ATE238401T1 - Verfahren zur herstellung von heissweissanlaufwiderstandsfähigen druckempfindlichen emulsionsklebestoffen - Google Patents
Verfahren zur herstellung von heissweissanlaufwiderstandsfähigen druckempfindlichen emulsionsklebestoffenInfo
- Publication number
- ATE238401T1 ATE238401T1 AT96933171T AT96933171T ATE238401T1 AT E238401 T1 ATE238401 T1 AT E238401T1 AT 96933171 T AT96933171 T AT 96933171T AT 96933171 T AT96933171 T AT 96933171T AT E238401 T1 ATE238401 T1 AT E238401T1
- Authority
- AT
- Austria
- Prior art keywords
- labels
- polymerization
- emulsion
- ethylene oxide
- per mole
- Prior art date
Links
- 239000000839 emulsion Substances 0.000 title abstract 4
- 239000000853 adhesive Substances 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 2
- 239000003945 anionic surfactant Substances 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 239000002736 nonionic surfactant Substances 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000002313 adhesive film Substances 0.000 abstract 1
- -1 alkyl acrylate ester Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003792 electrolyte Substances 0.000 abstract 1
- 238000002356 laser light scattering Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 230000002087 whitening effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/28—Non-macromolecular organic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerisation Methods In General (AREA)
- Adhesive Tapes (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US53730795A | 1995-09-29 | 1995-09-29 | |
| US53615395A | 1995-09-29 | 1995-09-29 | |
| US53428995A | 1995-09-29 | 1995-09-29 | |
| PCT/US1996/015545 WO1997011996A1 (en) | 1995-09-29 | 1996-09-27 | Process for preparing hot water whitening resistant emulsion pressure sensitive adhesives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE238401T1 true ATE238401T1 (de) | 2003-05-15 |
Family
ID=27415142
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT96933171T ATE238401T1 (de) | 1995-09-29 | 1996-09-27 | Verfahren zur herstellung von heissweissanlaufwiderstandsfähigen druckempfindlichen emulsionsklebestoffen |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6489387B2 (de) |
| EP (1) | EP0852602B1 (de) |
| CN (1) | CN1115362C (de) |
| AT (1) | ATE238401T1 (de) |
| AU (1) | AU706827B2 (de) |
| BR (1) | BR9610667A (de) |
| DE (1) | DE69627676T2 (de) |
| MX (1) | MX9802336A (de) |
| WO (1) | WO1997011996A1 (de) |
Families Citing this family (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19649383A1 (de) * | 1996-11-29 | 1998-06-04 | Basf Ag | Kaschierklebstoffe |
| US20030000643A1 (en) * | 1997-10-27 | 2003-01-02 | Bernhard Herlfterkamp | Aqueous adhesive preparation |
| FR2772032B1 (fr) * | 1997-12-08 | 2000-03-31 | Rhodia Chimie Sa | Procede de preparation d'une emulsion adhesive aqueuse sensible a la pression (psa), possedant une resistance au cisaillement elevee |
| US6013722A (en) * | 1998-01-27 | 2000-01-11 | 3M Innovative Properties Company | Non-whitening emulsion pressure sensitive adhesives |
| WO2000061670A1 (en) * | 1999-04-12 | 2000-10-19 | Ashland Inc. | Pressure sensitive adhesives |
| US6803091B2 (en) | 1999-07-20 | 2004-10-12 | Jack G. Winterowd | Edge sealant formulation for wood-based panels |
| CA2314394C (en) * | 1999-07-20 | 2007-06-05 | Weyerhaeuser Company | Edge sealant formulation for wood-based panels |
| JP2001055550A (ja) * | 1999-08-20 | 2001-02-27 | Nippon Nsc Ltd | アクリル系水性粘着剤組成物 |
| US6565968B1 (en) | 2000-04-12 | 2003-05-20 | Avery Dennison Corporation | UV-curable pressure-sensitive adhesives and protective coatings |
| US20040076785A1 (en) * | 2000-05-09 | 2004-04-22 | Richards Corlyss J. | Water-whitening resistant latex emulsion pressure sensitive adhesive and its production |
| US6686425B2 (en) * | 2001-06-08 | 2004-02-03 | Adhesives Research, Inc. | High Tg acrylic polymer and epoxy-containing blend therefor as pressure sensitive adhesive |
| US7169846B2 (en) | 2001-07-13 | 2007-01-30 | Cytec Surface Specialties, Inc. | Process for improving water-whitening resistance of pressure sensitive adhesives |
| US6964991B2 (en) * | 2001-07-13 | 2005-11-15 | Surf Chip, Inc. | Process for improving water-whitening resistance of pressure sensitive adhesives |
| US6883985B2 (en) * | 2002-02-26 | 2005-04-26 | Robin Catherine Roberson | Printable, reusable key masks |
| EG23499A (en) | 2002-07-03 | 2006-01-17 | Advanced Plastics Technologies | Dip, spray, and flow coating process for forming coated articles |
| EP1426428A1 (de) * | 2002-12-06 | 2004-06-09 | Ucb S.A. | Wässrige Polymerdispersionen als druckempfindlicher Kleber |
| TWI306111B (en) * | 2002-12-12 | 2009-02-11 | Four Pillars Entpr Co Ltd | An emulsion type modifier for improving emulsion acrylic pressure sensitive adhesives properties |
| DE10313652A1 (de) * | 2003-03-26 | 2004-10-07 | Tesa Ag | Klebemasse |
| US6995207B2 (en) | 2003-03-31 | 2006-02-07 | Chen Augustin T | Removable pressure sensitive adhesives with plasticizer resistance properties |
| EP1464656A1 (de) * | 2003-04-04 | 2004-10-06 | Ucb S.A. | Emulsionszusammensetzung |
| KR20060115890A (ko) * | 2003-11-07 | 2006-11-10 | 사이텍 설패이스 스페셜티즈, 에스.에이. | 접착제 조성물 |
| US20050176876A1 (en) * | 2004-02-09 | 2005-08-11 | Lee Sou P. | Water-whitening resistant pressure-sensitive adhesive |
| US20050186416A1 (en) * | 2004-02-25 | 2005-08-25 | 3M Innnovative Properties Company | Hydrophilic articles |
| US7306844B2 (en) * | 2004-03-10 | 2007-12-11 | Avery Dennison Corporation | Labels and labeling process |
| ATE424288T1 (de) | 2004-04-16 | 2009-03-15 | Advanced Plastics Technologies | Vorformling und verfahren zur herstellung der vorformling und eine flasche |
| TWI255289B (en) * | 2004-05-05 | 2006-05-21 | Four Pillars Entpr Co Ltd | Emulsion type acrylic pressure sensitive adhesives |
| US20080260851A1 (en) * | 2004-05-13 | 2008-10-23 | The Trustees Of Columbia University In The City Of New York | Polymeric Nanoparticles and Nanogels for Extraction and Release of Compounds |
| US20060100357A1 (en) * | 2004-11-09 | 2006-05-11 | Bunn Andrew G | Water-based adhesives for difficult substrates and low temperatures |
| EP1836048B1 (de) | 2005-01-10 | 2013-09-25 | Avery Dennison Corporation | Entfernbare kräuseletiketten |
| US20060199877A1 (en) * | 2005-03-01 | 2006-09-07 | Sivapackia Ganapathiappan | Shear stable latex particles |
| WO2006127513A1 (en) * | 2005-05-20 | 2006-11-30 | Avery Dennison Corporation | Water whitening-resistant pressure sensitive adhesives |
| US20070135542A1 (en) * | 2005-12-08 | 2007-06-14 | Boonstra Lykele J | Emulsifiers for use in water-based tackifier dispersions |
| US20070254985A1 (en) * | 2006-04-21 | 2007-11-01 | Maas Joost H | Resin dispersions with low surfactant concentrations |
| US20070249759A1 (en) * | 2006-04-21 | 2007-10-25 | Peter James Miller | Tackifier dispersions with improved humid age performance |
| US20090111929A1 (en) * | 2006-04-28 | 2009-04-30 | Basf Se | Contact adhesive containing 2-ethylhexylacrylate and hydroxybutyl(meth) acrylate |
| EP2094799B1 (de) | 2006-11-02 | 2013-08-28 | Avery Dennison Corporation | Emulsionshaftmittel für waschbare folie |
| US8282754B2 (en) | 2007-04-05 | 2012-10-09 | Avery Dennison Corporation | Pressure sensitive shrink label |
| US8535464B2 (en) | 2007-04-05 | 2013-09-17 | Avery Dennison Corporation | Pressure sensitive shrink label |
| US20090061219A1 (en) * | 2007-08-28 | 2009-03-05 | Valspar Sourcing, Inc. | Composition for Coating Glass |
| US20090162595A1 (en) * | 2007-12-19 | 2009-06-25 | Chan Ko | Striped adhesive construction and method and die for making same |
| CN102056952B (zh) * | 2008-04-15 | 2013-11-13 | 巴斯夫欧洲公司 | 用于粘合剂的聚合物水分散体 |
| JP2010037553A (ja) * | 2008-07-10 | 2010-02-18 | Fujifilm Corp | 再剥離性接着シート、画像記録方法および接着方法 |
| US20120034402A1 (en) | 2009-03-30 | 2012-02-09 | Avery Dennison Corporation | Removable Adhesive Label Containing Polymeric Film Layer Having Water Affinity |
| RU2011143933A (ru) | 2009-03-30 | 2013-05-10 | Авери Деннисон Корпорейшн | Удаляемая самоклеющаяся этикетка, включающая слой полимерной пленки с высоким модулем упругости при растяжении |
| CN107610582B (zh) | 2009-03-30 | 2020-07-31 | 艾利丹尼森公司 | 含有固有地可收缩高分子膜的可移除粘合标签 |
| EP2486103A1 (de) * | 2009-10-09 | 2012-08-15 | Berry Plastics Corporation | Wasserbasiertes silikonfreies klebeband für skier |
| BR122014017821A2 (pt) | 2010-01-28 | 2019-07-09 | Avery Dennison Corporation | Sistema para aplicação de rótulos em artigos |
| CN102834566B (zh) | 2010-03-23 | 2016-04-27 | 巴斯夫欧洲公司 | 纸张涂布或粘合配制剂及其制备方法和用途 |
| US9102848B2 (en) | 2011-02-28 | 2015-08-11 | Basf Se | Environmentally friendly, polymer dispersion-based coating formulations and methods of preparing and using same |
| US9421736B2 (en) | 2011-06-17 | 2016-08-23 | Sonoco Development, Inc. | Hybrid pressure sensitive adhesive |
| RU2014103792A (ru) * | 2011-07-05 | 2015-08-10 | Авери Деннисон Корпорейшн | Устойчивый к смыванию клей для этикеток напитков |
| EP2751214B1 (de) | 2011-08-31 | 2021-03-24 | Avery Dennison Corporation | Klebende acrylat-olefin-copolymerisate, verfahren zu deren herstelleung und diese verwendende zusammensetzungen |
| CN102796476A (zh) * | 2012-08-30 | 2012-11-28 | 江阴市尼美达助剂有限公司 | 水溶型丙烯酸酯印花台板胶的制备方法 |
| TWI519339B (zh) | 2012-12-28 | 2016-02-01 | 財團法人工業技術研究院 | 過濾膜 |
| MX2018004940A (es) | 2015-10-20 | 2018-08-01 | Basf Se | Composiciones de recubrimiento para recubrir placas de fibrocemento. |
| CN108456499A (zh) * | 2017-02-20 | 2018-08-28 | 上海阜杰环保科技有限公司 | 一种封口胶及其制备方法 |
| WO2022129700A1 (en) * | 2020-12-18 | 2022-06-23 | Upm Raflatac Oy | Acrylic pressure sensitive adhesive composition for food packaging label application |
| US11840591B2 (en) | 2020-12-31 | 2023-12-12 | Sanipeel, LLC | In situ peelable protective barrier films |
| TW202346520A (zh) * | 2022-05-20 | 2023-12-01 | 美商陶氏全球科技有限責任公司 | 用於ｐｅｔ之洗除型壓敏性黏著劑 |
| TW202407074A (zh) * | 2022-05-20 | 2024-02-16 | 美商陶氏全球科技有限責任公司 | 洗除型壓敏性黏著劑 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3740366A (en) * | 1969-04-28 | 1973-06-19 | Rohm & Haas | Pressure sensitive adhesive containing carboxylic acid groups and polyvalent metal |
| US4409355A (en) | 1980-03-10 | 1983-10-11 | National Distillers And Chemical Corporation | Process for preparing high solids copolymer latices with low viscosity |
| DE3103463A1 (de) | 1981-02-02 | 1982-08-26 | Basf Ag, 6700 Ludwigshafen | Verwendung von emulsionscopolymerisaten auf basis von acrylaten als alleiniges bindemittel fuer papierstreichmassen |
| US4588762A (en) | 1983-11-25 | 1986-05-13 | Graphic Controls Corporation | Pressure sensitive adhesive compositions for medical electrodes |
| US4599378A (en) | 1984-06-22 | 1986-07-08 | Air Products And Chemicals, Inc. | Vinyl acetate copolymer emulsions for paper coating compositions |
| US4713412A (en) | 1985-08-02 | 1987-12-15 | The Dow Chemical Company | Emulsion polymerized sec-butyl acrylate latexes suitable for use as pressure sensitive adhesives |
| JPH0651762B2 (ja) | 1987-05-19 | 1994-07-06 | 三菱油化バ−デイツシエ株式会社 | 粘接着剤用共重合体水性分散体の製造法 |
| US5240989A (en) * | 1987-12-11 | 1993-08-31 | Avery Dennison Corporation | Removable pressure-sensitive adhesive compositions comprising acrylic based emulsion polymers |
| JP2522344B2 (ja) | 1988-03-14 | 1996-08-07 | 日本合成ゴム株式会社 | 水系感圧接着剤 |
| DE3818869A1 (de) * | 1988-06-03 | 1989-12-14 | Basf Ag | Dispersionen von nicht-tertiaeren butyl(meth)acrylat-copolymerisaten mit glastemperaturen unter -10(grad)c |
| US4994538A (en) | 1989-02-24 | 1991-02-19 | Avery International Corporation | Siliconized emulsion based pressure-sensitive adhesives |
| US5202375A (en) | 1989-07-28 | 1993-04-13 | Rohm And Haas Company | Water-resistant polymeric emulsions |
| DE69008334T2 (de) | 1989-08-14 | 1994-11-03 | Avery Dennison Corp., Pasadena, Calif. | Emulsion druckempfindlicher klebepolymere mit ausgezeichnetem verhalten bei raum- und niedrigtemperaturen. |
| US5183459A (en) | 1989-08-14 | 1993-02-02 | Avery Dennison Corporation | Emulsion pressure-sensitive adhesive polymers in bandage and medical tape constructions |
| CA2067969A1 (en) * | 1991-05-30 | 1992-12-01 | Chung I. Young | Method for making structured suspension psa beads |
| WO1993006184A1 (en) * | 1991-09-23 | 1993-04-01 | Minnesota Mining And Manufacturing Company | PRESSURE SENSITIVE ADHESIVE COMPOSITION WHICH IS REPULPABLE UNDER ACIDIC pH CONDITIONS |
| US5420195A (en) * | 1992-01-10 | 1995-05-30 | Avery Dennison Corporation | Water resistant, removable acrylic emulsion pressure sensitive adhesive |
| US6048611A (en) * | 1992-02-03 | 2000-04-11 | 3M Innovative Properties Company | High solids moisture resistant latex pressure-sensitive adhesive |
| JP2534003B2 (ja) | 1992-03-17 | 1996-09-11 | 信越化学工業株式会社 | 積層ゴム成形体 |
| US5286843A (en) * | 1992-05-22 | 1994-02-15 | Rohm And Haas Company | Process for improving water-whitening resistance of pressure sensitive adhesives |
| DE4316379A1 (de) | 1993-05-17 | 1994-11-24 | Basf Ag | Geruchsarmer Dispersionshaftklebstoff |
| US5670557A (en) * | 1994-01-28 | 1997-09-23 | Minnesota Mining And Manufacturing Company | Polymerized microemulsion pressure sensitive adhesive compositions and methods of preparing and using same |
| US5550181A (en) | 1994-03-07 | 1996-08-27 | Avery Dennison Corporation | Repulpable splicing tape |
| US5532300A (en) | 1994-08-12 | 1996-07-02 | National Starch And Chemical Investment Holding Corporation | Water-borne, water redispersible, laminating adhesives for nonwoven applications |
| US5516865A (en) * | 1995-02-03 | 1996-05-14 | Minnesota Mining And Manufacturing Company | Waterborne (meth) acrylic latex polymers for release |
-
1996
- 1996-09-27 AU AU72002/96A patent/AU706827B2/en not_active Expired
- 1996-09-27 DE DE69627676T patent/DE69627676T2/de not_active Expired - Lifetime
- 1996-09-27 AT AT96933171T patent/ATE238401T1/de not_active IP Right Cessation
- 1996-09-27 BR BR9610667A patent/BR9610667A/pt unknown
- 1996-09-27 CN CN96197979A patent/CN1115362C/zh not_active Expired - Lifetime
- 1996-09-27 WO PCT/US1996/015545 patent/WO1997011996A1/en not_active Ceased
- 1996-09-27 EP EP96933171A patent/EP0852602B1/de not_active Expired - Lifetime
-
1997
- 1997-03-28 US US08/825,490 patent/US6489387B2/en not_active Expired - Lifetime
-
1998
- 1998-03-25 MX MX9802336A patent/MX9802336A/es not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BR9610667A (pt) | 1999-07-13 |
| US6489387B2 (en) | 2002-12-03 |
| WO1997011996A1 (en) | 1997-04-03 |
| EP0852602A4 (de) | 1999-09-08 |
| DE69627676D1 (de) | 2003-05-28 |
| AU7200296A (en) | 1997-04-17 |
| CN1201475A (zh) | 1998-12-09 |
| AU706827B2 (en) | 1999-06-24 |
| EP0852602B1 (de) | 2003-04-23 |
| EP0852602A1 (de) | 1998-07-15 |
| CN1115362C (zh) | 2003-07-23 |
| US20010003765A1 (en) | 2001-06-14 |
| MX9802336A (es) | 1998-08-30 |
| DE69627676T2 (de) | 2004-02-05 |
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