ATE206141T1 - Feste vorstufe eines katalysatorsystems zur olefinpolymerisation, verfahren zu ihrer herstellung und diese vorstufe enthaltendes katalysatorsystem und verfahren zur polymerisation von olefinen in gegenwart dieses katalysatorsystems - Google Patents

Feste vorstufe eines katalysatorsystems zur olefinpolymerisation, verfahren zu ihrer herstellung und diese vorstufe enthaltendes katalysatorsystem und verfahren zur polymerisation von olefinen in gegenwart dieses katalysatorsystems

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Publication number
ATE206141T1
ATE206141T1 AT97120938T AT97120938T ATE206141T1 AT E206141 T1 ATE206141 T1 AT E206141T1 AT 97120938 T AT97120938 T AT 97120938T AT 97120938 T AT97120938 T AT 97120938T AT E206141 T1 ATE206141 T1 AT E206141T1
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Austria
Prior art keywords
catalyst system
precursor
production
olefin polymerization
polymerizing olefins
Prior art date
Application number
AT97120938T
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English (en)
Inventor
Nicola Zandona
Original Assignee
Solvay
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Filing date
Publication date
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Publication of ATE206141T1 publication Critical patent/ATE206141T1/de

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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    • C—CHEMISTRY; METALLURGY
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C—CHEMISTRY; METALLURGY
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    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT97120938T 1993-03-01 1994-02-17 Feste vorstufe eines katalysatorsystems zur olefinpolymerisation, verfahren zu ihrer herstellung und diese vorstufe enthaltendes katalysatorsystem und verfahren zur polymerisation von olefinen in gegenwart dieses katalysatorsystems ATE206141T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BE9300191A BE1006880A3 (fr) 1993-03-01 1993-03-01 Precurseur solide d'un systeme catalytique pour la polymerisation d'olefines, procede pour sa preparation, systeme catalytique comprenant ce precurseur solide et procede de polymerisation d'olefines en presence de ce systeme catalytique.

Publications (1)

Publication Number Publication Date
ATE206141T1 true ATE206141T1 (de) 2001-10-15

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ID=3886874

Family Applications (2)

Application Number Title Priority Date Filing Date
AT94200399T ATE169033T1 (de) 1993-03-01 1994-02-17 Feste vorstufe eines katalysatorsystems zur olefinpolymerisation, verfahren zu ihrer herstellung und diese vorstufe enthaltendes katalysatorsystem
AT97120938T ATE206141T1 (de) 1993-03-01 1994-02-17 Feste vorstufe eines katalysatorsystems zur olefinpolymerisation, verfahren zu ihrer herstellung und diese vorstufe enthaltendes katalysatorsystem und verfahren zur polymerisation von olefinen in gegenwart dieses katalysatorsystems

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AT94200399T ATE169033T1 (de) 1993-03-01 1994-02-17 Feste vorstufe eines katalysatorsystems zur olefinpolymerisation, verfahren zu ihrer herstellung und diese vorstufe enthaltendes katalysatorsystem

Country Status (14)

Country Link
US (2) US5763349A (de)
EP (2) EP0613908B1 (de)
JP (1) JP3492749B2 (de)
KR (1) KR100300486B1 (de)
CN (1) CN1044372C (de)
AT (2) ATE169033T1 (de)
BE (1) BE1006880A3 (de)
BR (1) BR9400684A (de)
CA (1) CA2116404A1 (de)
DE (2) DE69428464T2 (de)
ES (2) ES2164979T3 (de)
PT (1) PT838476E (de)
RU (1) RU2141972C1 (de)
TW (1) TW332210B (de)

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BE1009186A3 (fr) * 1995-03-13 1996-12-03 Solvay Solide catalytique pour la (co)polymerisation d'ethylene, procede pour sa preparation, systeme catalytique pour la (co)polymerisation d'ethylene et procede de (co)polymerisation d'ethylene.
US6451725B1 (en) * 1995-04-12 2002-09-17 Borealis Technology Oy Method for preparing catalyst components
DE19606167A1 (de) 1996-02-20 1997-08-21 Basf Ag Geträgerte Katalysatorsysteme
DE19606165A1 (de) 1996-02-20 1997-08-21 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alkenen durch Gasphasenpolymerisation
DE19606166A1 (de) 1996-02-20 1997-08-21 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alkenen durch Suspensionspolymerisation
US5965477A (en) * 1997-02-21 1999-10-12 Council Of Scientific & Industrial Research Process for the preparation of supported metallocene catalyst
EP0878483B1 (de) * 1997-03-27 2008-03-12 Council of Scientific and Industrial Research Verfahren zur Polymerisation und Copolymerisation von Olefinen
AU702218B2 (en) * 1997-03-31 1999-02-18 Kyushu-Taiyoukasei., Ltd. Liner film for bulk container and container liner
EP0878485B1 (de) * 1997-05-14 2006-04-26 Council of Scientific and Industrial Research Verfahren zur Polymerisation von Olefinen
GB9712663D0 (en) * 1997-06-16 1997-08-20 Borealis As Process
DE19811934A1 (de) 1998-03-19 1999-09-23 Basf Ag Ethylencopolymere mit enger Comonomerverteilung
BE1012364A3 (fr) * 1998-12-22 2000-10-03 Solvay Procede pour la preparation d'une composition catalytique pour la polymerisation des alpha-olefines, composition catalytique obtenue et procede de polymerisation utilisant une telle composition catalytique
WO2005108442A1 (en) 2002-10-15 2005-11-17 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
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US7618913B2 (en) * 2006-08-31 2009-11-17 Formosa Plastics Corporation, U.S.A. Highly active alpha-olefin copolymerization catalyst system
MY157264A (en) * 2006-11-14 2016-05-31 Univation Tech Llc Catalyst systems and polymerization processes
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EP0613908B1 (de) 1998-07-29
BR9400684A (pt) 1994-10-18
PT838476E (pt) 2002-03-28
JPH06287212A (ja) 1994-10-11
US6214948B1 (en) 2001-04-10
BE1006880A3 (fr) 1995-01-17
US5763349A (en) 1998-06-09
EP0838476A1 (de) 1998-04-29
KR100300486B1 (ko) 2001-10-22
ES2164979T3 (es) 2002-03-01
DE69411968D1 (de) 1998-09-03
CN1098110A (zh) 1995-02-01
CA2116404A1 (fr) 1994-09-02
JP3492749B2 (ja) 2004-02-03
DE69428464D1 (de) 2001-10-31
EP0838476B1 (de) 2001-09-26
EP0613908A1 (de) 1994-09-07
DE69411968T2 (de) 1999-03-18
ATE169033T1 (de) 1998-08-15
RU2141972C1 (ru) 1999-11-27
DE69428464T2 (de) 2002-05-23
ES2122142T3 (es) 1998-12-16
KR940021589A (ko) 1994-10-19
CN1044372C (zh) 1999-07-28

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