ATE203028T1 - Katalysatorszusammensetzung mit verbesserter comonomerenreaktivität - Google Patents

Katalysatorszusammensetzung mit verbesserter comonomerenreaktivität

Info

Publication number
ATE203028T1
ATE203028T1 AT96308581T AT96308581T ATE203028T1 AT E203028 T1 ATE203028 T1 AT E203028T1 AT 96308581 T AT96308581 T AT 96308581T AT 96308581 T AT96308581 T AT 96308581T AT E203028 T1 ATE203028 T1 AT E203028T1
Authority
AT
Austria
Prior art keywords
carbon atoms
hydrocarbyl group
catalyst composition
formula
aluminoxane
Prior art date
Application number
AT96308581T
Other languages
English (en)
Inventor
Eric Paul Wasserman
Sun-Chueh Kao
Frederick John Karol
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Application granted granted Critical
Publication of ATE203028T1 publication Critical patent/ATE203028T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
AT96308581T 1995-11-28 1996-11-27 Katalysatorszusammensetzung mit verbesserter comonomerenreaktivität ATE203028T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/563,702 US5756416A (en) 1995-11-28 1995-11-28 Catalyst composition having improved comonomer reactivity

Publications (1)

Publication Number Publication Date
ATE203028T1 true ATE203028T1 (de) 2001-07-15

Family

ID=24251558

Family Applications (1)

Application Number Title Priority Date Filing Date
AT96308581T ATE203028T1 (de) 1995-11-28 1996-11-27 Katalysatorszusammensetzung mit verbesserter comonomerenreaktivität

Country Status (11)

Country Link
US (2) US5756416A (de)
EP (1) EP0776908B1 (de)
JP (1) JP3157475B2 (de)
AT (1) ATE203028T1 (de)
AU (1) AU713389B2 (de)
BR (1) BR9605727A (de)
CA (1) CA2191381C (de)
DE (1) DE69613798T2 (de)
ES (1) ES2161334T3 (de)
GR (1) GR3036842T3 (de)
PT (1) PT776908E (de)

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DE69612214T2 (de) * 1995-12-12 2001-06-28 Idemitsu Kosan Co. Ltd., Tokio/Tokyo Polymerisationskatalysator und verfahren zur herstellung von polymeren
US6034024A (en) * 1996-05-10 2000-03-07 Albemarle Corporation Heat treated alumoxanes
US5739368A (en) * 1996-05-10 1998-04-14 Albemarle Corporation Use of heat treated alumoxanes in preparing supported catalysts
IT1290848B1 (it) * 1996-12-12 1998-12-14 Additivi Per Carburanti Srl So Copolimeri etilene/alfa-olefine
US6822062B2 (en) 1997-03-10 2004-11-23 Eastman Chemical Company Supported group 8-10 transition metal olefin polymerization catalysts
US6660677B1 (en) 1997-03-10 2003-12-09 Eastman Chemical Company Supported group 8-10 transition metal olefin polymerization catalysts
US6103658A (en) * 1997-03-10 2000-08-15 Eastman Chemical Company Olefin polymerization catalysts containing group 8-10 transition metals, processes employing such catalysts and polymers obtained therefrom
IT1301681B1 (it) 1998-06-11 2000-07-07 Siac It Additivi Carburanti Polimeri dell'etilene con alfa-olefine.
DE19930706A1 (de) * 1999-07-02 2001-01-04 Buna Sow Leuna Olefinverb Gmbh Katalysatorzusammensetzung und Verfahren zur Herstellung von syndiotaktischen Styrolpolymeren
US7220804B1 (en) * 2000-10-13 2007-05-22 Univation Technologies, Llc Method for preparing a catalyst system and its use in a polymerization process
AU2001294964A1 (en) * 2000-11-17 2002-05-27 Univation Technologies, Llc A method for preparing a catalyst composition and its use in a polymerization process
US7244795B2 (en) * 2003-12-08 2007-07-17 Univation Technologies, Llc Polymerization process using metallocene catalyst systems
WO2009060681A1 (ja) * 2007-11-06 2009-05-14 Jsr Corporation 有機金属化合物、水分及び酸素捕捉用組成物、硬化体、及び有機ｅｌ素子
EP2119732A1 (de) 2008-05-16 2009-11-18 Borealis Technology Oy Metallocen-Katalysator-Zusammensetzungen mit verbesserten Eigenschaften, Verfahren zu ihrer Herstellung und ihre Verwendung zur Herstellung von Polyolefin-Homo- oder Copolymeren
WO2011078923A1 (en) 2009-12-23 2011-06-30 Univation Technologies, Llc Methods for producing catalyst systems
KR101846489B1 (ko) * 2010-11-22 2018-04-09 알베마를 코포레이션 활성화제 조성물, 그의 제법 및 촉매 작용에서의 그의 용도
CN103378295A (zh) * 2012-04-23 2013-10-30 海洋王照明科技股份有限公司 一种有机电致发光器件及其封装方法
EP3037437A1 (de) * 2014-12-23 2016-06-29 SABIC Global Technologies B.V. Verfahren zur Herstellung eines Polyolefins mit einem oder mehreren endfunktionalisierten Zweigen
EP3037438A1 (de) * 2014-12-23 2016-06-29 SABIC Global Technologies B.V. Verfahren zur Herstellung eines verzweigten Polyolefins
US10717826B2 (en) 2015-12-09 2020-07-21 Sabic Global Technologies B.V. Process for the preparation of polyolefin-based graft copolymers comprising a first long chain branched polyolefin block and one or multiple polymer side chains
EP3710502A1 (de) 2017-11-15 2020-09-23 ExxonMobil Chemical Patents Inc. Polymerisierungsverfahren
CN111448226B (zh) 2017-11-15 2023-08-25 埃克森美孚化学专利公司 聚合方法
CN111356705A (zh) 2017-11-15 2020-06-30 埃克森美孚化学专利公司 聚合方法
SG11202005184XA (en) 2017-12-18 2020-07-29 Dow Global Technologies Llc Zirconocene-titanocene catalyst system
EP3775035B1 (de) 2018-04-10 2025-12-10 ExxonMobil Chemical Patents Inc. Thermoplastische vulkanisierungszusammensetzungen
CN112969574A (zh) 2018-09-14 2021-06-15 埃克森美孚化学专利公司 用于油气应用的柔性管道的聚合物内/压力护套中的热塑性硫化橡胶组合物
WO2020068409A1 (en) 2018-09-24 2020-04-02 Exxonmobil Chemical Patents Inc. Crosslinked elastomer-polymer blends
CN113454130B (zh) * 2018-12-28 2024-12-13 陶氏环球技术有限责任公司 遥爪聚烯烃和用于制备遥爪聚烯烃的方法
EP3983483B1 (de) 2019-06-13 2025-08-20 ExxonMobil Chemical Patents Inc. Mit thermoplastischen vulkanisatzusammensetzungen hergestellte automobilwetterdichtungen
JP2022536829A (ja) 2019-06-21 2022-08-19 エクソンモービル・ケミカル・パテンツ・インク 熱可塑性加硫物組成物
US20220325086A1 (en) 2019-09-04 2022-10-13 Celanese International Corporation Propylene-Rich Thermoplastic Vulcanizate Compositions and Articles
WO2021080813A1 (en) 2019-10-22 2021-04-29 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizate compositions and processes for the production thereof

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US4242479A (en) * 1976-12-23 1980-12-30 Showa Yuka Kabushiki Kaisha Process for producing an improved ethylenic polymer
JPS60130604A (ja) * 1983-12-16 1985-07-12 Idemitsu Kosan Co Ltd ポリオレフインの製造方法
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WO1988008432A1 (fr) * 1987-04-20 1988-11-03 Mitsui Petrochemical Industries, Ltd. Catalyseur et procede de polymerisation d'olefines
US4925821A (en) * 1987-12-17 1990-05-15 Exxon Chemical Patents Inc. Method for utilizing triethyaluminum to prepare an alumoxane support for an active metallocene catalyst
US4937217A (en) * 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst
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DE4139262A1 (de) * 1991-11-29 1993-06-03 Basf Ag Getraegerte katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
JPH06100614A (ja) * 1992-08-06 1994-04-12 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびこれを用いるオレフィンの重合方法

Also Published As

Publication number Publication date
AU7401596A (en) 1997-06-05
CA2191381C (en) 1999-12-21
JP3157475B2 (ja) 2001-04-16
JPH09309909A (ja) 1997-12-02
EP0776908B1 (de) 2001-07-11
ES2161334T3 (es) 2001-12-01
PT776908E (pt) 2002-01-30
CA2191381A1 (en) 1997-05-29
EP0776908A1 (de) 1997-06-04
MX9605932A (es) 1998-05-31
US5756416A (en) 1998-05-26
US6028151A (en) 2000-02-22
DE69613798T2 (de) 2001-10-25
GR3036842T3 (en) 2002-01-31
DE69613798D1 (de) 2001-08-16
AU713389B2 (en) 1999-12-02
BR9605727A (pt) 1998-08-25

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Legal Events

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UEP Publication of translation of european patent specification
REN Ceased due to non-payment of the annual fee