ATE213250T1 - Metallkomplexe enthaltend in position 3 arylsubstituierte indenylderivate, und polymerisationsverfahren - Google Patents

Metallkomplexe enthaltend in position 3 arylsubstituierte indenylderivate, und polymerisationsverfahren

Info

Publication number
ATE213250T1
ATE213250T1 AT97946326T AT97946326T ATE213250T1 AT E213250 T1 ATE213250 T1 AT E213250T1 AT 97946326 T AT97946326 T AT 97946326T AT 97946326 T AT97946326 T AT 97946326T AT E213250 T1 ATE213250 T1 AT E213250T1
Authority
AT
Austria
Prior art keywords
aryl
metal complexes
polymerization processes
complexes containing
substituted indenyl
Prior art date
Application number
AT97946326T
Other languages
English (en)
Inventor
Peter N Nickias
Jasson T Patton
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ATE213250T1 publication Critical patent/ATE213250T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AT97946326T 1996-12-19 1997-10-17 Metallkomplexe enthaltend in position 3 arylsubstituierte indenylderivate, und polymerisationsverfahren ATE213250T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3481996P 1996-12-19 1996-12-19
PCT/US1997/019463 WO1998027102A1 (en) 1996-12-19 1997-10-17 3-aryl substituted indenyl containing metal complexes and polymerization process

Publications (1)

Publication Number Publication Date
ATE213250T1 true ATE213250T1 (de) 2002-02-15

Family

ID=21878814

Family Applications (1)

Application Number Title Priority Date Filing Date
AT97946326T ATE213250T1 (de) 1996-12-19 1997-10-17 Metallkomplexe enthaltend in position 3 arylsubstituierte indenylderivate, und polymerisationsverfahren

Country Status (19)

Country Link
US (2) US5866704A (de)
EP (1) EP0946574B1 (de)
JP (1) JP2001506260A (de)
KR (1) KR20000049229A (de)
CN (1) CN1094129C (de)
AR (1) AR010798A1 (de)
AT (1) ATE213250T1 (de)
AU (1) AU726123B2 (de)
BR (1) BR9712535A (de)
CA (1) CA2265515A1 (de)
DE (1) DE69710491T2 (de)
ES (1) ES2168681T3 (de)
ID (1) ID21507A (de)
MY (1) MY115258A (de)
NO (1) NO991816L (de)
RU (1) RU2186073C2 (de)
TR (1) TR199900841T2 (de)
TW (1) TW397845B (de)
WO (1) WO1998027102A1 (de)

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US6015868A (en) * 1996-10-03 2000-01-18 The Dow Chemical Company Substituted indenyl containing metal complexes and olefin polymerization process
US6218557B1 (en) * 1996-11-22 2001-04-17 Boulder Scientific Company Synthesis of titanocenes
DE19720171A1 (de) * 1997-05-14 1998-11-19 Bayer Ag Verbindungen der Seltenen Erden und ihre Verwendung als Polymerisationskatalysatoren für ungesättigte Verbindungen
US6630215B1 (en) * 1998-03-09 2003-10-07 Denki Kagaku Kogyo Kabushiki Kaisha Medical Device
US6015916A (en) * 1999-02-02 2000-01-18 Boulder Scientific Company Constrained geometry metallocene catalyst complexes
DE60001902T2 (de) * 1999-06-04 2003-11-13 Basell Polyolefine Gmbh Verfahren zur herstellung titankomplexen
WO2002018459A1 (en) * 2000-08-29 2002-03-07 Chevron Phillips Chemical Company Lp Process for the production of copolymers or terpolymers with functionalized pendant groups
WO2002068529A2 (en) * 2001-02-27 2002-09-06 Dow Global Technologies Inc. Fabricated articles prepared from blends of substantially random ethylene/propylene/vinyl aromatic interpolymers with polypropylene
US6946531B2 (en) * 2001-05-14 2005-09-20 Dow Global Technologies Inc. Low molecular weight ethylene interpolymers and polymerization process
WO2002092610A1 (en) * 2001-05-14 2002-11-21 Dow Global Technologies Inc. 3-aryl-substituted cyclopentadienyl metal complexes and polymerization process
US20040106739A1 (en) * 2002-02-19 2004-06-03 Cheung Yunwa Wilson Blends of substantially random interpolymers with enhanced thermal performance
KR20100101024A (ko) * 2002-03-14 2010-09-15 다우 글로벌 테크놀로지스 인크. 치환된 인데닐 금속 착물
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
US7737205B2 (en) 2003-07-28 2010-06-15 Dow Global Technologies Inc Thermoplastic vulcanizates and process to prepare them
DE602005013949D1 (de) * 2004-03-16 2009-05-28 Union Carbide Chem Plastic Oligomerisierung von ethylen mit aluminiumphosphat-geträgerten gruppe 6 metallamidkatalysatoren
NZ549262A (en) 2004-03-17 2010-08-27 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
WO2005090425A1 (en) 2004-03-17 2005-09-29 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for ethylene copolymer formation
EP2792690B1 (de) 2004-03-17 2019-05-15 Dow Global Technologies LLC Katalysatorzusammensetzung mit Kettenübertragungsreagenz (chain shuttling) zur Herstellung von Ethylen-Multiblock-Copolymeren
US20050217153A1 (en) * 2004-04-05 2005-10-06 Ward John W Ii Hanging greeting card with gift/care package container
CN102321201B (zh) 2004-06-16 2013-06-26 陶氏环球技术有限责任公司 选择聚合改性剂的方法
JP4734878B2 (ja) * 2004-09-28 2011-07-27 旭硝子株式会社 ガス吸収装置およびガス吸収方法、重合体の製造方法
EP2894176B1 (de) * 2005-03-17 2022-06-01 Dow Global Technologies LLC Katalysatorzusammensetzung mit reversiblem Kettenübertragungsreagenz für die regio-irreguläre Multiblock-Copolymer-Synthese
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
CA2600140A1 (en) 2005-03-17 2006-09-28 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
AR058449A1 (es) 2005-09-15 2008-02-06 Dow Global Technologies Inc Copolimeros de bloque de olefina cataliticos via un agente de transferencia polimerizable
KR20080055838A (ko) * 2005-09-15 2008-06-19 다우 글로벌 테크놀로지스 인크. 다중심 셔틀링제를 통한 중합체 구성 및 분자량 분포의제어
ITMI20070877A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari
ITMI20070878A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali
US7981517B2 (en) 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
WO2011014533A1 (en) 2009-07-29 2011-02-03 Dow Global Technologies Inc. Multifunctional chain shuttling agents
US20110054122A1 (en) * 2009-08-31 2011-03-03 Jerzy Klosin Catalyst and process for polymerizing an olefin and polyolefin prepared thereby
WO2011102990A2 (en) 2010-02-19 2011-08-25 Dow Global Technologies Llc Process for polymerizing an olefin monomer and catalyst therefor
US8202954B2 (en) 2010-02-19 2012-06-19 Dow Global Technologies Llc Metal-ligand complexes and catalysts
WO2012103080A1 (en) 2011-01-26 2012-08-02 Dow Global Technologies Llc Process for making a polyolefin-polysiloxane block copolymer
US9296836B2 (en) 2011-05-12 2016-03-29 Dow Global Technologies Llc Non-cyclopentadienyl-based chromium catalysts for olefin polymerization
CN103890023B (zh) 2011-10-24 2016-11-16 三菱化学株式会社 热塑性弹性体组合物及其制造方法
CN104379680B (zh) * 2012-08-03 2017-11-28 埃克森美孚化学专利公司 具有长链支化的乙烯基封端的聚烯烃
US9376559B2 (en) 2013-11-22 2016-06-28 Exxonmobil Chemical Patents Inc. Reverse staged impact copolymers
BR112016012971B1 (pt) 2013-12-19 2021-06-08 Dow Global Technologies Llc complexo de metal-ligante, catalisador e processo para preparar uma poliolefina
CN108026115B (zh) 2015-09-30 2021-11-09 陶氏环球技术有限责任公司 可用于链穿梭的多头或双头组合物及其制备方法
KR102010630B1 (ko) * 2016-01-20 2019-08-13 한화토탈 주식회사 올레핀 중합촉매 및 이를 이용한 올레핀 중합방법
JP7029448B2 (ja) 2016-09-30 2022-03-03 ダウ グローバル テクノロジーズ エルエルシー チェーンシャトリングに有用な封鎖されたマルチまたはデュアルヘッド組成物、およびそれを調製するプロセス
EP3519474B1 (de) 2016-09-30 2024-09-25 Dow Global Technologies LLC Verfahren zur herstellung von mehrfach- oder doppelkopfzusammensetzungen zur kettenübertragung
WO2018064553A1 (en) 2016-09-30 2018-04-05 Dow Global Technologies Llc Multi- or dual-headed compositions useful for chain shuttling and process to prepare the same
EP3596143B1 (de) 2017-03-15 2023-04-26 Dow Global Technologies LLC Katalysatorsystem für mehrblockcopolymerbildung
WO2018170248A1 (en) 2017-03-15 2018-09-20 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
WO2018170056A1 (en) 2017-03-15 2018-09-20 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
SG11201908307XA (en) 2017-03-15 2019-10-30 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
EP3596141B1 (de) 2017-03-15 2021-07-28 Dow Global Technologies LLC Katalysatorsystem für mehrblockcopolymerbildung
WO2019182988A1 (en) 2018-03-19 2019-09-26 Dow Global Technologies Llc Silicon-terminated organo-metal compounds and processes for preparing the same
KR102714698B1 (ko) 2019-02-28 2024-10-10 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
CN113264963A (zh) * 2021-05-19 2021-08-17 青岛科技大学 一种耐高温高活性限定几何构型催化剂的制备与应用

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Also Published As

Publication number Publication date
NO991816D0 (no) 1999-04-16
US5866704A (en) 1999-02-02
DE69710491D1 (de) 2002-03-21
EP0946574B1 (de) 2002-02-13
BR9712535A (pt) 1999-10-19
EP0946574A1 (de) 1999-10-06
AU726123B2 (en) 2000-11-02
CN1094129C (zh) 2002-11-13
US5959047A (en) 1999-09-28
CN1233253A (zh) 1999-10-27
JP2001506260A (ja) 2001-05-15
AU5152198A (en) 1998-07-15
RU2186073C2 (ru) 2002-07-27
NO991816L (no) 1999-04-16
DE69710491T2 (de) 2002-10-02
ES2168681T3 (es) 2002-06-16
CA2265515A1 (en) 1998-06-25
WO1998027102A1 (en) 1998-06-25
MY115258A (en) 2003-04-30
ID21507A (id) 1999-06-17
TW397845B (en) 2000-07-11
TR199900841T2 (xx) 1999-06-21
AR010798A1 (es) 2000-07-12
KR20000049229A (ko) 2000-07-25

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