ATE360039T1 - SOLID COCATALYST COMPONENT FOR OLEFIN POLYMERIZATION AND CATALYST SYSTEM THEREOF - Google Patents

SOLID COCATALYST COMPONENT FOR OLEFIN POLYMERIZATION AND CATALYST SYSTEM THEREOF

Info

Publication number
ATE360039T1
ATE360039T1 AT02782961T AT02782961T ATE360039T1 AT E360039 T1 ATE360039 T1 AT E360039T1 AT 02782961 T AT02782961 T AT 02782961T AT 02782961 T AT02782961 T AT 02782961T AT E360039 T1 ATE360039 T1 AT E360039T1
Authority
AT
Austria
Prior art keywords
olefin polymerization
group
catalyst system
solid cocatalyst
cocatalyst component
Prior art date
Application number
AT02782961T
Other languages
German (de)
Inventor
Satoru Ishigaki
Shinji Hinokuma
Original Assignee
Sunallomer Ltd
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sunallomer Ltd, Basell Polyolefine Gmbh filed Critical Sunallomer Ltd
Application granted granted Critical
Publication of ATE360039T1 publication Critical patent/ATE360039T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/645—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/642 - C08F4/643
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A solid cocatalyst for olefin polymerization in which an ion-containing compound comprising a cation expressed by [R<SUB>4</SUB>M]+, wherein the group R are each individually selected from the group consisting of hydrogen atom and a substituted or non-substituted hydrocarbon group having from 1 to 30 carbon atoms with the exception of an aryl group; two or more groups R may form a ring by bonding with one another; at least one of the groups R is a hydrocarbon group having from 1 to 30 carbon atoms with the exception of an aryl group; and M represents nitrogen or sulfur, and a non-coordinating anion expressed by [A] said ion-containing compound is chemically bonded to a fine particulate carrier is used.
AT02782961T 2001-10-19 2002-10-17 SOLID COCATALYST COMPONENT FOR OLEFIN POLYMERIZATION AND CATALYST SYSTEM THEREOF ATE360039T1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001322615A JP2003128720A (en) 2001-10-19 2001-10-19 Solid co-catalyst component for olefin polymerization, catalyst for olefin polymerization, and ion-containing compound

Publications (1)

Publication Number Publication Date
ATE360039T1 true ATE360039T1 (en) 2007-05-15

Family

ID=19139635

Family Applications (1)

Application Number Title Priority Date Filing Date
AT02782961T ATE360039T1 (en) 2001-10-19 2002-10-17 SOLID COCATALYST COMPONENT FOR OLEFIN POLYMERIZATION AND CATALYST SYSTEM THEREOF

Country Status (9)

Country Link
US (1) US7247686B2 (en)
EP (1) EP1442067B1 (en)
JP (1) JP2003128720A (en)
KR (1) KR20040045872A (en)
CN (1) CN1612900A (en)
AT (1) ATE360039T1 (en)
BR (1) BR0213665A (en)
DE (1) DE60219660T2 (en)
WO (1) WO2003035708A1 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005008719A (en) * 2003-06-18 2005-01-13 Mitsui Chemicals Inc Catalyst component for olefin polymerization excellent in storage stability
EP1763542B1 (en) * 2004-06-16 2011-04-06 Dow Global Technologies Inc. Technique for selecting polymerization modifiers
US7722929B2 (en) 2005-08-18 2010-05-25 Corning Incorporated Sealing technique for decreasing the time it takes to hermetically seal a device and the resulting hermetically sealed device
US7829147B2 (en) 2005-08-18 2010-11-09 Corning Incorporated Hermetically sealing a device without a heat treating step and the resulting hermetically sealed device
US20070040501A1 (en) 2005-08-18 2007-02-22 Aitken Bruce G Method for inhibiting oxygen and moisture degradation of a device and the resulting device
EP2050755A1 (en) 2007-10-19 2009-04-22 Total Petrochemicals Research Feluy Supported ionic liquids or activating supports
EP2070953A1 (en) 2007-12-11 2009-06-17 Total Petrochemicals Research Feluy Activating supports based on phosphonium complexes
US20090240640A1 (en) * 2008-03-21 2009-09-24 David Alan Blain Apparatus and method for predicting engine test performance from bench test data
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
US7799879B2 (en) 2008-08-01 2010-09-21 Exxonmobil Chemical Patents Inc. Catalyst system and process for olefin polymerization
CN102112499B (en) 2008-08-01 2014-02-05 埃克森美孚化学专利公司 Catalyst system and process for olefin polymerization
CN103857706B (en) 2011-09-30 2016-09-28 埃克森美孚化学专利公司 Kinetic Modulation of Metallocene Catalysts
US9266910B2 (en) 2013-10-29 2016-02-23 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
CN118891293A (en) 2022-02-07 2024-11-01 埃克森美孚化学专利公司 C1 symmetrical 5-OMe-6-alkyl substituted metallocenes

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US5621126A (en) * 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
JP2939354B2 (en) 1991-03-26 1999-08-25 出光興産株式会社 Method for producing styrenic polymer and catalyst thereof
ES2108861T3 (en) * 1991-11-25 1998-01-01 Exxon Chemical Patents Inc POLYTONIC CATALYTIC COMPOSITIONS OF TRANSITIONAL METALS.
JP3371118B2 (en) 1991-11-30 2003-01-27 バーゼル・ポリオレフィン・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング Metallocenes having benzene-fused indenyl derivatives as ligands, their preparation and their use as catalysts
TW294669B (en) * 1992-06-27 1997-01-01 Hoechst Ag
JPH06345809A (en) 1993-06-07 1994-12-20 Mitsui Petrochem Ind Ltd Novel transition metal compound, olefin polymerization catalyst component comprising the transition metal compound, olefin polymerization catalyst containing the olefin polymerization catalyst component, and olefin polymerization method
US5939347A (en) * 1995-01-25 1999-08-17 W.R. Grace & Co. -Conn. Supported catalytic activator
ATE233790T1 (en) 1995-03-10 2003-03-15 Dow Global Technologies Inc SUPPORTED CATALYST COMPONENT, SUPPORTED CATALYST, PRODUCTION PROCESS, POLYMERIZATION PROCESS, COMPLEX COMPOUNDS AND THEIR PRODUCTION
WO1996041808A1 (en) 1995-06-08 1996-12-27 Showa Denko K.K. Ionic compounds and catalyst for olefin polymerization using the compounds
DE19544828A1 (en) * 1995-12-01 1997-06-05 Hoechst Ag High molecular copolymers
EP1312619B1 (en) * 1996-12-09 2007-11-14 Mitsubishi Chemical Corporation Catalyst for the polymerisation of alpha olefins
JP3815876B2 (en) 1996-12-09 2006-08-30 三菱化学株式会社 α-Olefin Polymerization Catalyst and Method for Producing α-Olefin Polymer
JPH10279588A (en) 1997-04-01 1998-10-20 Mitsubishi Chem Corp Novel transition metal compound, α-olefin polymerization catalyst component and method for producing α-olefin polymer
WO2002000666A1 (en) 2000-06-23 2002-01-03 Exxonmobil Chemical Patents Inc. Siloxy substituted cocatalyst activators for olefin polymerization

Also Published As

Publication number Publication date
DE60219660T2 (en) 2008-01-10
BR0213665A (en) 2004-10-26
DE60219660D1 (en) 2007-05-31
JP2003128720A (en) 2003-05-08
US7247686B2 (en) 2007-07-24
KR20040045872A (en) 2004-06-02
WO2003035708A1 (en) 2003-05-01
EP1442067A1 (en) 2004-08-04
CN1612900A (en) 2005-05-04
US20050009689A1 (en) 2005-01-13
EP1442067B1 (en) 2007-04-18

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