ATE409714T1 - Mono-, oligo and poly-3-(1,1- difluoroalkyl)thiophene und ihre verwendung als ladungstransportmaterial - Google Patents

Mono-, oligo and poly-3-(1,1- difluoroalkyl)thiophene und ihre verwendung als ladungstransportmaterial

Info

Publication number
ATE409714T1
ATE409714T1 AT02014069T AT02014069T ATE409714T1 AT E409714 T1 ATE409714 T1 AT E409714T1 AT 02014069 T AT02014069 T AT 02014069T AT 02014069 T AT02014069 T AT 02014069T AT E409714 T1 ATE409714 T1 AT E409714T1
Authority
AT
Austria
Prior art keywords
difluoroalkyl
oligo
mono
charge transport
thiophenes
Prior art date
Application number
AT02014069T
Other languages
English (en)
Inventor
Martin Heeney
Louise Farrand
Mark Giles
Marcus Thompson
Steven Tierney
Maxim Shkunov
David Sparrowe
Iain Mcculloch
Original Assignee
Merck Patent Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Merck Patent Gmbh filed Critical Merck Patent Gmbh
Application granted granted Critical
Publication of ATE409714T1 publication Critical patent/ATE409714T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
    • C07D333/12—Radicals substituted by halogen atoms or nitro or nitroso radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
    • C07D333/22—Radicals substituted by doubly bound hetero atoms, or by two hetero atoms other than halogen singly bound to the same carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D333/28—Halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
    • C09K19/3491—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having sulfur as hetero atom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/38—Polymers
    • C09K19/3804—Polymers with mesogenic groups in the main chain
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Electroluminescent Light Sources (AREA)
  • Thin Film Transistor (AREA)
AT02014069T 2001-07-25 2002-07-01 Mono-, oligo and poly-3-(1,1- difluoroalkyl)thiophene und ihre verwendung als ladungstransportmaterial ATE409714T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP01117651 2001-07-25

Publications (1)

Publication Number Publication Date
ATE409714T1 true ATE409714T1 (de) 2008-10-15

Family

ID=8178100

Family Applications (1)

Application Number Title Priority Date Filing Date
AT02014069T ATE409714T1 (de) 2001-07-25 2002-07-01 Mono-, oligo and poly-3-(1,1- difluoroalkyl)thiophene und ihre verwendung als ladungstransportmaterial

Country Status (4)

Country Link
US (1) US6806374B2 (de)
JP (1) JP2003176338A (de)
AT (1) ATE409714T1 (de)
DE (1) DE60229090D1 (de)

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JP2004534100A (ja) * 2001-07-09 2004-11-11 メルク　パテント　ゲゼルシャフト　ミット　ベシュレンクテル　ハフトング 重合性電荷移動化合物
US6949762B2 (en) * 2002-01-11 2005-09-27 Xerox Corporation Polythiophenes and devices thereof
JP4588637B2 (ja) * 2003-03-14 2010-12-01 株式会社半導体エネルギー研究所 共役分子、電界発光素子、及び電子機器
DE602004016858D1 (de) * 2003-08-06 2008-11-13 Merck Patent Gmbh Verfahren zur herstellung von regioregulären polymeren
EP1654298B1 (de) * 2003-08-06 2008-10-01 MERCK PATENT GmbH Verfahren zur herstellung von regioregulären polymeren
JP2005166265A (ja) * 2003-11-28 2005-06-23 Hitachi Displays Ltd 有機ｅｌ表示装置
US7294850B2 (en) * 2004-06-10 2007-11-13 Xerox Corporation Device with small molecular thiophene compound having divalent linkage
US7321133B2 (en) * 2004-11-17 2008-01-22 Plextronics, Inc. Heteroatomic regioregular poly(3-substitutedthiophenes) as thin film conductors in diodes which are not light emitting or photovoltaic
US20060131567A1 (en) * 2004-12-20 2006-06-22 Jie Liu Surface modified electrodes and devices using reduced organic materials
JP4731942B2 (ja) * 2005-02-16 2011-07-27 住友化学株式会社 ポリチオフェン
WO2006087680A1 (en) * 2005-02-18 2006-08-24 Koninklijke Philips Electronics N.V. Electronic device
US7385221B1 (en) * 2005-03-08 2008-06-10 University Of Kentucky Research Foundation Silylethynylated heteroacenes and electronic devices made therewith
JP4931118B2 (ja) 2005-09-08 2012-05-16 住友化学株式会社 フッ素化シクロペンタン環と芳香環との縮合したユニットを含む重合体、並びにこれを用いた有機薄膜及び有機薄膜素子
US20090159876A1 (en) * 2005-09-21 2009-06-25 Mitsubishi Chemical Corporation Organic semiconductor material and organic field effect transistor
WO2007095061A2 (en) * 2006-02-09 2007-08-23 Qd Vision, Inc. Device including semiconductor nanocrystals and a layer including a doped organic material and methods
WO2007097395A1 (ja) * 2006-02-22 2007-08-30 Sumitomo Chemical Company, Limited 含フッ素化合物及びその製造方法、含フッ素重合体、有機薄膜、並びに、有機薄膜素子
WO2008033388A2 (en) * 2006-09-12 2008-03-20 Qd Vision, Inc. A composite including nanoparticles, methods, and products including a composite
US7964741B2 (en) * 2008-05-20 2011-06-21 The United States Of America As Represented By The Secretary Of The Army Bibenzothiophene derivatives
JP2010209264A (ja) * 2009-03-11 2010-09-24 Sumitomo Chemical Co Ltd 含フッ素重合体及びこれを用いた有機薄膜
DE102009034194A1 (de) * 2009-07-22 2011-01-27 Merck Patent Gmbh Materialien für elektronische Vorrichtungen
KR101512173B1 (ko) * 2013-10-10 2015-04-16 한국화학연구원 호스트 액정에 대한 용해도가 향상된 불소 도입 페닐-싸이오펜계 중합성 메조겐 화합물, 이의 제조방법 및 이를 포함하는 중합성 액정 조성물
WO2016026265A1 (en) 2014-08-21 2016-02-25 Dow Global Technologies Llc Polymeric charge transfer layer and organic electronic device containing the same
KR102837123B1 (ko) * 2021-03-03 2025-07-21 주식회사 엘지화학 폴리옥틸티오펜의 제조방법

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EP0261712A1 (de) 1986-09-04 1988-03-30 Koninklijke Philips Electronics N.V. Bildanzeigezelle, Verfahren zur Herstellung einer orientierenden Schicht über ein Substrat dieser Bildanzeigezelle und Monomer-Verbindung für ihre Anwendung als orientierende Schicht
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Also Published As

Publication number Publication date
DE60229090D1 (de) 2008-11-13
US6806374B2 (en) 2004-10-19
JP2003176338A (ja) 2003-06-24
US20030062509A1 (en) 2003-04-03

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