ATE296319T1 - Geträgerter ziegler - metallocene polymerisationskatalysator und dessen benutzung für die polymerisation von olefinen - Google Patents

Geträgerter ziegler - metallocene polymerisationskatalysator und dessen benutzung für die polymerisation von olefinen

Info

Publication number
ATE296319T1
ATE296319T1 AT02015565T AT02015565T ATE296319T1 AT E296319 T1 ATE296319 T1 AT E296319T1 AT 02015565 T AT02015565 T AT 02015565T AT 02015565 T AT02015565 T AT 02015565T AT E296319 T1 ATE296319 T1 AT E296319T1
Authority
AT
Austria
Prior art keywords
olefins
polymerization
compound
metallocene
supported ziegler
Prior art date
Application number
AT02015565T
Other languages
English (en)
Inventor
Akhlaq Moman
Orass Hamed
Atieh Abu-Raquabah
Khalid Al-Bahily
Original Assignee
Saudi Basic Ind Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Ind Corp filed Critical Saudi Basic Ind Corp
Application granted granted Critical
Publication of ATE296319T1 publication Critical patent/ATE296319T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT02015565T 2002-07-12 2002-07-12 Geträgerter ziegler - metallocene polymerisationskatalysator und dessen benutzung für die polymerisation von olefinen ATE296319T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP02015565A EP1380601B1 (de) 2002-07-12 2002-07-12 Geträgerter ziegler - metallocene polymerisationskatalysator und dessen benutzung für die polymerisation von olefinen

Publications (1)

Publication Number Publication Date
ATE296319T1 true ATE296319T1 (de) 2005-06-15

Family

ID=29724440

Family Applications (1)

Application Number Title Priority Date Filing Date
AT02015565T ATE296319T1 (de) 2002-07-12 2002-07-12 Geträgerter ziegler - metallocene polymerisationskatalysator und dessen benutzung für die polymerisation von olefinen

Country Status (7)

Country Link
US (1) US20040038806A1 (de)
EP (1) EP1380601B1 (de)
JP (1) JP4089968B2 (de)
CN (1) CN1296395C (de)
AT (1) ATE296319T1 (de)
DE (1) DE60204306T2 (de)
ES (1) ES2240613T3 (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100537018C (zh) * 2004-06-16 2009-09-09 陶氏环球技术公司 用于齐格勒-纳塔研究的装置和方法
CN1328310C (zh) * 2004-11-05 2007-07-25 中国科学院化学研究所 聚烯烃复合材料及其制备方法
CN102108104B (zh) * 2009-12-23 2012-11-14 中国石油天然气股份有限公司 合成宽或双峰分子量分布聚烯烃催化剂及其制备方法
CN102127176A (zh) * 2011-01-28 2011-07-20 中国科学院化学研究所 一种高熔体强度聚丙烯及其制备方法
US8664461B2 (en) 2012-03-19 2014-03-04 Exxonmobil Chemical Patents Inc. Catalysts for producing polyalpha-olefins and processes related thereto
KR20220042395A (ko) * 2019-07-31 2022-04-05 다우 글로벌 테크놀로지스 엘엘씨 지글러-나타 촉매 및 수소화 촉매를 사용한 용액 공정에서의 에틸렌의 중합
CN117624417A (zh) * 2022-08-12 2024-03-01 中国石油天然气股份有限公司 用于熔喷聚乙烯的茂金属催化剂的制备方法
CN116854840B (zh) * 2023-05-25 2025-12-30 朴烯晶新能源材料(上海)有限公司 一种用于制备窄分子量分布的高分子量聚乙烯的齐格勒-纳塔催化剂及其制备方法

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BG17623A3 (bg) * 1968-06-27 1973-11-10 Hoechst Aktiengesellschaft Метод за полимеризация на алфаолефини
US3676415A (en) * 1968-06-27 1972-07-11 Hoechst Ag Process for polymerizing {60 -olefins
FR2082153A5 (fr) * 1970-03-05 1971-12-10 Solvay Catalyseurs et procede perfectionnes pour la polymerisation et la copolymerisation des olefines
US3678019A (en) * 1970-03-16 1972-07-18 Exxon Research Engineering Co Novel process for olefin polymerization
US4496661A (en) * 1983-10-24 1985-01-29 The Dow Chemical Company High efficiency catalyst for polymerizing olefins
BE1007040A3 (fr) * 1993-05-25 1995-02-28 Solvay Support de catalyseur et catalyseur de polymerisation des alpha-olefines; procedes pour leur obtention et polymerisation des alpha-olefines en presence du catalyseur.
BR9407034A (pt) * 1993-06-24 1996-03-19 Dow Chemical Co Complexos de titânio ( I) ou zircônio (II) e catalisadores de polimerização por adição dos mesmos
US5614456A (en) * 1993-11-15 1997-03-25 Mobil Oil Corporation Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers
US5595950A (en) * 1993-12-20 1997-01-21 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
IT1270070B (it) * 1994-07-08 1997-04-28 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
US5625015A (en) * 1994-11-23 1997-04-29 Exxon Chemical Patents Inc. Method for making supported catalyst systems and catalyst systems therefrom
US5670439A (en) * 1995-03-29 1997-09-23 Quantum Chemical Corporation Vanadium-containing catalyst system
US5534472A (en) * 1995-03-29 1996-07-09 Quantum Chemical Corporation Vanadium-containing catalyst system
US6417130B1 (en) * 1996-03-25 2002-07-09 Exxonmobil Oil Corporation One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization
DE19706409A1 (de) * 1997-02-19 1998-08-20 Buna Sow Leuna Olefinverb Gmbh Verfahren und Katalysator zur Herstellung von mittel- bis ultrahochmolekularen Polyolefinen
CA2206944C (en) * 1997-05-30 2006-08-29 Douglas W. Stephan High temperature solution polymerization process
US6448348B1 (en) * 1998-10-16 2002-09-10 Saudi Basic Industries Corporation Process for polymerizing olefins with supported Ziegler-Natta catalyst systems
CN1096474C (zh) * 1998-12-30 2002-12-18 化学工业部北京化工研究院 用于合成宽分布乙烯聚合物的复合催化剂及其制法和应用
US6403520B1 (en) * 1999-09-17 2002-06-11 Saudi Basic Industries Corporation Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst
GC0000293A (en) * 2000-10-10 2006-11-01 Saudi Basic Ind Corp Catalyst composition and process for olfin polymerization and copolymerization using supported metallocene catalyst systems
US6964937B2 (en) * 2000-11-30 2005-11-15 Univation Technologies, Llc Bimetallic catalyst for producing polyethylene resins with bimodal molecular weight distribution, its preparation and use
DE60104809T2 (de) * 2001-02-07 2005-01-05 Saudi Basic Industries Corp. Katalysatorzusammensetzung für die Olefinpolymerisation und Verfahren zu ihrer Herstellung
US7172987B2 (en) * 2002-12-31 2007-02-06 Univation Technologies, Llc Bimetallic catalyst, method of polymerization and bimodal polyolefins therefrom

Also Published As

Publication number Publication date
US20040038806A1 (en) 2004-02-26
DE60204306T2 (de) 2005-10-20
CN1296395C (zh) 2007-01-24
CN1495202A (zh) 2004-05-12
EP1380601B1 (de) 2005-05-25
DE60204306D1 (de) 2005-06-30
EP1380601A1 (de) 2004-01-14
JP2004035893A (ja) 2004-02-05
JP4089968B2 (ja) 2008-05-28
ES2240613T3 (es) 2005-10-16

Similar Documents

Publication Publication Date Title
EP1548023A3 (de) Übergangsmetallverbindung, Katalysatorsystem und seine Verwendung zur Polymerisation und Copolymerisation von Olefinen
JP2006521436A5 (de)
NO996340D0 (no) Etylen-<alfa>-olefin-polymerer, fremgangsmåter og anvendelser
DE69717614D1 (de) Polymerisation verfahren zur herstellung von polyolefin-elastomeren kationenerzeugender co-katalysator für die activierung von metallocen-katalysatorvorläufer, polyolefin-elastomeren mit einer einziger kombination von eigenschaften und daraus hergestellte produkten
BR0016725B1 (pt) sistema catalisador compreendendo pelo menos um composto organometálico, pelo menos uma base de lewis, pelo menos um suporte e pelo menos um composto de organoelemento, uso do mesmo, e, processo para preparar poliolefinas.
ATE256136T1 (de) Metallocene
DE50005332D1 (de) Katalysatorsystem
HUT51651A (en) Cathalizator for polimerization of olefines
RU94033101A (ru) Способ получения полимеров этилена и продукты, полученные из них
ID21950A (id) Polimerisasi olefin
BR0010301B1 (pt) processo para produção de polìmeros de alfa-olefina, e processo para produção de um artigo moldado por injeção.
ATE430753T1 (de) Ligand für einen metallocenkatalysator für die polymerisation von propylen und dessen herstellungsverfahren
FR2659337B1 (fr) Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
DE60018775D1 (de) Geträgerter und modifizierter katalysator für die polymerisation von olefine
ATE301141T1 (de) AKTIVIERUNG VON ßSINGLE SITEß POLYMERISATIONSKATALYSATOREN DURCH (DIALKYLALUMINO)BRORONSÄUREESTER
ATE296319T1 (de) Geträgerter ziegler - metallocene polymerisationskatalysator und dessen benutzung für die polymerisation von olefinen
DE69904521D1 (de) Verbrückte Zirconocene, deren Herstellung und deren Verwendung als Katalysatorkomponente für die Polymerisation von Olefinen
DE69634589D1 (de) Katalysatorsystem für die Co-Polymerisation von Alphaolefinen
DE69319690D1 (de) Katalysator und Verfahren zur (Co)Polymerisation von Alpha-Olefinen
DE60211013D1 (de) Zweistufen-polymerisationsverfahren
MY134196A (en) Process for the polymerization of ethylene and interpolymers thereof.
ATE260945T1 (de) Zwitterionische, neutrale übergansmetallverbindung
DE69914012D1 (de) Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
BR9915578B1 (pt) processo para polimerizar etileno e/ou etileno e pelo menos uma ou mais outra(s) olefina(s), pelìcula, e, artigo.
KR920701272A (ko) 올레핀의 신디오택틱 단독중합체

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties