ATE377619T1 - Acryl-silikon-hybridschlagzähigkeitsmodifikator n und herstellungsverfahren dafür und vinylchloridharzzusammensetzungen damit - Google Patents

Acryl-silikon-hybridschlagzähigkeitsmodifikator n und herstellungsverfahren dafür und vinylchloridharzzusammensetzungen damit

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Publication number
ATE377619T1
ATE377619T1 AT04732844T AT04732844T ATE377619T1 AT E377619 T1 ATE377619 T1 AT E377619T1 AT 04732844 T AT04732844 T AT 04732844T AT 04732844 T AT04732844 T AT 04732844T AT E377619 T1 ATE377619 T1 AT E377619T1
Authority
AT
Austria
Prior art keywords
silicone hybrid
vinyl chloride
acryl
resin compositions
chloride resin
Prior art date
Application number
AT04732844T
Other languages
English (en)
Inventor
Kwang-Jin Lee
Jeong-Heon Ahn
Hye-Kyong Lee
Original Assignee
Lg Chemical Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lg Chemical Ltd filed Critical Lg Chemical Ltd
Application granted granted Critical
Publication of ATE377619T1 publication Critical patent/ATE377619T1/de

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/10Encapsulated ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/10Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of amides or imides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42Block-or graft-polymers containing polysiloxane sequences
    • C08G77/442Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/902Core-shell

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
AT04732844T 2003-08-02 2004-05-13 Acryl-silikon-hybridschlagzähigkeitsmodifikator n und herstellungsverfahren dafür und vinylchloridharzzusammensetzungen damit ATE377619T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR10-2003-0053585A KR100528771B1 (ko) 2003-08-02 2003-08-02 아크릴-실리콘계 복합 충격보강제, 이의 제조방법 및 이를함유하는 염화비닐 수지 조성물

Publications (1)

Publication Number Publication Date
ATE377619T1 true ATE377619T1 (de) 2007-11-15

Family

ID=36116050

Family Applications (1)

Application Number Title Priority Date Filing Date
AT04732844T ATE377619T1 (de) 2003-08-02 2004-05-13 Acryl-silikon-hybridschlagzähigkeitsmodifikator n und herstellungsverfahren dafür und vinylchloridharzzusammensetzungen damit

Country Status (9)

Country Link
US (1) US8013063B2 (de)
EP (1) EP1615965B1 (de)
JP (1) JP4468949B2 (de)
KR (1) KR100528771B1 (de)
CN (1) CN100473680C (de)
AT (1) ATE377619T1 (de)
DE (1) DE602004009907T2 (de)
RU (1) RU2289595C2 (de)
WO (1) WO2005012392A1 (de)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2006016490A1 (ja) * 2004-08-12 2008-05-01 株式会社カネカ ポリオルガノシロキサンラテックスの製造方法、該ラテックスを用いたグラフト共重合体および該グラフト共重合体を配合した樹脂組成物
KR100656971B1 (ko) * 2005-09-05 2006-12-14 제일모직주식회사 착색성과 저온 내충격성이 우수한 고굴절률 충격보강제 및제조방법
EP2399950B1 (de) 2004-12-31 2013-04-17 Cheil Industries Inc. Silikon-schlagzähigkeitsmodifikator mit hohem brechungsindex und herstellungsverfahren dafür
US7541401B2 (en) 2004-12-31 2009-06-02 Cheil Industries Inc. Impact modifier for a polymer composition and method for preparing the same
EP1888689B1 (de) * 2005-06-07 2012-09-12 LG Chem, Ltd. Polymeres schmiermittel mit mehrschichtstruktur und herstellungsverfahren dafür
KR100836731B1 (ko) * 2005-10-13 2008-06-10 주식회사 엘지화학 아크릴-실리콘계 고무 복합 중합체, 이의 제조방법 및 용도
KR100762740B1 (ko) * 2005-12-28 2007-10-04 제일모직주식회사 열안정성이 우수한 고굴절률 실리콘계 충격보강제와 그제조방법
CN101328246B (zh) * 2007-06-18 2010-10-06 山东瑞丰高分子材料股份有限公司 改性纳米氧化锌与纳米碳酸钙联用的高抗冲acr树脂
KR101056234B1 (ko) 2007-10-17 2011-08-11 주식회사 엘지화학 고무개질제 및 이를 포함하여 개질된아크릴로니트릴-부타디엔계 고무
EP2072542B1 (de) * 2007-12-20 2014-05-07 Rohm and Haas Company Kern-Schale-Polymere und die Verwendung in organischen Mitteln davon.
US7807751B2 (en) * 2008-02-25 2010-10-05 Sabic Innovative Plastics Ip B.V. Core-shell particle, method, and composition
US8153713B2 (en) * 2008-02-25 2012-04-10 Sabic Innovative Plastics Ip B.V. Core-shell particle, method, and composition
RU2544702C2 (ru) * 2009-04-24 2015-03-20 Хенкель Корпорейшн Клеи на основе силикон-акрилового гибридного полимера
KR101282707B1 (ko) * 2009-12-30 2013-07-05 제일모직주식회사 코어-쉘 구조를 포함하는 그라프트 공중합체로 이루어지는 실리콘계 충격보강제 및 이를 포함하는 열가소성 조성물
KR101466148B1 (ko) * 2010-09-16 2014-11-27 제일모직 주식회사 아크릴계 열가소성 수지 조성물 및 이를 이용한 성형품
FR2964970B1 (fr) * 2010-09-22 2013-11-01 Arkema France Nouveaux modifiants chocs et compositions thermoplastiques renforcees choc
KR20130090307A (ko) 2012-02-03 2013-08-13 주식회사 엘지화학 아크릴계 충격보강제 및 이를 포함하는 열가소성 수지 조성물
EP2975085B1 (de) * 2013-03-15 2017-02-01 Mitsubishi Rayon Co., Ltd. Schlagzähigkeitsmodifikator für chlorhaltiges harz, chlorhaltige harzzusammensetzung und daraus geformter gegenstand
KR101591565B1 (ko) * 2013-04-23 2016-02-03 주식회사 엘지화학 아크릴계 활제, 라텍스 분체의 제조방법 및 염화비닐계 수지 조성물
RU2683075C2 (ru) * 2014-04-16 2019-03-26 Аркема Инк. Применение модификаторов ударопрочности с высоким содержанием каучука в термопластичных составах
KR101800086B1 (ko) * 2014-11-21 2017-11-21 주식회사 엘지화학 폴리메틸메타크릴레이트 아크릴계 공중합체 얼로이 고광택 조성물 및 성형품
FR3031108B1 (fr) * 2014-12-24 2018-08-17 Arkema France Composition comprenant un polymere a phases multiples, son procede de preparation et son utlisation
KR102038561B1 (ko) * 2015-05-13 2019-10-30 주식회사 엘지화학 나노입자를 포함하는 충격보강제, 이의 제조방법 및 이를 포함하는 폴리유산수지
KR101752340B1 (ko) * 2016-09-30 2017-06-29 (주)리페이퍼 친환경성, 내수성 및 내유성을 갖는 제지 코팅제 및 이의 제조방법
CN106832947B (zh) * 2017-02-23 2019-11-26 中国林业科学研究院林产化学工业研究所 一种单组份增强型松香基室温硫化硅橡胶及其制备方法
KR20180099330A (ko) 2017-02-28 2018-09-05 엘에스산전 주식회사 주접점 인터록 기능을 갖는 배선용 차단기
CN106866971B (zh) * 2017-04-10 2020-05-05 广东优科艾迪高分子材料有限公司 一种耐候耐低温型有机硅抗冲改性剂及其制备方法与应用
CN107151296B (zh) * 2017-04-18 2019-01-29 华南理工大学 大粒径核壳结构聚硅氧烷-丙烯酸酯/苯乙烯共聚物的制备方法
JP6976785B2 (ja) * 2017-09-20 2021-12-08 デンカ株式会社 樹脂組成物及び成形体
KR102731875B1 (ko) 2018-03-29 2024-11-18 롬 앤드 하아스 컴패니 개질된 스티렌-아크릴로니트릴
JP7534217B2 (ja) 2018-03-29 2024-08-14 ローム アンド ハース カンパニー 3ステージポリマー粒子
JP7243403B2 (ja) * 2018-04-12 2023-03-22 三菱ケミカル株式会社 ポリオルガノシロキサン含有グラフト重合体、これを含む樹脂組成物及びその成形体、並びにポリオルガノシロキサン含有グラフト重合体の製造方法
KR102802870B1 (ko) 2018-07-27 2025-05-07 다우 실리콘즈 코포레이션 실리콘 및 아크릴 단량체 중합
JP7333380B2 (ja) 2018-07-27 2023-08-24 ローム アンド ハース カンパニー シリコーン-アクリルポリマー粒子
WO2020023819A1 (en) * 2018-07-27 2020-01-30 Rohm And Haas Company Polymerization process for silicone and acrylic monomers
JP7523423B2 (ja) * 2018-07-27 2024-07-26 ローム アンド ハース カンパニー 二元シリコーン-アクリルポリマー粒子
CN110818861B (zh) * 2019-10-25 2022-02-22 铨盛聚碳科技股份有限公司 一种pc填充体系用增韧补强剂及其制备方法
CN113939549B (zh) 2019-11-25 2024-10-01 株式会社Lg化学 接枝共聚物及其制备方法
CN116589626B (zh) * 2023-04-21 2026-04-03 威海金合思化工有限公司 一种pvc材料专用耐热改性剂及其制备方法
CN117567694B (zh) * 2024-01-17 2025-06-27 山东东临新材料股份有限公司 一种高抗冲mbs树脂的制备方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2299349A1 (fr) * 1975-02-03 1976-08-27 Ugine Kuhlmann Procede de preparation de copolymeres greffes
US4173596A (en) * 1977-12-23 1979-11-06 The B. F. Goodrich Company Soft-seeded tougheners for polyvinyl chloride
US4278576A (en) * 1978-12-05 1981-07-14 Rohm And Haas Company Isolation and improvement of impact modifier polymer powders
AU604179B2 (en) * 1988-01-25 1990-12-06 Mitsubishi Rayon Company Limited Vinyl chloride resin composition
JPH04272952A (ja) 1991-02-27 1992-09-29 Mitsubishi Rayon Co Ltd 塩化ビニル系樹脂組成物
TW246657B (de) * 1991-12-05 1995-05-01 Mitsubishi Gas Chemical Co
EP0700965B1 (de) * 1994-09-08 1998-05-13 Rohm And Haas Company Schlagzähmodifiziertes Vinylchloridharz
WO1997010283A1 (en) * 1995-09-12 1997-03-20 Kaneka Corporation Particulate silicone-modified acrylic rubber, particulate graft copolymer based on silicone-modified acrylic rubber, and thermoplastic resin composition
JPH10212387A (ja) 1997-01-30 1998-08-11 Mitsubishi Rayon Co Ltd 硬質塩化ビニル系樹脂組成物
DE69827467T2 (de) * 1997-07-29 2005-11-10 Kaneka Corp. Pfropfcopolymerteilchen und thermoplastische Harzzusammensetzungen
KR100309581B1 (ko) * 1998-05-19 2001-09-26 구광시 충격보강제가 캡슐화된 아크릴 수지 및 그의 제조방법.
CN1114635C (zh) * 1998-12-07 2003-07-16 中国石化齐鲁石油化工公司 一种透明型高抗冲改性剂的合成方法
US6730734B1 (en) * 1998-12-08 2004-05-04 Rohm And Haas Company Impact modifier compositions which enhance the impact strength properties and lower the viscosity of melt processed plastics resins and methods of making said compositions
JP2000212231A (ja) 1999-01-21 2000-08-02 Kanegafuchi Chem Ind Co Ltd シリコ―ン変性アクリルゴム粒子、シリコ―ン変性アクリルゴム系グラフト共重合体粒子および熱可塑性樹脂組成物
JP2001323033A (ja) 2000-05-12 2001-11-20 Kanegafuchi Chem Ind Co Ltd 粒子中に水を含むゴムラテックス及びその製造方法
JP4702998B2 (ja) * 2000-12-05 2011-06-15 株式会社カネカ ゴム変性樹脂およびそれを含有する熱可塑性樹脂組成物
JP2002317094A (ja) 2001-04-19 2002-10-31 Kanegafuchi Chem Ind Co Ltd 熱可塑性樹脂組成物
JP2002327027A (ja) 2001-05-02 2002-11-15 Kanegafuchi Chem Ind Co Ltd ゴム変性樹脂およびそれを含有する熱可塑性樹脂組成物
JP4980526B2 (ja) * 2001-09-21 2012-07-18 日本エイアンドエル株式会社 グラフト重合体の製造方法及び耐衝撃性樹脂の製造方法
JP2003137946A (ja) * 2001-11-02 2003-05-14 Kanegafuchi Chem Ind Co Ltd ゴム変性樹脂およびそれを含有する熱可塑性樹脂組成物
KR100544904B1 (ko) * 2002-12-24 2006-01-24 주식회사 엘지화학 다층구조를 갖는 충격보강제와 이의 제조방법 및 이를 포함하는 열가소성 수지

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Publication number Publication date
JP2006526051A (ja) 2006-11-16
DE602004009907D1 (de) 2007-12-20
EP1615965B1 (de) 2007-11-07
JP4468949B2 (ja) 2010-05-26
KR20050015088A (ko) 2005-02-21
CN100473680C (zh) 2009-04-01
RU2289595C2 (ru) 2006-12-20
DE602004009907T2 (de) 2008-08-28
US8013063B2 (en) 2011-09-06
US20070021557A1 (en) 2007-01-25
WO2005012392A1 (en) 2005-02-10
RU2005132993A (ru) 2006-03-10
KR100528771B1 (ko) 2005-11-15
EP1615965A4 (de) 2006-08-09
EP1615965A1 (de) 2006-01-18
CN1780873A (zh) 2006-05-31

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