ATE23864T1 - Katalytisches system und verfahren zur herstellung eines katalysators. - Google Patents

Katalytisches system und verfahren zur herstellung eines katalysators.

Info

Publication number: ATE23864T1
Authority: AT; Austria
Prior art keywords: phosphate; chromium; compound; cyclopentadienyl; bis
Prior art date: 1982-03-30

Application number

AT83102992T

Other languages

English (en)

Inventor

Max Paul Mcdaniel

James Newton Short

Original Assignee

Phillips Petroleum Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-03-30

Filing date

1983-03-25

Publication date

1986-12-15

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23431246&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE23864(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1983-03-25 Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co

1986-12-15 Application granted granted Critical

1986-12-15 Publication of ATE23864T1 publication Critical patent/ATE23864T1/de

Links

239000003054 catalyst Substances 0.000 title abstract 3
230000003197 catalytic effect Effects 0.000 title 1
238000004519 manufacturing process Methods 0.000 title 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
-1 bis-(cyclopentadienyl)chromium(II) compound Chemical class 0.000 abstract 4
229910019142 PO4 Inorganic materials 0.000 abstract 3
ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 abstract 3
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 3
239000010452 phosphate Substances 0.000 abstract 3
229920000642 polymer Polymers 0.000 abstract 3
239000000377 silicon dioxide Substances 0.000 abstract 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
239000005977 Ethylene Substances 0.000 abstract 1
125000005234 alkyl aluminium group Chemical group 0.000 abstract 1
229910052782 aluminium Inorganic materials 0.000 abstract 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
238000010533 azeotropic distillation Methods 0.000 abstract 1
229910052804 chromium Inorganic materials 0.000 abstract 1
239000011651 chromium Substances 0.000 abstract 1
229920001038 ethylene copolymer Polymers 0.000 abstract 1
239000000017 hydrogel Substances 0.000 abstract 1
229910052739 hydrogen Inorganic materials 0.000 abstract 1
239000001257 hydrogen Substances 0.000 abstract 1
125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
239000000155 melt Substances 0.000 abstract 1
150000002894 organic compounds Chemical class 0.000 abstract 1
150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
229920000573 polyethylene Polymers 0.000 abstract 1
229920000098 polyolefin Polymers 0.000 abstract 1
230000035945 sensitivity Effects 0.000 abstract 1
239000002002 slurry Substances 0.000 abstract 1
238000005406 washing Methods 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Catalysts (AREA)
Polymerization Catalysts (AREA)

AT83102992T 1982-03-30 1983-03-25 Katalytisches system und verfahren zur herstellung eines katalysators. ATE23864T1 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US06/363,681 US4424139A (en)	1982-03-30	1982-03-30	Catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound
EP83102992A EP0090374B2 (de)	1982-03-30	1983-03-25	Katalytisches System und Verfahren zur Herstellung eines Katalysators

Publications (1)

Publication Number	Publication Date
ATE23864T1 true ATE23864T1 (de)	1986-12-15

Family

ID=23431246

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AT83102992T ATE23864T1 (de)	1982-03-30	1983-03-25	Katalytisches system und verfahren zur herstellung eines katalysators.

Country Status (8)

Country	Link
US (1)	US4424139A (de)
EP (1)	EP0090374B2 (de)
JP (2)	JPS58208302A (de)
AT (1)	ATE23864T1 (de)
CA (1)	CA1197648A (de)
DE (1)	DE3367922D1 (de)
ES (1)	ES521093A0 (de)
SG (1)	SG58987G (de)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4659690A (en) *	1983-12-23	1987-04-21	Phillips Petroleum Company	Acid agglomeration of refractory gel in polar organic diluent
US4717701A (en) *	1985-01-04	1988-01-05	Phillips Petroleum Company	Olefin polymerization
US4622371A (en) *	1985-01-04	1986-11-11	Phillips Petroleum Company	Olefin polymerization
US5030431A (en) *	1985-08-29	1991-07-09	W. R. Grace & Co.-Conn.	High pore volume and pore diameter aluminum phosphate
US5292701A (en) *	1985-08-29	1994-03-08	W. R. Grace & Co.-Conn.	High pore volume and pore diameter aluminum phosphate and method of making the same
USRE34911E (en) *	1985-08-29	1995-04-18	W. R. Grace & Co.-Conn.	High pore volume and pore diameter aluminum phosphate
ATE72420T1 (de) *	1985-08-29	1992-02-15	Grace W R & Co	Aluminiumphosphat mit einem hohen porenvolumen.
DE3635710A1 (de) *	1986-10-21	1988-04-28	Basf Ag	Verfahren zum herstellen von homo- sowie copolymerisaten des ethens durch phillips-katalyse
US5010152A (en) *	1987-01-08	1991-04-23	Phillips Petroleum Company	Polymerization process utilizing chromium on an acid agglomerated refractory gel
US5153157A (en) †	1987-01-30	1992-10-06	Exxon Chemical Patents Inc.	Catalyst system of enhanced productivity
JPH0813860B2 (ja) *	1987-03-27	1996-02-14	出光興産株式会社	エチレン系共重合体の製造方法
EP0356692B1 (de) *	1988-07-29	1993-12-01	Idemitsu Kosan Company Limited	Verfahren zur Herstellung von Streckformteilen
US4910329A (en) *	1989-01-11	1990-03-20	Rohm And Haas Company	Process for preparing hydroxyalkyl esters
US5183868A (en) *	1990-07-23	1993-02-02	Phillips Petroleum Company	Olefin polymerization over pi-olefin complex of chromium supported on aluminophosphate
US5418200A (en) *	1991-03-29	1995-05-23	Chevron Chemical Company	Cyclopentadienyl group 6B metal α-olefin polymerization catalysts and process for polymerizing α-olefins
ATE153034T1 (de) *	1991-03-29	1997-05-15	Chevron Usa Inc	Cyclopentadienylgruppe enthaltende alpha-olefin- polymerisationskatalysatoren auf basis eines metals der 6b-gruppe und verfahren zur polymerisation von alpha-olefinen
US5552361A (en) *	1993-11-04	1996-09-03	W. R. Grace & Co.-Conn.	Aluminum phosphate composition with high pore volume and large pore diameter, process for its production and use thereof
DE4237145A1 (de) *	1992-11-04	1994-05-11	Grace Gmbh	Aluminiumphosphatzusammensetzung mit hohem Porenvolumen und großem Porendurchmesser, Verfahren zu deren Herstellung und deren Verwendung
US5240895A (en) *	1992-11-06	1993-08-31	Chevron Research And Technology Company	Dimeric and tetrameric cyclopentadienyl group 6B metal alpha-olefin polymerization catalysts and process for polymerizing alpha-olefins
DE4323192A1 (de) *	1993-07-10	1995-01-12	Basf Ag	Verfahren zur Herstellung von Homo- und Copolymerisaten von Alk-1-enen
US5576263A (en) *	1993-12-28	1996-11-19	Phillips Petroleum Company	Chromium catalyst compositions and ethylene polymerization processes therewith
US5543376A (en) *	1994-02-25	1996-08-06	Phillips Petroleum Company	Process for producing polyolefins
US5624877A (en) *	1994-02-25	1997-04-29	Phillips Petroleum Company	Process for producing polyolefins
US5637778A (en) *	1994-08-08	1997-06-10	Texaco Chemical Inc.	Isopropyl alcohol and diispropyl ether production from crude by-product acetone in one step
BE1009186A3 (fr) *	1995-03-13	1996-12-03	Solvay	Solide catalytique pour la (co)polymerisation d'ethylene, procede pour sa preparation, systeme catalytique pour la (co)polymerisation d'ethylene et procede de (co)polymerisation d'ethylene.
DE59606391D1 (de) *	1995-08-22	2001-03-01	Basf Ag	Polymerisate des ethylens mit hoher spannungsrissbeständigkeit und katalysatorsystem für deren herstellung
NO960350A (no)	1996-01-26	1997-04-28	Borealis As	Fremgangsmåte og katalysatorsystem for polymerisering av etylen, eventuelt sammen med <alfa>-olefiner, og fremstilt polymermateriale
US5869587A (en) *	1996-10-31	1999-02-09	Chevron Chemical Company	Process for the polymerization of alpha olefins using a new aluminophosphate support
US6022513A (en) *	1996-10-31	2000-02-08	Pecoraro; Theresa A.	Aluminophosphates and their method of preparation
KR20000070007A (ko)	1997-01-08	2000-11-25	마이클 비. 키한	탄화수소 수지 제조용 촉매로서의 고체 산
US6255413B1 (en)	1997-12-16	2001-07-03	Phillips Petroleum Company	Process to produce branched polymers from ethylene feedstock
DE19833858C2 (de)	1998-07-28	2000-06-08	Elenac Gmbh	Geruchsarme Polyethylen-Blends
CN1142190C (zh)	1998-08-26	2004-03-17	埃克森化学专利公司	高活性负载型催化剂组合物
US6153553A (en) *	1998-10-01	2000-11-28	Chevron Chemical Company	Process for the polymerization of alpha olefins using a new aluminophosphate support
US6548442B1 (en) *	1999-12-03	2003-04-15	Phillips Petroleum Company	Organometal compound catalyst
US6576583B1 (en) *	2000-02-11	2003-06-10	Phillips Petroleum Company	Organometal catalyst composition
US7429635B2 (en) *	2006-09-28	2008-09-30	Equistar Chemicals, Lp	Preparation of ultra high molecular weight linear low density polyethylene
US7638456B2 (en) *	2007-12-18	2009-12-29	Chevron Phillips Chemical Company Lp	Methods of preparing a polymerization catalyst
US8399580B2 (en)	2010-08-11	2013-03-19	Chevron Philips Chemical Company Lp	Additives to chromium catalyst mix tank

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2840551A (en) *	1955-08-18	1958-06-24	Standard Oil Co	Olefin polymerization with catalysts prepared from boron compounds and transition metal compounds
US3342750A (en)	1965-04-01	1967-09-19	Exxon Research Engineering Co	Compositions containing stable aluminum phosphate gel and methods of making and using same
US3453219A (en)	1966-12-19	1969-07-01	Universal Oil Prod Co	Petroleum crude oil hydrorefining catalyst
US3794628A (en)	1971-02-02	1974-02-26	Hercules Inc	Tris(bicycloheptyl)chromium compounds and use as polymerization catalysts
CA995396A (en) *	1971-03-18	1976-08-17	Robert N. Johnson	Catalyst modified with strong reducing agent and silane compounds and use in polymerization of olefins
US3709853A (en)	1971-04-29	1973-01-09	Union Carbide Corp	Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
US3757002A (en)	1971-09-24	1973-09-04	Union Carbide Corp	Pported diarene chromium compounds catalytic polymerization of olefins using cyclopentadiene modified su
US3806500A (en)	1972-07-21	1974-04-23	Union Carbide Corp	Polymerization with thermally aged catalyst
US3904550A (en) *	1973-10-19	1975-09-09	Exxon Research Engineering Co	Hydrocarbon conversion catalyst comprising alumina and aluminum phosphate
US4219444A (en)	1977-12-27	1980-08-26	Gulf Oil Corporation	Ethylene polymerization catalysts
US4289863A (en) *	1975-09-10	1981-09-15	Gulf Oil Corporation	Ethylene polymerization process
US4101445A (en)	1976-09-22	1978-07-18	Union Carbide Corporation	Preparation of modified and activated chromocene catalysts for ethylene polymerization
US4364840A (en)	1980-12-31	1982-12-21	Phillips Petroleum Company	Phosphated silica-chromium catalyst with boron-containing cocatalyst
US4364839A (en)	1980-12-31	1982-12-21	Phillips Petroleum Company	Catalyst comprising chromium on silica/phosphate support
US4364842A (en)	1980-12-31	1982-12-21	Phillips Petroleum Company	Phosphate supported chromium catalyst
US4364855A (en)	1980-12-31	1982-12-21	Phillips Petroleum Company	Production of aluminum phosphate from concentrated mass
US4364854A (en)	1980-12-31	1982-12-21	Phillips Petroleum Company	Acid gelling aluminum phosphate from concentrated mass and catalyst containing same
US4364841A (en)	1980-12-31	1982-12-21	Phillips Petroleum Company	Phosphate containing support with zerovalent chromium

1982
- 1982-03-30 US US06/363,681 patent/US4424139A/en not_active Expired - Lifetime
1983
- 1983-02-04 CA CA000420935A patent/CA1197648A/en not_active Expired
- 1983-03-25 AT AT83102992T patent/ATE23864T1/de not_active IP Right Cessation
- 1983-03-25 DE DE8383102992T patent/DE3367922D1/de not_active Expired
- 1983-03-25 EP EP83102992A patent/EP0090374B2/de not_active Expired - Lifetime
- 1983-03-29 ES ES521093A patent/ES521093A0/es active Granted
- 1983-03-30 JP JP58054974A patent/JPS58208302A/ja active Granted
1987
- 1987-07-21 SG SG589/87A patent/SG58987G/en unknown
1992
- 1992-03-10 JP JP4051830A patent/JPH0696612B2/ja not_active Expired - Lifetime

Also Published As

Publication number	Publication date
JPH0696612B2 (ja)	1994-11-30
US4424139A (en)	1984-01-03
DE3367922D1 (en)	1987-01-15
JPH055841B2 (de)	1993-01-25
CA1197648A (en)	1985-12-03
JPS58208302A (ja)	1983-12-05
SG58987G (en)	1987-10-23
JPH0578416A (ja)	1993-03-30
ES8502132A1 (es)	1984-12-16
EP0090374B2 (de)	1991-02-27
ES521093A0 (es)	1984-12-16
EP0090374B1 (de)	1986-11-26
EP0090374A1 (de)	1983-10-05

Legal Events

Date	Code	Title
1987-05-15	UEP	Publication of translation of european patent specification
1991-07-15	UEP	Publication of translation of european patent specification
1996-12-15	REN	Ceased due to non-payment of the annual fee

Publication	Publication Date	Title
ATE23864T1 (de)	1986-12-15	Katalytisches system und verfahren zur herstellung eines katalysators.
ES8304159A1 (es)	1983-03-01	Procedimiento para la obtencion de un catalizador para la polimerizacion de olefinas.
NO984568L (no)	1999-04-06	Bµrer for metallocenkatalysatorer, og fremgangsmÕte ved fremstilling av bµreren, samt katalysatorsystem og polymeriseringsfremgangsmÕte
ATE204884T1 (de)	2001-09-15	Verfahren zur herstellung von polyolefinkatalysatoren
DK0700403T3 (da)	1998-04-06	Fremgangsmåde til fremstilling af en katylasatorbærer, katylasator til polymerisation af olefiner ogfremgangsmåde til polymerisation af olefiner ved hjælp af denne katylasator
DE69532461D1 (de)	2004-02-26	Katalysatorsysteme und Verfahren zur Herstellung von Polyolefinen mit breiter Molekulargewichtverteilung
BR8603716A (pt)	1987-03-10	Processo para polimerizacao de alfa-olefinas
ATE89834T1 (de)	1993-06-15	Verfahren zur herstellung von ethylenpolymerisaten mittels eines vanadin enthaltenden ziegler-katalysatorsystems unter zerstoerung ueberschuessiger katalysatorreste.
DE69717614D1 (de)	2003-01-16	Polymerisation verfahren zur herstellung von polyolefin-elastomeren kationenerzeugender co-katalysator für die activierung von metallocen-katalysatorvorläufer, polyolefin-elastomeren mit einer einziger kombination von eigenschaften und daraus hergestellte produkten
DE69501971D1 (de)	1998-05-14	Ternäres Katalysatorsystem und Verfahren zur Herstellung von Polymeren von Diolefinen
KR850008175A (ko)	1985-12-13	촉매용 알루미나 처리법
DE69325603D1 (de)	1999-08-19	Verfahren zur Olefinpolymerisation in der Gasphase
ES484368A1 (es)	1980-05-16	Procedimiento de fabricacion de poliolefinas
ATE191723T1 (de)	2000-04-15	Verfahren zur gewinnung von polyolefinen mit breiter bimodularer oder multimodaler molekulargewichtsverteilung
HU910850D0 (en)	1991-09-30	Catalyst with carrier for polimerization of ethylene and for co-polymerization of ethylene with alpha-olefines as well as process for producing said catalyst
KR900009708A (ko)	1990-07-05	에틸렌 중합체의 분자량 분포를 조절하기 위한 촉매
ATE299153T1 (de)	2005-07-15	Verfahren zur polymerisierung von olefine
GB2090157B (en)	1984-06-27	Phosphated alumina or aluminum phosphate chromium-containing olefin polymerisation catalyst process for the preparation and use thereof
EP0101136A3 (de)	1984-09-26	Katalysator zur Polymerisation von Olefinen, Katalysatorkomponente davon und Verfahren zur Herstellung dieser Katalysatorkomponente
KR910011917A (ko)	1991-08-07	에틸렌 중합체의 분자량 분포를 조절하기 위한 촉매
FI905430L (fi)	1992-05-02	Foerfarande foer framstaellning av en fast prokatalysatorkomposition till ett katalysatorsystem avsett foer polymerisation av olefiner och en prokatalysatorkomposition framstaelld medelst foerfarandet.
WO2005063831A3 (en)	2005-12-08	Preparation of supported cocatalysts