ATE307831T1 - Copolymerisierung von vinylchlorid in gegenwart eines stabilen nitroxylradikals - Google Patents

Copolymerisierung von vinylchlorid in gegenwart eines stabilen nitroxylradikals

Info

Publication number
ATE307831T1
ATE307831T1 AT01993632T AT01993632T ATE307831T1 AT E307831 T1 ATE307831 T1 AT E307831T1 AT 01993632 T AT01993632 T AT 01993632T AT 01993632 T AT01993632 T AT 01993632T AT E307831 T1 ATE307831 T1 AT E307831T1
Authority
AT
Austria
Prior art keywords
copolymerization
vinyl chloride
nitroxyl radical
stable nitroxyl
stable
Prior art date
Application number
AT01993632T
Other languages
English (en)
Inventor
Rudolf Pfaendner
Thomas Wannemacher
Dietrich Braun
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Application granted granted Critical
Publication of ATE307831T1 publication Critical patent/ATE307831T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02—Monomers containing chlorine
    • C08F14/04—Monomers containing two carbon atoms
    • C08F14/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paper (AREA)
AT01993632T 2000-11-13 2001-11-06 Copolymerisierung von vinylchlorid in gegenwart eines stabilen nitroxylradikals ATE307831T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP00811066 2000-11-13
PCT/EP2001/012820 WO2002038632A1 (en) 2000-11-13 2001-11-06 (co)polymerization of vinyl chloride in the presence of a stable nitroxyl radical

Publications (1)

Publication Number Publication Date
ATE307831T1 true ATE307831T1 (de) 2005-11-15

Family

ID=8175022

Family Applications (1)

Application Number Title Priority Date Filing Date
AT01993632T ATE307831T1 (de) 2000-11-13 2001-11-06 Copolymerisierung von vinylchlorid in gegenwart eines stabilen nitroxylradikals

Country Status (15)

Country Link
US (1) US6844405B2 (de)
EP (1) EP1334140B1 (de)
JP (1) JP2004513996A (de)
KR (1) KR100786242B1 (de)
CN (1) CN1225485C (de)
AT (1) ATE307831T1 (de)
AU (1) AU2002221813A1 (de)
BR (1) BR0115280A (de)
CA (1) CA2426495A1 (de)
DE (1) DE60114442T2 (de)
ES (1) ES2250513T3 (de)
MX (1) MXPA03004170A (de)
RU (1) RU2273649C2 (de)
TW (1) TWI236482B (de)
WO (1) WO2002038632A1 (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW546311B (en) * 1999-11-25 2003-08-11 Ciba Sc Holding Ag Composition and method for color improvement of nitroxyl containing polymers
US7345127B2 (en) 2001-03-23 2008-03-18 University Of Pennsylvania Living radical polymerization of halogen-containing and acrylic monomers and the formation of block copolymers therefrom
FR2822832B1 (fr) * 2001-04-02 2005-01-14 Atofina Polymerisation en suspension acqueuse du chlorure de vinyle seul ou en melange avec un autre monomere vinylique avec utilisation d'un radical stable de type nitroxyde comme agent d'arret de polymerisation
CN1310972C (zh) * 2002-05-01 2007-04-18 西巴特殊化学品控股有限公司 Pvc聚合的链终止方法
CN100577692C (zh) * 2005-01-11 2010-01-06 西巴特殊化学品控股有限公司 用受控自由基聚合方法制备的均聚物和共聚物的后改性方法
CA2617547C (en) 2005-08-02 2013-10-08 Arkema Inc. Methods of producing vinyl aromatic polymers using (meth)acrylic macroinitiators
RU2425057C2 (ru) * 2005-08-30 2011-07-27 Циба Спешиалти Кемикэлз Холдинг Инк. Полимеры, полученные путем полимеризации под действием нитроксильных радикалов
EP1969397B1 (de) * 2005-12-14 2017-11-08 Novartis AG Verfahren zum herstellen von silikon-hydrogelen
CA2749240A1 (en) * 2009-01-19 2010-07-22 Basf Se Black pigment dispersion
KR101410547B1 (ko) * 2010-09-06 2014-06-20 주식회사 엘지화학 높은 생산성과 향상된 열 안정성을 갖는 염화비닐계 수지의 제조 방법
WO2012076542A1 (en) 2010-12-07 2012-06-14 Solvay Sa Controlled radical polymerization of halogenated monomers
WO2012076544A1 (en) 2010-12-07 2012-06-14 Solvay Sa Controlled radical polymerization of halogenated monomers
FR3030525B1 (fr) * 2014-12-18 2018-05-11 Arkema France Polymerisation radicalaire d'alcoxyamines a basse temperature
CN106432649B (zh) * 2016-10-22 2018-08-07 宁波大学 一种氯乙烯/异戊二烯共聚物的绿色制备方法
CN111116829A (zh) * 2020-01-07 2020-05-08 河南理工大学 聚氯乙烯接枝共聚物及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1235872A1 (ru) * 1984-08-06 1986-06-07 Научно-Исследовательский Институт Химии При Горьковском Ордена Трудового Красного Знамени Государственном Университете Им.Н.И.Лобачевского Способ получени виниловых полимеров
FR2730240A1 (fr) * 1995-02-07 1996-08-09 Atochem Elf Sa Stabilisation d'un polymere par un radical libre stable
US5880230A (en) * 1997-12-31 1999-03-09 Nalco/Exxon Energy Chemicals, L.P. Shortstop agents for vinyl polymerizations
CH693416A5 (de) * 1998-03-09 2003-07-31 Ciba Sc Holding Ag 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler.

Also Published As

Publication number Publication date
DE60114442D1 (de) 2005-12-01
KR100786242B1 (ko) 2007-12-17
TWI236482B (en) 2005-07-21
EP1334140A1 (de) 2003-08-13
WO2002038632A1 (en) 2002-05-16
AU2002221813A1 (en) 2002-05-21
CN1474835A (zh) 2004-02-11
CA2426495A1 (en) 2002-05-16
ES2250513T3 (es) 2006-04-16
KR20030051780A (ko) 2003-06-25
CN1225485C (zh) 2005-11-02
MXPA03004170A (es) 2003-09-22
US20040138393A1 (en) 2004-07-15
BR0115280A (pt) 2003-07-29
US6844405B2 (en) 2005-01-18
EP1334140B1 (de) 2005-10-26
DE60114442T2 (de) 2006-04-20
JP2004513996A (ja) 2004-05-13
RU2273649C2 (ru) 2006-04-10

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