ATE227299T1 - Polymerisationskatalysator - Google Patents
PolymerisationskatalysatorInfo
- Publication number
- ATE227299T1 ATE227299T1 AT99943094T AT99943094T ATE227299T1 AT E227299 T1 ATE227299 T1 AT E227299T1 AT 99943094 T AT99943094 T AT 99943094T AT 99943094 T AT99943094 T AT 99943094T AT E227299 T1 ATE227299 T1 AT E227299T1
- Authority
- AT
- Austria
- Prior art keywords
- polymerization catalyst
- polymerization
- copolymerization
- olefins
- transition metal
- Prior art date
Links
- 239000002685 polymerization catalyst Substances 0.000 title abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
- C07F13/005—Compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyridine Compounds (AREA)
- Glass Compositions (AREA)
- Control Of Throttle Valves Provided In The Intake System Or In The Exhaust System (AREA)
- Air Bags (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9819847.6A GB9819847D0 (en) | 1998-09-12 | 1998-09-12 | Novel compounds |
| PCT/GB1999/002888 WO2000015646A1 (en) | 1998-09-12 | 1999-09-01 | Polymerisation catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE227299T1 true ATE227299T1 (de) | 2002-11-15 |
Family
ID=10838730
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT99943094T ATE227299T1 (de) | 1998-09-12 | 1999-09-01 | Polymerisationskatalysator |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6461994B1 (de) |
| EP (1) | EP1123303B1 (de) |
| JP (1) | JP4467185B2 (de) |
| AT (1) | ATE227299T1 (de) |
| AU (1) | AU5637899A (de) |
| DE (1) | DE69903849T2 (de) |
| GB (1) | GB9819847D0 (de) |
| MY (1) | MY133993A (de) |
| TW (1) | TWI241308B (de) |
| WO (1) | WO2000015646A1 (de) |
Families Citing this family (70)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9817004D0 (en) * | 1998-08-06 | 1998-09-30 | Bp Chem Int Ltd | Preparation of polymerisation catalysts |
| DE19931873A1 (de) * | 1999-04-14 | 2000-10-19 | Bayer Ag | Katalysatorsystem zur Olefinpolymerisation |
| WO2001014391A1 (de) | 1999-08-20 | 2001-03-01 | Basf Aktiengesellschaft | Bisimidinoverbindungen und ihre übergangsmetallkomplexe sowie deren verwendung als katalysatoren |
| US6441117B1 (en) | 1999-09-01 | 2002-08-27 | E. I. Du Pont De Nemours And Company | High density polyethylene packaging |
| EP1125928A1 (de) * | 1999-09-02 | 2001-08-22 | Idemitsu Petrochemical Co., Ltd. | ÜBERGANGSMETALLVERBINDUNGEN, KATALYSATOREN FÜR DIE HERSTELLUNG VON -g(a)-OLEFINEN UND VERFAHREN DAFÜR |
| GB9923072D0 (en) * | 1999-09-29 | 1999-12-01 | Bp Chem Int Ltd | Polymerisation catalyst |
| KR20020037364A (ko) * | 1999-09-29 | 2002-05-18 | 메리 이. 보울러 | 폴리에틸렌의 제조 |
| US6710006B2 (en) | 2000-02-09 | 2004-03-23 | Shell Oil Company | Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins |
| US7056996B2 (en) | 2000-02-18 | 2006-06-06 | E. I. Du Pont De Nemours And Company | Productivity catalysts and microstructure control |
| GC0000291A (en) | 2000-06-30 | 2006-11-01 | Shell Int Research | Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins |
| US6534691B2 (en) * | 2000-07-18 | 2003-03-18 | E. I. Du Pont De Nemours And Company | Manufacturing process for α-olefins |
| CN1321956C (zh) * | 2000-08-03 | 2007-06-20 | 纳幕尔杜邦公司 | α－烯烃的连续制备方法 |
| US7037988B2 (en) * | 2000-10-03 | 2006-05-02 | Shell Oil Company | Process for the co-oligomerisation of ethylene and alpha olefins |
| WO2002036641A2 (en) * | 2000-11-06 | 2002-05-10 | Eastman Chemical Company | Improved productivity catalysts and microstructure control |
| JP4860837B2 (ja) * | 2001-06-18 | 2012-01-25 | 出光興産株式会社 | 遷移金属化合物、α−オレフィン製造用触媒及びα−オレフィンの製造方法 |
| ES2272770T3 (es) * | 2001-08-01 | 2007-05-01 | Shell Internationale Research Maatschappij B.V. | Ligandos y sistemas cataliticos derivados de ellos para oligomerizacion de etileno a alfa-olefinas lineales. |
| US8426535B2 (en) * | 2001-08-06 | 2013-04-23 | Ineos Europe Limited | Chain growth reaction process |
| US7087686B2 (en) * | 2001-08-06 | 2006-08-08 | Bp Chemicals Limited | Chain growth reaction process |
| DE10140203A1 (de) * | 2001-08-16 | 2003-02-27 | Bayer Ag | Katalysatoren für die Olefinpolymerisation |
| JP5022546B2 (ja) * | 2001-08-28 | 2012-09-12 | 出光興産株式会社 | α−オレフィン低重合体の製造方法 |
| RU2194056C1 (ru) * | 2001-09-25 | 2002-12-10 | Институт катализа им. Г.К. Борескова СО РАН | Катализатор полимеризации этилена на основе бис(имино)пиридильных комплексов |
| CN100528356C (zh) * | 2002-01-09 | 2009-08-19 | 纳幕尔杜邦公司 | 烯烃聚合催化剂 |
| JP4498926B2 (ja) * | 2002-09-25 | 2010-07-07 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 熱交換器を使用して直鎖状α−オレフィンオリゴマーを製造する方法 |
| WO2004037415A2 (en) | 2002-09-25 | 2004-05-06 | Shell Internationale Research Maatschappij B.V. | Catalyst systems for ethylene oligomerisation to linear alpha olefins |
| JP2006500412A (ja) * | 2002-09-25 | 2006-01-05 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 熱交換器を使用して直鎖状α−オレフィンオリゴマーを製造する方法 |
| US20040143147A1 (en) * | 2002-11-08 | 2004-07-22 | Ittel Steven Dale | Process for producing alpha-olefins |
| US20050014983A1 (en) * | 2003-07-07 | 2005-01-20 | De Boer Eric Johannes Maria | Process for producing linear alpha olefins |
| US20050187418A1 (en) * | 2004-02-19 | 2005-08-25 | Small Brooke L. | Olefin oligomerization |
| US7384886B2 (en) * | 2004-02-20 | 2008-06-10 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
| US20050187098A1 (en) * | 2004-02-20 | 2005-08-25 | Knudsen Ronald D. | Methods of preparation of an olefin oligomerization catalyst |
| US20070043181A1 (en) * | 2005-08-19 | 2007-02-22 | Knudsen Ronald D | Methods of preparation of an olefin oligomerization catalyst |
| US9550841B2 (en) | 2004-02-20 | 2017-01-24 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
| CN1934121A (zh) | 2004-03-24 | 2007-03-21 | 国际壳牌研究有限公司 | 过渡金属配合物 |
| US7297805B2 (en) * | 2004-06-29 | 2007-11-20 | Exxonmobil Research And Engineering Company | Chromium complexes and their use in olefin polymerization |
| AR049714A1 (es) | 2004-07-13 | 2006-08-30 | Shell Int Research | Proceso de preparacion de alfa olefinas lineales |
| EP1716924A1 (de) * | 2005-04-29 | 2006-11-02 | Saudi Basic Industries Corporation | Katalysatorvorläufer für die Herstellung von Olefinen mit ungerader Anzahl von Kohlenstoffatomen, Verfahren zu seiner Herstellung und Verfahren zur Herstellung derartiger Olefine |
| US7727926B2 (en) * | 2005-07-21 | 2010-06-01 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization |
| US7268096B2 (en) * | 2005-07-21 | 2007-09-11 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US7271121B2 (en) * | 2005-07-21 | 2007-09-18 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| EP1918311A1 (de) * | 2006-10-31 | 2008-05-07 | Ineos Europe Limited | Dienpolymerisation |
| CN101652178B (zh) * | 2007-03-06 | 2014-08-27 | 巴塞尔聚烯烃股份有限公司 | 铁络合物及其在聚合方法中的用途 |
| US7902415B2 (en) * | 2007-12-21 | 2011-03-08 | Chevron Phillips Chemical Company Lp | Processes for dimerizing or isomerizing olefins |
| US8415443B2 (en) | 2009-07-10 | 2013-04-09 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
| US8236915B2 (en) * | 2009-07-10 | 2012-08-07 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
| WO2012071358A2 (en) | 2010-11-24 | 2012-05-31 | Momentive Performance Materials Inc. | In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts |
| CN103732599B (zh) * | 2010-11-24 | 2016-09-14 | 莫门蒂夫性能材料股份有限公司 | 多不饱和化合物的金属催化的单-氢化硅烷化 |
| RU2598023C2 (ru) | 2011-05-13 | 2016-09-20 | Юнивейшн Текнолоджиз, Ллк | Полученные распылительной сушкой каталитические композиции и способы полимеризации, в которых они применяются |
| US9782763B2 (en) | 2011-12-14 | 2017-10-10 | Momentive Performance Materials Inc. | Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity |
| US9586872B2 (en) | 2011-12-30 | 2017-03-07 | Chevron Phillips Chemical Company Lp | Olefin oligomerization methods |
| US8927674B2 (en) | 2012-08-16 | 2015-01-06 | Princeton University | Dehydrogenative silylation and crosslinking using cobalt catalysts |
| US9447125B2 (en) | 2012-08-16 | 2016-09-20 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
| US9371340B2 (en) | 2012-08-16 | 2016-06-21 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts |
| WO2014182670A2 (en) | 2013-05-06 | 2014-11-13 | Momentive Performance Materials Inc. | Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts |
| US9371339B2 (en) | 2013-05-06 | 2016-06-21 | Momentive Performance Materials Inc. | Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation |
| WO2014186513A1 (en) | 2013-05-15 | 2014-11-20 | Momentive Performance Materials Inc. | Activation of metal salts with silylhydrides and their use in hydrosilylation reactions |
| WO2015023328A1 (en) | 2013-08-14 | 2015-02-19 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine dimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
| WO2015077298A1 (en) | 2013-11-19 | 2015-05-28 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts |
| EP3071552A1 (de) | 2013-11-19 | 2016-09-28 | The Trustees of Princeton University | Hydroborierung und borylierung mit kobalt-katalysatoren |
| JP6486925B2 (ja) | 2013-11-19 | 2019-03-20 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのその使用 |
| WO2015077304A1 (en) | 2013-11-19 | 2015-05-28 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| WO2017019473A1 (en) * | 2015-07-24 | 2017-02-02 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using pyridinediimine cobalt carboxylate catalysts |
| BR112018017060B1 (pt) * | 2016-03-22 | 2022-09-06 | Apalene Technology Co., Ltd. (Hangzhou) | Catalisador de poli-alfa-olefina linear e método de preparação dos mesmos |
| US9944661B2 (en) | 2016-08-09 | 2018-04-17 | Chevron Phillips Chemical Company Lp | Olefin hydroboration |
| US20180186708A1 (en) | 2016-12-29 | 2018-07-05 | Chevron Phillips Chemical Company Lp | Ethylene Oligomerization Processes |
| US10407360B2 (en) | 2017-12-22 | 2019-09-10 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization processes |
| US10604457B2 (en) | 2016-12-29 | 2020-03-31 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization processes |
| WO2020167821A1 (en) * | 2019-02-12 | 2020-08-20 | Exxonmobil Chemical Patents Inc. | Transition metal bis(phenolate) complexes and their use as catalysts for olefin polymerization |
| RU2704263C1 (ru) * | 2019-07-25 | 2019-10-25 | Федеральное государственное бюджетное учреждение науки Новосибирский институт органической химии им. Н.Н. Ворожцова Сибирского отделения Российской академии наук (НИОХ СО РАН) | Компонент катализатора для полимеризации этилена в высоколинейный полиэтилен, катализатор и способ его приготовления |
| WO2022035585A1 (en) * | 2020-08-13 | 2022-02-17 | Exxonmobil Chemical Patents Inc. | Cyclic containing polymer compositions obtained using transition metal bis(phenolate) catalyst complexes and process for production thereof |
| US11667590B2 (en) * | 2021-05-26 | 2023-06-06 | Chevron Phillips Chemical Company, Lp | Ethylene oligomerization processes |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL129929A0 (en) * | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| AU6018198A (en) * | 1997-01-13 | 1998-08-03 | E.I. Du Pont De Nemours And Company | Polymerization of propylene |
| DE69805638T2 (de) * | 1997-09-05 | 2002-11-21 | Bp Chemicals Ltd., London | Polymerisationskatalysatoren |
-
1998
- 1998-09-12 GB GBGB9819847.6A patent/GB9819847D0/en not_active Ceased
-
1999
- 1999-09-01 WO PCT/GB1999/002888 patent/WO2000015646A1/en not_active Ceased
- 1999-09-01 AU AU56378/99A patent/AU5637899A/en not_active Abandoned
- 1999-09-01 DE DE69903849T patent/DE69903849T2/de not_active Expired - Lifetime
- 1999-09-01 AT AT99943094T patent/ATE227299T1/de not_active IP Right Cessation
- 1999-09-01 JP JP2000570184A patent/JP4467185B2/ja not_active Expired - Lifetime
- 1999-09-01 EP EP99943094A patent/EP1123303B1/de not_active Expired - Lifetime
- 1999-09-10 TW TW088115666A patent/TWI241308B/zh active
- 1999-09-10 MY MYPI99003923A patent/MY133993A/en unknown
-
2000
- 2000-10-30 US US09/674,378 patent/US6461994B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| GB9819847D0 (en) | 1998-11-04 |
| EP1123303B1 (de) | 2002-11-06 |
| DE69903849D1 (de) | 2002-12-12 |
| US6461994B1 (en) | 2002-10-08 |
| MY133993A (en) | 2007-11-30 |
| JP4467185B2 (ja) | 2010-05-26 |
| JP2002524567A (ja) | 2002-08-06 |
| WO2000015646A1 (en) | 2000-03-23 |
| DE69903849T2 (de) | 2003-03-20 |
| EP1123303A1 (de) | 2001-08-16 |
| AU5637899A (en) | 2000-04-03 |
| TWI241308B (en) | 2005-10-11 |
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