ATE26110T1 - TRIS-(DIALKYLAMINO)-SULFONIUM BIFLUORIDE CATALYSTS. - Google Patents

TRIS-(DIALKYLAMINO)-SULFONIUM BIFLUORIDE CATALYSTS.

Info

Publication number
ATE26110T1
ATE26110T1 AT84302261T AT84302261T ATE26110T1 AT E26110 T1 ATE26110 T1 AT E26110T1 AT 84302261 T AT84302261 T AT 84302261T AT 84302261 T AT84302261 T AT 84302261T AT E26110 T1 ATE26110 T1 AT E26110T1
Authority
AT
Austria
Prior art keywords
dialkylamino
tris
sulfonium
sulfonium bifluoride
catalysts
Prior art date
Application number
AT84302261T
Other languages
German (de)
Inventor
William Brown Farnham
William Joseph Middleton
Dotsevi Yao Sogah
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Application granted granted Critical
Publication of ATE26110T1 publication Critical patent/ATE26110T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerization Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)
  • Exhaust Gas After Treatment (AREA)

Abstract

Tris(dialkylamino)sulfonium bifluoride salts are obtained by hydrolysis, methanolysis, or pyrolysis of corresponding tris(dialkylamino)sulfonium difluorotrimethylsilicates, reaction of dialkylaminotrialkylsilanes with sulfur tetrafluoride, or reaction of bis(dialkylamino)sulfur difluorides with dialkylamines. These bifluoride salts, which have the general formula (R1R2N)(R3R4N)(R5R6N)S(+)HF2(-), are useful polymerization catalysts.
AT84302261T 1983-04-04 1984-04-03 TRIS-(DIALKYLAMINO)-SULFONIUM BIFLUORIDE CATALYSTS. ATE26110T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/481,927 US4598161A (en) 1983-04-04 1983-04-04 Tris(dialkylamino)sulfonium bifluoride catalysts
EP84302261A EP0121439B1 (en) 1983-04-04 1984-04-03 Tris(dialkylamino)sulfonium bifluoride catalysts

Publications (1)

Publication Number Publication Date
ATE26110T1 true ATE26110T1 (en) 1987-04-15

Family

ID=23913945

Family Applications (1)

Application Number Title Priority Date Filing Date
AT84302261T ATE26110T1 (en) 1983-04-04 1984-04-03 TRIS-(DIALKYLAMINO)-SULFONIUM BIFLUORIDE CATALYSTS.

Country Status (6)

Country Link
US (1) US4598161A (en)
EP (1) EP0121439B1 (en)
JP (1) JPS59184157A (en)
AT (1) ATE26110T1 (en)
CA (1) CA1256440A (en)
DE (1) DE3462793D1 (en)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4681918A (en) * 1981-06-30 1987-07-21 E. I. Du Pont De Nemours And Company "Living" polymers and process for their preparation
US5260424A (en) * 1986-05-29 1993-11-09 E. I. Du Pont De Nemours And Company B-(keto or sulfonyl) esters from reaction of silylketene acetal and acyl or sulfonyl compound
US4983679A (en) * 1986-05-29 1991-01-08 E. I. Dupont De Nemours And Company β-(keto or sulfonyl)esters from reaction of silylketene acetal and acyl or sulfonyl compound
US5110869A (en) * 1986-05-29 1992-05-05 E. I. Du Pont De Nemours And Company β-(keto or sulfonyl)esters from reaction of silyketene acetal and acyl or sulfonyl compound
US4806605A (en) * 1987-01-27 1989-02-21 E. I. Du Pont De Nemours And Company Monomers and initiators for group transfer polymerization
US4771116A (en) * 1987-04-30 1988-09-13 E. I. Du Pont De Nemours And Company Silylamines as additives in group transfer polymerization
US4771117A (en) * 1987-04-30 1988-09-13 E. I. Du Pont De Nemours And Company Polymerization of acrylic esters
US4845156A (en) * 1987-12-21 1989-07-04 E. I. Du Pont De Nemours And Company Preparation of macromonomers
US5019634A (en) * 1988-02-16 1991-05-28 E. I. Du Pont De Nemours And Company Group transfer living polymer grafted to an initiator support
US4866145A (en) * 1988-04-01 1989-09-12 E. I. Du Pont De Nemours And Company Catalyst for group transfer polymerization
US4943648A (en) * 1988-04-01 1990-07-24 E. I. Du Pont De Nemours And Company Initiators for group transfer polymerization
US5021524A (en) * 1988-04-14 1991-06-04 E. I. Du Pont De Nemours And Company Initiator for group transfer polymerization
US4939211A (en) * 1989-03-01 1990-07-03 E. I. Du Pont De Nemours And Company Phosphonate-capped polymers
US4978723A (en) * 1989-03-01 1990-12-18 E. I. Du Pont De Nemours And Company Phosphonate-capped polymers
US6943203B2 (en) * 1998-03-02 2005-09-13 Johnson & Johnson Vision Care, Inc. Soft contact lenses
US9180321B2 (en) * 2005-07-13 2015-11-10 L'oreal S.A. Cosmetic compositions containing liposoluble polymers and tackifiers
US7884158B2 (en) * 2005-09-06 2011-02-08 L'Oré´al Cosmetic compositions containing block copolymers, tackifiers and phenylated silicones
CN107406466B (en) * 2015-03-24 2021-05-11 捷恩智株式会社 Production method of dialkylaminosilane
ES2887584T3 (en) * 2015-06-22 2021-12-23 Scripps Research Inst Polymerization of silyl and fluoro containing monomers
EP3548465A4 (en) 2016-11-29 2020-06-17 The Scripps Research Institute MODIFIED THIONYL TETRAFLUORIDE COMPOUNDS AND USES THEREOF
CN107344949A (en) * 2017-06-26 2017-11-14 江苏南大光电材料股份有限公司 High-purity N, the synthetic method of N dimethyl trimethyl silicane amine

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3121112A (en) * 1959-09-29 1964-02-11 Du Pont N-trifluoromethyl amino-sulfur compounds
US3577459A (en) * 1968-05-20 1971-05-04 Procter & Gamble N-alkyl and n,n-dialkyl alkanesulfonamide bis(alkylimines)and n-alkyl and n,n-dialkyl alkylimines and processes for preparing same
US3636103A (en) * 1969-12-29 1972-01-18 Procter & Gamble Tetraalkyl sulfoximinium salts as cationic bactericides
US3940402A (en) * 1974-09-19 1976-02-24 E. I. Dupont De Nemours And Company Tris(substituted amino) sulfonium salts
US4417034A (en) * 1981-06-30 1983-11-22 E. I. Du Pont De Nemours & Co. Living polymers and process for their preparation

Also Published As

Publication number Publication date
DE3462793D1 (en) 1987-04-30
EP0121439A1 (en) 1984-10-10
EP0121439B1 (en) 1987-03-25
US4598161A (en) 1986-07-01
JPS59184157A (en) 1984-10-19
CA1256440A (en) 1989-06-27

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Legal Events

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UEP Publication of translation of european patent specification
REN Ceased due to non-payment of the annual fee