ATE248199T1 - Blockiertes isocyanat aufweisende verbindungen und diese enthaltende zusammensetzungen - Google Patents
Blockiertes isocyanat aufweisende verbindungen und diese enthaltende zusammensetzungenInfo
- Publication number
- ATE248199T1 ATE248199T1 AT00968421T AT00968421T ATE248199T1 AT E248199 T1 ATE248199 T1 AT E248199T1 AT 00968421 T AT00968421 T AT 00968421T AT 00968421 T AT00968421 T AT 00968421T AT E248199 T1 ATE248199 T1 AT E248199T1
- Authority
- AT
- Austria
- Prior art keywords
- compositions
- isocyanate
- based compounds
- compound
- novel
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 7
- 239000012948 isocyanate Substances 0.000 title abstract 7
- 239000000203 mixture Substances 0.000 title abstract 7
- 150000002513 isocyanates Chemical class 0.000 title abstract 6
- 239000008199 coating composition Substances 0.000 abstract 4
- 239000000843 powder Substances 0.000 abstract 3
- 239000000853 adhesive Substances 0.000 abstract 2
- 230000001070 adhesive effect Effects 0.000 abstract 2
- 150000001491 aromatic compounds Chemical class 0.000 abstract 2
- 239000006260 foam Substances 0.000 abstract 2
- -1 isocyanate compound Chemical class 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 239000004033 plastic Substances 0.000 abstract 2
- 229920003023 plastic Polymers 0.000 abstract 2
- 238000007581 slurry coating method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
- C08G18/4615—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen containing nitrogen
- C08G18/4638—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen containing nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
- C08G18/4661—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen containing nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing three nitrogen atoms in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
- C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
- C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
- C08G18/8012—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with diols
- C08G18/8016—Masked aliphatic or cycloaliphatic polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/8064—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds
- C08G18/8067—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds phenolic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2150/00—Compositions for coatings
- C08G2150/20—Compositions for powder coatings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/431,787 US6288199B1 (en) | 1999-11-02 | 1999-11-02 | Blocked isocyanate-based compounds and compositions containing the same |
| PCT/US2000/026479 WO2001032737A1 (en) | 1999-11-02 | 2000-09-27 | Blocked isocyanate-based compounds and compositions containing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE248199T1 true ATE248199T1 (de) | 2003-09-15 |
Family
ID=23713419
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT00968421T ATE248199T1 (de) | 1999-11-02 | 2000-09-28 | Blockiertes isocyanat aufweisende verbindungen und diese enthaltende zusammensetzungen |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6288199B1 (de) |
| EP (1) | EP1226199B1 (de) |
| AT (1) | ATE248199T1 (de) |
| AU (1) | AU7833800A (de) |
| BR (1) | BR0015217A (de) |
| CA (1) | CA2387783A1 (de) |
| DE (1) | DE60004872T2 (de) |
| ES (1) | ES2204703T3 (de) |
| PT (1) | PT1226199E (de) |
| WO (1) | WO2001032737A1 (de) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ513289A (en) * | 1998-12-22 | 2003-04-29 | Pfizer Prod Inc | Infectious cDNA clone of north american procine reproductive and respiratory syndrome (PRRS) virus and uses thereof |
| US6958155B2 (en) | 2002-06-12 | 2005-10-25 | L'oreal | Cosmetic compositions comprising at least one polysiloxane based polyamide |
| DE10328064A1 (de) * | 2003-06-23 | 2005-01-13 | Bayer Materialscience Ag | Blockierte Polyisocyanate |
| US20050230027A1 (en) * | 2004-04-15 | 2005-10-20 | L&L Products, Inc. | Activatable material and method of forming and using same |
| US7758848B2 (en) | 2004-10-22 | 2010-07-20 | L'oreal | Cosmetic composition containing a polyorganosiloxane polymer |
| EP1661549A1 (de) | 2004-11-04 | 2006-05-31 | L'oreal | Kosmetische Zusammensetzungen und Verwendungsmethoden |
| JP2006274002A (ja) * | 2005-03-29 | 2006-10-12 | Dainippon Ink & Chem Inc | 接着剤用樹脂粒子水分散体 |
| US9180321B2 (en) | 2005-07-13 | 2015-11-10 | L'oreal S.A. | Cosmetic compositions containing liposoluble polymers and tackifiers |
| US7884158B2 (en) | 2005-09-06 | 2011-02-08 | L'Oré´al | Cosmetic compositions containing block copolymers, tackifiers and phenylated silicones |
| US8313735B2 (en) | 2006-10-30 | 2012-11-20 | Oreal | Long-wearing cosmetic product system for providing extended shine and gloss |
| MX2007016506A (es) | 2006-12-29 | 2008-10-28 | Oreal | Composicion que contiene un polimero de poliorganosiloxano un agente espesante y al menos un alcohol volatil. |
| US8658141B2 (en) | 2007-01-12 | 2014-02-25 | L'oreal | Cosmetic composition containing a block copolymer, a tackifier, a silsesquioxane wax and/or resin |
| US8652451B2 (en) | 2009-06-29 | 2014-02-18 | L'oreal | Composition comprising a sugar silicone surfactant and a oil-soluble polar modified polymer |
| US8551465B2 (en) | 2009-06-29 | 2013-10-08 | L' Oréal | Composition comprising a polyol and a oil-soluble polar modified polymer |
| US9005590B2 (en) | 2009-06-29 | 2015-04-14 | L'oréal | Composition comprising a polyol, a sugar silicone surfctant and a oil-soluble high carbon polar modified polymer |
| EP2269569A3 (de) | 2009-06-29 | 2014-04-23 | L'oreal S.A. | Zusammensetzung aus Polyol und einem Reaktionsprodukt |
| EP2322139A3 (de) | 2009-06-29 | 2014-03-26 | L'oreal S.A. | Zusammensetzung mit einem Polyol und einem öllöslichen polarmodifizierten Polymer mit hohem Kohlenstoffanteil |
| BRPI1002597A2 (pt) | 2009-06-29 | 2012-03-13 | L'oreal S.A. | Composição que compreende pelo menos um polímero polar modificado solúvel em óleo |
| EP2305211A3 (de) | 2009-06-29 | 2011-04-13 | L'oreal S.A. | Zusammensetzung mit einem Zucker-Silikon-Tensid und einem öllöslichen polarmodifizierten Polymer mit hohen Kohlenstoffanteil |
| EP2359805A1 (de) | 2009-12-18 | 2011-08-24 | L'oreal S.A. | Zusammensetzung enthaltend eine wässrige Dispersion von Polyurethan und ein öllösliches, polar modifiziertes Polymer |
| ES2728959T3 (es) | 2009-12-18 | 2019-10-29 | Oreal | Máscara de pestañas que contiene una dispersión acuosa de poliuretano y una cera dura |
| EP2359806A1 (de) | 2009-12-18 | 2011-08-24 | L'oreal S.A. | Zusammensetzung mit einer wässrigen Dispersion aus Polyurethan und einem öllöslichen, polar modifizierten Polymer |
| US8747868B2 (en) | 2010-12-30 | 2014-06-10 | L'oreal | Reaction product of a polar modified polymer and an alkoxysilane and a composition containing the reaction product |
| US20140193354A1 (en) | 2011-09-30 | 2014-07-10 | L'oreal | Water-in-oil-in-water emulsions |
| US9789055B2 (en) | 2014-06-18 | 2017-10-17 | L'oreal | Solid lipstick composition having improved hardness |
| US10272027B2 (en) | 2014-06-18 | 2019-04-30 | L'oreal | Lipstick composition having improved comfort |
| EP3233048A4 (de) | 2014-12-18 | 2018-09-12 | L'oreal | Zusammensetzungen und verfahren zur verbesserung der erscheinung der haut |
| JP7066312B2 (ja) | 2015-12-21 | 2022-05-13 | ロレアル | グロー及びモイスチャー感をもたらす組成物 |
| US10292922B2 (en) | 2015-12-31 | 2019-05-21 | L'oreal | Silicone-wax dispersion compositions for removing cosmetic films |
| US10835479B2 (en) | 2015-12-31 | 2020-11-17 | L'oreal | Systems and methods for improving the appearance of the skin |
| BR112018013452A2 (pt) | 2015-12-31 | 2019-02-12 | Oreal | composições contendo policarbodiimidas e polímeros de látex para tratamento de substratos queratinosos |
| WO2018222794A1 (en) | 2017-05-31 | 2018-12-06 | L'oreal | Volumizing and lengthening compositions and applicators therefor |
| US10952954B2 (en) | 2017-09-29 | 2021-03-23 | L'oreal | Cosmetic compositions capable of forming a multilayer structure after application to a keratinous material |
| US10881601B2 (en) | 2017-09-29 | 2021-01-05 | L'oreal | Cosmetic compositions capable of forming a multilayer structure after application to a keratinous material |
| WO2021021978A1 (en) | 2019-07-31 | 2021-02-04 | L'oreal | Compositions containing copolymer of vinylpyrrolidone and acrylic acid and film forming agent |
| WO2021165122A1 (en) * | 2020-02-20 | 2021-08-26 | Basf Se | Hyperbranched polyester polyols suitable for use in organic solvent-based two-component polyurethane coating compositions |
| FR3113588B1 (fr) | 2020-08-28 | 2023-06-09 | Oreal | Emulsions eau dans huile contenant un tensioactif a faible hlb, une gomme de silicone et une resine de siloxysilicate |
| WO2021222764A1 (en) | 2020-04-30 | 2021-11-04 | L'oreal | Water-in-oil emulsions containing surfactant, silicone gum and/or latex, and siloxysilicate resin |
| FR3125413B1 (fr) | 2021-07-22 | 2025-12-26 | Oreal | Compositions cosmétiques pour les cheveux |
| EP4701620A1 (de) | 2023-04-28 | 2026-03-04 | L'oreal | Langanhaltende zusammensetzungen mit silikonacrylatcopolymer und glyceriniertem silikonharz |
| FR3151496B3 (fr) | 2023-07-26 | 2025-08-15 | Oreal | Compositions longue tenue contenant du copolymère d’acrylate de silicone et de la résine de silicone glycérolée |
| WO2025096502A1 (en) | 2023-10-31 | 2025-05-08 | L'oreal | Long-wear compositions containing silicone acrylate copolymer and t-modified silicone resin |
| US12703794B2 (en) | 2023-10-31 | 2026-08-11 | L'oreal | Long-wear compositions containing silicone acrylate copolymer and T-modified silicone resin |
| FR3158231B3 (fr) | 2024-01-12 | 2026-02-13 | Oreal | Compositions longue tenue contenant un copolymère d’acrylate de silicone et une résine de silicone t-modifiée |
| FR3160580B3 (fr) | 2024-04-02 | 2026-04-17 | Oreal | Compositions incluant un polymère organosilicone et un filmogène en phase aqueuse |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4994729A (de) * | 1972-11-30 | 1974-09-09 | ||
| US4000214A (en) | 1973-05-29 | 1976-12-28 | Reichhold Chemicals, Inc. | Urethane additive to a standard epoxy resin to improve adhesion to vinyl materials |
| CH588513A5 (de) | 1973-12-19 | 1977-06-15 | Ciba Geigy Ag | |
| CH586243A5 (de) | 1973-12-19 | 1977-03-31 | Ciba Geigy Ag | |
| JPS5830346B2 (ja) | 1974-04-04 | 1983-06-28 | ニツポンエステル カブシキガイシヤ | フンタイトリヨウヨウ ソセイブツ |
| US4755623A (en) | 1983-09-06 | 1988-07-05 | American Cyanamid Company | Polyfunctional amine crosslinker, process for making same, and compositions containing same |
| US4578453A (en) | 1984-11-23 | 1986-03-25 | Eastman Kodak Company | High molecular weight polyesters |
| US4554343A (en) | 1984-11-23 | 1985-11-19 | Eastman Kodak Company | Process for the production of high molecular weight polyester |
| CA1336521C (en) * | 1985-08-19 | 1995-08-01 | Satoru Sugino | Plastisol composition and undercoating material |
| US5097006A (en) | 1990-11-21 | 1992-03-17 | U C B S.A. | Weatherable powder coating compositions |
| NL9101275A (nl) | 1991-07-22 | 1993-02-16 | Dsm Nv | Polyesters toepasbaar in buitenduurzame coatingsystemen. |
| US5262494A (en) | 1991-12-23 | 1993-11-16 | Morton Coatings, Inc. | Hard, flexible, and durable architectural coating |
| US5786437A (en) * | 1993-04-08 | 1998-07-28 | Tremco Incorporated | One-step sealant based on electronegatively substituted phenolic blocking agents and aliphatic isocyanates providing fast cures and improved stability |
| FR2719594A1 (fr) | 1994-05-04 | 1995-11-10 | Rhone Poulenc Chimie | Isocyanates masqués au moyen de composés hydroxyaromatiques. |
| US6103826A (en) * | 1995-04-19 | 2000-08-15 | Eastern Michigan University | Clearcoat compositions containing phenolic ester compounds |
| US6051674A (en) * | 1996-08-26 | 2000-04-18 | Exxon Chemical Patents, Inc. | Polymeric vehicles which include a phenol blocked isocyanate having aliphatic hydroxyl fucntionality |
| US5777061A (en) * | 1996-02-14 | 1998-07-07 | Bayer Corporation | Blocked polyisocyanate crosslinkers for providing improved flow properties to coating compositions |
| JP3943162B2 (ja) * | 1996-02-28 | 2007-07-11 | 旭化成ケミカルズ株式会社 | 接着性付与剤組成物及びそれを含有するプラスチゾル組成物 |
| EP0822210A1 (de) | 1996-07-30 | 1998-02-04 | Rhone-Poulenc Chimie | Zusammensetzung für die Herstellung einer Matten oder seidigen Beschichtung, Verwendung dieser Zusammensetzung sowie daraus hergestellte Beschichtung |
| US5925698A (en) | 1997-03-14 | 1999-07-20 | The Lubrizol Corporation | Powder coating composition and method for coating a substrate using said powder coating composition |
| JPH1157615A (ja) | 1997-08-26 | 1999-03-02 | Kansai Paint Co Ltd | 塗膜形成方法 |
| EP0985607A1 (de) | 1998-07-28 | 2000-03-15 | Guala Closures S.P.A. | Sicherheitsverschluss |
-
1999
- 1999-11-02 US US09/431,787 patent/US6288199B1/en not_active Expired - Lifetime
-
2000
- 2000-09-27 WO PCT/US2000/026479 patent/WO2001032737A1/en not_active Ceased
- 2000-09-27 BR BR0015217-0A patent/BR0015217A/pt not_active Application Discontinuation
- 2000-09-28 CA CA002387783A patent/CA2387783A1/en not_active Abandoned
- 2000-09-28 AU AU78338/00A patent/AU7833800A/en not_active Abandoned
- 2000-09-28 AT AT00968421T patent/ATE248199T1/de not_active IP Right Cessation
- 2000-09-28 DE DE60004872T patent/DE60004872T2/de not_active Expired - Fee Related
- 2000-09-28 EP EP00968421A patent/EP1226199B1/de not_active Expired - Lifetime
- 2000-09-28 PT PT00968421T patent/PT1226199E/pt unknown
- 2000-09-28 ES ES00968421T patent/ES2204703T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1226199A1 (de) | 2002-07-31 |
| BR0015217A (pt) | 2002-06-18 |
| WO2001032737A1 (en) | 2001-05-10 |
| DE60004872T2 (de) | 2004-06-09 |
| AU7833800A (en) | 2001-05-14 |
| WO2001032737A8 (en) | 2005-11-24 |
| DE60004872D1 (de) | 2003-10-02 |
| ES2204703T3 (es) | 2004-05-01 |
| PT1226199E (pt) | 2003-12-31 |
| US6288199B1 (en) | 2001-09-11 |
| CA2387783A1 (en) | 2001-05-10 |
| EP1226199B1 (de) | 2003-08-27 |
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