ATE210621T1 - Verwendung einer kurzen verweilzeit in der umwandlung von sauerstoffverbindungen - Google Patents

Verwendung einer kurzen verweilzeit in der umwandlung von sauerstoffverbindungen

Info

Publication number
ATE210621T1
ATE210621T1 AT97952642T AT97952642T ATE210621T1 AT E210621 T1 ATE210621 T1 AT E210621T1 AT 97952642 T AT97952642 T AT 97952642T AT 97952642 T AT97952642 T AT 97952642T AT E210621 T1 ATE210621 T1 AT E210621T1
Authority
AT
Austria
Prior art keywords
conversion
residence time
short residence
oxygen compounds
oxygen
Prior art date
Application number
AT97952642T
Other languages
English (en)
Inventor
Stephen N Vaughn
Hsiang-Ning Sun
David R Lumgair Jr
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Application granted granted Critical
Publication of ATE210621T1 publication Critical patent/ATE210621T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/322—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a sulfur atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/323—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/54—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed
    • C10G3/55—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds
    • C10G3/57—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds according to the fluidised bed technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/90—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the eroionite or offretite type, e.g. zeolite T
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4025—Yield
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22—Higher olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Contacts (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
  • Catalysts (AREA)
AT97952642T 1996-12-31 1997-12-31 Verwendung einer kurzen verweilzeit in der umwandlung von sauerstoffverbindungen ATE210621T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3411596P 1996-12-31 1996-12-31
PCT/US1997/023887 WO1998029363A1 (en) 1996-12-31 1997-12-31 Use of short contact time in oxygenate conversion

Publications (1)

Publication Number Publication Date
ATE210621T1 true ATE210621T1 (de) 2001-12-15

Family

ID=21874400

Family Applications (1)

Application Number Title Priority Date Filing Date
AT97952642T ATE210621T1 (de) 1996-12-31 1997-12-31 Verwendung einer kurzen verweilzeit in der umwandlung von sauerstoffverbindungen

Country Status (19)

Country Link
US (1) US5952538A (de)
EP (1) EP0960085B1 (de)
JP (1) JP2001507698A (de)
KR (1) KR100518055B1 (de)
CN (1) CN1133608C (de)
AR (1) AR010865A1 (de)
AT (1) ATE210621T1 (de)
AU (1) AU731024B2 (de)
BR (1) BR9713665A (de)
CA (1) CA2274662C (de)
DE (1) DE69709175T2 (de)
ES (1) ES2169883T3 (de)
ID (1) ID22538A (de)
MY (1) MY129420A (de)
NO (1) NO324730B1 (de)
SA (1) SA98181084B1 (de)
TW (1) TW444002B (de)
WO (1) WO1998029363A1 (de)
ZA (1) ZA9711648B (de)

Families Citing this family (58)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6436869B1 (en) 1996-05-29 2002-08-20 Exxonmobil Chemical Patents Inc. Iron, cobalt and/or nickel containing ALPO bound SAPO molecular sieve catalyst for producing olefins
US6552240B1 (en) 1997-07-03 2003-04-22 Exxonmobil Chemical Patents Inc. Method for converting oxygenates to olefins
RO114524B1 (ro) 1997-10-02 1999-05-28 Sc Zecasin Sa Procedeu de fabricare a oleofinelor cu greutate moleculara mica prin conversia catalitica in strat fluidizat a metanolului
US6137022A (en) * 1997-12-03 2000-10-24 Exxon Chemical Patents Inc Process for increasing the selectivity of a reaction to convert oxygenates to olefins
US6444868B1 (en) 1999-02-17 2002-09-03 Exxon Mobil Chemical Patents Inc. Process to control conversion of C4+ and heavier stream to lighter products in oxygenate conversion reactions
US6559428B2 (en) 2001-01-16 2003-05-06 General Electric Company Induction heating tool
US6395674B1 (en) * 1999-06-07 2002-05-28 Exxon Mobil Chemical Patents, Inc. Heat treating a molecular sieve and catalyst
US6316683B1 (en) * 1999-06-07 2001-11-13 Exxonmobil Chemical Patents Inc. Protecting catalytic activity of a SAPO molecular sieve
WO2001060746A1 (en) 2000-02-16 2001-08-23 Exxonmobil Chemical Patents Inc. Treatment of molecular sieves with silicon containing compounds
US6531639B1 (en) * 2000-02-18 2003-03-11 Exxonmobil Chemical Patents, Inc. Catalytic production of olefins at high methanol partial pressures
US6743747B1 (en) 2000-02-24 2004-06-01 Exxonmobil Chemical Patents Inc. Catalyst pretreatment in an oxgenate to olefins reaction system
CA2399232C (en) * 2000-02-24 2009-11-24 Exxonmobil Chemical Patents Inc. Catalyst pretreatment in an oxygenate to olefins reaction system
US7102050B1 (en) * 2000-05-04 2006-09-05 Exxonmobil Chemical Patents Inc. Multiple riser reactor
US6613950B1 (en) * 2000-06-06 2003-09-02 Exxonmobil Chemical Patents Inc. Stripping hydrocarbon in an oxygenate conversion process
US6441261B1 (en) 2000-07-28 2002-08-27 Exxonmobil Chemical Patents Inc. High pressure oxygenate conversion process via diluent co-feed
US6486219B1 (en) 2000-09-27 2002-11-26 Exxonmobil Chemical Patents, Inc. Methanol, olefin, and hydrocarbon synthesis process
US6444712B1 (en) 2000-09-28 2002-09-03 Exxonmobil Chemical Patents, Inc. Methanol, olefin, and hydrocarbon synthesis process
US6518475B2 (en) 2001-02-16 2003-02-11 Exxonmobil Chemical Patents Inc. Process for making ethylene and propylene
US6441262B1 (en) 2001-02-16 2002-08-27 Exxonmobil Chemical Patents, Inc. Method for converting an oxygenate feed to an olefin product
US20030060672A1 (en) * 2001-06-15 2003-03-27 Lehigh University Production of hydrocarbons from mercaptans
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US7227048B2 (en) 2001-12-31 2007-06-05 Exxonmobil Chemical Patents Inc. Converting oxygenates to olefins over a catalyst comprising acidic molecular sieve of controlled carbon atom to acid site ratio
WO2004016574A1 (en) 2002-08-14 2004-02-26 Exxonmobil Chemical Patents Inc. Process for preparing olefins from oxygenates
US7030284B2 (en) * 2002-08-20 2006-04-18 Exxonmobil Chemical Patents Inc. Method and reactor system for converting oxygenate contaminants in an MTO reactor system product effluent to hydrocarbons
US7122160B2 (en) * 2002-09-24 2006-10-17 Exxonmobil Chemical Patents Inc. Reactor with multiple risers and consolidated transport
US20040064007A1 (en) * 2002-09-30 2004-04-01 Beech James H. Method and system for regenerating catalyst from a plurality of hydrocarbon conversion apparatuses
US7083762B2 (en) * 2002-10-18 2006-08-01 Exxonmobil Chemical Patents Inc. Multiple riser reactor with centralized catalyst return
US7273960B2 (en) * 2002-10-25 2007-09-25 Exxonmobil Chemical Patents Inc Fluid bed oxygenates to olefins reactor apparatus and process of controlling same
US7007701B2 (en) * 2002-10-28 2006-03-07 Exxonmobil Chemical Patents Inc. Processor for removing contaminants from a compressor in a methanol to olefin separation system
US7115791B2 (en) * 2002-12-19 2006-10-03 Exxonmobil Chemical Patents Inc. Method and apparatus for controlling effluent composition in oxygenates to olefins conversion
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7199277B2 (en) * 2004-07-01 2007-04-03 Exxonmobil Chemical Patents Inc. Pretreating a catalyst containing molecular sieve and active metal oxide
EP1850958B1 (de) 2005-01-31 2018-07-04 ExxonMobil Chemical Patents Inc. Molsiebkatalysatorzusammensetzung, deren herstellung und verwendung bei umwandlungsverfahren
CN101817720A (zh) 2006-02-03 2010-09-01 Grt公司 天然气转化为液体烃的连续方法
EP1993951B1 (de) 2006-02-03 2014-07-30 GRT, Inc. Trennung von lichtgasen von brom
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
AU2008256606A1 (en) 2007-05-24 2008-12-04 Grt, Inc. Zone reactor incorporating reversible hydrogen halide capture and release
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
NZ591207A (en) 2008-07-18 2013-03-28 Grt Inc Continuous process for converting natural gas to liquid hydrocarbons
CA2787926A1 (en) 2009-01-23 2010-07-29 Signa Chemistry, Inc. Catalytic dehydration of alcohols using phase pure, calcined single-and multi-site heterogeneous catalysts
WO2011075224A1 (en) * 2009-12-18 2011-06-23 Exxonmobil Chemical Patents Inc. Method of preparing a molecular sieve and its use in the conversion of oxygenates to olefins
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8697930B2 (en) 2010-06-14 2014-04-15 Dow Global Technologies Llc Conversion of methylamine to olefin or mixture of olefins
CN102372539A (zh) * 2010-08-23 2012-03-14 中国石油化工股份有限公司 生产低碳烯烃的方法
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
US20140352533A1 (en) * 2012-01-11 2014-12-04 The Regents Of The University Of Colorado A Body Corporate Seeded-gel synthesis of high flux and high selectivity sapo-34 membranes for co2/ch4 separations
KR101616827B1 (ko) 2014-05-15 2016-04-29 한국화학연구원 경질 올레핀의 제조공정 및 이를 위한 제조장치

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4052479A (en) * 1973-08-09 1977-10-04 Mobil Oil Corporation Conversion of methanol to olefinic components
US4069136A (en) * 1976-10-26 1978-01-17 Uop Inc. Countercurrent hydrocarbon conversion with gravity-flowing catalyst particles
US4359595A (en) * 1980-04-28 1982-11-16 Mobil Oil Corporation Selective production of olefins
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4677243A (en) * 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins from aliphatic hetero compounds
US4499327A (en) * 1982-10-04 1985-02-12 Union Carbide Corporation Production of light olefins
GB9024342D0 (en) * 1990-11-08 1990-12-19 British Petroleum Co Plc Process for the preparation of branched olefins
US5157181A (en) * 1990-12-03 1992-10-20 Uop Moving bed hydrocarbon conversion process
US5095163A (en) * 1991-02-28 1992-03-10 Uop Methanol conversion process using SAPO catalysts
US5126308A (en) * 1991-11-13 1992-06-30 Uop Metal aluminophosphate catalyst for converting methanol to light olefins
JP2715186B2 (ja) * 1992-05-27 1998-02-18 エクソン・ケミカル・パテンツ・インク 高純度オレフィンの製造法
EP0644866B1 (de) * 1992-05-27 1996-08-14 Exxon Chemical Patents Inc. Verwendung von mit säure extrahierten molekularen siebkatalysatoren bei der umsetzung von sauerstoffverbindungen

Also Published As

Publication number Publication date
NO324730B1 (no) 2007-12-03
ID22538A (id) 1999-11-04
US5952538A (en) 1999-09-14
DE69709175T2 (de) 2002-08-14
CA2274662C (en) 2007-06-19
NO993229L (no) 1999-08-31
MY129420A (en) 2007-03-30
JP2001507698A (ja) 2001-06-12
NO993229D0 (no) 1999-06-29
AU5620798A (en) 1998-07-31
KR100518055B1 (ko) 2005-09-28
CN1241990A (zh) 2000-01-19
ES2169883T3 (es) 2002-07-16
BR9713665A (pt) 2000-04-04
AR010865A1 (es) 2000-07-12
EP0960085A1 (de) 1999-12-01
ZA9711648B (en) 1998-12-07
CA2274662A1 (en) 1998-07-09
TW444002B (en) 2001-07-01
DE69709175D1 (de) 2002-01-24
KR20000062374A (ko) 2000-10-25
SA98181084B1 (ar) 2006-05-20
CN1133608C (zh) 2004-01-07
WO1998029363A1 (en) 1998-07-09
EP0960085B1 (de) 2001-12-12
AU731024B2 (en) 2001-03-22

Similar Documents

Publication Publication Date Title
DE69709175D1 (de) Verwendung einer kurzen verweilzeit in der umwandlung von sauerstoffverbindungen
DE69316711D1 (de) Leistungswandler
FI20021086L (fi) Moodinmuunnin
DE69126540D1 (de) Kraftwandler
DE69504036D1 (de) Wandler mit verbesserter kompensation
DE59306537D1 (de) Magnetostriktiver wandler
NO173284C (no) Antigro-maling
DE69333058D1 (de) Piezoelektrischer Wandler
DE69325523D1 (de) Analog-Digital-Wandler
DE69308305D1 (de) Verwendung von zeoliten bei der umsetzung von sauerstoffverbindungen in kohlenwasserstoffen
DE69409163D1 (de) Leistungskonverter
FI935644A0 (fi) Retrovirala proteasinhibitorer
DE69425928D1 (de) Photoelektrischer Umwandler
DE69317611D1 (de) Spannungs-Strom-Umsetzerschaltungsanordnung
DE69210940D1 (de) Leistungsumrichter
DE69329126D1 (de) Photoelektrischer Umwandler
DE69224634D1 (de) Wasserwellenenergieumsetzer
FI932860A7 (fi) Laskostettu energiamuunnin
DE69403739D1 (de) Spannung-Strom-Umsetzter
DE69416796D1 (de) Leistungsumwandler
FI933016A0 (fi) Konjugerade polymerer
DE59503454D1 (de) Verwendung einer walze
DE59407292D1 (de) Spannungswandler
ATA175791A (de) Sperrwandler
DE69326923D1 (de) Parallel-Serien-Umsetzer

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties