESOPOROUS GEL AND METHOD FOR THE PRODUCTION THEREOF ATE187703T1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI941399A IT1270069B (en) 1994-07-06 1994-07-06 MICRO-MESOPOROUS GEL AND PROCEDURE FOR ITS PREPARATION

Publications (1)

Publication Number Publication Date
ATE187703T1 true ATE187703T1 (en) 2000-01-15

Family

ID=11369221

Family Applications (1)

Application Number Title Priority Date Filing Date
AT95200093T ATE187703T1 (en) 1994-07-06 1995-01-14 MICRO-MESOPOROUS GEL AND METHOD FOR THE PRODUCTION THEREOF

Country Status (8)

Country Link
US (1) US5789336A (en)
EP (1) EP0691305B1 (en)
JP (1) JP3926403B2 (en)
AT (1) ATE187703T1 (en)
DE (1) DE69513893T2 (en)
DK (1) DK0691305T3 (en)
ES (1) ES2139143T3 (en)
IT (1) IT1270069B (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1273514B (en) * 1995-04-07 1997-07-08 Eniricerche Spa PROCEDURE FOR THE PREPARATION OF A MICRO-MESOPOROUS GEL
IT1277442B1 (en) * 1995-08-04 1997-11-10 Enichem Spa PROCEDURE FOR THE PREPARATION OF MIXED SILICA-ZIRCONIA SOL AND MIXED OXIDES OBTAINED IN SPHERICAL FORM
IT1284007B1 (en) * 1996-06-13 1998-05-08 Eniricerche Spa PROCEDURE FOR THE PREPARATION OF A POROUS MICRO-MONTH MATERIAL WITH A HIGH SURFACE AREA WITH CONTROLLED DISTRIBUTION OF THE
US6107236A (en) * 1998-04-14 2000-08-22 Chevron Chemical Company Llc Powders of silica-oxide and mixed silica-oxide and method of preparing same
CN1096296C (en) * 1998-11-13 2002-12-18 中国石油化工集团公司 Hydrocracking catalyst for producing middle distillate and its preparation method
US6492014B1 (en) * 1999-04-01 2002-12-10 The United States Of America As Represented By The Secretary Of The Navy Mesoporous composite gels an aerogels
US6548440B1 (en) * 1999-05-26 2003-04-15 Science & Technology Corporation @ Unm Synthesis of attrition-resistant heterogeneous catalysts using templated mesoporous silica
DE60003461T2 (en) * 1999-11-23 2004-05-06 UNIVERSITé LAVAL MESOPOROUS ZEOLITHIC MATERIAL WITH MICROPOROUS CRYSTALLINE MESOPORAL WALLS
JP4750303B2 (en) * 2001-03-23 2011-08-17 水澤化学工業株式会社 Mesoporous silica alumina gel, humidity control agent and catalyst support
IT1392165B1 (en) 2008-12-01 2012-02-22 Eni Spa GAS SEPARATION PROCESS
US8609032B2 (en) * 2010-11-29 2013-12-17 Corning Incorporated Porous ceramic honeycomb articles and methods for making the same
KR101305182B1 (en) * 2010-11-30 2013-09-12 현대자동차주식회사 Highly efficient catalyst by using precious metal
SG2013023585A (en) * 2012-11-01 2014-06-27 Agency Science Tech & Res Methanation catalyst
CN114477117A (en) * 2021-12-17 2022-05-13 中建材蚌埠玻璃工业设计研究院有限公司 Aluminum phosphate-based powder for heat insulation and preparation method thereof

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1012892A (en) * 1964-04-24 1965-12-08 Grace W R & Co Process for the preparation of modified silica gels
GR66589B (en) * 1978-06-22 1981-03-30 Snam Progetti
CA1177811A (en) * 1981-04-13 1984-11-13 Theo G. Spek Process for the preparation of silica particles; silica particles with a narrow pore diameter distribution, catalysts made therefrom and use of these catalysts
IT1219692B (en) * 1988-05-06 1990-05-24 Eniricerche Spa SILICA GEL AND CATALYTICALLY ACTIVE ALUMINUM AND PROCEDURE FOR ITS PREPARATION
IT1244478B (en) * 1990-12-21 1994-07-15 Eniricerche Spa CATALYTICALLY ACTIVE GEL AND PROCEDURE FOR ITS PREPARATION
IT1251614B (en) * 1991-10-04 1995-05-17 Eniricerche Spa CATALYST AND PROCEDURE FOR THE OLIGOMERIZATION OF OLEFINE
IT1265320B1 (en) * 1993-12-22 1996-10-31 Eniricerche Spa PROCEDURE FOR THE PREPARATION OF CATALYTICALLY ACTIVE AMORPHOUS SILICON-ALUMIN

Also Published As

Publication number Publication date
EP0691305B1 (en) 1999-12-15
US5789336A (en) 1998-08-04
ITMI941399A0 (en) 1994-07-06
ITMI941399A1 (en) 1996-01-06
DE69513893D1 (en) 2000-01-20
IT1270069B (en) 1997-04-28
JPH0859223A (en) 1996-03-05
DE69513893T2 (en) 2000-05-25
JP3926403B2 (en) 2007-06-06
ES2139143T3 (en) 2000-02-01
EP0691305A1 (en) 1996-01-10
DK0691305T3 (en) 2000-04-25

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UEP Publication of translation of european patent specification