ATE38820T1 - CARBONIC-SULPHONIC-POLYALKYLENE OXIDE COPOLYMERS AND THEIR USE AS CORROSION AND TANK INHIBITORS. - Google Patents
CARBONIC-SULPHONIC-POLYALKYLENE OXIDE COPOLYMERS AND THEIR USE AS CORROSION AND TANK INHIBITORS.Info
- Publication number
- ATE38820T1 ATE38820T1 AT85306894T AT85306894T ATE38820T1 AT E38820 T1 ATE38820 T1 AT E38820T1 AT 85306894 T AT85306894 T AT 85306894T AT 85306894 T AT85306894 T AT 85306894T AT E38820 T1 ATE38820 T1 AT E38820T1
- Authority
- AT
- Austria
- Prior art keywords
- acid
- weight
- salt
- polyalkylene oxide
- unsaturated
- Prior art date
Links
- 229920000233 poly(alkylene oxides) Polymers 0.000 title abstract 3
- 238000005260 corrosion Methods 0.000 title abstract 2
- 230000007797 corrosion Effects 0.000 title abstract 2
- 239000003112 inhibitor Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 6
- 150000003839 salts Chemical class 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229920003169 water-soluble polymer Polymers 0.000 abstract 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 abstract 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical group OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 abstract 1
- XEEYSDHEOQHCDA-UHFFFAOYSA-N 2-methylprop-2-ene-1-sulfonic acid Chemical compound CC(=C)CS(O)(=O)=O XEEYSDHEOQHCDA-UHFFFAOYSA-N 0.000 abstract 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 239000011976 maleic acid Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 abstract 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 abstract 1
- 150000003460 sulfonic acids Chemical class 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/12—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/173—Macromolecular compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
A method of inhibiting corrosion and the formation and deposition of scale and iron oxide in aqueous systems comprises adding to the system at least 0.1 ppm of a water-soluble polymer having an intrinsic viscosity of 0.05 to 2.5 dl/g, prepared from: (a) 35 to 90% by weight of an unsaturated carboxylic acid or its salt; and (b) 5 to 40% by weight of an unsaturated sulfonic acid or its salt; and (c) 5 to 40% by weight of an unsaturated polyalkylene oxide compound. A novel water soluble polymer having an intrinsic viscosity of 0.05 to 2.5 dl/g is prepared from: (a) 35 to 90% by weight of an unsaturated carboxylic compound that is acrylic acid, methacrylic acid, maleic acid, itaconic acid, a salt of such an acid or a mixture of two or more such compounds; (b) 5 to 40% by weight of an unsaturated sulfonic compound that is 2-acrylamido-2-methylpropylsulfonic acid, 2-methacrylamido-2-methylpropylsulfonc acid, methallylsulfonic acid, allylsulfonic acid, vinylsulfonic acid, styrenesulfonic acid; a salt of such an acid or a mixture ot two or more such compounds; and (c) 5 to 40% by weight of an unsaturated polyalkylene oxide compound.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66990384A | 1984-11-09 | 1984-11-09 | |
| EP85306894A EP0184894B2 (en) | 1984-11-09 | 1985-09-27 | Carboxylic-sulfonic-polyalkylene oxide polymers and their use as scale and corrosion inhibitors |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE38820T1 true ATE38820T1 (en) | 1988-12-15 |
Family
ID=24688195
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT85306894T ATE38820T1 (en) | 1984-11-09 | 1985-09-27 | CARBONIC-SULPHONIC-POLYALKYLENE OXIDE COPOLYMERS AND THEIR USE AS CORROSION AND TANK INHIBITORS. |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0184894B2 (en) |
| JP (1) | JPH0685919B2 (en) |
| AT (1) | ATE38820T1 (en) |
| AU (3) | AU4819285A (en) |
| CA (1) | CA1239742A (en) |
| DE (1) | DE3566387D1 (en) |
| HK (1) | HK80790A (en) |
| NZ (1) | NZ213578A (en) |
| SG (1) | SG42090G (en) |
| ZA (1) | ZA857324B (en) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0302153A1 (en) * | 1984-11-09 | 1989-02-08 | Calgon Corporation | Carboxylic/sulfonic polymer and carboxylic/polyalkylene oxide polymer admixtures for use in iron oxide deposit control |
| WO1988001656A2 (en) * | 1986-08-28 | 1988-03-10 | Wright Chemical Corporation | Polyethylene glycol-containing corrosion inhibitors |
| CA1337323C (en) * | 1986-12-08 | 1995-10-17 | Zahid Amjad | Treatment of aqueous medium with copolymers containing acrylamidoalkane sulfonic acid |
| AU613925B2 (en) * | 1987-06-23 | 1991-08-15 | Ciba-Geigy Ag | Scale inhibition |
| EP0297049B1 (en) * | 1987-06-23 | 1991-01-16 | Ciba-Geigy Ag | Scale inhibition |
| US4798683A (en) * | 1988-04-21 | 1989-01-17 | Calgon Corporation | Method for controlling corrosion using molybdate compositions |
| NZ230686A (en) * | 1988-09-26 | 1991-11-26 | Calgon Corp | Inhibiting sulphide attack on carbon steels with a water-soluble polymer |
| GB9321917D0 (en) * | 1993-10-23 | 1993-12-15 | Albright & Wilson | Corrosion inhibitors |
| DE4343993A1 (en) * | 1993-12-22 | 1995-06-29 | Stockhausen Chem Fab Gmbh | Graft copolymers of unsaturated monomers and polyhydroxy compounds, process for their preparation and their use |
| CA2143405C (en) * | 1994-03-11 | 2005-12-13 | Donald T. Freese | Method of inhibiting scale and controlling corrosion in cooling water systems |
| US5575920A (en) * | 1994-03-11 | 1996-11-19 | Betzdearborn Inc. | Method of inhibiting scale and controlling corrosion in cooling water systems |
| US5755972A (en) * | 1996-03-01 | 1998-05-26 | Rohm And Haas Company | Method for metal sulfate scale control in harsh oilfield conditions |
| JPH09255740A (en) * | 1996-03-26 | 1997-09-30 | Nof Corp | Terpolymer |
| FR2803304B1 (en) * | 1999-12-29 | 2006-03-24 | Ceca Sa | INORGANIC DEPOSIT INHIBITORS, ESPECIALLY IN OIL WELLS |
| FR2810261B1 (en) * | 2000-06-15 | 2002-08-30 | Coatex Sa | USE OF LOW ANIONIC COPOLYMERS AS A DISPERSING AGENT AND / OR AID FOR GRINDING AQUEOUS SUSPENSION OF MINERALS, AQUEOUS SUSPENSIONS OBTAINED AND USES THEREOF |
| CA2734878C (en) * | 2008-09-01 | 2014-10-21 | The Procter & Gamble Company | Laundry detergent or cleaning composition comprising sulfonate group-containing copolymers and manufacturing method thereof |
| US20110049053A1 (en) * | 2009-09-02 | 2011-03-03 | Hirsch Keith A | Method for inhibiting the deposition of silica and/or silicate compounds in aqueous systems |
| CN102575054B (en) * | 2009-09-21 | 2014-06-25 | Sika技术股份公司 | Fe(III)-complexing agent for stabilizing comb polymers in mineral binding agents |
| EP2643370B1 (en) * | 2010-11-23 | 2019-07-03 | Basf Se | Copolymers containing carboxylic acid groups, sulfonic acid groups, and polyalkylene oxide groups, used as scale-inhibiting additives to detergents and cleaning agents |
| MX365529B (en) * | 2011-08-10 | 2019-06-06 | Basf Se | Polymer blends as coating inhibitors in water-carrying systems. |
| JP5946363B2 (en) * | 2012-08-10 | 2016-07-06 | 伯東株式会社 | Silica scale prevention method and scale inhibitor in water system, and water treatment method and water treatment agent that suppress silica scale and suppress metal corrosion |
| DE112014004369B4 (en) | 2013-09-24 | 2021-05-06 | Nippon Shokubai Co., Ltd. | (Meth) acrylic acid copolymer and process for its preparation |
| US20180057626A1 (en) * | 2015-03-25 | 2018-03-01 | Nippon Shokubai Co., Ltd. | Copolymer |
| AR104517A1 (en) | 2015-12-07 | 2017-07-26 | Dow Global Technologies Llc | METHOD FOR THE TREATMENT OF INHIBITION OF FRESH WATER INCRUSTATIONS USED IN A WELL OF OIL, GAS, OR GEOTHERMAL PRODUCTION OR UNDERGROUND TRAINING |
| CN110066358B (en) * | 2018-01-23 | 2022-09-27 | 中国石油化工股份有限公司 | Phosphorus-free polymer corrosion inhibitor and preparation method and application thereof |
| SG11202011971RA (en) * | 2018-06-01 | 2020-12-30 | Dow Global Technologies Llc | Inhibition of silica scale using a chelating agent blended with acid and alkylene oxide derived polymer dispersants |
| CN118754330B (en) * | 2024-08-21 | 2025-03-14 | 中节能(象山)环保能源有限公司 | Turbine circulating water scale inhibition dispersing agent and preparation method thereof |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2123732A1 (en) * | 1971-05-13 | 1972-11-16 | Schnell, Karl, 7065 Winterbach | Sausage skin loader - for extrusion nozzle of sausage machines |
| US3898037A (en) * | 1972-06-01 | 1975-08-05 | Betz Laboratories | Acrylamido-sulfonic acid polymers and their use |
| US3928196A (en) * | 1973-12-05 | 1975-12-23 | Calgon Corp | Inhibition of scale deposition |
| DE2758122A1 (en) * | 1977-12-24 | 1979-07-05 | Basf Ag | WATER-SOLUBLE COPOLYMERISATES BASED ON HYDROPHILIC AETHYLENICALLY UNSATURATED MONOMERS |
| JPS6024807B2 (en) * | 1979-02-19 | 1985-06-14 | 昭和電工株式会社 | Method for producing super absorbent hydrogel |
| JPS5944119B2 (en) * | 1980-06-26 | 1984-10-26 | 栗田工業株式会社 | water treatment agent |
| JPS5914277B2 (en) * | 1981-07-01 | 1984-04-03 | 株式会社日本触媒 | Anti-scale agent |
| JPS5922698A (en) * | 1982-07-27 | 1984-02-04 | Sanyo Chem Ind Ltd | Scale preventive agent for boiler water and cooling water |
| JPS59105892A (en) * | 1982-12-10 | 1984-06-19 | Kurita Water Ind Ltd | water treatment agent |
| JPH0643469B2 (en) * | 1983-03-25 | 1994-06-08 | 花王株式会社 | Method for producing maleic acid copolymer |
| IN161206B (en) * | 1983-06-28 | 1987-10-17 | Goodrich Co B F |
-
1985
- 1985-09-23 NZ NZ213578A patent/NZ213578A/en unknown
- 1985-09-24 ZA ZA857324A patent/ZA857324B/en unknown
- 1985-09-25 CA CA000491558A patent/CA1239742A/en not_active Expired
- 1985-09-27 EP EP85306894A patent/EP0184894B2/en not_active Expired - Lifetime
- 1985-09-27 DE DE8585306894T patent/DE3566387D1/en not_active Expired
- 1985-09-27 AT AT85306894T patent/ATE38820T1/en not_active IP Right Cessation
- 1985-09-30 JP JP60217773A patent/JPH0685919B2/en not_active Expired - Lifetime
- 1985-10-02 AU AU48192/85A patent/AU4819285A/en not_active Abandoned
-
1989
- 1989-10-20 AU AU43598/89A patent/AU615353B2/en not_active Ceased
-
1990
- 1990-06-19 SG SG420/90A patent/SG42090G/en unknown
- 1990-10-03 HK HK807/90A patent/HK80790A/en not_active IP Right Cessation
-
1991
- 1991-07-17 AU AU81159/91A patent/AU8115991A/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP0184894A1 (en) | 1986-06-18 |
| EP0184894B1 (en) | 1988-11-23 |
| CA1239742A (en) | 1988-07-26 |
| JPH0685919B2 (en) | 1994-11-02 |
| ZA857324B (en) | 1986-05-28 |
| AU4819285A (en) | 1986-05-15 |
| AU8115991A (en) | 1991-10-31 |
| SG42090G (en) | 1993-01-29 |
| HK80790A (en) | 1990-10-12 |
| JPS61114797A (en) | 1986-06-02 |
| NZ213578A (en) | 1988-04-29 |
| AU4359889A (en) | 1990-02-01 |
| DE3566387D1 (en) | 1988-12-29 |
| AU615353B2 (en) | 1991-09-26 |
| EP0184894B2 (en) | 1993-03-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| UEP | Publication of translation of european patent specification | ||
| UEP | Publication of translation of european patent specification | ||
| REN | Ceased due to non-payment of the annual fee |