ATE234869T1 - Verfahren zur herstellung von geträgertem metallocen-katalysator und olefin- polymerisationsverfahren unter dessen verwendung - Google Patents

Verfahren zur herstellung von geträgertem metallocen-katalysator und olefin- polymerisationsverfahren unter dessen verwendung

Info

Publication number
ATE234869T1
ATE234869T1 AT99914784T AT99914784T ATE234869T1 AT E234869 T1 ATE234869 T1 AT E234869T1 AT 99914784 T AT99914784 T AT 99914784T AT 99914784 T AT99914784 T AT 99914784T AT E234869 T1 ATE234869 T1 AT E234869T1
Authority
AT
Austria
Prior art keywords
metallocene catalyst
same
polymerization process
olefin polymerization
supported metallocene
Prior art date
Application number
AT99914784T
Other languages
English (en)
Inventor
Bun-Yeoul Lee
Jae-Seung Oh
Original Assignee
Lg Chemical Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lg Chemical Ltd filed Critical Lg Chemical Ltd
Application granted granted Critical
Publication of ATE234869T1 publication Critical patent/ATE234869T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • C08F4/18—Oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT99914784T 1998-04-09 1999-04-09 Verfahren zur herstellung von geträgertem metallocen-katalysator und olefin- polymerisationsverfahren unter dessen verwendung ATE234869T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1019980012660A KR100380018B1 (ko) 1998-04-09 1998-04-09 메탈로센담지촉매및이를이용한올레핀중합방법
PCT/KR1999/000169 WO1999052949A1 (en) 1998-04-09 1999-04-09 Method for producing supported metallocene catalyst and olefin polymerization process using the same

Publications (1)

Publication Number Publication Date
ATE234869T1 true ATE234869T1 (de) 2003-04-15

Family

ID=19536047

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99914784T ATE234869T1 (de) 1998-04-09 1999-04-09 Verfahren zur herstellung von geträgertem metallocen-katalysator und olefin- polymerisationsverfahren unter dessen verwendung

Country Status (11)

Country Link
US (1) US6469113B1 (de)
EP (1) EP0988326B1 (de)
JP (1) JP2002504184A (de)
KR (1) KR100380018B1 (de)
CN (1) CN1159349C (de)
AT (1) ATE234869T1 (de)
AU (1) AU762873B2 (de)
CA (1) CA2293277C (de)
DE (1) DE69905997T2 (de)
ES (1) ES2194453T3 (de)
WO (1) WO1999052949A1 (de)

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KR100380018B1 (ko) * 1998-04-09 2003-10-04 주식회사 엘지화학 메탈로센담지촉매및이를이용한올레핀중합방법
KR100358225B1 (ko) 1998-04-09 2003-01-24 주식회사 엘지화학 조촉매의 재순환이 가능한 메탈로센 촉매 중합 방법
KR100354290B1 (ko) * 1999-06-22 2002-09-28 주식회사 엘지화학 담지 메탈로센 촉매 및 이를 이용한 올레핀 중합
US7247595B2 (en) * 1999-06-22 2007-07-24 Lg Chem, Ltd. Supported metallocene catalyst and olefin polymerization using the same
US7041618B2 (en) * 1999-06-22 2006-05-09 Lg Chemical Ltd. Supported metallocene catalyst and olefin polymerization using the same
DE60102789T2 (de) 2001-01-18 2005-05-12 Repsol Quimica S.A. Olefinpolymerisationskatalysatoren
KR100536181B1 (ko) * 2001-05-25 2005-12-14 주식회사 엘지화학 표면 개질 담체와 작용기를 가진 촉매 전구체를 사용한중합 담지 촉매 및 이를 이용한 올레핀 중합
US7589160B2 (en) * 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
KR100579843B1 (ko) * 2003-04-01 2006-05-12 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 그의 제조방법과 이를 이용한폴리올레핀의 제조방법
US6992034B2 (en) * 2003-07-10 2006-01-31 Formosa Plastics Corporation, U.S.A. Catalyst component for olefin polymerization
KR101610879B1 (ko) 2013-06-18 2016-04-08 주식회사 엘지화학 실리카 담체 및 그 제조방법과 이를 이용한 메탈로센 촉매
KR101498814B1 (ko) * 2013-09-17 2015-03-05 한화케미칼 주식회사 메탈로센 담지 촉매의 제조 방법
US10404048B2 (en) * 2013-11-26 2019-09-03 Commscope Technologies Llc Adapter for sealing cover for electrical interconnections
EP4428166A3 (de) * 2015-12-31 2024-12-11 Hanwha Chemical Corporation Geträgerter hybridmetallocenkatalysator, verfahren zur herstellung von olefinpolymer damit und olefinpolymer mit verbesserter schmelzfestigkeit
WO2018151790A1 (en) * 2017-02-20 2018-08-23 Exxonmobil Chemical Patents Inc. Hafnocene catalyst compounds and process for use thereof
US10479846B2 (en) * 2017-02-20 2019-11-19 Exxonmobil Chemical Patents Inc. Hafnocene catalyst compounds and process for use thereof
US20230212328A1 (en) * 2020-06-18 2023-07-06 Ineos Europe Ag Method for preparing a catalyst
CN116693724B (zh) * 2023-07-04 2024-11-15 临沂大学 一种纳米SiO2负载的铁催化剂及其制备方法和在异戊二烯聚合中的应用

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KR100380018B1 (ko) * 1998-04-09 2003-10-04 주식회사 엘지화학 메탈로센담지촉매및이를이용한올레핀중합방법
KR101312992B1 (ko) * 2011-08-29 2013-10-01 한국건설기술연구원 소프트 갱폼과 폼타이를 이용한 현장 중단열벽체 시공방법

Also Published As

Publication number Publication date
CN1263537A (zh) 2000-08-16
ES2194453T3 (es) 2003-11-16
KR19980025282A (ko) 1998-07-06
AU3345199A (en) 1999-11-01
KR100380018B1 (ko) 2003-10-04
WO1999052949A1 (en) 1999-10-21
DE69905997D1 (de) 2003-04-24
EP0988326A1 (de) 2000-03-29
US6469113B1 (en) 2002-10-22
EP0988326B1 (de) 2003-03-19
CA2293277A1 (en) 1999-10-21
AU762873B2 (en) 2003-07-10
DE69905997T2 (de) 2003-12-04
CA2293277C (en) 2008-07-22
CN1159349C (zh) 2004-07-28
JP2002504184A (ja) 2002-02-05

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