ATE395134T1 - Hochaktiver photokatalysator - Google Patents
Hochaktiver photokatalysatorInfo
- Publication number
- ATE395134T1 ATE395134T1 AT01272926T AT01272926T ATE395134T1 AT E395134 T1 ATE395134 T1 AT E395134T1 AT 01272926 T AT01272926 T AT 01272926T AT 01272926 T AT01272926 T AT 01272926T AT E395134 T1 ATE395134 T1 AT E395134T1
- Authority
- AT
- Austria
- Prior art keywords
- light
- photocatalytic
- particles
- powder
- highly active
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3653—Treatment with inorganic compounds
- C09C1/3661—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/34—Mechanical properties
- B01J35/36—Mechanical strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/10—Magnesium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
- B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
- B01J27/1806—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with alkaline or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/395—Thickness of the active catalytic layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/07—Producing by vapour phase processes, e.g. halide oxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
- B01J2235/10—Infrared [IR]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
- B01J2235/15—X-ray diffraction
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Catalysts (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000402470 | 2000-12-28 | ||
| JP2001388615 | 2001-12-21 | ||
| JP2001390736 | 2001-12-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE395134T1 true ATE395134T1 (de) | 2008-05-15 |
Family
ID=27345632
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT01272926T ATE395134T1 (de) | 2000-12-28 | 2001-12-28 | Hochaktiver photokatalysator |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP1354854B1 (de) |
| JP (1) | JP3949055B2 (de) |
| KR (1) | KR100603998B1 (de) |
| CN (1) | CN100447188C (de) |
| AT (1) | ATE395134T1 (de) |
| CA (1) | CA2436747C (de) |
| DE (1) | DE60134050D1 (de) |
| MX (1) | MXPA03005892A (de) |
| WO (1) | WO2002053501A1 (de) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2316568A1 (de) * | 2001-12-21 | 2011-05-04 | Showa Denko K.K. | Photokatalysatorteilchen enthaltend kondensierte Fosfaten |
| ATE425810T1 (de) | 2003-10-30 | 2009-04-15 | Showa Denko Kk | Zusammensetzung zur herstellung eines transparenten films |
| JP4522082B2 (ja) * | 2003-12-05 | 2010-08-11 | 石原産業株式会社 | 光触媒液状組成物およびそれを用いて形成した光触媒体 |
| US20070225436A1 (en) * | 2004-01-26 | 2007-09-27 | Kaneka Corporation | Curable Composition |
| JP4393963B2 (ja) | 2004-03-17 | 2010-01-06 | 住友化学株式会社 | 光触媒体コーティング液 |
| KR100559377B1 (ko) * | 2004-05-28 | 2006-03-10 | 율촌화학 주식회사 | 생분해성 전분 용기용 조성물 및 이를 이용한 생분해성전분 용기 |
| DE102004027118B4 (de) * | 2004-06-03 | 2006-05-11 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zum Nachweis des photokatalytischen Abbaus organischer Farbstoffe mittels Fluoreszenzanalyse |
| JP4810678B2 (ja) * | 2005-09-01 | 2011-11-09 | 国立大学法人九州工業大学 | 光触媒の製造方法、光触媒の使用方法及び有害物質の分解方法 |
| KR100714849B1 (ko) * | 2005-11-17 | 2007-05-04 | 경희대학교 산학협력단 | 광촉매 조성물, 그 고정방법 및 상기 광촉매를 이용한연속식 광촉매 반응기 |
| US7901660B2 (en) | 2005-12-29 | 2011-03-08 | The Board Of Trustees Of The University Of Illinois | Quaternary oxides and catalysts containing quaternary oxides |
| US7521394B2 (en) | 2005-12-29 | 2009-04-21 | The Board Of Trustees Of The University Of Illinois | Nanoparticles containing titanium oxide |
| EP1997781B1 (de) | 2007-05-22 | 2014-07-16 | Evonik Degussa GmbH | Verfahren zur Herstellung von Titandioxid mit variabler Sinteraktivität |
| JP2010115635A (ja) | 2008-06-05 | 2010-05-27 | Sumitomo Chemical Co Ltd | 光触媒体分散液、その製造方法およびその用途 |
| JP2011036770A (ja) | 2009-08-07 | 2011-02-24 | Hokkaido Univ | 貴金属担持光触媒体粒子の製造方法 |
| JP2011224534A (ja) | 2009-09-16 | 2011-11-10 | Sumitomo Chemical Co Ltd | 光触媒複合体、およびこれを用いた光触媒機能製品 |
| CN102372997A (zh) * | 2011-10-11 | 2012-03-14 | 徐梅 | 一种成膜物为聚脂肪酸乙烯醚的涂料 |
| US9210939B2 (en) * | 2011-12-22 | 2015-12-15 | Showa Denko K.K. | Copper-and-titanium-containing composition and production method therefor |
| CN103756597A (zh) * | 2013-12-25 | 2014-04-30 | 大连润鸣材料技术有限公司 | 光触媒氟树脂表面涂层 |
| CN106362584A (zh) * | 2016-08-25 | 2017-02-01 | 杭州利纯环保科技有限公司 | 一种纳米光触媒空气除味剂及其制备方法 |
| DE202020107565U1 (de) | 2020-12-28 | 2022-03-29 | Mursall Active Coating Gmbh | Masterbatch, Kunststoffelement, Glaselement und Glasschmelze mit photokatalytisch aktiven Partikeln |
| CN118048106B (zh) * | 2024-02-19 | 2024-11-12 | 重庆大学 | 一种太阳能光伏板表面自清洁涂层及其制备方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5242880A (en) * | 1992-05-27 | 1993-09-07 | Eastman Kodak Company | Photoactive catalyst of barium phosphate or calcium phosphate supported on anatase titanium dioxide |
| JPH09296364A (ja) * | 1996-04-26 | 1997-11-18 | Lion Corp | 繊維布帛用抗菌防臭処理剤およびそれを用いた繊維布帛の抗菌防臭処理方法 |
| JP3275032B2 (ja) * | 1997-03-03 | 2002-04-15 | 独立行政法人産業技術総合研究所 | 環境浄化材料及びその製造方法 |
| JPH11156202A (ja) * | 1997-11-21 | 1999-06-15 | Toto Ltd | 光触媒性親水性組成物 |
| ATE422964T1 (de) * | 1997-12-25 | 2009-03-15 | Agency Ind Science Techn | Fotokatalysatorpulver zur reinigung der umwelt, das pulver enthaltende polymerzusammensetzung und formgegenstand daraus, sowie verfahren zu deren herstellung |
| JP4071384B2 (ja) * | 1998-04-14 | 2008-04-02 | 独立行政法人産業技術総合研究所 | 光触媒を含む塗料組成物 |
| US5981425A (en) * | 1998-04-14 | 1999-11-09 | Agency Of Industrial Science & Tech. | Photocatalyst-containing coating composition |
| JPH11302596A (ja) * | 1998-04-20 | 1999-11-02 | Kansai Paint Co Ltd | 有害物質分解性被覆組成物及びこれを塗布した基材 |
| JPH11309379A (ja) * | 1998-04-27 | 1999-11-09 | Toto Ltd | 光触媒性親水性部材、及び光触媒性親水性コ−ティング組成物 |
| WO2000006300A1 (fr) * | 1998-07-30 | 2000-02-10 | Toto Ltd. | Procede de production d'un materiau haute performance a fonction photocatalytique et dispositif y relatif |
| US6908881B1 (en) * | 1998-08-21 | 2005-06-21 | Ecodevice Laboratory Co., Ltd. | Visible radiation type photocatalyst and production method thereof |
| DE69935203T2 (de) * | 1998-12-07 | 2007-10-25 | Bridgestone Corp. | Verwendung einer farbstoffbeinhaltenden beschichtungsflüssigkeit zur herstellung von einem fotokatalysatorenthaltenden beschichtungsfilm |
| JP2000218161A (ja) * | 1999-01-29 | 2000-08-08 | Sharp Corp | 光触媒体 |
| JP3959213B2 (ja) * | 1999-06-30 | 2007-08-15 | 住友化学株式会社 | 酸化チタン、それを用いてなる光触媒体及び光触媒体コーティング剤 |
| WO2001023483A1 (fr) * | 1999-09-30 | 2001-04-05 | Showa Denko Kabushiki Kaisha | Composition de revetement photocatalytique et produit ayant un film photocatalytique mince |
| JP4647803B2 (ja) * | 2000-04-21 | 2011-03-09 | 昭和電工株式会社 | 光触媒粉体の製造法 |
-
2001
- 2001-12-28 EP EP01272926A patent/EP1354854B1/de not_active Expired - Lifetime
- 2001-12-28 DE DE60134050T patent/DE60134050D1/de not_active Expired - Lifetime
- 2001-12-28 CA CA2436747A patent/CA2436747C/en not_active Expired - Fee Related
- 2001-12-28 WO PCT/JP2001/011685 patent/WO2002053501A1/ja not_active Ceased
- 2001-12-28 CN CNB018214967A patent/CN100447188C/zh not_active Expired - Fee Related
- 2001-12-28 MX MXPA03005892A patent/MXPA03005892A/es unknown
- 2001-12-28 AT AT01272926T patent/ATE395134T1/de not_active IP Right Cessation
- 2001-12-28 KR KR1020037008828A patent/KR100603998B1/ko not_active Expired - Fee Related
- 2001-12-28 JP JP2002554625A patent/JP3949055B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR100603998B1 (ko) | 2006-07-25 |
| JP3949055B2 (ja) | 2007-07-25 |
| CN1483002A (zh) | 2004-03-17 |
| CN100447188C (zh) | 2008-12-31 |
| EP1354854A4 (de) | 2004-06-09 |
| JPWO2002053501A1 (ja) | 2004-04-30 |
| CA2436747C (en) | 2010-04-06 |
| EP1354854B1 (de) | 2008-05-14 |
| MXPA03005892A (es) | 2003-09-10 |
| EP1354854A1 (de) | 2003-10-22 |
| WO2002053501A1 (en) | 2002-07-11 |
| DE60134050D1 (de) | 2008-06-26 |
| KR20030067737A (ko) | 2003-08-14 |
| CA2436747A1 (en) | 2002-07-11 |
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