ATE318854T1 - Polybenzazolverbindung mit sulfo- und/oder phosphonogruppe, diese enthaltende harzzusammensetzung, harzformteil, polymerfestelektrolytfolie, verbund aus festelektrolytfolie und elektrodenkatalysatorschicht und verfahren zur herstellung des verbunds - Google Patents

Polybenzazolverbindung mit sulfo- und/oder phosphonogruppe, diese enthaltende harzzusammensetzung, harzformteil, polymerfestelektrolytfolie, verbund aus festelektrolytfolie und elektrodenkatalysatorschicht und verfahren zur herstellung des verbunds

Info

Publication number
ATE318854T1
ATE318854T1 AT01982763T AT01982763T ATE318854T1 AT E318854 T1 ATE318854 T1 AT E318854T1 AT 01982763 T AT01982763 T AT 01982763T AT 01982763 T AT01982763 T AT 01982763T AT E318854 T1 ATE318854 T1 AT E318854T1
Authority
AT
Austria
Prior art keywords
composite
solid electrolyte
electrolyte film
polybenzazole compound
polymer electrolyte
Prior art date
Application number
AT01982763T
Other languages
English (en)
Inventor
Yoshimitsu Sakaguchi
Kota Kitamura
Hiroaki Taguchi
Junko Nakao
Shiro Hamamoto
Hiroshi Tachimori
Satoshi Takase
Original Assignee
Toyo Boseki
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2000345606A external-priority patent/JP3968625B2/ja
Priority claimed from JP2000348328A external-priority patent/JP2002146017A/ja
Priority claimed from JP2001001615A external-priority patent/JP3959669B2/ja
Priority claimed from JP2001002661A external-priority patent/JP2002206025A/ja
Priority claimed from JP2001101021A external-priority patent/JP2002212291A/ja
Priority claimed from JP2001101022A external-priority patent/JP3690589B2/ja
Application filed by Toyo Boseki filed Critical Toyo Boseki
Application granted granted Critical
Publication of ATE318854T1 publication Critical patent/ATE318854T1/de

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/22—Polybenzoxazoles
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/122—Ionic conductors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Sustainable Development (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Energy (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Fuel Cell (AREA)
  • Conductive Materials (AREA)
  • Inert Electrodes (AREA)
AT01982763T 2000-11-13 2001-11-12 Polybenzazolverbindung mit sulfo- und/oder phosphonogruppe, diese enthaltende harzzusammensetzung, harzformteil, polymerfestelektrolytfolie, verbund aus festelektrolytfolie und elektrodenkatalysatorschicht und verfahren zur herstellung des verbunds ATE318854T1 (de)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
JP2000345604 2000-11-13
JP2000345606A JP3968625B2 (ja) 2000-11-13 2000-11-13 ホスホン酸含有ポリアゾール
JP2000348328A JP2002146017A (ja) 2000-11-15 2000-11-15 イオン伝導性ホスホン酸含有ポリアゾール
JP2000348327 2000-11-15
JP2001001615A JP3959669B2 (ja) 2001-01-09 2001-01-09 イオン伝導性スルホン酸基含有ポリアゾール及びそれを主成分とする膜
JP2001002661A JP2002206025A (ja) 2001-01-10 2001-01-10 スルホン酸基含有ポリオキサゾール及びそれを主成分とする膜
JP2001101021A JP2002212291A (ja) 2000-11-15 2001-03-30 スルホン酸またはホスホン酸含有ポリイミダゾール化合物およびその成型物
JP2001101022A JP3690589B2 (ja) 2000-11-13 2001-03-30 スルホン酸含有ポリイミダゾール化合物およびその成型物

Publications (1)

Publication Number Publication Date
ATE318854T1 true ATE318854T1 (de) 2006-03-15

Family

ID=27573727

Family Applications (1)

Application Number Title Priority Date Filing Date
AT01982763T ATE318854T1 (de) 2000-11-13 2001-11-12 Polybenzazolverbindung mit sulfo- und/oder phosphonogruppe, diese enthaltende harzzusammensetzung, harzformteil, polymerfestelektrolytfolie, verbund aus festelektrolytfolie und elektrodenkatalysatorschicht und verfahren zur herstellung des verbunds

Country Status (6)

Country Link
US (1) US7288603B2 (de)
EP (1) EP1354907B1 (de)
CN (1) CN100358938C (de)
AT (1) ATE318854T1 (de)
DE (1) DE60117595T2 (de)
WO (1) WO2002038650A1 (de)

Families Citing this family (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10117686A1 (de) * 2001-04-09 2002-10-24 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
DE10209419A1 (de) 2002-03-05 2003-09-25 Celanese Ventures Gmbh Verfahren zur Herstellung einer Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
ES2292993T3 (es) 2002-03-06 2008-03-16 Basf Fuel Cell Gmbh Membrana electrolitica conductora de protones con permeabilidad reducida de metanol y su aplicacion en pilas de combustible.
CA2483015A1 (en) 2002-04-25 2003-11-06 Pemeas Gmbh Multilayer electrolyte membrane
DE10230477A1 (de) 2002-07-06 2004-01-15 Celanese Ventures Gmbh Funktionalisierte Polyazole, Verfahren zu ihrer Herstellung sowie ihre Verwendung
EP1527494B1 (de) 2002-08-02 2005-12-28 Pemeas GmbH Protonenleitende polymembran, welche sulfonsäuregruppen enthaltende polymere umfasst, und deren anwendung in brennstoffzellen
DE10235358A1 (de) * 2002-08-02 2004-02-12 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Phosphonsäuregruppen enthaltende Polymere und deren Anwendung in Brennstoffzellen
DE10239701A1 (de) 2002-08-29 2004-03-11 Celanese Ventures Gmbh Polymerfolie auf Basis von Polyazolen und deren Verwendung
DE10242708A1 (de) * 2002-09-13 2004-05-19 Celanese Ventures Gmbh Protonenleitende Membranen und deren Verwendung
DE10246372A1 (de) * 2002-10-04 2004-04-15 Celanese Ventures Gmbh Mit einer Katalysatorschicht beschichtete protonenleitende Polymermembran enthaltend Polyazole und deren Anwendung in Brennstoffzellen
DE10246459A1 (de) 2002-10-04 2004-04-15 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Phosphonsäuregruppen enthaltende Polyazole und deren Anwendung in Brennstoffzellen
DE10246373A1 (de) * 2002-10-04 2004-04-15 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Sulfonsäuregruppen enthaltende Polyazole und deren Anwendung in Brennstoffzellen
DE10246461A1 (de) * 2002-10-04 2004-04-15 Celanese Ventures Gmbh Protonenleitende Polymermembran enthaltend Polyazolblends und deren Anwendung in Brennstoffzellen
JP3925382B2 (ja) * 2002-10-11 2007-06-06 トヨタ自動車株式会社 高耐久性高分子電解質、同組成物、および燃料電池
US6878475B2 (en) * 2002-11-22 2005-04-12 T/J Technologies, Inc. Membrane for fuel cell, and fuel cell incorporating that membrane
DE10258580A1 (de) * 2002-12-16 2004-06-24 Celanese Ventures Gmbh Hochmolekular Polyazole
EP1465277A1 (de) * 2003-03-19 2004-10-06 HONDA MOTOR CO., Ltd. Feststoff Polymerelektrolyt und Protonenleitende Membran
JP4875489B2 (ja) 2003-07-27 2012-02-15 ベーアーエスエフ フューエル セル ゲーエムベーハー プロトン伝導性膜およびその使用
DE10340927A1 (de) * 2003-09-04 2005-03-31 Celanese Ventures Gmbh Protonenleitende Polymermembran enthaltend Polymere mit an aromatische Gruppen kovalent gebundene Sulfonsäuregruppen, Membran-Elektoden-Einheit und deren Anwendung in Brennstoffzellen
US20080038624A1 (en) * 2003-09-04 2008-02-14 Jorg Belack Proton-conducting polymer membrane coated with a catalyst layer, said polymer membrane comprising phosphonic acid polymers, membrane/electrode unit and use thereof in fuel cells
DE10340928A1 (de) * 2003-09-04 2005-04-07 Celanese Ventures Gmbh Mit einer Katalysatorschicht beschichtete protonenleitende Polymermembran enthaltend Phosphonensäuregruppen umfassende Polymere, Membran-Elektroden-Einheit und deren Anwendung in Brennstoffzellen
US20050053821A1 (en) * 2003-09-08 2005-03-10 Jang Bor Z. Self-moisturizing proton exchange membrane, membrane-electrode assembly and fuel cell
KR100508691B1 (ko) * 2003-10-30 2005-08-17 한국화학연구원 직접메탄올 연료전지용 술폰산 함유폴리아릴에테르벤즈이미다졸 전해질 및 이를 이용한전해질 복합막
GB0400626D0 (en) * 2004-01-13 2004-02-11 Johnson Matthey Plc Polymer
DE102004024844A1 (de) * 2004-05-13 2005-12-08 Volkswagen Ag Elektrodenpaste zur Herstellung einer Katalysatorschicht für eine elektrochemische Zelle sowie Verfahren zur Herstellung einer Katalysatorschicht
JP4664626B2 (ja) * 2004-07-05 2011-04-06 ポリマテック株式会社 イオン伝導性高分子電解質膜及びその製造方法
JP2006032135A (ja) * 2004-07-16 2006-02-02 Toyota Motor Corp 固体高分子電解質膜の製造方法、固体高分子電解質膜、およびこれを備える燃料電池
EP1657274A1 (de) * 2004-11-10 2006-05-17 SOLVAY (Société Anonyme) Polybenzazol Blockcopolymer
EP1826846A4 (de) 2004-11-10 2010-01-13 Toyo Boseki Aromatische kohlenwasserstoffbasenprotonen-austauschmembran und direktmethanol-brennstoffzelle damit
KR100727216B1 (ko) 2004-11-19 2007-06-13 주식회사 엘지화학 신규한 술폰화 공중합체 및 이를 이용한 전해질막
KR100657740B1 (ko) * 2004-12-22 2006-12-14 주식회사 엘지화학 브랜치된 술폰화 멀티 블록 공중합체 및 이를 이용한전해질막
KR20060087140A (ko) * 2005-01-28 2006-08-02 삼성에스디아이 주식회사 고분자 전해질막 및 이를 채용한 연료전지
EP2463865B1 (de) * 2005-02-15 2016-11-02 Toray Industries, Inc. Verfahren zur Herstellung eines geformten Polymerelektrolytprodukts, Polymerelektrolytmaterial, Polymerelektrolytmembran und feste Polymerelektrolyt-Brennstoffzelle
KR20060104163A (ko) * 2005-03-29 2006-10-09 한국과학기술연구원 연료전지용 고분자 및 그 제조 방법
EP1889876A1 (de) * 2005-05-26 2008-02-20 Teijin Limited Formenschmiermittel
EP1901378A4 (de) 2005-06-03 2009-11-18 Samsung Yokohama Res Inst Protonenleitende polymermembran, herstellungsverfahren dafür und brennstoffzelle damit
JP4579073B2 (ja) * 2005-07-15 2010-11-10 本田技研工業株式会社 固体高分子型燃料電池用膜−電極構造体
KR100756457B1 (ko) * 2005-11-01 2007-09-07 주식회사 엘지화학 퍼플루오로싸이클로부탄기를 포함하는 블록 공중합체 및이를 이용한 전해질막
KR101417139B1 (ko) 2006-02-16 2014-07-16 바스프 에스이 소중합체 및 중합체 방향족 포스폰산, 이들의 배합물, 이들의 제조 방법 및 고분자 전해질로서의 용도
KR100902411B1 (ko) * 2006-12-22 2009-06-11 한국과학기술연구원 술폰산이 부분적으로 도입된 폴리벤지이미다졸, 그 제조방법, 상기 폴리벤지이미다졸을 이용한 연료전지용막전극접합체 및 그 제조 방법
CN101303938B (zh) * 2007-05-09 2011-08-17 郑州泰达电子材料科技有限公司 固体电解电容器
CN101303937B (zh) * 2007-05-09 2010-09-01 郑州泰达电子材料科技有限公司 固体电解电容器及固体电解电容器的制备方法
TWI340773B (en) * 2008-07-07 2011-04-21 Univ Taipei Medical Method of fabricating nano-fibers by electrospinning
US8512909B2 (en) * 2008-08-12 2013-08-20 Samsung Electronics Co., Ltd. Laminated electrolyte membrane, method of preparing the same, and membrane electrode assembly and fuel cell including the laminated electrolyte membrane
US8846133B2 (en) * 2008-12-06 2014-09-30 Basf Se Method for producing a proton-conducting membrane
KR20120047856A (ko) * 2009-06-20 2012-05-14 바스프 에스이 고분자량 폴리아졸의 제조방법
KR101093703B1 (ko) * 2009-06-25 2011-12-15 삼성에스디아이 주식회사 연료전지용 고분자 전해질막 및 그 제조방법
US20120219879A1 (en) * 2009-09-24 2012-08-30 Ewe-Forschungszentrum Für Energietechnologie E.V. Proton exchange membrane comprising polymer blends for use in high temperature proton exchange membrane fuel cells
WO2011093495A1 (ja) * 2010-02-01 2011-08-04 旭化成イーマテリアルズ株式会社 塗料及び積層体
KR101350858B1 (ko) 2012-02-20 2014-01-16 한국과학기술연구원 폴리벤지이미다졸코벤족사졸 및 그 제조 방법
CN105037709A (zh) * 2015-07-06 2015-11-11 天津砚津科技有限公司 骨架含有膦酸和磺酸基团的无规聚合物及其制备方法
CN105001414A (zh) * 2015-07-06 2015-10-28 天津砚津科技有限公司 骨架含有膦酸和磺酸基团的交替聚合物及其制备方法
CN105017751A (zh) * 2015-07-06 2015-11-04 天津师范大学 骨架含有膦酸和磺酸基团的聚合物共混物及其制备方法
CN105001424A (zh) * 2015-07-06 2015-10-28 天津师范大学 骨架含有膦酸和磺酸基团的嵌段聚合物及其制备方法
JP7847407B2 (ja) * 2020-03-31 2026-04-17 住友化学株式会社 固体電解質含有層
CN115627072B (zh) * 2022-11-01 2023-10-10 河北科技大学 一种聚苯并咪唑/磺化聚亚芳基靛红复合质子交换膜的制备和应用
CN116253673B (zh) * 2023-01-30 2024-10-18 南阳师范学院 一种吲哚类磺化单体、吲哚类磺化聚合物和质子交换膜及其制备方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1202721A (en) * 1967-01-18 1970-08-19 Ici Ltd Polyamides
US3574169A (en) * 1969-12-03 1971-04-06 Us Air Force Arylene sulfimide polymers
US4634530A (en) 1980-09-29 1987-01-06 Celanese Corporation Chemical modification of preformed polybenzimidazole semipermeable membrane
CS242625B1 (en) * 1983-08-04 1986-05-15 Jiri Albrecht Industry filter
US5216114A (en) 1991-02-19 1993-06-01 The Dow Chemical Company Sulfonation of polybenzoxazole and polybenzothiazole for improved adhesion to matrix resins
SG73410A1 (en) 1992-06-13 2000-06-20 Hoechst Ag Polymer electrolyte membrane and process for the production thereof
DE4241150C1 (de) 1992-12-07 1994-06-01 Fraunhofer Ges Forschung Elektrodenmembran-Verbund, Verfahren zu dessen Herstellung sowie dessen Verwendung
US5312895A (en) * 1993-03-12 1994-05-17 The United States Of America As Represented By The Secretary Of The Air Force Benzobisazole copolymer system soluble in aprotic solvents
US5492996A (en) * 1995-02-21 1996-02-20 The United States Of America As Represented By The Secretary Of The Air Force Alcohol soluble benzazole polymers
US5498784A (en) * 1995-02-21 1996-03-12 The United States Of America As Represented By The Secretary Of The Air Force Phosphonic acid-pendent benzoxazole copolymers
US5599639A (en) * 1995-08-31 1997-02-04 Hoechst Celanese Corporation Acid-modified polybenzimidazole fuel cell elements
JP3521579B2 (ja) * 1995-10-18 2004-04-19 Ｊｓｒ株式会社 リン酸基含有重合体
JP4092594B2 (ja) 1996-11-29 2008-05-28 東洋紡績株式会社 微粉状芳香族ジカルボン酸
JP4092516B2 (ja) 1998-04-01 2008-05-28 日産化学工業株式会社 耐熱性含リンポリアミド共重合体
US6176984B1 (en) * 1998-06-29 2001-01-23 Sri International High temperature polybenzazole and polyether electrolytes

Also Published As

Publication number Publication date
US7288603B2 (en) 2007-10-30
DE60117595D1 (de) 2006-04-27
CN100358938C (zh) 2008-01-02
DE60117595T2 (de) 2006-12-21
WO2002038650A1 (en) 2002-05-16
EP1354907A4 (de) 2004-10-27
CN1474844A (zh) 2004-02-11
US20040062969A1 (en) 2004-04-01
EP1354907B1 (de) 2006-03-01
EP1354907A1 (de) 2003-10-22

Similar Documents

Publication Publication Date Title
ATE318854T1 (de) Polybenzazolverbindung mit sulfo- und/oder phosphonogruppe, diese enthaltende harzzusammensetzung, harzformteil, polymerfestelektrolytfolie, verbund aus festelektrolytfolie und elektrodenkatalysatorschicht und verfahren zur herstellung des verbunds
EP1457511A4 (de) Vernetzbare aromatische harze mit protonensäuregruppen und ionenleitende polymermembranen, bindemittel und damit hergestellte brennstoffzellen
KR910007007B1 (ko) 폴리페닐렌 술피드 조성물 및 그 제조방법
CA2454493A1 (en) Method of forming conductive polymeric nanocomposite materials and materials produced thereby
WO2003041091A1 (fr) Membrane conductrice de protons, son procede de production et piles a combustible obtenues au moyen de cette membrane
ATE427972T1 (de) Schmelzverarbeitbare polyetheretherketon polymere
CA2367332A1 (en) Proton-conducting membrane, method for producing the same, and fuel cell using the same
DE602004018380D1 (de) Polymerelektrolyt mit aromatischer sulfonvernetzung
US4868240A (en) Polyarylene thioether of high crystallizing rate and a process for producing the same
JP4337175B2 (ja) 高分子電解質およびイオン交換体
DE60208649D1 (de) Verwendung von Sulfon-, Phosphon- und Phosphor-Säuren als Dotierstoffe von Polyanilinen und aus Polyanilinen leitfähigen Verbundmaterialien
KR101129162B1 (ko) 양성자 전도성 고분자막 및 그의 제조 방법, 및 이를이용한 연료 전지
DE10347530A1 (de) Blockcopolymer und dessen Verwendung
JP4208455B2 (ja) スルホン化フッ素含有重合体、それを含有する樹脂組成物および高分子電解質膜
JP5439812B2 (ja) 電解質膜の製造方法
Huang et al. Blend proton exchange membranes with high performance based on sulfonated poly (arylene ether phosphine oxide) s and poly (vinylidene fluoride)
JP7541682B2 (ja) ポリフルオレン系イオノマーを含む電解質膜およびその製造方法
JP2010006940A (ja) 固体高分子電解質組成物
CN117916218A (zh) 环辛烯-二苯甲酮单体、以及阳离子聚合物、交联聚电解质、复合材料、膜、电极和由此制备的电化学装置，例如电解槽
KR100590556B1 (ko) 프로톤 전도성 전해질 및 이를 이용한 연료전지
CN101400721A (zh) 聚酰亚胺固化的催化
CN103143267A (zh) 聚砜/聚氨酯/聚氯乙烯共混中空纤维分离膜的制备方法
JP2004263051A (ja) 架橋ポリアリーレンエーテルスルホン
JPS5837024A (ja) 気体分離用複合膜
JPS63156856A (ja) ポリアミド樹脂成形物

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties