ATE220657T1 - Verfahren zum herstellen mit grosser ausbeute von methylmethacrylat oder methacrylsäure - Google Patents
Verfahren zum herstellen mit grosser ausbeute von methylmethacrylat oder methacrylsäureInfo
- Publication number
- ATE220657T1 ATE220657T1 AT99308376T AT99308376T ATE220657T1 AT E220657 T1 ATE220657 T1 AT E220657T1 AT 99308376 T AT99308376 T AT 99308376T AT 99308376 T AT99308376 T AT 99308376T AT E220657 T1 ATE220657 T1 AT E220657T1
- Authority
- AT
- Austria
- Prior art keywords
- methacrylic acid
- methyl methacrylate
- high yield
- producing high
- yield methyl
- Prior art date
Links
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 title abstract 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C231/00—Preparation of carboxylic acid amides
- C07C231/06—Preparation of carboxylic acid amides from nitriles by transformation of cyano groups into carboxamide groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/02—Apparatus characterised by being constructed of material selected for its chemically-resistant properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/242—Tubular reactors in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/243—Tubular reactors spirally, concentrically or zigzag wound
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/08—Preparation of carboxylic acids or their salts, halides or anhydrides from nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/18—Preparation of carboxylic acid esters by conversion of a group containing nitrogen into an ester group
- C07C67/20—Preparation of carboxylic acid esters by conversion of a group containing nitrogen into an ester group from amides or lactams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00164—Controlling or regulating processes controlling the flow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/02—Apparatus characterised by their chemically-resistant properties
- B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
- B01J2219/0277—Metal based
- B01J2219/029—Non-ferrous metals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10694798P | 1998-11-04 | 1998-11-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE220657T1 true ATE220657T1 (de) | 2002-08-15 |
Family
ID=22314086
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT99308376T ATE220657T1 (de) | 1998-11-04 | 1999-10-22 | Verfahren zum herstellen mit grosser ausbeute von methylmethacrylat oder methacrylsäure |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US6545176B1 (de) |
| EP (1) | EP0999200B1 (de) |
| JP (2) | JP4553425B2 (de) |
| KR (1) | KR100691647B1 (de) |
| CN (1) | CN1173921C (de) |
| AT (1) | ATE220657T1 (de) |
| BR (1) | BR9904993B1 (de) |
| DE (1) | DE69902137T2 (de) |
| ES (1) | ES2179599T3 (de) |
| TW (1) | TW505629B (de) |
Families Citing this family (77)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4736165B2 (ja) * | 2000-08-23 | 2011-07-27 | 住友化学株式会社 | トリエチルアミンの回収方法およびエマルジョン層の削減方法 |
| US6906164B2 (en) * | 2000-12-07 | 2005-06-14 | Eastman Chemical Company | Polyester process using a pipe reactor |
| FR2827279B1 (fr) * | 2001-07-13 | 2004-06-18 | Atofina | Procede de preparation de methacrylamide sulfurique et dispositif pour sa mise en oeuvre |
| ZA200303241B (en) * | 2002-05-01 | 2003-11-04 | Rohm & Haas | Improved process for methacrylic acid and methcrylic acid ester production. |
| US7128813B2 (en) | 2002-05-01 | 2006-10-31 | Rohm And Haas Company | Process for manufacturing high purity methacrylic acid |
| BRPI0503134B1 (pt) | 2004-08-02 | 2018-03-20 | Rohm And Haas Company | Método de formação de uma chapa de tubo laminada |
| US20060091084A1 (en) * | 2004-11-02 | 2006-05-04 | Baldwin Filters, Inc. | Fluted filter media with intermediate flow restriction and method of making same |
| US20060090431A1 (en) * | 2004-11-02 | 2006-05-04 | Baldwin Filters, Inc. | Filter assembly with combination filter element |
| US7318851B2 (en) | 2004-11-02 | 2008-01-15 | Baldwin Filters, Inc. | Filter element |
| US8042694B2 (en) * | 2004-11-02 | 2011-10-25 | Baldwin Filters, Inc. | Gathered filter media for an air filter and method of making same |
| US20110197556A1 (en) | 2004-11-02 | 2011-08-18 | Baldwin Filters, Inc. | Filter element |
| US7931725B2 (en) | 2004-11-02 | 2011-04-26 | Baldwin Filters, Inc. | Fluted filter apparatus |
| US7255300B2 (en) | 2004-11-03 | 2007-08-14 | Baldwin Filters, Inc. | Method and apparatus for winding a filter media pack |
| US7909954B2 (en) | 2004-11-03 | 2011-03-22 | Baldwin Filters, Inc. | Method and apparatus for winding a filter media pack |
| US7753982B2 (en) * | 2006-02-17 | 2010-07-13 | Baldwin Filters, Inc. | Filter with drained jacket, seal indicator/lock means, and seal baffle |
| US9757676B2 (en) | 2006-12-06 | 2017-09-12 | Baldwin Filters, Inc. | Method and apparatus for winding a filter element |
| US10040020B2 (en) | 2006-12-06 | 2018-08-07 | Baldwin Filters, Inc. | Fluid filter apparatus having filter media wound about a winding frame |
| US7943094B2 (en) | 2006-12-07 | 2011-05-17 | Grupo Petrotemex, S.A. De C.V. | Polyester production system employing horizontally elongated esterification vessel |
| US7649109B2 (en) | 2006-12-07 | 2010-01-19 | Eastman Chemical Company | Polyester production system employing recirculation of hot alcohol to esterification zone |
| DE102006058251A1 (de) * | 2006-12-08 | 2008-06-12 | Evonik Röhm Gmbh | Verfahren und Vorrichtung zur Herstellung von Methacrylsäurealkylestern |
| US7892498B2 (en) * | 2007-03-08 | 2011-02-22 | Eastman Chemical Company | Polyester production system employing an unagitated esterification reactor |
| US7863477B2 (en) | 2007-03-08 | 2011-01-04 | Eastman Chemical Company | Polyester production system employing hot paste to esterification zone |
| US7872089B2 (en) * | 2007-07-12 | 2011-01-18 | Eastman Chemical Company | Multi-level tubular reactor with internal tray |
| US7842777B2 (en) * | 2007-07-12 | 2010-11-30 | Eastman Chemical Company | Sloped tubular reactor with divided flow |
| US7858730B2 (en) * | 2007-07-12 | 2010-12-28 | Eastman Chemical Company | Multi-level tubular reactor with dual headers |
| US7868129B2 (en) * | 2007-07-12 | 2011-01-11 | Eastman Chemical Company | Sloped tubular reactor with spaced sequential trays |
| US7872090B2 (en) * | 2007-07-12 | 2011-01-18 | Eastman Chemical Company | Reactor system with optimized heating and phase separation |
| US7829653B2 (en) * | 2007-07-12 | 2010-11-09 | Eastman Chemical Company | Horizontal trayed reactor |
| US7847053B2 (en) * | 2007-07-12 | 2010-12-07 | Eastman Chemical Company | Multi-level tubular reactor with oppositely extending segments |
| US7868130B2 (en) * | 2007-07-12 | 2011-01-11 | Eastman Chemical Company | Multi-level tubular reactor with vertically spaced segments |
| US9545593B2 (en) | 2007-11-01 | 2017-01-17 | Baldwin Filters, Inc. | Winding core pressure relief for fluted filter |
| EP2085376B1 (de) | 2008-01-30 | 2012-09-05 | Evonik Röhm GmbH | Verfahren zur Herstellung hochreiner Methacrylsäure |
| DE102008000787A1 (de) * | 2008-03-20 | 2009-09-24 | Evonik Röhm Gmbh | Verfahren zur Aufreinigung von Methacrylsäure |
| DE102008000785A1 (de) | 2008-03-20 | 2009-09-24 | Evonik Röhm Gmbh | Verfahren zur Herstellung von Methacrylsäure |
| US8048187B2 (en) | 2008-06-30 | 2011-11-01 | Baldwin Filters, Inc. | Filter frame attachment and fluted filter having same |
| US7959703B2 (en) | 2008-06-30 | 2011-06-14 | Baldwin Filters, Inc. | Fluted filter with integrated frame |
| EP2349961B1 (de) * | 2008-10-13 | 2016-11-23 | Blue Cube IP LLC | Verfahren zur herstellung chlorierter und/oder fluorierter propene |
| JP5432852B2 (ja) * | 2009-09-30 | 2014-03-05 | ローム アンド ハース カンパニー | メタクリル酸メチルの精製によって生じる流れから価値のある化合物を回収する方法 |
| CN102596387B (zh) * | 2009-10-09 | 2015-11-25 | 陶氏环球技术有限责任公司 | 生产氯化和/或氟化丙烯和高级烯烃的等温多管反应器和方法 |
| WO2011044536A1 (en) * | 2009-10-09 | 2011-04-14 | Dow Global Technologies, Inc | Process for the production of chlorinated and/or fluorinated propenes and higher alkenes |
| KR20120093202A (ko) * | 2009-10-09 | 2012-08-22 | 다우 글로벌 테크놀로지스 엘엘씨 | 단열식 플러그 흐름 반응기 및 염화 및/또는 불화 프로펜 및 고급 알켄의 제조 방법 |
| WO2011044447A2 (en) * | 2009-10-09 | 2011-04-14 | Dow Global Technologies, Inc | Process for the production of chlorinated and/or fluorinated propenes |
| KR101174203B1 (ko) | 2010-04-09 | 2012-08-14 | 박병진 | 폐인조 대리석으로부터 메타크릴산메틸을 회수하는 장치 및 그 방법 |
| WO2012047883A1 (en) * | 2010-10-07 | 2012-04-12 | Rohm And Haas Company | Process for production of methacrylic acid ester |
| CA2837292C (en) | 2011-05-31 | 2020-01-28 | Blue Cube Ip Llc | Process for the production of chlorinated propenes |
| JP6212035B2 (ja) | 2011-05-31 | 2017-10-11 | ブルー キューブ アイピー エルエルシー | 塩素化プロペンの製造方法 |
| CA2837956C (en) | 2011-06-08 | 2016-06-28 | Dow Agrosciences, Llc | Process for the production of chlorinated and/or fluorinated propenes |
| EP3366661A1 (de) | 2011-08-07 | 2018-08-29 | Blue Cube IP LLC | Verfahren zur herstellung chlorierter propene |
| CN108929192A (zh) | 2011-08-07 | 2018-12-04 | 蓝立方知识产权有限责任公司 | 生产氯化的丙烯的方法 |
| US9067855B2 (en) | 2011-11-21 | 2015-06-30 | Dow Global Technologies Llc | Process for the production of chlorinated alkanes |
| CA2856717A1 (en) | 2011-12-02 | 2013-06-06 | Dow Global Technologies Llc | Process for the production of chlorinated alkanes |
| EP2785670B1 (de) | 2011-12-02 | 2017-10-25 | Blue Cube IP LLC | Verfahren zur herstellung von chlorierten alkanen |
| CN104024188B (zh) | 2011-12-13 | 2018-05-01 | 蓝立方知识产权有限责任公司 | 生产氯化丙烷和丙烯的方法 |
| CN110128239A (zh) | 2011-12-22 | 2019-08-16 | 蓝立方知识产权有限责任公司 | 生产四氯甲烷的方法 |
| BR112014015123A2 (pt) | 2011-12-23 | 2017-06-13 | Dow Global Technologies Llc | processo para a produção de um ou mais alcenos ou compostos aromáticos |
| US9970394B2 (en) | 2012-07-25 | 2018-05-15 | Baldwin Filters, Inc. | Filter housing, fluted filter and safety filter |
| EP2897930A1 (de) | 2012-09-20 | 2015-07-29 | Dow Global Technologies LLC | Verfahren zur herstellung von chlorierten propenen |
| US9598334B2 (en) | 2012-09-20 | 2017-03-21 | Blue Cube Ip Llc | Process for the production of chlorinated propenes |
| CN104768920B (zh) * | 2012-09-28 | 2017-03-08 | 罗门哈斯公司 | 由丙酮氰醇和硫酸生产mma和/或maa的方法 |
| CN104718020A (zh) | 2012-09-30 | 2015-06-17 | 陶氏环球技术有限公司 | 堰式骤冷器和并入所述堰式骤冷器的工艺 |
| CA2887559A1 (en) | 2012-10-26 | 2014-05-01 | Dow Global Technologies Llc | Mixer and reactor and process incorporating the same |
| JP6247311B2 (ja) | 2012-12-18 | 2017-12-13 | ブルー キューブ アイピー エルエルシー | 塩素化プロペンを生成するための方法 |
| EP2935166A1 (de) | 2012-12-19 | 2015-10-28 | Blue Cube IP LLC | Verfahren zur herstellung von chlorierten propenen |
| CA2901450A1 (en) | 2013-02-27 | 2014-09-04 | Blue Cube Ip Llc | Process for the production of chlorinated propenes |
| JP6449791B2 (ja) | 2013-03-09 | 2019-01-09 | ブルー キューブ アイピー エルエルシー | クロロアルカンの製造方法 |
| CN103254091B (zh) * | 2013-05-21 | 2015-04-08 | 重庆紫光化工股份有限公司 | 一种甲基丙烯酰胺、甲基丙烯酸甲酯和甲基丙烯酸的联合生产方法 |
| FR3008692B1 (fr) * | 2013-07-19 | 2016-12-23 | Arkema France | Installation et procede pour la preparation de cyanure d'hydrogene |
| FR3008627B1 (fr) | 2013-07-19 | 2017-02-24 | Arkema France | Cuve de conversion thermique utilisee dans un procede d'amidification de cyanohydrine d'acetone |
| FR3012143B1 (fr) * | 2013-10-18 | 2016-08-26 | Arkema France | Cuve d'hydrolyse dans un procede d'amidification de cyanohydrine d'acetone |
| US10294190B2 (en) | 2014-10-27 | 2019-05-21 | Rohm And Haas Company | Reduced fouling process for the production of methyl methacrylate |
| BR112017007928B1 (pt) * | 2014-10-27 | 2022-05-17 | Rohm And Haas Company | Processo para a produção de metacrilato de metila |
| US10682597B2 (en) | 2016-04-14 | 2020-06-16 | Baldwin Filters, Inc. | Filter system |
| CN110394143B (zh) * | 2019-08-21 | 2024-06-07 | 兖矿能源集团股份有限公司 | 一种煤消解管式反应装置 |
| CN116348444A (zh) * | 2020-10-23 | 2023-06-27 | 罗姆化学有限责任公司 | 通过在转化过程中减少的返混而改进的用于制备甲基丙烯酸甲酯和/或甲基丙烯酸的方法 |
| CN113121343A (zh) * | 2021-03-15 | 2021-07-16 | 江苏新东风化工科技有限公司 | 一种丙烯酸正丁酯的中和生产工艺 |
| CN118804909A (zh) | 2022-03-08 | 2024-10-18 | 罗姆化学有限责任公司 | 制备高纯度(甲基)丙烯酸酯的方法 |
| KR20250048021A (ko) | 2022-07-28 | 2025-04-07 | 닛토덴코 가부시키가이샤 | 접합체, 접합체의 해체 방법 및 접합체에 사용되는 열경화성 점착제 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2416756A (en) * | 1941-10-23 | 1947-03-04 | Du Pont | Continuous production of esters of methacrylic acid |
| US2373464A (en) * | 1942-05-22 | 1945-04-10 | Du Pont | Process for inhibiting polymerization |
| US2786739A (en) * | 1954-05-10 | 1957-03-26 | Allied Chem & Dye Corp | Continuous process for the production of methacrylic acid esters and ammonium sulphate |
| US3027328A (en) * | 1958-12-09 | 1962-03-27 | Degussa | Process for the preparation of acetonecyanohydrin/sulfuric acid mixtures |
| JPS49135917A (de) * | 1973-05-15 | 1974-12-27 | ||
| PL84285B1 (de) * | 1973-07-12 | 1976-03-31 | ||
| JPS5767534A (en) * | 1980-10-16 | 1982-04-24 | Mitsui Toatsu Chem Inc | Preparation of alpha,beta-unsaturated carboxylic ester and alpha,beta-unsaturated carboxylic acid |
| US4529816A (en) * | 1984-02-13 | 1985-07-16 | E. I. Du Pont De Nemours And Company | Process for producing alkyl methacrylates |
| JPS61261391A (ja) * | 1985-05-13 | 1986-11-19 | 東洋エンジニアリング株式会社 | 熱分解改質油の製法 |
| US4748268A (en) | 1986-07-31 | 1988-05-31 | Amoco Corporation | Continuous process for production of methacrylic acid ester of C1 to C4 aliphatic alcohol |
| JP2778131B2 (ja) * | 1989-07-14 | 1998-07-23 | 三菱瓦斯化学株式会社 | メタクリル酸メチルの製造方法 |
| US5393918A (en) | 1993-12-02 | 1995-02-28 | Rohm And Haas Company | High yield process for the production of methacrylic acid esters |
| KR960000850A (ko) * | 1994-06-06 | 1996-01-25 | 사토 아키오 | 메타크릴산메틸의 연속제조방법 |
| JPH0853393A (ja) * | 1994-06-06 | 1996-02-27 | Mitsui Toatsu Chem Inc | メタクリル酸メチルの連続製造方法 |
-
1999
- 1999-10-22 EP EP99308376A patent/EP0999200B1/de not_active Expired - Lifetime
- 1999-10-22 DE DE69902137T patent/DE69902137T2/de not_active Expired - Lifetime
- 1999-10-22 ES ES99308376T patent/ES2179599T3/es not_active Expired - Lifetime
- 1999-10-22 AT AT99308376T patent/ATE220657T1/de not_active IP Right Cessation
- 1999-10-28 US US09/428,729 patent/US6545176B1/en not_active Expired - Lifetime
- 1999-11-03 KR KR1019990048260A patent/KR100691647B1/ko not_active Expired - Fee Related
- 1999-11-03 CN CNB991234030A patent/CN1173921C/zh not_active Expired - Lifetime
- 1999-11-03 BR BRPI9904993-7A patent/BR9904993B1/pt not_active IP Right Cessation
- 1999-11-04 TW TW088119234A patent/TW505629B/zh not_active IP Right Cessation
- 1999-11-04 JP JP31370199A patent/JP4553425B2/ja not_active Expired - Lifetime
-
2002
- 2002-07-29 US US10/207,518 patent/US6610177B2/en not_active Expired - Lifetime
-
2010
- 2010-04-20 JP JP2010096906A patent/JP5213901B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR100691647B1 (ko) | 2007-03-09 |
| JP4553425B2 (ja) | 2010-09-29 |
| JP2010209087A (ja) | 2010-09-24 |
| ES2179599T3 (es) | 2003-01-16 |
| CN1254706A (zh) | 2000-05-31 |
| KR20000035177A (ko) | 2000-06-26 |
| US20020188153A1 (en) | 2002-12-12 |
| EP0999200A1 (de) | 2000-05-10 |
| EP0999200B1 (de) | 2002-07-17 |
| US6610177B2 (en) | 2003-08-26 |
| CN1173921C (zh) | 2004-11-03 |
| US6545176B1 (en) | 2003-04-08 |
| BR9904993B1 (pt) | 2011-02-08 |
| DE69902137D1 (de) | 2002-08-22 |
| BR9904993A (pt) | 2000-08-08 |
| DE69902137T2 (de) | 2003-01-30 |
| JP2000159728A (ja) | 2000-06-13 |
| TW505629B (en) | 2002-10-11 |
| JP5213901B2 (ja) | 2013-06-19 |
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