ATE234825T1 - Verfahren zur direktoxidation von olefinen zu olefinoxiden - Google Patents

Verfahren zur direktoxidation von olefinen zu olefinoxiden

Info

Publication number: ATE234825T1
Authority: AT; Austria
Prior art keywords: titanium; olefin; catalyst; direct oxidation; silica
Prior art date: 1998-12-16

Application number

AT99964088T

Other languages

English (en)

Inventor

Robert G Bowman

Howard W Clark

Alex Kuperman

George E Hartwell

Garmt R Meima

Original Assignee

Dow Global Technologies Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-12-16

Filing date

1999-12-07

Publication date

2003-04-15

1999-12-07 Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc

2003-04-15 Application granted granted Critical

2003-04-15 Publication of ATE234825T1 publication Critical patent/ATE234825T1/de

Links

150000001336 alkenes Chemical class 0.000 title abstract 5
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 4
238000000034 method Methods 0.000 title abstract 3
230000003647 oxidation Effects 0.000 title abstract 2
238000007254 oxidation reaction Methods 0.000 title abstract 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 4
239000003054 catalyst Substances 0.000 abstract 4
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 3
229910052719 titanium Inorganic materials 0.000 abstract 3
239000010936 titanium Substances 0.000 abstract 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
229910052751 metal Inorganic materials 0.000 abstract 2
239000002184 metal Substances 0.000 abstract 2
229910052760 oxygen Inorganic materials 0.000 abstract 2
239000001301 oxygen Substances 0.000 abstract 2
239000000377 silicon dioxide Substances 0.000 abstract 2
239000004408 titanium dioxide Substances 0.000 abstract 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
229910052768 actinide Inorganic materials 0.000 abstract 1
150000001255 actinides Chemical class 0.000 abstract 1
229910052793 cadmium Inorganic materials 0.000 abstract 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract 1
125000004432 carbon atom Chemical group C* 0.000 abstract 1
238000006243 chemical reaction Methods 0.000 abstract 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 1
229910052737 gold Inorganic materials 0.000 abstract 1
239000010931 gold Substances 0.000 abstract 1
229910052739 hydrogen Inorganic materials 0.000 abstract 1
239000001257 hydrogen Substances 0.000 abstract 1
229910052747 lanthanoid Inorganic materials 0.000 abstract 1
150000002602 lanthanoids Chemical class 0.000 abstract 1
229910052914 metal silicate Inorganic materials 0.000 abstract 1
-1 platinum group metals Chemical class 0.000 abstract 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
229910052709 silver Inorganic materials 0.000 abstract 1
239000004332 silver Substances 0.000 abstract 1
229910052725 zinc Inorganic materials 0.000 abstract 1
239000011701 zinc Substances 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Catalysts (AREA)
Epoxy Compounds (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

AT99964088T 1998-12-16 1999-12-07 Verfahren zur direktoxidation von olefinen zu olefinoxiden ATE234825T1 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US11242998P	1998-12-16	1998-12-16
PCT/US1999/028699 WO2000035893A1 (en)	1998-12-16	1999-12-07	Process for the direct oxidation of olefins to olefin oxides

Publications (1)

Publication Number	Publication Date
ATE234825T1 true ATE234825T1 (de)	2003-04-15

Family

ID=22343859

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AT99964088T ATE234825T1 (de)	1998-12-16	1999-12-07	Verfahren zur direktoxidation von olefinen zu olefinoxiden

Country Status (12)

Country	Link
US (1)	US6646142B1 (de)
EP (1)	EP1140883B1 (de)
JP (1)	JP2002532482A (de)
KR (1)	KR20010082357A (de)
CN (1)	CN1172921C (de)
AT (1)	ATE234825T1 (de)
AU (1)	AU756230B2 (de)
BR (1)	BR9917025B1 (de)
DE (1)	DE69906136T2 (de)
ES (1)	ES2190280T3 (de)
ID (1)	ID29813A (de)
WO (1)	WO2000035893A1 (de)

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US6821923B1 (en) *	1999-04-08	2004-11-23	Dow Global Technologies Inc.	Method of preparing a catalyst containing gold and titanium
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US6281369B1 (en) †	2000-12-07	2001-08-28	Arco Chemical Technology, L.P.	Epoxidation catalyst and process
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WO2003011454A2 (en)	2001-08-01	2003-02-13	Dow Global Technologies Inc.	Method of increasing the lifetime of a hydro-oxidation catalyst
DE10300526A1 (de) *	2003-01-09	2004-07-22	Hte Ag The High Throughput Experimentation Company	Silberhaltige Katalysatoren zur Umsetzung von Substraten mit C-C-Doppelbindungen
US7256149B2 (en) *	2004-02-24	2007-08-14	Lyondell Chemical Technology, L.P.	Catalyst regeneration process
SG151323A1 (en) *	2004-04-01	2009-04-30	Dow Global Technologies Inc	Hydro-oxidation of hydrocarbons using catalyst prepared by microwave heating
US7273826B2 (en) *	2005-07-26	2007-09-25	Lyondell Chemical Technology, L.P.	Epoxidation catalyst
US7615654B2 (en) *	2005-10-20	2009-11-10	Lyondell Chemical Technology, L.P.	Direct epoxidation process
US7432384B2 (en) *	2005-10-25	2008-10-07	Lyondell Chemical Technology, L.P.	Direct epoxidation process
US7365217B2 (en) *	2006-01-25	2008-04-29	Lyondell Chemical Technology, L.P.	Oxidation process
US7238817B1 (en)	2006-02-22	2007-07-03	Lyondell Chemical Technology, L.P.	Direct epoxidation process
ATE527057T1 (de) *	2006-11-17	2011-10-15	Dow Global Technologies Llc	Hydrooxidierungsverfahren mittels katalysator aus einem goldclusterkomplex
US7563740B2 (en) *	2006-12-19	2009-07-21	Lyondell Chemical Technology, L.P.	Direct epoxidation process
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US7696367B2 (en) *	2007-04-10	2010-04-13	Lyondell Chemical Technology, L.P.	Direct epoxidation process using a mixed catalyst system
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US7648936B2 (en) *	2008-01-29	2010-01-19	Lyondell Chemical Technology, L.P.	Spray-dried transition metal zeolite and its use
WO2011145487A1 (en) *	2010-05-17	2011-11-24	Sumitomo Chemical Company, Limited	Method for producing olefin oxide
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CN103121983B (zh) *	2011-11-18	2015-01-07	中国石油化工股份有限公司	氯丙烯环氧化反应的方法
WO2017040121A1 (en) *	2015-08-28	2017-03-09	Lyondell Chemical Technology, L.P.	Epoxidation processes and catalysts for use therein
JP6646747B2 (ja) *	2015-12-02	2020-02-14	ライオンデルケミカルテクノロジー、エル．ピー．	ブルッカイト型チタニウムを含有する触媒
CN109721568A (zh) *	2017-10-27	2019-05-07	中国石油化工股份有限公司	一种固体酸催化氧化烯烃的方法
CN114340791B (zh) *	2019-09-30	2024-04-05	陶氏环球技术有限责任公司	金属硅酸盐催化剂再生
CN111716841B (zh)	2020-06-10	2022-03-29	南通纺织丝绸产业技术研究院	一种防丙烯口罩及其制备方法
CN113912571B (zh) *	2020-07-10	2023-12-05	中国石油化工股份有限公司	丙烯直接环氧化以制备环氧丙烷的方法
US12534445B2 (en)	2020-07-10	2026-01-27	China Petroleum & Chemical Corporation	Method for preparing propylene oxide by means of direct epoxidation of propylene
CN115999529B (zh) *	2022-12-26	2025-02-07	中国科学技术大学	一种催化剂及制备方法以及催化甲醇制备环氧乙烷的方法

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BR0016486A (pt)	1999-12-09	2002-11-26	Dow Chemical Co	Processo para ativar ou regenerar um catalisador de hidro-oxidação

1999
- 1999-12-07 AU AU20401/00A patent/AU756230B2/en not_active Ceased
- 1999-12-07 ID IDW00200101282A patent/ID29813A/id unknown
- 1999-12-07 ES ES99964088T patent/ES2190280T3/es not_active Expired - Lifetime
- 1999-12-07 US US09/831,427 patent/US6646142B1/en not_active Expired - Fee Related
- 1999-12-07 CN CNB998144088A patent/CN1172921C/zh not_active Expired - Fee Related
- 1999-12-07 DE DE69906136T patent/DE69906136T2/de not_active Expired - Lifetime
- 1999-12-07 EP EP99964088A patent/EP1140883B1/de not_active Expired - Lifetime
- 1999-12-07 WO PCT/US1999/028699 patent/WO2000035893A1/en not_active Ceased
- 1999-12-07 AT AT99964088T patent/ATE234825T1/de not_active IP Right Cessation
- 1999-12-07 KR KR1020017007553A patent/KR20010082357A/ko not_active Withdrawn
- 1999-12-07 BR BRPI9917025-6A patent/BR9917025B1/pt not_active IP Right Cessation
- 1999-12-07 JP JP2000588154A patent/JP2002532482A/ja active Pending

Also Published As

Publication number	Publication date
DE69906136T2 (de)	2004-01-08
AU2040100A (en)	2000-07-03
EP1140883B1 (de)	2003-03-19
BR9917025B1 (pt)	2010-10-19
KR20010082357A (ko)	2001-08-29
ID29813A (id)	2001-10-11
ES2190280T3 (es)	2003-07-16
BR9917025A (pt)	2001-09-25
DE69906136D1 (de)	2003-04-24
AU756230B2 (en)	2003-01-09
WO2000035893A1 (en)	2000-06-22
JP2002532482A (ja)	2002-10-02
US6646142B1 (en)	2003-11-11
EP1140883A1 (de)	2001-10-10
CN1330644A (zh)	2002-01-09
CN1172921C (zh)	2004-10-27

Legal Events

Date	Code	Title	Description
2003-09-15	RER	Ceased as to paragraph 5 lit. 3 law introducing patent treaties

Publication	Publication Date	Title
DE69906136D1 (de)	2003-04-24	Verfahren zur direktoxidation von olefinen zu olefinoxiden
WO1999000188A8 (en)	1999-10-28	Silver and titanium containing catalyst and process for the direct oxidation of olefins to olefin oxides
ATE192668T1 (de)	2000-05-15	Katalysator zur oxydation von kohlenmonoxid
EP0169939A3 (de)	1987-12-02	Katalysator zur Entfernung von Stickoxiden aus Abgasen
JPS644250A (en)	1989-01-09	Catalyst for cleaning exhaust gas and its production
UA12325A (uk)	1996-12-25	Каталізатор для неселективного окислення органічних сполук
ES8707705A1 (es)	1987-08-16	Procedimiento para la conversion catalitica del metano
KR970702751A (ko)	1997-06-10	고활성 촉매(high activity catalysts)
ZA872977B (en)	1987-11-25	Process for the preparation of a silver-containing catalyst
KR910002824A (ko)	1991-02-26	산화에틸렌 생성방법
BR0011184A (pt)	2002-03-05	Processo para a hidro-oxidação de olefinas a óxidos de olefinas usando catalisador de ouro oxidado, composição de catalisador e método para preparar uma composição de catalisador
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