ATE270584T1 - Verfahren zur gewinnung von synthesegas mittels eines nickel- und rhodiumhaltiger katalysators - Google Patents
Verfahren zur gewinnung von synthesegas mittels eines nickel- und rhodiumhaltiger katalysatorsInfo
- Publication number
- ATE270584T1 ATE270584T1 AT00972221T AT00972221T ATE270584T1 AT E270584 T1 ATE270584 T1 AT E270584T1 AT 00972221 T AT00972221 T AT 00972221T AT 00972221 T AT00972221 T AT 00972221T AT E270584 T1 ATE270584 T1 AT E270584T1
- Authority
- AT
- Austria
- Prior art keywords
- rhodium
- synthesis gas
- nickel
- catalyst containing
- containing nickel
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/892—Nickel and noble metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8986—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with manganese, technetium or rhenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/464—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1023—Catalysts in the form of a monolith or honeycomb
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1029—Catalysts in the form of a foam
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16010099P | 1999-10-18 | 1999-10-18 | |
| US09/687,684 US6409940B1 (en) | 1999-10-18 | 2000-10-13 | Nickel-rhodium based catalysts and process for preparing synthesis gas |
| PCT/US2000/028648 WO2001028678A1 (en) | 1999-10-18 | 2000-10-16 | Nickel-rhodium based catalysts and process for preparing synthesis gas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE270584T1 true ATE270584T1 (de) | 2004-07-15 |
Family
ID=26856601
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT00972221T ATE270584T1 (de) | 1999-10-18 | 2000-10-16 | Verfahren zur gewinnung von synthesegas mittels eines nickel- und rhodiumhaltiger katalysators |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US6409940B1 (de) |
| EP (1) | EP1222024B1 (de) |
| AT (1) | ATE270584T1 (de) |
| AU (1) | AU767267B2 (de) |
| CA (1) | CA2387883A1 (de) |
| DE (1) | DE60012036D1 (de) |
| DK (1) | DK1222024T3 (de) |
| WO (1) | WO2001028678A1 (de) |
Families Citing this family (86)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6579510B2 (en) * | 1999-07-30 | 2003-06-17 | Alfred E. Keller | SPOX-enhanced process for production of synthesis gas |
| US7122170B2 (en) * | 2000-07-25 | 2006-10-17 | Conocophillips Company | Catalysts for SPOC™ enhanced synthesis gas production |
| US7357908B2 (en) * | 2000-12-18 | 2008-04-15 | Conocophillips Company | Apparatus and catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream |
| US7326397B2 (en) * | 2000-12-18 | 2008-02-05 | Conocophillips Company | Catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream |
| WO2002066403A1 (en) * | 2001-02-16 | 2002-08-29 | Conoco Inc. | Supported rhodium-spinel catalysts and process for producing synthesis gas |
| US20020179887A1 (en) * | 2001-05-01 | 2002-12-05 | Yongxian Zeng | Supported perovskite-type oxides and methods for preparation thereof |
| FR2826293B1 (fr) * | 2001-06-21 | 2004-01-30 | Elf Antar France | Procede d'obtention de gaz de synthese par oxydation catalytique partielle |
| US6855272B2 (en) * | 2001-07-18 | 2005-02-15 | Kellogg Brown & Root, Inc. | Low pressure drop reforming exchanger |
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| WO2003072492A1 (en) * | 2002-02-22 | 2003-09-04 | Conoco Inc. | Promoted nickel-magnesium oxide catalysts and process for producing synthesis gas |
| US20030162846A1 (en) * | 2002-02-25 | 2003-08-28 | Wang Shoou-L | Process and apparatus for the production of synthesis gas |
| US20040052725A1 (en) * | 2002-06-28 | 2004-03-18 | Conocophillips Company | Oxidized metal catalysts and process for producing synthesis gas |
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| CA2504206A1 (en) * | 2002-11-11 | 2004-05-27 | Conocophillips Company | Stabilized alumina supports, catalysts made therefrom, and their use in partial oxidation |
| EP1419814A1 (de) * | 2002-11-15 | 2004-05-19 | L'AIR LIQUIDE, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des | Perovskit-Katalysator für die partielle Oxidation von Erdgas |
| US6872753B2 (en) * | 2002-11-25 | 2005-03-29 | Conocophillips Company | Managing hydrogen and carbon monoxide in a gas to liquid plant to control the H2/CO ratio in the Fischer-Tropsch reactor feed |
| US7041621B2 (en) | 2003-01-17 | 2006-05-09 | Conocophillips Company | Sulfided catalysts for improved performance in hydrocarbon processing |
| US7008560B2 (en) * | 2003-02-10 | 2006-03-07 | Conocophillips Company | Silicon carbide-supported catalysts for partial oxidation of natural gas to synthesis gas |
| US20040171900A1 (en) * | 2003-02-28 | 2004-09-02 | Conocophillips Company | Method and device for reactions start-up |
| US6958363B2 (en) * | 2003-03-15 | 2005-10-25 | Conocophillips Company | Hydrogen use in a GTL plant |
| US6946493B2 (en) * | 2003-03-15 | 2005-09-20 | Conocophillips Company | Managing hydrogen in a gas to liquid plant |
| US7057081B2 (en) * | 2003-05-09 | 2006-06-06 | Conocophillips Company | Method for treating alkanes |
| US20040225164A1 (en) * | 2003-05-09 | 2004-11-11 | Conocophillips Company | Method for treating ethane |
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| US6938439B2 (en) * | 2003-05-22 | 2005-09-06 | Cool Clean Technologies, Inc. | System for use of land fills and recyclable materials |
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| US7585810B2 (en) * | 2004-09-01 | 2009-09-08 | Umicore Ag & Co. Kg | Method for partial oxidation of hydrocarbons, catalyst member therefor and method of manufacture |
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| US6974842B1 (en) | 2004-11-22 | 2005-12-13 | Conocophillips Company | Process for catalyst recovery from a slurry containing residual hydrocarbons |
| FR2879185B1 (fr) * | 2004-12-10 | 2007-03-09 | Air Liquide | Reacteur catalytique membranaire |
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| US7915196B2 (en) * | 2005-10-07 | 2011-03-29 | Alliance For Sustainable Energy, Llc | Attrition resistant fluidizable reforming catalyst |
| US20070111884A1 (en) * | 2005-11-14 | 2007-05-17 | Laiyuan Chen | Catalyst support, supported catalyst, and methods of making and using the same |
| US7226572B1 (en) * | 2006-03-03 | 2007-06-05 | Conocophillips Company | Compact sulfur recovery plant and process |
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| US7501111B2 (en) | 2006-08-25 | 2009-03-10 | Conoco Phillips Company | Increased capacity sulfur recovery plant and process for recovering elemental sulfur |
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| KR100892033B1 (ko) | 2007-10-08 | 2009-04-07 | 한국에너지기술연구원 | 고표면적 스핀넬 구조의 나노크기 결정을 가지는yMgO(1-y)Al₂O₃에 나노크기로 담지된 니켈계개질촉매 및 이를 이용한 수증기-이산화탄소 복합개질에의한 천연가스로부터 합성가스의 제조방법 |
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| US8658559B2 (en) | 2010-03-08 | 2014-02-25 | National University Of Singapore | Implantation of Ni nano domains in refractory metal oxide support by means of sol-gel encapsulation—an effective solution to coke formation in the partial oxidation of natural gas |
| MX2012010596A (es) * | 2010-03-19 | 2012-10-03 | Topsoe Haldor As | Catalizador de reformado. |
| IT1400492B1 (it) | 2010-06-03 | 2013-06-11 | Eni Spa | Sistema catalitico per processi di ossidazione parziale catalitica a basso tempo di contatto |
| RU2453366C1 (ru) * | 2010-11-29 | 2012-06-20 | Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН | Катализатор и способ получения синтез-газа |
| WO2012154172A1 (en) * | 2011-05-10 | 2012-11-15 | Utc Power Corporation | Core-shell catalyst for natural gas reforming |
| JPWO2013125690A1 (ja) * | 2012-02-22 | 2015-07-30 | 三菱重工業株式会社 | カーボンナノチューブ生成用触媒 |
| CN103801299B (zh) * | 2012-11-07 | 2015-09-30 | 中国石油化工股份有限公司 | 一种甲烷部分氧化制合成气催化剂的制备方法 |
| KR101480801B1 (ko) * | 2013-05-08 | 2015-01-12 | 한국화학연구원 | 이산화탄소 개질반응용 모노리스 촉매, 이의 제조방법 및 이를 이용한 합성가스의 제조방법 |
| EP2994227A2 (de) | 2013-05-09 | 2016-03-16 | SABIC Global Technologies B.V. | Tonmineralgeträgerte katalysatoren |
| EP2994226A2 (de) * | 2013-05-09 | 2016-03-16 | SABIC Global Technologies B.V. | Erdalkalimetall-/metalloxidgeträgerte katalysatoren |
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-
2000
- 2000-10-13 US US09/687,684 patent/US6409940B1/en not_active Expired - Fee Related
- 2000-10-16 DK DK00972221T patent/DK1222024T3/da active
- 2000-10-16 AT AT00972221T patent/ATE270584T1/de not_active IP Right Cessation
- 2000-10-16 WO PCT/US2000/028648 patent/WO2001028678A1/en not_active Ceased
- 2000-10-16 AU AU10916/01A patent/AU767267B2/en not_active Ceased
- 2000-10-16 DE DE60012036T patent/DE60012036D1/de not_active Expired - Lifetime
- 2000-10-16 EP EP00972221A patent/EP1222024B1/de not_active Expired - Lifetime
- 2000-10-16 CA CA002387883A patent/CA2387883A1/en not_active Abandoned
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2002
- 2002-04-18 US US10/125,717 patent/US6878667B2/en not_active Expired - Fee Related
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|---|---|
| US6878667B2 (en) | 2005-04-12 |
| US20020177628A1 (en) | 2002-11-28 |
| DE60012036D1 (de) | 2004-08-12 |
| CA2387883A1 (en) | 2001-04-26 |
| EP1222024A1 (de) | 2002-07-17 |
| DK1222024T3 (da) | 2004-10-18 |
| EP1222024B1 (de) | 2004-07-07 |
| WO2001028678A1 (en) | 2001-04-26 |
| AU1091601A (en) | 2001-04-30 |
| AU767267B2 (en) | 2003-11-06 |
| US6409940B1 (en) | 2002-06-25 |
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