ATE295855T1 - POLYMERIZABLE COMPOUNDS AND USE THEREOF - Google Patents

POLYMERIZABLE COMPOUNDS AND USE THEREOF

Info

Publication number
ATE295855T1
ATE295855T1 AT01922845T AT01922845T ATE295855T1 AT E295855 T1 ATE295855 T1 AT E295855T1 AT 01922845 T AT01922845 T AT 01922845T AT 01922845 T AT01922845 T AT 01922845T AT E295855 T1 ATE295855 T1 AT E295855T1
Authority
AT
Austria
Prior art keywords
ester
surfactant
polymerizable
units
typically
Prior art date
Application number
AT01922845T
Other languages
German (de)
Inventor
Herve Adam
Hui Shirley Yang
Jonathan D Kiplinger
Eugene J Anderson Jr
Ning Chen
Robert Lee Reierson
Original Assignee
Rhodia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia filed Critical Rhodia
Application granted granted Critical
Publication of ATE295855T1 publication Critical patent/ATE295855T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F30/00—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F30/02—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymerisation Methods In General (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Dental Preparations (AREA)

Abstract

Polymerizable ester surfactant, or a salt thereof, having the formula:wherein:R1 is an optionally substituted vinyl radical,R2 is a divalent polyoxyalkylene radical having at least two oxypropylene units, optional oxyethylene units in a block or random pattern, and a molar ratio oxypropylene units to oxyethylene units of at least about 2:1, preferably at least about 3:1, typically at least about 4:1 and more typically at least about 5:1, andX is a phosphate group, wherein in the ester the mono-phosphate ester to di-phosphate ester weight ratio is greater than 80:20. These polymerizable surfactant compounds are useful as the sole surfactant in producing polymer latices by emulsion polymerization by polymerization of them with another polymerizable monomer.
AT01922845T 2000-03-31 2001-03-29 POLYMERIZABLE COMPOUNDS AND USE THEREOF ATE295855T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US19387400P 2000-03-31 2000-03-31
PCT/US2001/010099 WO2001074909A2 (en) 2000-03-31 2001-03-29 Polymerizable compounds and uses thereof

Publications (1)

Publication Number Publication Date
ATE295855T1 true ATE295855T1 (en) 2005-06-15

Family

ID=22715360

Family Applications (1)

Application Number Title Priority Date Filing Date
AT01922845T ATE295855T1 (en) 2000-03-31 2001-03-29 POLYMERIZABLE COMPOUNDS AND USE THEREOF

Country Status (12)

Country Link
US (1) US6534597B2 (en)
EP (1) EP1274738B1 (en)
JP (1) JP4880853B2 (en)
KR (1) KR100695692B1 (en)
CN (2) CN1271090C (en)
AT (1) ATE295855T1 (en)
AU (2) AU2001249603B2 (en)
BR (1) BR0109649B1 (en)
CA (1) CA2403473C (en)
DE (1) DE60110903T2 (en)
MX (1) MXPA02009425A (en)
WO (1) WO2001074909A2 (en)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070043152A1 (en) * 2003-05-21 2007-02-22 Jean-Marie Bernard Isocyanate-based compositions, process for using them, use thereof for making direct-to-metal coatings and coatings thus obtained
FR2855768B1 (en) * 2003-05-21 2006-06-16 Rhodia Chimie Sa ISOCYANATE-BASED COMPOSITIONS, THEIR USE METHOD FOR PRODUCING CLOTHES AND COATINGS THUS OBTAINED
US7820754B2 (en) 2004-03-10 2010-10-26 Cray Valley S.A. Aqueous polymer dispersion for barrier coating
EP1582567B2 (en) † 2004-04-01 2011-11-16 Rohm And Haas Company Aqueous coating composition
US7666924B2 (en) 2004-06-10 2010-02-23 Kao Corporation Polymeric dispersants
KR20070033431A (en) * 2004-07-15 2007-03-26 가오가부시끼가이샤 Phosphate Ester Polymer
EP1789486B1 (en) * 2004-08-26 2008-01-09 Lubrizol Advanced Materials, Inc. Coating compositions having improved stability
US7297748B2 (en) * 2004-08-31 2007-11-20 Rhodia Inc. Direct to metal polyurethane coating compositions
US20060264332A1 (en) * 2005-05-20 2006-11-23 Halliburton Energy Services, Inc. Methods of using reactive surfactants in subterranean operations
US7671152B2 (en) 2005-12-22 2010-03-02 The Goodyear Tire & Rubber Company Surfactantless synthesis of amphiphilic cationic block copolymers
EP1860122A1 (en) * 2006-05-24 2007-11-28 Rhodia Recherches et Technologies Process of making aqueous dispersions of polymers, emulsions polymers and use thereof
US7442746B2 (en) 2006-10-19 2008-10-28 The Goodyear Tire & Rubber Company Epoxidation of unsaturated cationically stabilized polymer latex
KR101574365B1 (en) 2008-03-20 2015-12-03 바스프 에스이 Polymer dispersions containing phosphorous polymers and emulsifiers
US8592040B2 (en) 2008-09-05 2013-11-26 Basf Se Polymer emulsion coating or binding formulations and methods of making and using same
CN102762668B (en) * 2009-12-23 2019-02-05 莫门蒂夫性能材料股份有限公司 Network copolymer crosslinked compositions and products containing the same
US8461253B2 (en) 2010-01-15 2013-06-11 Ppg Industries Ohio, Inc. One-component, ambient curable waterborne coating compositions, related methods and coated substrates
CN102834566B (en) 2010-03-23 2016-04-27 巴斯夫欧洲公司 Paper Coating or bonding preparaton and its production and use
CN101982224B (en) * 2010-09-16 2012-08-29 佛山市科的气体化工有限公司 Polymerizable surfactant
CA2759137C (en) 2010-12-31 2016-02-09 Rohm And Haas Company New polymeric bead compositions
JP2012140597A (en) 2010-12-31 2012-07-26 Rohm & Haas Co Method for producing polymeric bead from phosphorous acid-containing monomer
US9102848B2 (en) 2011-02-28 2015-08-11 Basf Se Environmentally friendly, polymer dispersion-based coating formulations and methods of preparing and using same
US9950306B2 (en) * 2011-07-14 2018-04-24 Basf Se Process for producing water-absorbing polymer particles with high free swell rate
MX352168B (en) 2012-02-10 2017-11-13 Arkema Inc Polymer latex binders useful in zero or low voc coating compositions.
CN102719166A (en) * 2012-06-12 2012-10-10 天长市巨龙车船涂料有限公司 Water-based coating for interior and exterior walls of buildings and preparation method of water-based coating
US9676932B2 (en) * 2012-08-02 2017-06-13 Rohm And Haas Company Adsorbing vinyl ester binders
CN103554470B (en) * 2013-10-09 2016-08-31 上海优创化学品有限公司 A kind of double bond containing alcohol ether and phosphate thereof and the production method of described material
JP6410269B2 (en) * 2014-04-25 2018-10-24 積水化成品工業株式会社 Method for producing composite particles
US10800927B2 (en) 2014-12-22 2020-10-13 Dow Global Technologies Llc Aqueous emulsion paint with improved stain removal and anticlogging properties
MX2018006530A (en) * 2015-12-02 2018-08-15 Arkema Inc Emulsion polymers and stain resistant coating compositions made therefrom.
CN113174005A (en) 2015-12-02 2021-07-27 阿科玛股份有限公司 Emulsion polymers and low VOC coating compositions prepared therefrom
CN105859921B (en) * 2016-04-12 2018-07-06 湖南省金海科技有限公司 A kind of ultraviolet light cures phosphate modified acrylic resin and its manufacturing method

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3855364A (en) * 1973-01-05 1974-12-17 Alcolac Inc Phosphate esters of hydroxyalkyl acrylates and hydroxyalkyl methacrylates
NL160278C (en) * 1975-09-25 1979-10-15 Synres Internationaal Nv PROCEDURE FOR PREPARING Aqueous EMULSIONS OF ADDITIONAL POLYMERS.
JPH0822991B2 (en) 1990-05-21 1996-03-06 日本ペイント株式会社 Aqueous coating composition
US5550274A (en) * 1994-03-30 1996-08-27 Reierson; Robert L. In-situ phosphation reagent process
DE69528405T2 (en) * 1994-03-30 2003-06-18 Rhodia Inc., Cranbury Phosphorylation reagent, method and use
JP4031831B2 (en) * 1996-01-30 2008-01-09 株式会社Adeka Compounds and surfactants
DE19810658A1 (en) 1998-03-12 1999-11-25 Basf Ag Aqueous polymer dispersion containing an emulsifier with phosphate groups

Also Published As

Publication number Publication date
WO2001074909A3 (en) 2002-03-28
US6534597B2 (en) 2003-03-18
DE60110903T2 (en) 2006-01-12
CN1524883A (en) 2004-09-01
BR0109649A (en) 2003-04-22
KR20020087112A (en) 2002-11-21
CN1271090C (en) 2006-08-23
BR0109649B1 (en) 2011-01-25
CN1420894A (en) 2003-05-28
CN1289535C (en) 2006-12-13
EP1274738B1 (en) 2005-05-18
US20020123588A1 (en) 2002-09-05
MXPA02009425A (en) 2003-04-10
JP2003529645A (en) 2003-10-07
AU2001249603B2 (en) 2005-02-03
CA2403473C (en) 2007-09-18
WO2001074909A2 (en) 2001-10-11
EP1274738A2 (en) 2003-01-15
AU4960301A (en) 2001-10-15
DE60110903D1 (en) 2005-06-23
JP4880853B2 (en) 2012-02-22
CA2403473A1 (en) 2001-10-11
KR100695692B1 (en) 2007-03-15

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