ATE346688T1 - Carbonylierungskatalysator auf einen träger aus einen karbunisiert persulfoniert styrol- divinylbenzolcopolymer - Google Patents

Carbonylierungskatalysator auf einen träger aus einen karbunisiert persulfoniert styrol- divinylbenzolcopolymer

Info

Publication number
ATE346688T1
ATE346688T1 AT01916574T AT01916574T ATE346688T1 AT E346688 T1 ATE346688 T1 AT E346688T1 AT 01916574 T AT01916574 T AT 01916574T AT 01916574 T AT01916574 T AT 01916574T AT E346688 T1 ATE346688 T1 AT E346688T1
Authority
AT
Austria
Prior art keywords
styrene
carbunized
persulfonated
support made
divinylbenzene copolymer
Prior art date
Application number
AT01916574T
Other languages
English (en)
Inventor
Joseph Robert Zoeller
Andy Hugh Singleton
Gerald Charles Tustin
Donald Lee Carver
Original Assignee
Eastman Chem Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chem Co filed Critical Eastman Chem Co
Application granted granted Critical
Publication of ATE346688T1 publication Critical patent/ATE346688T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/468—Iridium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
AT01916574T 2000-04-05 2001-03-12 Carbonylierungskatalysator auf einen träger aus einen karbunisiert persulfoniert styrol- divinylbenzolcopolymer ATE346688T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/543,772 US6235673B1 (en) 2000-04-05 2000-04-05 Carbonylation catalyst supported on a carbonized polysulfonated divinylbenzene-styrene copolymer

Publications (1)

Publication Number Publication Date
ATE346688T1 true ATE346688T1 (de) 2006-12-15

Family

ID=24169503

Family Applications (1)

Application Number Title Priority Date Filing Date
AT01916574T ATE346688T1 (de) 2000-04-05 2001-03-12 Carbonylierungskatalysator auf einen träger aus einen karbunisiert persulfoniert styrol- divinylbenzolcopolymer

Country Status (8)

Country Link
US (1) US6235673B1 (de)
EP (1) EP1268061B1 (de)
JP (1) JP2003530218A (de)
CN (1) CN1196528C (de)
AT (1) ATE346688T1 (de)
BR (1) BR0109620A (de)
DE (1) DE60124878T2 (de)
WO (1) WO2001077053A2 (de)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6452043B1 (en) * 2000-04-05 2002-09-17 Eastman Chemical Company Carbonylation of lower alkyl alcohols and their derivatives using metals supported on carbonized polysulfonated divinylbenzene-styrene copolymers
US6509293B1 (en) * 2000-05-22 2003-01-21 Eastman Chemical Company Gold based heterogeneous carbonylation catalysts
US6586650B2 (en) * 2000-07-21 2003-07-01 Exxonmobil Research And Engineering Company Ring opening with group VIII metal catalysts supported on modified substrate
US6903045B2 (en) 2001-06-19 2005-06-07 Eastman Chemical Company Tin promoted platinum catalyst for carbonylation of lower alkyl alcohols
US6537944B1 (en) 2001-06-20 2003-03-25 Eastman Chemical Company Tungsten promoted catalyst for carbonylation of lower alkyl alcohols
US6548444B2 (en) * 2001-06-20 2003-04-15 Eastman Chemical Company Tin promoted iridium catalyst for carbonylation of lower alkyl alcohols
US6716997B1 (en) 2001-10-09 2004-04-06 Eastman Chemical Company Systems and methods for generation of ascorbic acid with reduced color
US6977314B2 (en) * 2001-12-19 2005-12-20 Rohm And Haas Company Metal-doped sulfonated ion exchange resin catalysts
US7390768B2 (en) * 2002-01-22 2008-06-24 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Stabilized tin-oxide-based oxidation/reduction catalysts
US7318915B2 (en) * 2002-01-25 2008-01-15 United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Oxidation-reduction catalyst and its process of use
CA2477248A1 (en) * 2002-02-25 2003-12-18 Robert A. Sallavanti Multi-functional protective fiber and methods for use
US6911161B2 (en) * 2002-07-02 2005-06-28 Conocophillips Company Stabilized nickel-containing catalysts and process for production of syngas
US20040097371A1 (en) * 2002-11-19 2004-05-20 Juzer Jangbarwala Application of conductive adsorbents, activated carbon granules and carbon fibers as substrates in catalysis
US20050049434A1 (en) * 2003-08-28 2005-03-03 Tustin Gerald Charles Fluidizable carbon catalysts
CN1307133C (zh) * 2004-10-28 2007-03-28 中国石油化工股份有限公司 一种低碳烯烃的叠合反应方法
GB0601863D0 (en) * 2006-01-30 2006-03-08 Bp Chem Int Ltd Process
US20070238610A1 (en) * 2006-04-05 2007-10-11 Laiyuan Chen Fuel reformer catalyst
JP4800902B2 (ja) * 2006-11-06 2011-10-26 エヌ・イーケムキャット株式会社 選択的官能基還元性能を有するPd担持ポリマー触媒
EP1985362A1 (de) * 2007-04-26 2008-10-29 BP Chemicals Limited Verfahren zur Carbonylierung von Dimethylether
EP2199272A1 (de) * 2008-11-27 2010-06-23 BP Chemicals Limited Carbonylierungsverfahren
BRPI1106072A2 (pt) * 2010-02-09 2016-05-03 Chiyoda Corp método para produzir ácido acético, e, veículo a ser usado em um catalisador para a reação de carbonilação de metanol
US9421522B2 (en) * 2011-12-28 2016-08-23 Eastman Chemical Company Iridium catalysts for carbonylation
CN106807367A (zh) * 2015-12-02 2017-06-09 中国科学院大连化学物理研究所 一种碳基材料负载的铱基催化剂及其制备方法和应用
CN106807368A (zh) * 2015-12-02 2017-06-09 中国科学院大连化学物理研究所 一种活性炭负载的铱基催化剂及其制备方法和应用
CN109759086B (zh) * 2017-11-09 2021-11-30 中国科学院大连化学物理研究所 含有助剂的活性炭负载的硫化铁基催化剂及其制备与应用
CN109759085B (zh) * 2017-11-09 2021-11-30 中国科学院大连化学物理研究所 一种活性炭负载的硫化铁基催化剂及其制备与应用
CN109759090B (zh) * 2017-11-09 2021-11-23 中国科学院大连化学物理研究所 活性炭负载的含硫化铁镍的铱基催化剂及其制备与应用
CN114534794A (zh) * 2020-11-24 2022-05-27 中国科学院大连化学物理研究所 一种固体多相催化剂及其制备与应用

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3717670A (en) 1968-08-02 1973-02-20 Monsanto Co Production of carboxylic acids and esters
US3689533A (en) 1971-03-15 1972-09-05 Monsanto Co Production of carboxylic acids and esters
US4040990A (en) * 1975-02-18 1977-08-09 Rohm And Haas Company Partially pyrolyzed macroporous polymer particles having multimodal pore distribution with macropores ranging from 50-100,000 angstroms
US4235744A (en) * 1978-10-30 1980-11-25 Standard Oil Company (Ohio) Carbonylation of olefinically unsaturated compounds
US4328125A (en) 1979-05-14 1982-05-04 University Of Illinois Foundation Heterogeneous anionic transition metal catalysts
US4417077A (en) 1980-10-01 1983-11-22 University Of Illinois Foundation Heterogeneous anionic transition metal catalysts
US4413151A (en) * 1982-07-14 1983-11-01 Exxon Research & Engineering Co. Process for hydroxylating olefins using a supported osmium catalyst
DE3463257D1 (en) 1983-03-25 1987-05-27 Texaco Development Corp A process for producing carboxylic acids by carbonylation of alkanols over a carbon catalyst
US5144068A (en) 1984-05-03 1992-09-01 Hoechst Celanese Corporation Methanol carbonylation process
GB8414767D0 (en) * 1984-06-09 1984-07-11 Bp Chem Int Ltd Catalysis by supported catalysts
DE3660719D1 (en) 1985-03-27 1988-10-20 Hoechst Ag Supported catalyst and procedure for the production of monocarboxylic acid anhydrides
US4667053A (en) * 1986-06-30 1987-05-19 Texaco Inc. Process for oxidative carbonylation using a catalyst having a novel support
US5155261A (en) 1987-02-05 1992-10-13 Reilly Industries, Inc. Process for acetic acid preparation and heterogenous catalyst for same
DE3889233T2 (de) * 1987-02-05 1994-08-11 Reilly Ind Inc Verfahren zur Herstellung von Essigsäure und heterogener Katalysator dafür.
US4839311A (en) 1987-08-14 1989-06-13 National Semiconductor Corporation Etch back detection
JPH01135536A (ja) * 1987-11-19 1989-05-29 Sumitomo Chem Co Ltd 微分散金属担持化合物およびその製法
GB9013116D0 (en) 1990-06-12 1990-08-01 British Petroleum Co Plc Carbonylation of methanol
WO1992004118A1 (en) * 1990-08-31 1992-03-19 The Governors Of The University Of Alberta Carbonylation of methanol using a novel transition metal catalyst precursor
US5300685A (en) * 1991-11-25 1994-04-05 Hoechst Celanese Corporation Removal of halide impurities from organic liquids
DE4215907C2 (de) * 1992-05-14 2003-02-13 Mhb Filtration Gmbh & Co Kg Katalysatoren auf Basis von karbonisierten Ionenaustauschern
US5488143A (en) 1992-06-30 1996-01-30 Korea Institute Of Science And Technology Processes for the carbonylation of methanol to form acetic acid, methyl acetate and acetic anhydride
GB9303770D0 (en) 1993-02-25 1993-04-14 Bp Chem Int Ltd Process
US5672743A (en) * 1993-09-10 1997-09-30 Bp Chemicals Limited Process for the production of acetic acid
US5364963A (en) * 1993-04-30 1994-11-15 Chiyoda Corporation Supported rhodium catalyst, method of preparing same and process of producing acetic acid by methanol carbonylation using same
US5488023A (en) * 1994-08-12 1996-01-30 Corning Incorporated Method of making activated carbon having dispersed catalyst
US5510524A (en) 1995-02-21 1996-04-23 Bp Chemicals Limited Process for the production of a carboxylic acid
US5897915A (en) * 1996-10-28 1999-04-27 Corning Incorporated Coated substrates, method for producing same, and use therefor
GB9626317D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
US5900505A (en) 1997-02-04 1999-05-04 Eastman Chemical Company Heterogeneous vapor phase carbonylation process
US6159896A (en) * 1999-02-16 2000-12-12 Eastman Chemical Company Iridium catalyst for carbonylation of lower aliphatic alcohols
US6452043B1 (en) * 2000-04-05 2002-09-17 Eastman Chemical Company Carbonylation of lower alkyl alcohols and their derivatives using metals supported on carbonized polysulfonated divinylbenzene-styrene copolymers
US6177380B1 (en) * 2000-05-22 2001-01-23 Eastman Chemical Company Iridium-gold carbonylation co-catalysts

Also Published As

Publication number Publication date
EP1268061B1 (de) 2006-11-29
WO2001077053A3 (en) 2002-01-24
DE60124878T2 (de) 2007-09-27
US6235673B1 (en) 2001-05-22
CN1422178A (zh) 2003-06-04
DE60124878D1 (de) 2007-01-11
EP1268061A2 (de) 2003-01-02
CN1196528C (zh) 2005-04-13
WO2001077053A2 (en) 2001-10-18
JP2003530218A (ja) 2003-10-14
BR0109620A (pt) 2003-02-04

Similar Documents

Publication Publication Date Title
DE60124878D1 (de) Carbonylierungskatalysator auf einen träger aus einen karbunisiert persulfoniert styrol-divinylbenzolcopolymer
ID28416A (id) Karbonilasi methanol dengan keberadaan sebuah sistem katalitik ion rhodium, iridium atau iodida
DE60206623D1 (de) Zinn aktivierter platinum katalysator für die karbonylierung von niedrigen aliphatischen alkoholen
TW429162B (en) Polymeric carbonylation catalyst system and carbonylation process using the same
DE60103387D1 (de) Carbonylierung von niedrigen aliphatischen alkoholen und ihre derivate unter verwendung von metallen auf karbonisierten und polysulfonierten divinylbenzol-styrolcopolymeren
DE3862601D1 (de) Katalytische hydrierung von carbonsaeuren und ihre anhydriden zu alkoholen und/oder estern.
AU3567389A (en) The production of alcohols and ethers by the catalysed hydrogenation of esters
ES8206407A1 (es) Procedimiento de hidrocarbonilacion y-o de carbonilacion de carboxilatos de alquilo en medio acuoso
AU6037686A (en) Hydrogenation of carboxylic acid esters to alcohols
JP2002501941A5 (de)
MY146278A (en) Improved catalyst system
UA91994C2 (ru) Каталитическая система для получения уксусной кислоты и способ получения уксусной кислоты
MY122500A (en) Loaded ion- exchange resins, their preparation and uses.
TR200200546T2 (tr) Metanol karbonilasyon işlemi için rodyum/inorganik iyodid katalizatör sistemi
ES2121613T3 (es) Procedimiento para la fabricacion de esteres de acidos carboxilicos de formilo.
DE60036002D1 (de) Verfahren für die herstellung von fettsäureestern
DE60226320D1 (de) Mit zinn gefördertem iridiumkatalysator zur carbonylierung von niedrigen alkylalkoholen
TW200702053A (en) Catalyst and process for preparing carboxylic acid esters
CA2077007A1 (en) Process for the preparation of alcohols
CN201610105U (zh) 叉车倒车警示装置
GB1102224A (en) Dihydro derivatives of vinblastine and related compounds
ES8206423A1 (es) Procedimiento de preparacion de esteres por carbonilacion decompuestos monoolefinicos
MY139572A (en) Process for the production of carbonylation products
FR2317269A1 (fr) Procede de fabrication d'acides et d'esters alcane carboxyliques par reaction d'alcools avec le monoxyde de carbone en presence de catalyseurs contenant de l'iridium
MY121111A (en) Preparation of acetic acid and/or methyl acetate in the presence of iridium and platinum

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties