ATE281500T1 - Selbstabsetzender klebstoff - Google Patents

Selbstabsetzender klebstoff

Info

Publication number: ATE281500T1
Authority: AT; Austria
Prior art keywords: adhesive; covercoat; bonding; modifying agent; phenolic resin
Prior art date: 1999-01-22

Application number

AT00906970T

Other languages

English (en)

Inventor

Helmut W Kucera

Douglas H Mowrey

Rebecca S Cowles

Original Assignee

Lord Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-01-22

Filing date

2000-01-20

Publication date

2004-11-15

2000-01-20 Application filed by Lord Corp filed Critical Lord Corp

2004-11-15 Application granted granted Critical

2004-11-15 Publication of ATE281500T1 publication Critical patent/ATE281500T1/de

Links

239000000853 adhesive Substances 0.000 title abstract 6
230000001070 adhesive effect Effects 0.000 title abstract 6
239000000758 substrate Substances 0.000 abstract 4
KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 3
239000003795 chemical substances by application Substances 0.000 abstract 3
229920001568 phenolic resin Polymers 0.000 abstract 3
239000005011 phenolic resin Substances 0.000 abstract 3
239000002243 precursor Substances 0.000 abstract 2
239000004971 Cross linker Substances 0.000 abstract 1
239000002253 acid Substances 0.000 abstract 1
239000007795 chemical reaction product Substances 0.000 abstract 1
239000006185 dispersion Substances 0.000 abstract 1
229920001971 elastomer Polymers 0.000 abstract 1
239000000806 elastomer Substances 0.000 abstract 1
239000004816 latex Substances 0.000 abstract 1
229920000126 latex Polymers 0.000 abstract 1
229910052751 metal Inorganic materials 0.000 abstract 1
239000002184 metal Substances 0.000 abstract 1
150000001455 metallic ions Chemical class 0.000 abstract 1
150000002739 metals Chemical class 0.000 abstract 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
- C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
- C08J5/127—Aqueous adhesives
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/088—Autophoretic paints
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/02—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving pretreatment of the surfaces to be joined
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/10—Presence of inorganic materials
- C09J2400/16—Metal
- C09J2400/163—Metal in the substrate
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/10—Presence of inorganic materials
- C09J2400/16—Metal
- C09J2400/166—Metal in the pretreated surface to be joined
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2421/00—Presence of unspecified rubber
- C09J2421/006—Presence of unspecified rubber in the substrate
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2461/00—Presence of condensation polymers of aldehydes or ketones
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2463/00—Presence of epoxy resin
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
- Y10T428/31696—Including polyene monomers [e.g., butadiene, etc.]
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
- Y10T428/31699—Ester, halide or nitrile of addition polymer

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Engineering & Computer Science (AREA)
Health & Medical Sciences (AREA)
Manufacturing & Machinery (AREA)
Inorganic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Life Sciences & Earth Sciences (AREA)
Wood Science & Technology (AREA)
Adhesives Or Adhesive Processes (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Laminated Bodies (AREA)

AT00906970T 1999-01-22 2000-01-20 Selbstabsetzender klebstoff ATE281500T1 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US11676799P	1999-01-22	1999-01-22
PCT/US2000/001417 WO2000043131A2 (en)	1999-01-22	2000-01-20	Autodepositable adhesive

Publications (1)

Publication Number	Publication Date
ATE281500T1 true ATE281500T1 (de)	2004-11-15

Family

ID=22369081

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AT00906970T ATE281500T1 (de)	1999-01-22	2000-01-20	Selbstabsetzender klebstoff

Country Status (10)

Country	Link
US (2)	US6521687B2 (de)
EP (1)	EP1144535B1 (de)
JP (1)	JP5496438B2 (de)
AT (1)	ATE281500T1 (de)
AU (1)	AU2854400A (de)
BR (1)	BR0008184B1 (de)
CA (1)	CA2359054C (de)
DE (1)	DE60015497T2 (de)
ES (1)	ES2226789T3 (de)
WO (1)	WO2000043131A2 (de)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
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AU2854400A (en) *	1999-01-22	2000-08-07	Lord Corporation	Autodepositable adhesive
AU2001243188A1 (en) *	2000-02-18	2001-08-27	Henkel Kommanditgesellschaft Auf Aktien	Rubber-metal composites
US20040033374A1 (en) *	2002-08-16	2004-02-19	Mowrey Douglas H.	Phenolic adhesives for bonding peroxide-cured elastomers
US7700707B2 (en)	2002-10-15	2010-04-20	Exxonmobil Chemical Patents Inc.	Polyolefin adhesive compositions and articles made therefrom
WO2004046214A2 (en)	2002-10-15	2004-06-03	Exxonmobil Chemical Patents Inc.	Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7541402B2 (en)	2002-10-15	2009-06-02	Exxonmobil Chemical Patents Inc.	Blend functionalized polyolefin adhesive
US7550528B2 (en)	2002-10-15	2009-06-23	Exxonmobil Chemical Patents Inc.	Functionalized olefin polymers
DE10327452A1 (de) *	2003-06-18	2005-01-05	Bayer Materialscience Ag	Klebstoffe
WO2005000480A2 (en) *	2003-06-27	2005-01-06	Lord Corporation	Improved coating process utilizing automated systems
US20050074567A1 (en) *	2003-09-24	2005-04-07	Corbett Bradford G.	Protective coating compositions and techniques for fluid piping systems
US20070244247A1 (en) *	2006-04-13	2007-10-18	Mowrey Douglas H	Aqueous adhesive for rubber to metal bonding
US20070243372A1 (en) *	2006-04-13	2007-10-18	Mowrey Douglas H	Aqueous adhesive
US8288447B2 (en)	2006-06-07	2012-10-16	Henkel Ag & Co. Kgaa	Foamable compositions based on epoxy resins and polyesters
CA2663920C (en)	2006-09-18	2015-11-24	Henkel Ag & Co. Kgaa	Off-white and gray autodeposition coatings
DE102009003082A1 (de)	2009-05-13	2010-11-18	Henkel Ag & Co. Kgaa	Anionische Netzmittel zur Stabilisierung selbstabscheidender Zusammensetzungen enthaltend oxidische Pigmente
JP5603156B2 (ja) *	2010-07-12	2014-10-08	ダンロップスポーツ株式会社	ゴルフボール
US9916555B2 (en)	2012-04-10	2018-03-13	Geoforce, Inc.	Location tracking with integrated identification of cargo carrier contents and related system and method
BR112015012665A2 (pt) *	2012-11-29	2017-07-11	Georgia Pacific Chemicals Llc	preparação de microesferas de resina fenol-aldeído fórmico empregando polimerização em suspensão ou emulsão
JP2018522954A (ja)	2015-05-01	2018-08-16	ロードコーポレイション	ゴム接合用接着剤
WO2017095813A1 (en)	2015-11-30	2017-06-08	Intabio, Inc.	Devices and methods for sample characterization
KR102691269B1 (ko)	2018-01-29	2024-08-05	인타바이오 엘엘씨	샘플 특성화를 위한 장치, 방법 및 키트

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FR2627499B1 (fr) *	1988-02-24	1990-08-03	Hoechst France	Dispersion aqueuse de polymeres du type styrene-acrylique et son application pour l'obtention de compositions adhesives resistant a l'eau convenant notamment dans le domaine du carrelage
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US5717031A (en) *	1995-06-21	1998-02-10	Lord Corporation	Aqueous adhesive compositions
US5616635A (en)	1995-11-27	1997-04-01	The Goodyear Tire & Rubber Company	Aqueous multicolor paint
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JPH1161052A (ja) *	1997-08-11	1999-03-05	Tokai Rubber Ind Ltd	金属・ゴム複合製品の製造方法
DE19755421A1 (de)	1997-12-13	1999-06-17	Henkel Kgaa	Gummi-Metall-Verbund
BR9907927B1 (pt) *	1998-01-27	2009-08-11		composição aquosa, método para proporcionar um revestimento protetor sobre um substrato metálico, método para ligação de uma superfìcie de substrato elastomérico a uma superfìcie de substrato metálico, e método para proporcionar um revestimento ou primer protetor sobre uma superfìcie de substrato metálico.
EP1049748B1 (de)	1998-01-27	2007-01-10	Lord Corporation	Wässrige metallbehandlungszusammensetzung
WO1999037712A1 (en)	1998-01-27	1999-07-29	Lord Corporation	Aqueous phenolic dispersion
US6399702B1 (en) *	1998-01-27	2002-06-04	Lord Corporation	Butadiene polymer latex
AU2854400A (en)	1999-01-22	2000-08-07	Lord Corporation	Autodepositable adhesive

2000
- 2000-01-20 AU AU28544/00A patent/AU2854400A/en not_active Abandoned
- 2000-01-20 US US09/488,716 patent/US6521687B2/en not_active Expired - Lifetime
- 2000-01-20 JP JP2000594580A patent/JP5496438B2/ja not_active Expired - Fee Related
- 2000-01-20 BR BRPI0008184-1A patent/BR0008184B1/pt not_active IP Right Cessation
- 2000-01-20 CA CA2359054A patent/CA2359054C/en not_active Expired - Fee Related
- 2000-01-20 DE DE60015497T patent/DE60015497T2/de not_active Expired - Lifetime
- 2000-01-20 AT AT00906970T patent/ATE281500T1/de not_active IP Right Cessation
- 2000-01-20 EP EP00906970A patent/EP1144535B1/de not_active Expired - Lifetime
- 2000-01-20 ES ES00906970T patent/ES2226789T3/es not_active Expired - Lifetime
- 2000-01-20 WO PCT/US2000/001417 patent/WO2000043131A2/en not_active Ceased
2002
- 2002-11-26 US US10/304,219 patent/US7109265B2/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
WO2000043131A3 (en)	2000-09-28
ES2226789T3 (es)	2005-04-01
WO2000043131A2 (en)	2000-07-27
EP1144535B1 (de)	2004-11-03
US20030100649A1 (en)	2003-05-29
US7109265B2 (en)	2006-09-19
DE60015497T2 (de)	2005-10-20
JP2002535421A (ja)	2002-10-22
BR0008184B1 (pt)	2010-11-30
BR0008184A (pt)	2001-11-06
EP1144535A2 (de)	2001-10-17
US20030008960A1 (en)	2003-01-09
WO2000043131A8 (en)	2001-07-26
AU2854400A (en)	2000-08-07
JP5496438B2 (ja)	2014-05-21
US6521687B2 (en)	2003-02-18
DE60015497D1 (de)	2004-12-09
CA2359054A1 (en)	2000-07-27
CA2359054C (en)	2011-07-05

Legal Events

Date	Code	Title	Description
2005-05-15	RER	Ceased as to paragraph 5 lit. 3 law introducing patent treaties

Publication	Publication Date	Title
DE60015497D1 (de)	2004-12-09	Selbstabsetzender klebstoff
WO2003093376A3 (en)	2004-01-08	Aqueous metal treatment composition
WO2002077078A3 (en)	2002-11-14	Improved fiber substrate adhesion and coatings by metathesis polymerization
ATE312147T1 (de)	2005-12-15	Verfahren zur verwendung von latenten, über- tackifizierten klebstoffen
TW200706620A (en)	2007-02-16	Aqueous dispersions
MXPA01002392A (es)	2004-06-25	Metodos y composiciones acidificadas para reducir la corrosion en las superficies de metal y la precipitacion del sulfuro.
WO2005009225A3 (en)	2005-10-27	Tissue adhesive sealant
MX9704522A (es)	1998-04-30	Adhesivos sensibles a la presion.
AU2003216536A1 (en)	2003-09-22	Silane functional adhesive composition and method of bonding a window to a substrate without a primer
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