ATE332330T1 - Thermisch ausdehnbare mikroteilchen und verfahren zu ihrer herstellung - Google Patents
Thermisch ausdehnbare mikroteilchen und verfahren zu ihrer herstellungInfo
- Publication number
- ATE332330T1 ATE332330T1 AT01917780T AT01917780T ATE332330T1 AT E332330 T1 ATE332330 T1 AT E332330T1 AT 01917780 T AT01917780 T AT 01917780T AT 01917780 T AT01917780 T AT 01917780T AT E332330 T1 ATE332330 T1 AT E332330T1
- Authority
- AT
- Austria
- Prior art keywords
- production
- thermally expandable
- weight
- monomer
- expandable microparticles
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000011859 microparticle Substances 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 5
- 239000004005 microsphere Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 238000010557 suspension polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/20—Making expandable particles by suspension polymerisation in the presence of the blowing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/08—Homopolymers or copolymers of vinylidene chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
- Y10T428/2987—Addition polymer from unsaturated monomers only
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000131859 | 2000-04-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE332330T1 true ATE332330T1 (de) | 2006-07-15 |
Family
ID=18640677
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT01917780T ATE332330T1 (de) | 2000-04-28 | 2001-04-02 | Thermisch ausdehnbare mikroteilchen und verfahren zu ihrer herstellung |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7232607B2 (de) |
| EP (1) | EP1288272B2 (de) |
| KR (1) | KR100716484B1 (de) |
| CN (1) | CN1200987C (de) |
| AT (1) | ATE332330T1 (de) |
| DE (1) | DE60121328T3 (de) |
| WO (1) | WO2001083636A1 (de) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6866906B2 (en) | 2000-01-26 | 2005-03-15 | International Paper Company | Cut resistant paper and paper articles and method for making same |
| JP2004536172A (ja) * | 2001-05-25 | 2004-12-02 | アパーチェ・プロダクツ・カンパニー | 発泡体断熱のための膨張性ミクロスフェアおよび方法 |
| JP5044074B2 (ja) | 2001-06-11 | 2012-10-10 | 株式会社クレハ | 熱発泡性マイクロスフェアー及びその製造方法 |
| JP2003001099A (ja) * | 2001-06-21 | 2003-01-07 | Sekisui Chem Co Ltd | 熱膨張性マイクロカプセルの製造方法 |
| ES2347993T3 (es) | 2002-09-13 | 2010-11-26 | International Paper Company | Papel con rigidez y cuerpo mejorados y método para fabricarlo campo de aplicación de la invención. |
| JP2004155999A (ja) * | 2002-11-08 | 2004-06-03 | Sekisui Chem Co Ltd | 熱膨張性マイクロカプセル |
| EP1598405B1 (de) | 2003-02-24 | 2014-10-01 | Matsumoto Yushi-Seiyaku Co., Ltd. | Wärmeexpandierbare mikrokugel, deren herstellung und verwendung |
| EP1687343B1 (de) * | 2003-08-04 | 2014-07-23 | Matrix Innovation Inc. | Neue polyetherbasierte monomere und hochvernetzte amphiphile harze |
| CN1882638B (zh) * | 2003-11-19 | 2010-05-05 | 松本油脂制药株式会社 | 已热膨胀的微球体及其制造方法、热膨胀性微球体以及用途 |
| WO2006030946A1 (ja) * | 2004-09-13 | 2006-03-23 | Kureha Corporation | 熱発泡性マイクロスフェアー、その製造方法、その使用、それを含む組成物、及び物品 |
| US20060131362A1 (en) * | 2004-12-22 | 2006-06-22 | Akzo Nobel N.V. | Chemical composition and process |
| EP1857519A4 (de) * | 2005-02-07 | 2012-12-26 | Kureha Corp | Thermisch aufschäumbare mikrokugel, herstellungsverfahren dafür sowie zusammensetzung |
| CA2600801C (en) | 2005-03-11 | 2012-07-10 | International Paper Company | Compositions containing expandable microspheres and an ionic compound, as well as methods of making and using the same |
| EP1953184B1 (de) * | 2005-09-16 | 2018-08-01 | Matsumoto Yushi-Seiyaku Co., Ltd. | Thermisch expandierte mikrokugel und herstellungsverfahren dafür |
| CN101291958B (zh) * | 2005-10-20 | 2010-12-08 | 松本油脂制药株式会社 | 热膨胀性微球及其制造方法 |
| EP1964903B1 (de) * | 2005-12-19 | 2017-03-22 | Kureha Corporation | Wärmeexpandierbare mikrokugeln, ihre herstellung und ihre verwendung |
| WO2007091961A1 (en) * | 2006-02-10 | 2007-08-16 | Akzo Nobel N.V. | Microspheres |
| US8388809B2 (en) | 2006-02-10 | 2013-03-05 | Akzo Nobel N.V. | Microspheres |
| JP5448459B2 (ja) * | 2006-02-10 | 2014-03-19 | アクゾ ノーベル ナムローゼ フェンノートシャップ | 微小球 |
| US7956096B2 (en) * | 2006-02-10 | 2011-06-07 | Akzo Nobel N.V. | Microspheres |
| US20070287776A1 (en) * | 2006-06-08 | 2007-12-13 | Akzo Nobel N.V. | Microspheres |
| PL2026902T3 (pl) * | 2006-06-08 | 2017-02-28 | Akzo Nobel N.V. | Mikrosfery |
| KR101217865B1 (ko) * | 2006-10-17 | 2013-01-03 | 주식회사 제이앤드제이 캐미칼 | 발포제 개질 방법 |
| JP2010511798A (ja) | 2006-12-01 | 2010-04-15 | アクゾ ノーベル ナムローゼ フェンノートシャップ | 包装材積層体 |
| KR20110018447A (ko) | 2008-06-17 | 2011-02-23 | 아크조 노벨 엔.브이. | 셀룰로스계 제품 |
| CN102137878B (zh) | 2008-08-28 | 2014-06-18 | 国际纸业公司 | 可膨胀微球及其制造和使用方法 |
| WO2010072663A1 (en) | 2008-12-22 | 2010-07-01 | Akzo Nobel N.V. | Microspheres |
| CN101486801B (zh) * | 2008-12-30 | 2012-05-30 | 浙江华峰新材料股份有限公司 | 添加热发泡性微球的低密度聚氨酯微孔弹性体及其制备方法 |
| DE102009016404A1 (de) | 2009-04-07 | 2010-10-21 | Evonik Stockhausen Gmbh | Verwendung von Hohlkörpern zur Herstellung wasserabsorbierender Polymergebilde |
| US9126178B2 (en) * | 2009-06-09 | 2015-09-08 | Matsumoto Yushi-Seiyaku Co., Ltd. | Heat-expandable microspheres and a method of making heat-expandable microspheres and application thereof |
| EP2526463B1 (de) | 2010-01-22 | 2016-07-13 | DSM IP Assets B.V. | Verfahren zur herstellung eines dreidimensionalen artikels mit selektiven visuellen effekten |
| ES2600077T3 (es) | 2012-04-27 | 2017-02-07 | Compagnie Gervais Danone | Artículo que comprende ácido poliláctico espumado y proceso para fabricarlo |
| CN104334268B (zh) | 2012-05-30 | 2017-03-01 | 阿克佐诺贝尔化学国际公司 | 微球 |
| EP2671716A1 (de) | 2012-06-08 | 2013-12-11 | Hexcel Composites SASU | Verbundstoffmaterialien mit geringer Dichte, deren Herstellung und Verwendung |
| CN102702449B (zh) * | 2012-06-13 | 2013-09-18 | 福建省锦浪精细化工有限公司 | 一种耐热性发泡微胶囊的制备方法 |
| WO2014037361A1 (en) | 2012-09-07 | 2014-03-13 | Akzo Nobel Chemicals International B.V. | A method and a device for preparation of expanded thermoplastic microspheres |
| AU2014280422C1 (en) * | 2013-06-12 | 2017-05-04 | Sicpa Holding Sa | Heat sensitive tamper indicating markings |
| US10030115B2 (en) | 2013-10-24 | 2018-07-24 | Matsumoto Yushi-Seiyaku Co., Ltd. | Heat-expandable microspheres, process for producing the same, and application thereof |
| WO2016093220A1 (ja) | 2014-12-08 | 2016-06-16 | 株式会社クレハ | 熱発泡性マイクロスフェアー、並びにそれを含む組成物及び成形体 |
| WO2016091847A1 (en) | 2014-12-11 | 2016-06-16 | Akzo Nobel Chemicals International B.V. | Apparatus and method for expanding thermally expandable thermoplastic microspheres to expanded thermoplastic microspheres |
| DE102015200875A1 (de) * | 2015-01-20 | 2016-08-04 | Volkswagen Aktiengesellschaft | Verfahren zur Herstellung eines naturfaserverstärkten Kunststoffbauteils |
| KR20170102982A (ko) * | 2015-03-30 | 2017-09-12 | 가부시끼가이샤 구레하 | 열발포성 마이크로스피어 |
| US10731021B2 (en) | 2015-06-29 | 2020-08-04 | Matsumoto Yushi-Seiyaku Co., Ltd. | Process for producing heat-expandable microspheres and application thereof |
| CN104962225A (zh) * | 2015-07-07 | 2015-10-07 | 东方电气集团东方汽轮机有限公司 | 一种制造风能叶片用环氧胶黏剂 |
| CN105396524B (zh) * | 2015-08-07 | 2018-04-24 | 西能化工科技(上海)有限公司 | 一种已膨胀微球发泡剂制备装置 |
| US10640580B2 (en) * | 2015-12-22 | 2020-05-05 | Ddp Specialty Electronic Materials Us 8, Llc | Method of suspension polymerization of droplets distributed in an aqueous medium |
| JP6889177B2 (ja) * | 2016-04-12 | 2021-06-18 | クローダ インターナショナル パブリック リミティド カンパニー | マイクロカプセル |
| GB2558971A (en) | 2016-12-16 | 2018-07-25 | Formformform Ltd | Silicone elastomer composition |
| CN108003577B (zh) * | 2017-12-22 | 2020-06-02 | 重庆纳研新材料科技有限公司 | 一种可降解闭孔发泡材料及其制备方法 |
| JP7377213B2 (ja) | 2018-04-05 | 2023-11-09 | ヌーリオン ケミカルズ インターナショナル ベスローテン フェノーツハップ | 膨張したマイクロスフェアの調製のための装置 |
| EP3628710A1 (de) | 2018-09-26 | 2020-04-01 | Holland Novochem Technical Coatings B.V. | Beschichtungszusammensetzung |
| JP7616997B2 (ja) | 2018-12-05 | 2025-01-17 | サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ | 発泡性の、貯蔵安定なポリマービーズ |
| EP3816143B1 (de) | 2019-10-30 | 2023-07-26 | Alloy Surfaces Company, Inc. | Pyrophore pellets, die infrarotstrahlung emittieren |
| KR102860849B1 (ko) | 2020-05-20 | 2025-09-16 | 누리온 케미칼즈 인터내셔널 비.브이. | 낮은 팽창 온도를 갖는 열 팽창성 셀룰로오스계 미소구체 |
| JP7279210B2 (ja) * | 2020-08-25 | 2023-05-22 | 浙江衢州巨塑化工有限公司 | 熱膨張性ポリ塩化ビニリデンミクロスフェア |
| CN113121740B (zh) * | 2021-04-09 | 2022-11-04 | 万华化学(四川)有限公司 | 一种用于制备高白度abs树脂的聚丁二烯胶乳及其制备方法和用途 |
| KR20250149178A (ko) | 2023-02-17 | 2025-10-15 | 누리온 케미칼즈 인터내셔널 비.브이. | 패키지 재료 및 그 재료의 제조 방법 |
| EP4739483A1 (de) | 2023-07-06 | 2026-05-13 | Cellofibers Sweden Ab | Material für eine verpackung und verfahren zur herstellung eines solchen materials |
| SE547856C2 (en) | 2024-04-03 | 2025-12-09 | Grafoam Ab | Nanomaterial for strength and durability improvment of cementitious materials |
| EP4736999A1 (de) | 2024-10-31 | 2026-05-06 | Nouryon Chemicals International B.V. | Vorrichtung zur herstellung von expandierten mikrosphären |
| CN122011346B (zh) * | 2026-04-15 | 2026-06-30 | 同光(昆山)生物科技有限公司 | 一种交联型聚酯微球的制备方法、交联型聚酯微球及其应用 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL302030A (de) | 1962-12-21 | 1900-01-01 | ||
| JPS6021770B2 (ja) † | 1980-02-14 | 1985-05-29 | 松本油脂製薬株式会社 | 熱膨張性マイクロカプセルの製造法 |
| JPS62286534A (ja) | 1986-06-04 | 1987-12-12 | Matsumoto Yushi Seiyaku Kk | 熱膨張性マイクロカプセルの製造法 |
| US4722943A (en) † | 1987-03-19 | 1988-02-02 | Pierce & Stevens Corporation | Composition and process for drying and expanding microspheres |
| JP2927933B2 (ja) † | 1990-11-09 | 1999-07-28 | 松本油脂製薬株式会社 | 中空微粒子組成物 |
| JP3659979B2 (ja) | 1992-04-15 | 2005-06-15 | 松本油脂製薬株式会社 | 熱膨張性マイクロカプセルとその製法 |
| JP3186835B2 (ja) | 1992-05-28 | 2001-07-11 | 松本油脂製薬株式会社 | 熱膨張性マイクロカプセルおよびその製法と膨張方法 |
| SE500077C2 (sv) * | 1992-06-03 | 1994-04-11 | Casco Nobel Ab | Plastisolbaserad beläggningskomposition, förfarande för sprutbeläggning av en yta samt användning av beläggningskompositionen som beläggningsmassa på bilar |
| US5753156A (en) † | 1993-12-28 | 1998-05-19 | Dainichiseika Color & Chemicals Mfg. Co., Ltd. | Process for producing non-scattering hollow plastic balloons |
| JP2894990B2 (ja) | 1996-06-14 | 1999-05-24 | 松本油脂製薬株式会社 | 耐熱性と耐溶剤性に優れた熱膨張性マイクロカプセル |
| JPH1160868A (ja) | 1997-08-19 | 1999-03-05 | Chisso Corp | 発泡押出し成形用塩化ビニル系樹脂組成物 |
| KR100562729B1 (ko) * | 1998-01-26 | 2006-03-20 | 가부시끼가이샤 구레하 | 발포성 마이크로스페어 및 그 제조방법 |
| JP4172871B2 (ja) | 1998-02-24 | 2008-10-29 | 松本油脂製薬株式会社 | 熱膨張性マイクロカプセルとその製造方法 |
| JP4460768B2 (ja) | 1998-02-24 | 2010-05-12 | 松本油脂製薬株式会社 | 熱膨張性マイクロカプセルとその製造方法及びその利用方法 |
| JP4047460B2 (ja) | 1998-07-02 | 2008-02-13 | リケンテクノス株式会社 | 熱膨張性マイクロカプセル含有樹脂組成物の製造方法 |
| JP3055622B2 (ja) * | 1998-11-27 | 2000-06-26 | 横浜ゴム株式会社 | 氷上性能を高めたタイヤトレッド用ゴム組成物及びそれを用いた空気入りタイヤ |
-
2001
- 2001-04-02 WO PCT/JP2001/002854 patent/WO2001083636A1/ja not_active Ceased
- 2001-04-02 AT AT01917780T patent/ATE332330T1/de not_active IP Right Cessation
- 2001-04-02 US US10/258,790 patent/US7232607B2/en not_active Expired - Fee Related
- 2001-04-02 DE DE60121328.9T patent/DE60121328T3/de not_active Expired - Lifetime
- 2001-04-02 CN CNB018087213A patent/CN1200987C/zh not_active Expired - Fee Related
- 2001-04-02 EP EP01917780.7A patent/EP1288272B2/de not_active Expired - Lifetime
- 2001-04-02 KR KR1020027014381A patent/KR100716484B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US7232607B2 (en) | 2007-06-19 |
| EP1288272A4 (de) | 2004-06-23 |
| EP1288272B2 (de) | 2016-04-13 |
| CN1426444A (zh) | 2003-06-25 |
| DE60121328T3 (de) | 2016-09-15 |
| WO2001083636A1 (en) | 2001-11-08 |
| CN1200987C (zh) | 2005-05-11 |
| EP1288272B1 (de) | 2006-07-05 |
| DE60121328T2 (de) | 2007-06-28 |
| US20030143399A1 (en) | 2003-07-31 |
| KR20020091247A (ko) | 2002-12-05 |
| DE60121328D1 (de) | 2006-08-17 |
| KR100716484B1 (ko) | 2007-05-10 |
| EP1288272A1 (de) | 2003-03-05 |
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