ATE368061T1 - Ionomer mit niedrigem äquivalentgewicht - Google Patents

Ionomer mit niedrigem äquivalentgewicht

Info

Publication number
ATE368061T1
ATE368061T1 AT02786747T AT02786747T ATE368061T1 AT E368061 T1 ATE368061 T1 AT E368061T1 AT 02786747 T AT02786747 T AT 02786747T AT 02786747 T AT02786747 T AT 02786747T AT E368061 T1 ATE368061 T1 AT E368061T1
Authority
AT
Austria
Prior art keywords
ionomer
equivalent weight
low equivalent
low
weight ionomer
Prior art date
Application number
AT02786747T
Other languages
English (en)
Inventor
Huey Shen Wu
Charles Martin
Xin Kang Chen
Original Assignee
Gore Enterprise Holdings Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gore Enterprise Holdings Inc filed Critical Gore Enterprise Holdings Inc
Application granted granted Critical
Publication of ATE368061T1 publication Critical patent/ATE368061T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/26—Tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14—Monomers containing only one unsaturated aliphatic radical
    • C08F216/1408—Monomers containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0289—Means for holding the electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0088—Composites
    • H01M2300/0094—Composites in the form of layered products, e.g. coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Energy (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Fuel Cell (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Conductive Materials (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Inert Electrodes (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polymerisation Methods In General (AREA)
  • Saccharide Compounds (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT02786747T 2001-12-06 2002-11-19 Ionomer mit niedrigem äquivalentgewicht ATE368061T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/011,243 US7094851B2 (en) 2001-12-06 2001-12-06 Low equivalent weight ionomer

Publications (1)

Publication Number Publication Date
ATE368061T1 true ATE368061T1 (de) 2007-08-15

Family

ID=21749487

Family Applications (1)

Application Number Title Priority Date Filing Date
AT02786747T ATE368061T1 (de) 2001-12-06 2002-11-19 Ionomer mit niedrigem äquivalentgewicht

Country Status (9)

Country Link
US (5) US7094851B2 (de)
EP (1) EP1451233B1 (de)
JP (6) JP2005511830A (de)
KR (1) KR100777479B1 (de)
CN (4) CN100457792C (de)
AT (1) ATE368061T1 (de)
AU (1) AU2002350216A1 (de)
DE (1) DE60221429T2 (de)
WO (1) WO2003050151A1 (de)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7094851B2 (en) * 2001-12-06 2006-08-22 Gore Enterprise Holdings, Inc. Low equivalent weight ionomer
US6861489B2 (en) * 2001-12-06 2005-03-01 Gore Enterprise Holdings, Inc. Low equivalent weight ionomer
JP2006512428A (ja) 2002-05-13 2006-04-13 ポリフューエル・インコーポレイテッド イオン伝導性ブロックコポリマー
WO2004006991A1 (ja) * 2002-07-12 2004-01-22 Kuraray Co., Ltd. 多孔質膜
US7348088B2 (en) * 2002-12-19 2008-03-25 3M Innovative Properties Company Polymer electrolyte membrane
DE602004031958D1 (de) 2003-09-17 2011-05-05 Asahi Chemical Ind Membran-elektrodenbaugruppe für eine festpolymer-brennstoffzelle
US7473748B2 (en) 2004-01-22 2009-01-06 Asahi Kasei Kabushiki Kaisha Vinyl monomer with superacid ester group and polymer of the same
ITMI20040789A1 (it) * 2004-04-22 2004-07-22 Solvay Solexis Spa Membrane fluorurate
US8652705B2 (en) * 2005-09-26 2014-02-18 W.L. Gore & Associates, Inc. Solid polymer electrolyte and process for making same
US7977392B2 (en) * 2005-12-22 2011-07-12 Daimler Ag Water insoluble additive for improving conductivity of an ion exchange membrane
CA2673069C (en) * 2006-12-22 2016-06-21 Vincenzo Arcella Process for operating a fuel cell in dry conditions
US7989115B2 (en) * 2007-12-14 2011-08-02 Gore Enterprise Holdings, Inc. Highly stable fuel cell membranes and methods of making them
JP5474762B2 (ja) * 2008-03-19 2014-04-16 旭化成イーマテリアルズ株式会社 高分子電解質及びその製造方法
US7897691B2 (en) * 2008-05-09 2011-03-01 Gm Global Technology Operations, Inc. Proton exchange membranes for fuel cell applications
US7897693B2 (en) * 2008-05-09 2011-03-01 Gm Global Technology Operations, Inc. Proton conductive polymer electrolytes and fuel cells
US7888433B2 (en) 2008-05-09 2011-02-15 Gm Global Technology Operations, Inc. Sulfonated-polyperfluoro-cyclobutane-polyphenylene polymers for PEM fuel cell applications
US7897692B2 (en) * 2008-05-09 2011-03-01 Gm Global Technology Operations, Inc. Sulfonated perfluorocyclobutane block copolymers and proton conductive polymer membranes
KR100978553B1 (ko) * 2008-07-10 2010-08-27 한양대학교 산학협력단 불소계 또는 부분불소계 분산제를 포함하는 불소계 고분자전해질막 및 이를 포함하는 연료전지
ATE524513T1 (de) * 2008-07-17 2011-09-15 Gore W L & Ass Gmbh Antimikrobielle beschichtungen mit einem komplex aus einem ionischen fluorpolymer und einem antimikrobiellen gegenion
EP2145916B1 (de) 2008-07-17 2013-06-19 W.L.Gore & Associates Gmbh Substratbeschichtung mit einem Komplex aus einem ionischen Fluorpolymer und oberflächengeladenen Nanopartikeln
EP2145917B1 (de) * 2008-07-17 2012-06-06 W.L. Gore & Associates GmbH Polymerbeschichtung mit einem Komplex aus Ionfluorpolyether und einem Gegenionwirkstoff
US7976730B2 (en) * 2008-08-25 2011-07-12 GM Global Technology Operations LLC Blends of low equivalent molecular weight PFSA ionomers with Kynar 2751
US8436054B2 (en) * 2008-12-23 2013-05-07 E I Du Pont De Nemours And Company Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer produced in situ
US8436053B2 (en) * 2008-12-23 2013-05-07 E.I. Du Pont De Nemours And Company Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer
WO2010096027A1 (en) * 2009-02-18 2010-08-26 Huey-Shen Wu Fluorochloro ionomers
WO2011034179A1 (ja) 2009-09-18 2011-03-24 旭化成イーマテリアルズ株式会社 電解質エマルション及びその製造方法
CA2783850C (en) 2009-12-11 2016-07-12 Shandong Huaxia Shenzhou New Material Co., Ltd Perfluorinated ion exchange resin, preparation method and use thereof
US9090723B2 (en) 2009-12-15 2015-07-28 Shandong Huaxia Shenzou New Material Co., Ltd. High exchange capacity perfluorinated ion exchange resin, preparation method and use thereof
JP5461588B2 (ja) 2010-02-01 2014-04-02 旭化成イーマテリアルズ株式会社 塗料及び積層体
US8609739B2 (en) 2011-02-17 2013-12-17 GM Global Technology Operations LLC Poly(perfluorocyclobutane) ionomer with phosphonic acid groups for high temperature fuel cells
JP5680770B2 (ja) 2011-03-11 2015-03-04 ユーティーシー パワー コーポレイション 高当量イオノマを有するユニット化電極アセンブリ
EP2500393B1 (de) 2011-03-15 2018-05-02 W.L.Gore & Associates Gmbh Verwendung eines ionischen Fluorpolymers als antistatische Beschichtung
WO2014023611A1 (en) 2012-08-10 2014-02-13 Solvay Specialty Polymers Italy S.P.A. Allyl-bearing fluorinated ionomers
WO2014098907A1 (en) 2012-12-21 2014-06-26 Utc Power Corporation Method of fabricating an electrolyte material
US9923223B2 (en) 2012-12-21 2018-03-20 Audi Ag Electrolyte membrane, dispersion and method therefor
US9923224B2 (en) 2012-12-21 2018-03-20 Audi Ag Proton exchange material and method therefor
US20150096884A1 (en) * 2013-10-07 2015-04-09 W. L. Gore & Associates, Inc. Humidification Control Device
WO2015182676A1 (ja) * 2014-05-28 2015-12-03 ダイキン工業株式会社 高酸素透過性アイオノマー
US10734660B2 (en) 2016-03-10 2020-08-04 Nissan North America, Inc. Functionalized carbon layer for membrane degradation mitigation under fuel cell operating conditions
WO2018231232A1 (en) 2017-06-15 2018-12-20 W. L. Gore & Associates, Inc. Highly reinforced ionomer membranes for high selectivity and high strength
US11103864B2 (en) 2018-09-04 2021-08-31 Xergy Inc. Multilayered ion exchange membranes
EP4127002A1 (de) 2020-03-30 2023-02-08 3M Innovative Properties Company Fluorpolymere mit seitengruppen mit ionischer bis(sulfonyl)imid-einheit und perfluoretherendgruppe

Family Cites Families (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) * 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
GB1034197A (en) * 1963-09-13 1966-06-29 Du Pont Sulphonic acid derivatives of fluorocarbon vinyl ethers, and polymers thereof
US3291843A (en) * 1963-10-08 1966-12-13 Du Pont Fluorinated vinyl ethers and their preparation
US3692569A (en) * 1970-02-12 1972-09-19 Du Pont Surface-activated fluorocarbon objects
US4417969A (en) * 1980-06-11 1983-11-29 The Dow Chemical Co. Sulfonic acid electrolytic cell membranes
US4478695A (en) * 1980-06-11 1984-10-23 The Dow Chemical Company Sulfonic acid electrolytic cell membranes and use thereof in the electrolysis of sodium chloride
US4358545A (en) * 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
WO1986006879A1 (en) * 1985-05-17 1986-11-20 The Dow Chemical Company Proton exchange polymer film fuel cells
US4661411A (en) * 1986-02-25 1987-04-28 The Dow Chemical Company Method for depositing a fluorocarbonsulfonic acid polymer on a support from a solution
JPS62288617A (ja) * 1986-06-06 1987-12-15 Asahi Glass Co Ltd スルホン酸型官能基を有するパ−フルオロカ−ボン重合体を製造する方法
IL82308A (en) * 1986-06-26 1990-11-29 Ausimont Spa Microemulsions containing perfluoropolyethers
US4940525A (en) * 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
WO1990015828A1 (en) 1989-06-20 1990-12-27 Raychem Corporation Thermoplastic fluoropolymers
EP0662249B1 (de) * 1990-06-11 1997-01-22 The Dow Chemical Company Ionenaustauschermembran mit verbessertem wirkungsgrad in protonenaustauscherverfahren
US5082472A (en) * 1990-11-05 1992-01-21 Mallouk Robert S Composite membrane for facilitated transport processes
JPH06176771A (ja) * 1991-09-13 1994-06-24 Tanaka Kikinzoku Kogyo Kk 燃料電池用イオン交換膜の構造
US5463005A (en) * 1992-01-03 1995-10-31 Gas Research Institute Copolymers of tetrafluoroethylene and perfluorinated sulfonyl monomers and membranes made therefrom
US5264508A (en) * 1992-06-25 1993-11-23 The Dow Chemical Company Polymers of haloperfluoro and perfluoro ethers
US5595676A (en) * 1992-07-30 1997-01-21 Imperial Chemical Industries Plc Fluorinated polymers
JP2780590B2 (ja) * 1992-12-18 1998-07-30 旭硝子株式会社 スルホン酸型官能基を有するパーフルオロカーボン重合体の製造方法
US5281680A (en) * 1993-01-14 1994-01-25 E. I. Du Pont De Nemours And Company Polymerization of fluorinated copolymers
US5608022A (en) * 1993-10-12 1997-03-04 Asahi Kasei Kogyo Kabushiki Kaisha Perfluorocarbon copolymer containing functional groups and a method for producing it
US6156451A (en) * 1994-11-10 2000-12-05 E. I. Du Pont De Nemours And Company Process for making composite ion exchange membranes
USRE37307E1 (en) * 1994-11-14 2001-08-07 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
US5547551A (en) * 1995-03-15 1996-08-20 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
US5599614A (en) * 1995-03-15 1997-02-04 W. L. Gore & Associates, Inc. Integral composite membrane
US6054230A (en) * 1994-12-07 2000-04-25 Japan Gore-Tex, Inc. Ion exchange and electrode assembly for an electrochemical cell
US6046271A (en) * 1995-01-18 2000-04-04 W. L. Gore & Associates, Inc. Microemulsion polymerization systems for the production of small melt-processible fluoropolymer particles
US5718947A (en) * 1995-03-14 1998-02-17 The Dow Chemicalcompany Processes for forming thin, durable coatings of cation-containing polymers on selected substrates
US5654109A (en) * 1995-06-30 1997-08-05 The Dow Chemical Company Composite fuel cell membranes
US5981097A (en) * 1996-12-23 1999-11-09 E.I. Du Pont De Nemours And Company Multiple layer membranes for fuel cells employing direct feed fuels
US5989741A (en) * 1997-06-10 1999-11-23 E.I. Du Pont De Nemours And Company Electrochemical cell system with side-by-side arrangement of cells
US6294612B1 (en) * 1998-02-02 2001-09-25 E. I. Du Pont De Nemours And Company Highly fluorinated ion exchange/nonfunctional polymer blends
US6100324A (en) 1998-04-16 2000-08-08 E. I. Du Pont De Nemours And Company Ionomers and ionically conductive compositions
MY135964A (en) 1998-10-26 2008-07-31 Du Pont Ionomers and polymers for electrochemical uses
FR2785904B1 (fr) * 1998-11-13 2000-12-15 Atochem Elf Sa Polymeres fluores par polymerisation en miniemulsion
US6602968B1 (en) 1999-03-02 2003-08-05 Paul Gregory Bekiarian Free radical polymerization method for fluorinated copolymers
US6277512B1 (en) 1999-06-18 2001-08-21 3M Innovative Properties Company Polymer electrolyte membranes from mixed dispersions
JP2001030427A (ja) * 1999-07-23 2001-02-06 Teijin Ltd 表面保護用積層フィルムおよびそれからなる積層体
JP4406984B2 (ja) * 1999-12-22 2010-02-03 旭硝子株式会社 固体高分子電解質型燃料電池用電極用塗工液及び固体高分子電解質型燃料電池用電極の製造方法
US6255536B1 (en) * 1999-12-22 2001-07-03 Dyneon Llc Fluorine containing vinyl ethers
ATE290026T1 (de) * 1999-12-29 2005-03-15 Hydro Quebec Fluorosulfoneelastomere mit niedrigem tg basierend auf vinylidenfluorit
JP5007009B2 (ja) * 1999-12-29 2012-08-22 ハイドロ−ケベック 低いＴｇを有し、ヘキサフルオロプロペンを主成分とし、テトラフルオロエチレンも、シロキサン基も含まない、フルオロスルホン化エラストマー
JP3855585B2 (ja) * 2000-03-16 2006-12-13 コニカミノルタホールディングス株式会社 画像形成方法
IT1318593B1 (it) * 2000-06-23 2003-08-27 Ausimont Spa Ionomeri fluorurati.
JP2002015743A (ja) * 2000-06-30 2002-01-18 Asahi Glass Co Ltd 固体高分子型燃料電池
IT1318669B1 (it) * 2000-08-08 2003-08-27 Ausimont Spa Ionomeri fluorurati solfonici.
AU2002239798A1 (en) 2000-10-27 2002-06-03 E.I. Du Pont De Nemours And Company Production of catalyst coated membranes
JP4067315B2 (ja) * 2001-02-07 2008-03-26 旭化成ケミカルズ株式会社 フッ素系イオン交換樹脂膜
JP5105340B2 (ja) * 2001-05-23 2012-12-26 独立行政法人日本原子力研究開発機構 広いイオン交換容量を有するフッ素系高分子イオン交換膜及びその製造方法
US7094851B2 (en) * 2001-12-06 2006-08-22 Gore Enterprise Holdings, Inc. Low equivalent weight ionomer
US6861489B2 (en) * 2001-12-06 2005-03-01 Gore Enterprise Holdings, Inc. Low equivalent weight ionomer

Also Published As

Publication number Publication date
CN1688621A (zh) 2005-10-26
CN1935864A (zh) 2007-03-28
US20030146148A1 (en) 2003-08-07
JP2005511830A (ja) 2005-04-28
JP2015045016A (ja) 2015-03-12
EP1451233A1 (de) 2004-09-01
EP1451233B1 (de) 2007-07-25
US7615307B2 (en) 2009-11-10
CN100445306C (zh) 2008-12-24
AU2002350216A1 (en) 2003-06-23
CN100457792C (zh) 2009-02-04
CN100465200C (zh) 2009-03-04
US20060241261A1 (en) 2006-10-26
JP2011057999A (ja) 2011-03-24
KR20050044736A (ko) 2005-05-12
JP2009228009A (ja) 2009-10-08
WO2003050151A1 (en) 2003-06-19
US20060241262A1 (en) 2006-10-26
US7094851B2 (en) 2006-08-22
DE60221429D1 (de) 2007-09-06
US20060241260A1 (en) 2006-10-26
JP6049670B2 (ja) 2016-12-21
JP2014005471A (ja) 2014-01-16
CN1935856A (zh) 2007-03-28
CN1935863A (zh) 2007-03-28
US8071702B2 (en) 2011-12-06
US7579102B2 (en) 2009-08-25
KR100777479B1 (ko) 2007-11-28
DE60221429T2 (de) 2008-04-17
CN100519601C (zh) 2009-07-29
US20120046371A1 (en) 2012-02-23
JP2015227455A (ja) 2015-12-17

Similar Documents

Publication Publication Date Title
ATE368061T1 (de) Ionomer mit niedrigem äquivalentgewicht
DE60232361D1 (de) Ein fluoriertes ionomeres vernetztes copolymer
AU2003247766A1 (en) Thermally insulating products for footwear and other apparel
TR200102308T2 (tr) Yüzey etkinliğine sahip yapay peptidler ve bunların yapay yüzey aktif maddelerin hazırlanmasında kullanımı
ES2064355T3 (es) Procedimiento para cultivar celulas recombinantes.
BR0000268A (pt) Método para controlar chamada em comunicação móvel e, sistema para este método
BR9912798B1 (pt) material de mancal, mancal, e, mÉtodo para fabricaÇço de material de mancal.
DE69622413D1 (de) Zusammensetzbares spielgerät,insbesondere zur herstellung von rollbahnen
DE60134081D1 (de) Herstellungsverfahren von Dünnschichten, Gerät zur Herstellung von Dünnschichten und Sonnenzelle
ATE175116T1 (de) Synthetische, oberflächen aktive zusammensetzung für die lunge mit antioxidativen eigenschaften
DE3689703D1 (de) Kornorientiertes Elektrostahlblech mit Glasfilmeigenschaften und niedrigem Wattverlust sowie dessen Herstellung.
DE60107718D1 (de) Konservierung von zellen
ITRM930797A1 (it) Procedimento e dispositivo per la fabbricazione di vetro piano con caratteristiche migliorate.
DE50114664D1 (de) Silikonkautschukformulierungen und deren verwendung
ATE148265T1 (de) Ionenaustauschermembran mit verbessertem wirkungsgrad in protonenaustauscherverfahren
SI1456238T1 (sl) Proizvodnja f(ab)2 fragmentov v sesalskih celicah
DE69210901D1 (de) Ionisch vulkanisierbare, fluorelastomere Copolymere
ATE259664T1 (de) Vorrichtung zur pflege von kontaktlinsen
TW200605461A (en) Semiconductor laser device
DE59405101D1 (de) Duvetdecke
ES2189705T1 (es) Gelatinas con buen poder deslizante, procedimientos para su preparacion y sus aplicaciones.
JPS52143543A (en) Manufacturing system of wave-like fin
ES2196802T3 (es) Lactatos de citronelilo y/o de dihidrocitronelilo, su preparacion y su utilizacion.
DE69627688D1 (de) Kühlmittelzusammensetzungen
ATE201780T1 (de) Prozessoreinheit mit steckbarem speicher

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties