ATE382595T1 - Neuartige diazaphospholan-liganden für asymmetrische katalysatoren - Google Patents

Neuartige diazaphospholan-liganden für asymmetrische katalysatoren

Info

Publication number
ATE382595T1
ATE382595T1 AT05792834T AT05792834T ATE382595T1 AT E382595 T1 ATE382595 T1 AT E382595T1 AT 05792834 T AT05792834 T AT 05792834T AT 05792834 T AT05792834 T AT 05792834T AT E382595 T1 ATE382595 T1 AT E382595T1
Authority
AT
Austria
Prior art keywords
diazaphospholane
ligands
novel
optically active
asymmetric catalysts
Prior art date
Application number
AT05792834T
Other languages
English (en)
Inventor
Clark R Landis
Thomas P Clark
Jerzy Klosin
Original Assignee
Dow Chemical Co
Wisconsin Alumni Res Found
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co, Wisconsin Alumni Res Found filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ATE382595T1 publication Critical patent/ATE382595T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505—Asymmetric hydroformylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/16—Preparation of optical isomers
    • C07C231/18—Preparation of optical isomers by stereospecific synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6581—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms
    • C07F9/6584—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms having one phosphorus atom as ring hetero atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AT05792834T 2004-08-27 2005-08-25 Neuartige diazaphospholan-liganden für asymmetrische katalysatoren ATE382595T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US60515304P 2004-08-27 2004-08-27

Publications (1)

Publication Number Publication Date
ATE382595T1 true ATE382595T1 (de) 2008-01-15

Family

ID=35478863

Family Applications (1)

Application Number Title Priority Date Filing Date
AT05792834T ATE382595T1 (de) 2004-08-27 2005-08-25 Neuartige diazaphospholan-liganden für asymmetrische katalysatoren

Country Status (7)

Country Link
US (1) US7189883B2 (de)
EP (1) EP1781590B1 (de)
JP (1) JP5122956B2 (de)
CN (1) CN101072745A (de)
AT (1) ATE382595T1 (de)
DE (1) DE602005004162T2 (de)
WO (1) WO2006026489A1 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7071357B2 (en) * 2001-07-23 2006-07-04 Wisconsin Alumni Research Foundation Diazaphosphacycles
DE102008050414A1 (de) * 2008-10-04 2010-04-08 Bayer Materialscience Ag 1,4,2-Diazaphospholidin-Derivate
JP5458303B2 (ja) * 2009-03-12 2014-04-02 国立大学法人名古屋大学 光学活性アリールアミノホスホニウム塩、不斉合成反応用触媒、及び光学活性化合物の製造方法
EP2482978B1 (de) * 2009-09-28 2018-05-09 The Governors of the University of Alberta Heterogene rhodiummetallkatalysatoren
CN110105204A (zh) * 2019-06-04 2019-08-09 荆楚理工学院 一种4-(2-卤代异丁酰基)苯乙醇衍生物及其制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5360938A (en) * 1991-08-21 1994-11-01 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses
US5530150A (en) * 1993-03-12 1996-06-25 Takasago International Corporation Phosphine compound, complex containing the phosphine compound as ligand, process for producing optically active aldehyde using the phosphine compound or the complex, and 4-[(R)-1'-formylethyl]azetidin-2-one derivatives
US6727377B2 (en) * 1998-08-21 2004-04-27 The Penn State Research Foundation Asymmetric catalysis based on chiral phospholanes and hydroxyl phospholanes
ATE244721T1 (de) * 1999-02-23 2003-07-15 Stylacats Ltd Chirale diazaphospholidinliganden
DE10027505A1 (de) * 2000-06-06 2001-12-13 Studiengesellschaft Kohle Mbh Chirale Monophosphite als Liganden für die asymmetrische Übergangsmetall-katalysierte Hydrierung
US7071357B2 (en) * 2001-07-23 2006-07-04 Wisconsin Alumni Research Foundation Diazaphosphacycles
WO2003010174A1 (en) * 2001-07-23 2003-02-06 Wisconsin Alumini Research Foundation Diazaphosphacycles
CN1608074B (zh) 2001-11-09 2011-09-07 宾夕法尼亚州研究基金会 P-手性磷杂戊环和磷环化合物及其在不对称催化反应中的用途
US7169953B2 (en) * 2001-11-09 2007-01-30 The Penn State Research Foundation P-chiral phospholanes and phosphocyclic compounds and their use in asymmetric catalytic reactions
US20040072680A1 (en) * 2002-04-26 2004-04-15 The Penn State Research Foundation Chiral phosphorus cyclic compounds for transition metal-catalyzed asymmetric reactions
US7015360B2 (en) * 2003-03-28 2006-03-21 Dow Global Technologies, Inc. Asymmetric catalysts prepared from optically active bisphosphites bridged by achiral diols

Also Published As

Publication number Publication date
CN101072745A (zh) 2007-11-14
JP5122956B2 (ja) 2013-01-16
WO2006026489A1 (en) 2006-03-09
DE602005004162D1 (de) 2008-02-14
EP1781590B1 (de) 2008-01-02
US20060069281A1 (en) 2006-03-30
JP2008511636A (ja) 2008-04-17
DE602005004162T2 (de) 2008-05-08
US7189883B2 (en) 2007-03-13
EP1781590A1 (de) 2007-05-09

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