ATE409512T1 - Verbindungen zur kontrollierten freigabe aktiver molekülen - Google Patents

Verbindungen zur kontrollierten freigabe aktiver molekülen

Info

Publication number
ATE409512T1
ATE409512T1 AT02781640T AT02781640T ATE409512T1 AT E409512 T1 ATE409512 T1 AT E409512T1 AT 02781640 T AT02781640 T AT 02781640T AT 02781640 T AT02781640 T AT 02781640T AT E409512 T1 ATE409512 T1 AT E409512T1
Authority
AT
Austria
Prior art keywords
compounds
controlled release
active molecules
perfumery
present
Prior art date
Application number
AT02781640T
Other languages
English (en)
Inventor
Charles Fehr
Arnaud Struillou
Jose Galindo
Original Assignee
Firmenich & Cie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Firmenich & Cie filed Critical Firmenich & Cie
Application granted granted Critical
Publication of ATE409512T1 publication Critical patent/ATE409512T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • C11D3/502Protected perfumes
    • C11D3/507Compounds releasing perfumes by thermal or chemical activation
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/0007Aliphatic compounds
    • C11B9/0015Aliphatic compounds containing oxygen as the only heteroatom
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/57Compounds covalently linked to a(n inert) carrier molecule, e.g. conjugates, pro-fragrances

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fats And Perfumes (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Cosmetics (AREA)
AT02781640T 2001-12-13 2002-12-11 Verbindungen zur kontrollierten freigabe aktiver molekülen ATE409512T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IB0102520 2001-12-13

Publications (1)

Publication Number Publication Date
ATE409512T1 true ATE409512T1 (de) 2008-10-15

Family

ID=11004233

Family Applications (1)

Application Number Title Priority Date Filing Date
AT02781640T ATE409512T1 (de) 2001-12-13 2002-12-11 Verbindungen zur kontrollierten freigabe aktiver molekülen

Country Status (15)

Country Link
US (2) US7723286B2 (de)
EP (1) EP1460994B1 (de)
JP (2) JP4694785B2 (de)
CN (1) CN1290485C (de)
AT (1) ATE409512T1 (de)
AU (1) AU2002348801B2 (de)
BR (1) BRPI0214515B1 (de)
CA (1) CA2468231A1 (de)
DE (1) DE60229165D1 (de)
ES (1) ES2312635T3 (de)
MX (1) MXPA04005512A (de)
PL (1) PL209377B1 (de)
RU (1) RU2296118C2 (de)
WO (1) WO2003049666A2 (de)
ZA (1) ZA200403708B (de)

Families Citing this family (77)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0227807D0 (en) * 2002-11-29 2003-01-08 Givaudan Sa Improvements in or relating ot organic compounds
EP1814924A2 (de) * 2004-10-08 2007-08-08 Firmenich Sa Amphiphile sternblockcopolymere
EP1904541B1 (de) * 2005-07-14 2016-03-16 Firmenich Sa Amphiphile copolymerkonjugate zur kontrollierten freisetzung aktiver moleküle
US20070275866A1 (en) * 2006-05-23 2007-11-29 Robert Richard Dykstra Perfume delivery systems for consumer goods
US8022030B2 (en) 2006-10-10 2011-09-20 Firmenich Sa Polymer conjugates for a controlled release of active molecules
US7879747B2 (en) * 2007-03-30 2011-02-01 Kimberly-Clark Worldwide, Inc. Elastic laminates having fragrance releasing properties and methods of making the same
US20080305977A1 (en) * 2007-06-05 2008-12-11 The Procter & Gamble Company Perfume systems
WO2010029462A1 (en) 2008-09-12 2010-03-18 Firmenich Sa Divinyl ether derivatives capable of releasing active aldehydes and ketones and methods of use for perfuming surfaces
CN102170858A (zh) 2008-10-21 2011-08-31 弗门尼舍有限公司 加香组合物及其应用
US20100102142A1 (en) * 2008-10-28 2010-04-29 Daria Tagliareni Scent dispenser assembly
BRPI0922770A2 (pt) 2008-12-01 2019-09-24 Procter & Gamble sistemas de perfume
US8754028B2 (en) * 2008-12-16 2014-06-17 The Procter & Gamble Company Perfume systems
ES2767877T3 (es) 2009-06-19 2020-06-18 Firmenich & Cie Composiciones para contrarrestar el mal olor y procedimiento para su uso para contrarrestar el mal olor del sudor
EP2270124A1 (de) 2009-06-30 2011-01-05 The Procter & Gamble Company Bleichzusammensetzungen mit Parfümliefersystem
MX2012006616A (es) 2009-12-09 2012-06-21 Procter & Gamble Productos para el cuidado de las telas y el hogar.
KR101463727B1 (ko) 2009-12-17 2014-11-21 더 프록터 앤드 갬블 캄파니 악취 결합 중합체 및 악취 제어 성분을 포함하는 청향 조성물
JP5911480B2 (ja) 2010-06-10 2016-04-27 フイルメニツヒ ソシエテ アノニムFirmenich Sa 香料組成物及びそれらの使用
EP3287511A1 (de) 2010-06-22 2018-02-28 The Procter & Gamble Company Parfümsysteme
JP5744192B2 (ja) 2010-06-22 2015-07-01 ザ プロクター アンド ギャンブルカンパニー 香料系
BR112013000101A2 (pt) 2010-07-02 2016-05-17 Procter & Gamble filamentos compreendendo mantas de não tecido com agente ativo e métodos de fabricação dos mesmos
CN103025930B (zh) 2010-07-02 2014-11-12 宝洁公司 递送活性剂的方法
MX345025B (es) 2010-07-02 2017-01-12 Procter & Gamble Producto detergente.
CN102971126B (zh) 2010-07-02 2016-03-23 宝洁公司 由非织造纤维网制备膜的方法
RU2541275C2 (ru) 2010-07-02 2015-02-10 Дзе Проктер Энд Гэмбл Компани Филаменты, содержащие неароматизированный активный агент, нетканые полотна и способы их получения
US8907134B2 (en) * 2011-02-17 2014-12-09 Firmenich Sa Perfuming ingredient of the galbanum family
WO2012113746A1 (en) * 2011-02-21 2012-08-30 Firmenich Sa Consumer products containing pro-fragrances
BR112013033049A2 (pt) 2011-06-23 2017-01-31 Procter & Gamble sistemas de perfume
WO2013002786A1 (en) 2011-06-29 2013-01-03 Solae Baked food compositions comprising soy whey proteins that have been isolated from processing streams
JP5253608B2 (ja) * 2011-07-26 2013-07-31 花王株式会社 香料放出剤
MX352264B (es) * 2011-10-06 2017-11-16 Firmenich & Cie Latex fotolabil para la liberacion de perfumes.
WO2013060691A2 (en) 2011-10-27 2013-05-02 Firmenich Sa Perfuming compositions and uses thereof
CN104125847B (zh) 2011-11-04 2017-09-08 弗门尼舍有限公司 加香组合物及其用途
EP4592449A3 (de) 2012-01-04 2025-10-22 The Procter & Gamble Company Faserstrukturen mit teilchen und verfahren zu ihrer herstellung
RU2591704C2 (ru) 2012-01-04 2016-07-20 Дзе Проктер Энд Гэмбл Компани Содержащие активные агенты волокнистые структуры с множеством областей
CN104039945B (zh) 2012-01-04 2017-03-15 宝洁公司 具有不同密度的多个区域的含活性物质纤维结构
JP6000438B2 (ja) 2012-03-20 2016-09-28 フイルメニツヒ ソシエテ アノニムFirmenich Sa 活性な香料分子の制御放出のための化合物
US20140323383A1 (en) * 2013-04-26 2014-10-30 The Procter & Gamble Company Pouch comprising a liquid detergent composition
BR112015027665B1 (pt) * 2013-06-19 2022-05-31 Firmenich Sa Conjugados de polissiloxano como sistemas de liberação de fragrância
CN105431126A (zh) * 2013-07-22 2016-03-23 高砂香料工业株式会社 2,2,6-三甲基环己烷羧酸酯的衍生物
CN105518116B (zh) * 2013-09-09 2019-12-10 弗门尼舍有限公司 用作活性分子受控释放用的前体的硫醚衍生物
EP4253649B1 (de) 2013-12-09 2025-04-23 The Procter & Gamble Company Faserstrukturen mit einem wirkstoff und mit darauf aufgedruckter grafik
CN105829514B (zh) * 2013-12-19 2020-12-22 花王株式会社 赋香方法
US20150217015A1 (en) * 2014-02-04 2015-08-06 The Procter & Gamble Company Long lasting freshening compositions
JP6762935B2 (ja) * 2014-12-10 2020-09-30 フイルメニツヒ ソシエテ アノニムFirmenich Sa ファイン香料におけるフレグランス送達システムとしてのポリシロキサン
EP3259339B1 (de) 2015-02-17 2018-10-31 Firmenich SA Aus poly(asparaginsäure) abgeleitete copolymere zur kontrollierten freisetzung von duftstoffen
WO2016135193A1 (en) 2015-02-25 2016-09-01 Firmenich Sa A synergistic perfuming composition
EP3365326B1 (de) * 2015-10-19 2019-12-11 Firmenich SA Peroxyhemiacetale produftstoff- und proaroma-verbindungen
US9796948B2 (en) 2016-01-13 2017-10-24 The Procter & Gamble Company Laundry detergent compositions comprising renewable components
JP6643160B2 (ja) * 2016-03-24 2020-02-12 ライオン株式会社 液体柔軟剤組成物
WO2017172567A1 (en) * 2016-03-28 2017-10-05 The Procter & Gamble Company Long lasting and stable freshening compositions and methods of freshening the air
US12016943B2 (en) 2016-08-25 2024-06-25 Firmenich Sa Antiperspirant or deodorant composition
US11697905B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles that exhibit consumer acceptable article in-use properties
US11697906B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles and product-shipping assemblies for containing the same
US11697904B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles that exhibit consumer acceptable article in-use properties
JP6886045B2 (ja) 2017-01-27 2021-06-16 ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company 消費者に許容可能な物品使用特性を示す、活性剤含有物品
GB201803410D0 (en) * 2018-03-02 2018-04-18 Givaudan Sa Improvements in or relating to organic compounds
EP3533786A1 (de) 2018-03-02 2019-09-04 Givaudan SA Thioether-vorstufen für keton- und aldehydduftstoffe
MX2020009660A (es) * 2018-06-21 2020-10-08 Firmenich & Cie Compuestos para proporcionar un olor a fresa de larga duracion.
US12264295B2 (en) 2019-03-20 2025-04-01 Firmenich Sa Encapsulated pro-perfume compounds
WO2020224767A1 (en) * 2019-05-07 2020-11-12 Givaudan Sa Organic compounds
CN114096651A (zh) 2019-06-27 2022-02-25 弗门尼舍有限公司 已加香消费产品
JP6850834B2 (ja) * 2019-07-19 2021-03-31 ライオン株式会社 液体柔軟剤組成物
CN110845629A (zh) * 2019-12-02 2020-02-28 佛山欧神诺陶瓷有限公司 一种反应型香味缓释纳米微晶纤维素及其制备方法
US12122981B2 (en) 2019-12-05 2024-10-22 The Procter & Gamble Company Cleaning composition
EP4069811A1 (de) 2019-12-05 2022-10-12 The Procter & Gamble Company Verfahren zur herstellung einer reinigungszusammensetzung
US12291689B2 (en) 2019-12-19 2025-05-06 Firmenich Sa Compounds for providing a long-lasting floral and fruity odor
MX2022005374A (es) * 2019-12-20 2022-05-19 Firmenich & Cie Composicion de jabon.
EP4097081A1 (de) 2020-01-28 2022-12-07 Symrise AG Selenidderivate von duftstoffverbindungen
US20230159426A1 (en) * 2020-04-14 2023-05-25 Firmenich Sa Lily of the valley odorant
US12590264B2 (en) 2020-06-03 2026-03-31 International Flavors & Fragrances Inc. Profragrance conjugates
WO2022063943A1 (en) 2020-09-24 2022-03-31 Firmenich Sa Consumer products containing pro-fragrances
CN116018124A (zh) 2020-10-23 2023-04-25 弗门尼舍有限公司 限制或消除汗臭味感知的组合物
MX2023008851A (es) 2021-02-11 2023-08-15 Firmenich & Cie Proceso para la preparacion de un tioeter.
WO2023275056A1 (en) * 2021-06-28 2023-01-05 Firmenich Sa Textile articles for tumble-drying
US12600926B2 (en) 2022-01-13 2026-04-14 The Procter & Gamble Company Treatment compositions with modified amino acid dimers for delivering a benefit agent
US20230220300A1 (en) * 2022-01-13 2023-07-13 The Procter & Gamble Company Treatment compositions with modified amino acid multimers
EP4731739A1 (de) 2023-06-21 2026-04-29 Givaudan SA Neue verbindungen

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3403686A (en) * 1965-09-17 1968-10-01 Brown & Williamson Tobacco Corp Flavorant incorporation in smoking tobacco
CH530459A (de) * 1969-09-10 1972-11-15 Givaudan & Cie Sa Riech- und/oder Geschmackstoffkompositionen
US3952062A (en) * 1969-09-10 1976-04-20 Givaudan Corporation Mercapto- or alkylthio-substituted menthenones
CH551957A (de) * 1970-12-08 1974-07-31 Givaudan & Cie Sa Verfahren zur herstellung von neuen jononderivaten.
US3883572A (en) * 1971-11-26 1975-05-13 Givaudan Corp Novel mercaptoderivatives of ionones and irones
CH571484A5 (de) * 1972-10-17 1976-01-15 Givaudan & Cie Sa
US4065408A (en) * 1976-09-15 1977-12-27 International Flavors & Fragrances Inc. α-Oxy(oxo) sulfide perfume and cologne compositions
GB1566538A (en) * 1977-02-25 1980-04-30 Naarden Internationale Nv Acyl polyalkyo indan compounds their preparation and their use in perfumery
US4107209A (en) * 1977-03-03 1978-08-15 International Flavors & Fragrances Inc. 1-[3-(Methylthio)butyryl]-2,6,6-trimethyl-cyclohexene and the 1,3-cyclohexadiene analog
US4162335A (en) * 1977-03-03 1979-07-24 Int Flavors & Fragrances Inc Flavoring with 1-{8 3-(methylthio)butyryl{9 -2,6,6-trimethyl-cyclohexene and the 1,3-cyclohexadiene analog
US4209025A (en) * 1977-03-03 1980-06-24 International Flavors & Fragrances Inc. Process for augmenting or enhancing the flavor of tobacco using 1-(3-methylthio)butyryl)-2,6,6-trimethyl-cyclohexene and the 1,3-cyclohexadiene analog thereof
US4149020A (en) * 1978-04-05 1979-04-10 International Flavors & Fragrances Inc. Intermediate for preparation of 2,3-dimethyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-pentanol
JPS55136249A (en) * 1979-04-09 1980-10-23 T Hasegawa Co Ltd Alkyl 3-alkylcarbonyl oxy-cis (or trans)-5-octenoate, its preparation and use
JPS5665842A (en) * 1979-10-31 1981-06-03 T Hasegawa Co Ltd 3-substituted-cis- or -trans-4-octenoic acid or its ester, their preparation and use
JPS57197262A (en) * 1981-05-29 1982-12-03 Res Dev Corp Of Japan Production of optically active beta-arylthio or alkylthioketone
DE3228289A1 (de) * 1982-07-29 1984-02-09 Dragoco Gerberding & Co Gmbh, 3450 Holzminden 1-(1-methylthio-3-oxo-butyl)-2,6,6-trimethyl- cyclohexene und deren verwendung als riech- und aromastoff
DE3307869A1 (de) * 1983-03-05 1984-09-06 Dragoco Gerberding & Co Gmbh, 3450 Holzminden Methylsubstituierte 1-((3-methylthio)-1-oxo-butyl)-cyclohex-2-ene, verfahren zu deren herstellung und deren verwendung als riech- und aromastoffe
JPS61225138A (ja) * 1985-03-29 1986-10-06 Daicel Chem Ind Ltd 多重結合を含む原子団を持つアルコ−ルの光学分割方法
SU1698276A1 (ru) * 1988-07-20 1991-12-15 Научно-производственное объединение по эфиромасличным культурам и маслам "Эфирмасло" Способ получени ароматического продукта с запахом розы
US5143900A (en) * 1989-05-19 1992-09-01 Colgate-Palmolive Company Perfumes containing N-lower alkyl neoalkanamide (s)
US5158941A (en) * 1990-06-08 1992-10-27 E. I. Du Pont De Nemours And Company Lipid A analog as stimulant for production of interleukin-1 in human monocytes and tumor cell growth inhibitor
JP2981621B2 (ja) * 1990-11-30 1999-11-22 イハラケミカル工業株式会社 ビフェニルビスホスフィン錯体
US5531910A (en) * 1995-07-07 1996-07-02 The Procter & Gamble Company Biodegradable fabric softener compositions with improved perfume longevity
RU2113133C1 (ru) * 1995-12-01 1998-06-20 Всероссийский научно-исследовательский институт пищевых ароматизаторов, кислот и красителей Пищевой ароматизатор со вкусом и ароматом тропических плодов
WO1997024308A1 (fr) * 1995-12-29 1997-07-10 Nippon Zeon Co., Ltd. Procede de preparation de composes carbonyle
US5919752A (en) * 1997-04-24 1999-07-06 Procter & Gamble Perfumes having odor longevity benefits
ES2195468T3 (es) * 1998-05-08 2003-12-01 Firmenich & Cie Cetonas insaturadas y su utilizacion en perfumeria.
JP4469441B2 (ja) * 1999-02-10 2010-05-26 明治乳業株式会社 神経変性疾患の予防又は治療薬
DE60000397T2 (de) * 1999-08-18 2003-05-22 Givaudan Sa, Vernier Weichmittelzusammensetzung
JP4071421B2 (ja) * 2000-06-07 2008-04-02 高砂香料工業株式会社 シクロヘキセニルメチルケトンの製造法
EP1318144B1 (de) * 2001-12-05 2008-01-16 Firmenich Sa Ungesättigter Ester als Riechstoffkomponente

Also Published As

Publication number Publication date
JP2010215910A (ja) 2010-09-30
CN1290485C (zh) 2006-12-20
JP2005511710A (ja) 2005-04-28
BR0214515A (pt) 2004-11-30
WO2003049666A3 (en) 2004-07-15
RU2296118C2 (ru) 2007-03-27
ES2312635T3 (es) 2009-03-01
RU2004121218A (ru) 2006-01-10
CN1602184A (zh) 2005-03-30
EP1460994B1 (de) 2008-10-01
DE60229165D1 (de) 2008-11-13
MXPA04005512A (es) 2004-12-06
CA2468231A1 (en) 2003-06-19
BRPI0214515B1 (pt) 2016-03-22
ZA200403708B (en) 2005-06-29
US20090181878A1 (en) 2009-07-16
JP4694785B2 (ja) 2011-06-08
JP5409457B2 (ja) 2014-02-05
PL371541A1 (en) 2005-06-27
US20040220074A1 (en) 2004-11-04
PL209377B1 (pl) 2011-08-31
US7723286B2 (en) 2010-05-25
EP1460994A2 (de) 2004-09-29
US7935669B2 (en) 2011-05-03
AU2002348801B2 (en) 2007-11-22
WO2003049666A2 (en) 2003-06-19
AU2002348801A1 (en) 2003-06-23

Similar Documents

Publication Publication Date Title
DE60229165D1 (de) Verbindungen zur kontrollierten freigabe aktiver molekülen
ATE501179T1 (de) Polymerkonjugate zur kontrollierten freigabe von aktiven molekülen
MX339323B (es) Tricomas individualizados y productos que los utilizan.
TR200003487T2 (tr) Koku veren terkiplerin 2-benzoil benzoat, 2-alkanoil benzoat veya alfa -keto ester kullanılarak yavaş salınışı
EP1941870A3 (de) Parfümzusammensetzung, die Perilla-Aldehyd enthält
ATE515252T1 (de) Pseudokörpergeruchszusammensetzung
ATE291002T1 (de) Geruchsunterdrücker enthaltende kohlenwasserstoffhaltige zubereitung
IN2014CN03668A (de)
MX2009012419A (es) Derivados de 1,3,-diaza-4-oxo-heterociclicos de 3 a 7 elementos capaces de liberar aldehidos o cetonas activos.
ATE520638T1 (de) Aldehyde als parfüm- oder geschmackstoffbestandteile
ATE476410T1 (de) Alicyclische ester mit moschusgeruch
DE602004005890D1 (de) Moschus-geruchsstoffe
DE60032002D1 (de) Verfahren zur herstellung von antimikrobiellen parfümierenden zusammensetzungen
BR0102430A (pt) Precursores de fragrância
MX2017006401A (es) Polisiloxanos como sistemas de suministro de fragancias en perfumeria fina.
ATE384043T1 (de) Ungesättigter ester als riechstoffkomponente
DE60301363T2 (de) Anwendung einer Heterospiroverbindung als Parfüm und Aromabestandteil
WO2007007216A3 (en) Amphiphilic co-polymer conjugates for a controlled release of active molecules
DE60107580D1 (de) Riechstoffe
DE50207401D1 (de) Gemische zur verwendung als moschusriechstoff
DE60037679D1 (de) Verwendung von 2,4,7-decatrienal als duft- oder aromastoff
DE602006020162D1 (de) Sorbol-ester als parfüm-inhaltsstoffe
ATE449152T1 (de) Parfümierungsbestandteile, die zur verleihung von holzgerüchen befähigt sind
ATE473220T1 (de) 1-oxaspiro (4, 5 ) dec-3-en-derivate als duftstoffe
DE60319079D1 (de) Gehinderte ketone als riechstoff

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties