ATE359249T1 - Oligomerisierung von olefinen mit einem nicht geträgerten preaktivierten festen metallocen katalysator - Google Patents

Oligomerisierung von olefinen mit einem nicht geträgerten preaktivierten festen metallocen katalysator

Info

Publication number
ATE359249T1
ATE359249T1 AT03250014T AT03250014T ATE359249T1 AT E359249 T1 ATE359249 T1 AT E359249T1 AT 03250014 T AT03250014 T AT 03250014T AT 03250014 T AT03250014 T AT 03250014T AT E359249 T1 ATE359249 T1 AT E359249T1
Authority
AT
Austria
Prior art keywords
olefins
unsupported
oligomerization
metallocene catalyst
solid metallocene
Prior art date
Application number
AT03250014T
Other languages
English (en)
Inventor
Vahid Bagheri
Robert E Farritor
Randall J Stolk
Andrew D Overstreet
David Eisenberg
Frederic Grzeszczak
Original Assignee
Ineos Usa Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ineos Usa Llc filed Critical Ineos Usa Llc
Application granted granted Critical
Publication of ATE359249T1 publication Critical patent/ATE359249T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C07C2/34—Metal-hydrocarbon complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT03250014T 2002-01-03 2003-01-02 Oligomerisierung von olefinen mit einem nicht geträgerten preaktivierten festen metallocen katalysator ATE359249T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/037,654 US6680417B2 (en) 2002-01-03 2002-01-03 Oligomerization using a solid, unsupported metallocene catalyst system

Publications (1)

Publication Number Publication Date
ATE359249T1 true ATE359249T1 (de) 2007-05-15

Family

ID=21895537

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03250014T ATE359249T1 (de) 2002-01-03 2003-01-02 Oligomerisierung von olefinen mit einem nicht geträgerten preaktivierten festen metallocen katalysator

Country Status (5)

Country Link
US (1) US6680417B2 (de)
EP (1) EP1325899B1 (de)
AT (1) ATE359249T1 (de)
CA (1) CA2414108C (de)
DE (1) DE60313053T2 (de)

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US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US6869917B2 (en) * 2002-08-16 2005-03-22 Exxonmobil Chemical Patents Inc. Functional fluid lubricant using low Noack volatility base stock fluids
US7294599B2 (en) 2004-06-25 2007-11-13 Chevron Phillips Chemical Co. Acidic activator-supports and catalysts for olefin polymerization
US7148298B2 (en) 2004-06-25 2006-12-12 Chevron Phillips Chemical Company, L.P. Polymerization catalysts for producing polymers with low levels of long chain branching
JP4731181B2 (ja) * 2005-02-21 2011-07-20 出光興産株式会社 不飽和炭化水素化合物の製造方法
JP5368706B2 (ja) * 2005-12-28 2013-12-18 出光興産株式会社 金属加工用潤滑剤
US7517939B2 (en) 2006-02-02 2009-04-14 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching
US7619047B2 (en) 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US7576163B2 (en) 2006-03-31 2009-08-18 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing polymers with low levels of long chain branching
JPWO2010058769A1 (ja) * 2008-11-18 2012-04-19 出光興産株式会社 石油掘削油用基油および石油掘削油組成物
WO2011003047A1 (en) * 2009-07-01 2011-01-06 Conocophillips Company - Ip Services Group Heterogeneous dimerization of alpha-olefins with activated metallocene complexes
US8344196B2 (en) * 2009-07-29 2013-01-01 The United States Of America As Represented By The Secretary Of The Navy Selective isomerization and oligomerization of olefin feedstocks for the production of turbine and diesel fuels
US8987539B1 (en) 2009-07-29 2015-03-24 The United States Of America As Represented By The Secretary Of The Navy Acyclic monoterpenes as biofuels based on linalool and method for making the same
US8912373B2 (en) 2009-07-29 2014-12-16 The United States Of America As Represented By The Secretary Of The Navy Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes
US8969636B2 (en) 2009-07-29 2015-03-03 The United States Of America As Represented By The Secretary Of The Navy Homogeneous metallocene ziegler-natta catalysts for the oligomerization of olefins in aliphatic-hydrocarbon solvents
US9181144B2 (en) * 2009-07-29 2015-11-10 The United States Of America As Represented By The Secretary Of The Navy Diesel and jet fuels based on the oligomerization of butene
US9649626B2 (en) * 2009-07-29 2017-05-16 The United States Of America As Represented By The Secretary Of The Navy Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes
US9266792B2 (en) 2009-07-29 2016-02-23 The United States Of America As Represented By The Secretary Of The Navy Process and apparatus for the selective dimerization of terpenes and alpha-olefin oligomers with a single-stage reactor and a single-stage fractionation system
US9242226B2 (en) 2009-07-29 2016-01-26 The Government Of The United States Of America As Represented By The Secretary Of The Navy Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes
US8395007B2 (en) * 2009-07-29 2013-03-12 The United States Of America As Represented By The Secretary Of The Navy Diesel and jet fuels based on the oligomerization of butene
US8785702B2 (en) 2009-07-29 2014-07-22 The United States Of America As Represented By The Secretary Of The Navy Turbine and diesel fuels and methods for making the same
US8067652B2 (en) * 2009-08-13 2011-11-29 Chemtura Corporation Processes for controlling the viscosity of polyalphaolefins
US9234151B2 (en) 2011-10-10 2016-01-12 Exxonmobil Research And Engineering Company Lubricating compositions
US8664461B2 (en) 2012-03-19 2014-03-04 Exxonmobil Chemical Patents Inc. Catalysts for producing polyalpha-olefins and processes related thereto
WO2013162573A1 (en) * 2012-04-26 2013-10-31 The Government Of The Usa As Represented By The Secretary Of The Navy Diesel and jet fuels based on the oligomerization of butene
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9266793B2 (en) 2012-12-26 2016-02-23 Chevron Phillips Chemical Company Lp Acid-catalyzed olefin oligomerizations
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US20140275664A1 (en) 2013-03-13 2014-09-18 Chevron Phillips Chemical Company Lp Processes for Preparing Low Viscosity Lubricants
EP2986586B1 (de) * 2013-06-28 2018-08-08 Dow Global Technologies LLC Verfahren zur herstellungs eines leicht verzweigten hydrophoben produkts und dessen abgeleitenden tensiden und deren anwendungen
US9303106B1 (en) 2014-10-17 2016-04-05 Chevron Phillips Chemical Company Lp Processes for preparing solid metallocene-based catalyst systems
US11021553B2 (en) 2018-02-12 2021-06-01 Exxonmobil Chemical Patents Inc. Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers
US11084894B2 (en) 2018-02-12 2021-08-10 Exxonmobil Chemical Patents Inc. Catalyst systems and processes for poly alpha-olefin having high vinylidene content
US11078308B2 (en) 2018-02-12 2021-08-03 Exxonmobil Chemical Patents Inc. Processes to produce poly alpha-olefin trimers
CN112912357B (zh) * 2018-09-17 2024-06-04 埃克森美孚化学专利公司 聚α-烯烃三聚物的制备方法和制备设备

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US4752597A (en) 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
US4658078A (en) 1986-08-15 1987-04-14 Shell Oil Company Vinylidene olefin process
JP2618384B2 (ja) 1986-12-27 1997-06-11 三井石油化学工業株式会社 オレフイン重合用固体触媒およびその製法
US5914376A (en) 1993-01-21 1999-06-22 Targor Gmbh Catalyst for the polymerization of olefins, process for the preparation thereof, and use thereof
DE19827323A1 (de) 1998-06-19 1999-12-23 Basf Ag Verwendung von metallocenkatalysiert hergestellten Oligodecenen als Komponenten in Schmierstoffen
AU2393000A (en) 1998-12-30 2000-07-31 Union Carbide Chemicals & Plastics Technology Corporation Preactivated unsupported catalysts and methods of using same
ES2231239T3 (es) * 1999-09-23 2005-05-16 Bp Corporation North America Inc. Aceites oligomeros y su preparacion.

Also Published As

Publication number Publication date
CA2414108C (en) 2008-10-07
DE60313053D1 (de) 2007-05-24
US20030125595A1 (en) 2003-07-03
DE60313053T2 (de) 2007-12-13
US6680417B2 (en) 2004-01-20
EP1325899A1 (de) 2003-07-09
EP1325899B1 (de) 2007-04-11
CA2414108A1 (en) 2003-07-03

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