ATE332330T1 - Thermisch ausdehnbare mikroteilchen und verfahren zu ihrer herstellung - Google Patents
Thermisch ausdehnbare mikroteilchen und verfahren zu ihrer herstellungInfo
- Publication number
- ATE332330T1 ATE332330T1 AT01917780T AT01917780T ATE332330T1 AT E332330 T1 ATE332330 T1 AT E332330T1 AT 01917780 T AT01917780 T AT 01917780T AT 01917780 T AT01917780 T AT 01917780T AT E332330 T1 ATE332330 T1 AT E332330T1
- Authority
- AT
- Austria
- Prior art keywords
- production
- thermally expandable
- weight
- monomer
- expandable microparticles
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000011859 microparticle Substances 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 5
- 239000004005 microsphere Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 238000010557 suspension polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/20—Making expandable particles by suspension polymerisation in the presence of the blowing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/08—Homopolymers or copolymers of vinylidene chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
- Y10T428/2987—Addition polymer from unsaturated monomers only
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000131859 | 2000-04-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE332330T1 true ATE332330T1 (de) | 2006-07-15 |
Family
ID=18640677
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT01917780T ATE332330T1 (de) | 2000-04-28 | 2001-04-02 | Thermisch ausdehnbare mikroteilchen und verfahren zu ihrer herstellung |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7232607B2 (de) |
| EP (1) | EP1288272B2 (de) |
| KR (1) | KR100716484B1 (de) |
| CN (1) | CN1200987C (de) |
| AT (1) | ATE332330T1 (de) |
| DE (1) | DE60121328T3 (de) |
| WO (1) | WO2001083636A1 (de) |
Families Citing this family (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6866906B2 (en) | 2000-01-26 | 2005-03-15 | International Paper Company | Cut resistant paper and paper articles and method for making same |
| AU2002303871A1 (en) * | 2001-05-25 | 2002-12-09 | Apache Products Company | Foam insulation made with expandable microspheres and methods |
| JP5044074B2 (ja) | 2001-06-11 | 2012-10-10 | 株式会社クレハ | 熱発泡性マイクロスフェアー及びその製造方法 |
| JP2003001099A (ja) * | 2001-06-21 | 2003-01-07 | Sekisui Chem Co Ltd | 熱膨張性マイクロカプセルの製造方法 |
| RU2387752C2 (ru) | 2002-09-13 | 2010-04-27 | Интернэшнл Пейпер Компани | Бумага с улучшенной жесткостью и пухлостью и способ для ее изготовления |
| JP2004155999A (ja) * | 2002-11-08 | 2004-06-03 | Sekisui Chem Co Ltd | 熱膨張性マイクロカプセル |
| JP4362474B2 (ja) | 2003-02-24 | 2009-11-11 | 松本油脂製薬株式会社 | 熱膨張性微小球、その製造方法およびその使用方法 |
| US7842767B2 (en) | 2003-08-04 | 2010-11-30 | Matrix Innovation Inc. | Polyether based monomers and highly cross-linked amphiphile resins |
| US7807729B2 (en) * | 2003-11-19 | 2010-10-05 | Matsumoto Yushi-Seiyaku Co., Ltd. | Heat-expanded microspheres, production process thereof, heat-expandable microspheres and application thereof |
| CN100566811C (zh) * | 2004-09-13 | 2009-12-09 | 株式会社吴羽 | 热发泡性微球及其制造方法、其用途、含有其的组合物、和物品 |
| US20060131362A1 (en) * | 2004-12-22 | 2006-06-22 | Akzo Nobel N.V. | Chemical composition and process |
| CN101115816B (zh) * | 2005-02-07 | 2010-06-09 | 株式会社吴羽 | 热发泡性微球和其制造方法及组合物 |
| JP5302670B2 (ja) | 2005-03-11 | 2013-10-02 | インターナショナル・ペーパー・カンパニー | 膨張可能な微小球体とイオン性化合物とを含有する組成物、およびこれらの組成物の製造法と使用法 |
| WO2007032436A1 (ja) * | 2005-09-16 | 2007-03-22 | Matsumoto Yushi-Seiyaku Co., Ltd. | 熱膨張した微小球およびその製造方法 |
| WO2007046273A1 (ja) * | 2005-10-20 | 2007-04-26 | Matsumoto Yushi-Seiyaku Co., Ltd. | 熱膨張性微小球およびその製造方法 |
| CN101341227B (zh) * | 2005-12-19 | 2012-05-30 | 株式会社吴羽 | 热发泡性微球及其制造方法和用途 |
| US7956096B2 (en) | 2006-02-10 | 2011-06-07 | Akzo Nobel N.V. | Microspheres |
| JP5438324B2 (ja) * | 2006-02-10 | 2014-03-12 | アクゾ ノーベル ナムローゼ フェンノートシャップ | 微小球 |
| US8388809B2 (en) | 2006-02-10 | 2013-03-05 | Akzo Nobel N.V. | Microspheres |
| BRPI0707628B1 (pt) * | 2006-02-10 | 2021-10-19 | Akzo Nobel Chemicals International B.V. | Microesferas termoplásticas termicamente expansíveis, processo para a produção de microesferas termicamente expansíveis, pasta fluida aquosa, usos de microesferas termicamente expansíveis, e processo para a produção de papel |
| KR101482048B1 (ko) * | 2006-06-08 | 2015-01-13 | 아크조 노벨 엔.브이. | 미소구체 |
| US20070287776A1 (en) * | 2006-06-08 | 2007-12-13 | Akzo Nobel N.V. | Microspheres |
| KR101217865B1 (ko) * | 2006-10-17 | 2013-01-03 | 주식회사 제이앤드제이 캐미칼 | 발포제 개질 방법 |
| US20100047404A1 (en) | 2006-12-01 | 2010-02-25 | Akzo Nobel N.V. | Packaging laminate |
| RU2011101414A (ru) | 2008-06-17 | 2012-07-27 | Акцо Нобель Н.В. (NL) | Целлюлозный продукт |
| CN102137878B (zh) | 2008-08-28 | 2014-06-18 | 国际纸业公司 | 可膨胀微球及其制造和使用方法 |
| EP2367618A1 (de) | 2008-12-22 | 2011-09-28 | Akzo Nobel N.V. | Mikrokugeln |
| CN101486801B (zh) * | 2008-12-30 | 2012-05-30 | 浙江华峰新材料股份有限公司 | 添加热发泡性微球的低密度聚氨酯微孔弹性体及其制备方法 |
| DE102009016404A1 (de) | 2009-04-07 | 2010-10-21 | Evonik Stockhausen Gmbh | Verwendung von Hohlkörpern zur Herstellung wasserabsorbierender Polymergebilde |
| JP4677058B2 (ja) * | 2009-06-09 | 2011-04-27 | 松本油脂製薬株式会社 | 熱膨張性微小球、その製造方法および用途 |
| JP5866686B2 (ja) | 2010-01-22 | 2016-02-17 | ディーエスエム アイピー アセッツ ビー.ブイ. | 選択的視覚効果を有して層状に硬化可能な液状放射線硬化性樹脂およびその使用方法 |
| ES2600077T3 (es) | 2012-04-27 | 2017-02-07 | Compagnie Gervais Danone | Artículo que comprende ácido poliláctico espumado y proceso para fabricarlo |
| JP6043427B2 (ja) | 2012-05-30 | 2016-12-14 | アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップAkzo Nobel Chemicals International B.V. | 微小球体 |
| EP2671716A1 (de) | 2012-06-08 | 2013-12-11 | Hexcel Composites SASU | Verbundstoffmaterialien mit geringer Dichte, deren Herstellung und Verwendung |
| CN102702449B (zh) * | 2012-06-13 | 2013-09-18 | 福建省锦浪精细化工有限公司 | 一种耐热性发泡微胶囊的制备方法 |
| ES2602909T3 (es) | 2012-09-07 | 2017-02-22 | Akzo Nobel Chemicals International B.V. | Método y dispositivo para la preparación de microesferas termoplásticas expandidas |
| CA2913856A1 (en) * | 2013-06-12 | 2014-12-18 | Sicpa Holding Sa | Heat sensitive tamper indicating markings |
| SE540663C2 (en) | 2013-10-24 | 2018-10-09 | Matsumoto Yushi Seiyaku Kk | Thermally expandable microspheres and method for producing the same and use thereof |
| WO2016093220A1 (ja) | 2014-12-08 | 2016-06-16 | 株式会社クレハ | 熱発泡性マイクロスフェアー、並びにそれを含む組成物及び成形体 |
| US10214624B2 (en) | 2014-12-11 | 2019-02-26 | Akzo Nobel Chemicals International B.V. | Apparatus and method for expanding thermally expandable thermoplastic microspheres to expanded thermoplastic microspheres |
| DE102015200875A1 (de) * | 2015-01-20 | 2016-08-04 | Volkswagen Aktiengesellschaft | Verfahren zur Herstellung eines naturfaserverstärkten Kunststoffbauteils |
| JP6419948B2 (ja) * | 2015-03-30 | 2018-11-07 | 株式会社クレハ | 熱発泡性マイクロスフェアー |
| CN107735171B (zh) * | 2015-06-29 | 2020-12-18 | 松本油脂制药株式会社 | 热膨胀性微球的制造方法及其利用 |
| CN104962225A (zh) * | 2015-07-07 | 2015-10-07 | 东方电气集团东方汽轮机有限公司 | 一种制造风能叶片用环氧胶黏剂 |
| CN105396524B (zh) * | 2015-08-07 | 2018-04-24 | 西能化工科技(上海)有限公司 | 一种已膨胀微球发泡剂制备装置 |
| CN108367254B (zh) * | 2015-12-22 | 2021-08-24 | 罗门哈斯公司 | 悬浮聚合分布在水性介质中的液滴的方法 |
| CN108883386A (zh) * | 2016-04-12 | 2018-11-23 | 禾大国际股份公开有限公司 | 微胶囊 |
| GB2558971A (en) | 2016-12-16 | 2018-07-25 | Formformform Ltd | Silicone elastomer composition |
| CN108003577B (zh) * | 2017-12-22 | 2020-06-02 | 重庆纳研新材料科技有限公司 | 一种可降解闭孔发泡材料及其制备方法 |
| PL3774259T3 (pl) | 2018-04-05 | 2022-12-27 | Nouryon Chemicals International B.V. | Urządzenie i sposób przygotowania rozszerzonych mikrosfer |
| EP3628710A1 (de) | 2018-09-26 | 2020-04-01 | Holland Novochem Technical Coatings B.V. | Beschichtungszusammensetzung |
| EP3898800A1 (de) | 2018-12-05 | 2021-10-27 | SABIC Global Technologies B.V. | Verhinderung von sichtbarer partikelbildung in wässrigen proteinlösungen |
| EP3816143B1 (de) | 2019-10-30 | 2023-07-26 | Alloy Surfaces Company, Inc. | Pyrophore pellets, die infrarotstrahlung emittieren |
| WO2021234010A1 (en) | 2020-05-20 | 2021-11-25 | Nouryon Chemicals International B.V. | Thermally expandable cellulose-based microspheres having low expansion temperatures |
| US12428536B2 (en) | 2020-08-25 | 2025-09-30 | Zhejiang Quzhou Jusu Chemical Industry Co., Ltd | Heat-expandable polyvinylidene chloride microsphere and its preparation method |
| CN113121740B (zh) * | 2021-04-09 | 2022-11-04 | 万华化学(四川)有限公司 | 一种用于制备高白度abs树脂的聚丁二烯胶乳及其制备方法和用途 |
| CN120917088A (zh) | 2023-02-17 | 2025-11-07 | 诺力昂化学品国际有限公司 | 包装材料及其制造方法 |
| WO2025008196A1 (en) | 2023-07-06 | 2025-01-09 | Cellofibers Sweden Ab | A material useful for a package and a method for making such material |
| SE547856C2 (en) | 2024-04-03 | 2025-12-09 | Grafoam Ab | Nanomaterial for strength and durability improvment of cementitious materials |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL302030A (de) | 1962-12-21 | 1900-01-01 | ||
| JPS6021770B2 (ja) † | 1980-02-14 | 1985-05-29 | 松本油脂製薬株式会社 | 熱膨張性マイクロカプセルの製造法 |
| JPS62286534A (ja) | 1986-06-04 | 1987-12-12 | Matsumoto Yushi Seiyaku Kk | 熱膨張性マイクロカプセルの製造法 |
| US4722943A (en) † | 1987-03-19 | 1988-02-02 | Pierce & Stevens Corporation | Composition and process for drying and expanding microspheres |
| JP2927933B2 (ja) | 1990-11-09 | 1999-07-28 | 松本油脂製薬株式会社 | 中空微粒子組成物 |
| JP3659979B2 (ja) * | 1992-04-15 | 2005-06-15 | 松本油脂製薬株式会社 | 熱膨張性マイクロカプセルとその製法 |
| JP3186835B2 (ja) | 1992-05-28 | 2001-07-11 | 松本油脂製薬株式会社 | 熱膨張性マイクロカプセルおよびその製法と膨張方法 |
| SE500077C2 (sv) * | 1992-06-03 | 1994-04-11 | Casco Nobel Ab | Plastisolbaserad beläggningskomposition, förfarande för sprutbeläggning av en yta samt användning av beläggningskompositionen som beläggningsmassa på bilar |
| US5753156A (en) † | 1993-12-28 | 1998-05-19 | Dainichiseika Color & Chemicals Mfg. Co., Ltd. | Process for producing non-scattering hollow plastic balloons |
| JP2894990B2 (ja) | 1996-06-14 | 1999-05-24 | 松本油脂製薬株式会社 | 耐熱性と耐溶剤性に優れた熱膨張性マイクロカプセル |
| JPH1160868A (ja) | 1997-08-19 | 1999-03-05 | Chisso Corp | 発泡押出し成形用塩化ビニル系樹脂組成物 |
| CA2320966A1 (en) † | 1998-01-26 | 1999-07-29 | Kureha Chemical Industry Company, Limited | Expandable microspheres and process for producing the same |
| US6235394B1 (en) | 1998-02-24 | 2001-05-22 | Matsumoto Yushi-Seiyaku Co., Ltd. | Heat-expandable microcapsules, process for producing the same, and method of utilizing the same |
| JP4172871B2 (ja) * | 1998-02-24 | 2008-10-29 | 松本油脂製薬株式会社 | 熱膨張性マイクロカプセルとその製造方法 |
| JP4047460B2 (ja) | 1998-07-02 | 2008-02-13 | リケンテクノス株式会社 | 熱膨張性マイクロカプセル含有樹脂組成物の製造方法 |
| JP3055622B2 (ja) * | 1998-11-27 | 2000-06-26 | 横浜ゴム株式会社 | 氷上性能を高めたタイヤトレッド用ゴム組成物及びそれを用いた空気入りタイヤ |
-
2001
- 2001-04-02 DE DE60121328.9T patent/DE60121328T3/de not_active Expired - Lifetime
- 2001-04-02 CN CNB018087213A patent/CN1200987C/zh not_active Expired - Fee Related
- 2001-04-02 KR KR1020027014381A patent/KR100716484B1/ko not_active Expired - Fee Related
- 2001-04-02 WO PCT/JP2001/002854 patent/WO2001083636A1/ja not_active Ceased
- 2001-04-02 AT AT01917780T patent/ATE332330T1/de not_active IP Right Cessation
- 2001-04-02 EP EP01917780.7A patent/EP1288272B2/de not_active Expired - Lifetime
- 2001-04-02 US US10/258,790 patent/US7232607B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE60121328T3 (de) | 2016-09-15 |
| KR100716484B1 (ko) | 2007-05-10 |
| CN1426444A (zh) | 2003-06-25 |
| US20030143399A1 (en) | 2003-07-31 |
| DE60121328T2 (de) | 2007-06-28 |
| EP1288272B1 (de) | 2006-07-05 |
| US7232607B2 (en) | 2007-06-19 |
| EP1288272B2 (de) | 2016-04-13 |
| KR20020091247A (ko) | 2002-12-05 |
| EP1288272A4 (de) | 2004-06-23 |
| WO2001083636A1 (en) | 2001-11-08 |
| CN1200987C (zh) | 2005-05-11 |
| EP1288272A1 (de) | 2003-03-05 |
| DE60121328D1 (de) | 2006-08-17 |
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