ATE425994T1 - Verfahren zur herstellung von bromiertem polystyrol mit verbessertem farbverhalten - Google Patents
Verfahren zur herstellung von bromiertem polystyrol mit verbessertem farbverhaltenInfo
- Publication number
- ATE425994T1 ATE425994T1 AT97948425T AT97948425T ATE425994T1 AT E425994 T1 ATE425994 T1 AT E425994T1 AT 97948425 T AT97948425 T AT 97948425T AT 97948425 T AT97948425 T AT 97948425T AT E425994 T1 ATE425994 T1 AT E425994T1
- Authority
- AT
- Austria
- Prior art keywords
- polystyrene
- brominating agent
- catalyst
- reactant
- selecting
- Prior art date
Links
- 239000004793 Polystyrene Substances 0.000 title abstract 11
- 229920002223 polystyrene Polymers 0.000 title abstract 11
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 abstract 5
- 239000003054 catalyst Substances 0.000 abstract 4
- 239000000376 reactant Substances 0.000 abstract 4
- 150000008282 halocarbons Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- 239000002841 Lewis acid Substances 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 230000029936 alkylation Effects 0.000 abstract 1
- 238000005804 alkylation reaction Methods 0.000 abstract 1
- 230000031709 bromination Effects 0.000 abstract 1
- 238000005893 bromination reaction Methods 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- CODNYICXDISAEA-UHFFFAOYSA-N bromine monochloride Chemical compound BrCl CODNYICXDISAEA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 230000001939 inductive effect Effects 0.000 abstract 1
- 238000002955 isolation Methods 0.000 abstract 1
- 150000007517 lewis acids Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 230000035484 reaction time Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F112/02—Monomers containing only one unsaturated aliphatic radical
- C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F112/06—Hydrocarbons
- C08F112/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/58—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with silicon, germanium, tin, lead, antimony, bismuth or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/06—Treatment of polymer solutions
- C08F6/12—Separation of polymers from solutions
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/663,657 US5723549A (en) | 1996-06-14 | 1996-06-14 | Process for the preparation of brominated polystyrene having improved color characteristics |
| PCT/US1997/021240 WO1999025746A1 (en) | 1996-06-14 | 1997-11-18 | Process for the preparation of brominated polystyrene having improved color characteristics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE425994T1 true ATE425994T1 (de) | 2009-04-15 |
Family
ID=24662768
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT97948425T ATE425994T1 (de) | 1996-06-14 | 1997-11-18 | Verfahren zur herstellung von bromiertem polystyrol mit verbessertem farbverhalten |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5723549A (de) |
| EP (1) | EP1032602B9 (de) |
| KR (1) | KR100506019B1 (de) |
| AT (1) | ATE425994T1 (de) |
| ES (1) | ES2324564T3 (de) |
| WO (1) | WO1999025746A1 (de) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6518368B2 (en) | 1996-06-14 | 2003-02-11 | Albemarle Corporation | Brominated polystyrene having improved thermal stability and color and process for the preparation thereof |
| US5637650A (en) | 1996-06-14 | 1997-06-10 | Ferro Corporation | Brominated polysytrene having improved thermal stability and color and process for the preparation thereof |
| CA2265642C (en) | 1996-09-26 | 2006-03-14 | Albemarle Corporation | Process for brominated styrenic polymers |
| US6235831B1 (en) | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Polymer compositions containing brominated polystyrenic resins |
| US6232408B1 (en) | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Brominated polstyrenic resins |
| US6232393B1 (en) | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Polymers flame retarded with brominated polystyrenic resins |
| US6235844B1 (en) | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Brominated polystyrenic resins |
| US6326439B1 (en) | 1996-09-26 | 2001-12-04 | Albemarle Corporation | Process for brominating polystyrenic resins |
| US6133381A (en) * | 1996-09-26 | 2000-10-17 | Albelmarle Corporation | Brominated polystyrenic flame retardants |
| US6521714B2 (en) | 1996-09-26 | 2003-02-18 | Albemarle Corporation | Brominated polystyrenic resins |
| US6146555A (en) * | 1998-01-19 | 2000-11-14 | Ferro Corporation | Brominated copolymer flame retardant additives having improved color characteristics and related method |
| JP4450510B2 (ja) * | 1998-09-10 | 2010-04-14 | アルベマール・コーポレーシヨン | 改良臭素置換ポリスチレン系樹脂およびそれらの使用 |
| AU3844499A (en) * | 1999-05-07 | 2000-11-21 | Salviac Limited | Improved filter element for embolic protection device |
| US6992148B2 (en) * | 2003-12-31 | 2006-01-31 | Albemarle Corporation | Recovery of antimony catalyst residues from bromination reaction mixtures |
| BRPI0418907A (pt) * | 2004-05-20 | 2007-11-27 | Albemarle Corp | aglomerados de polìmeros estirênicos aniÈnicos bromatadas inalterados e método de preparação |
| ES2612575T3 (es) * | 2005-06-30 | 2017-05-17 | Albemarle Corporation | Polímeros estirénicos bromados y su preparación |
| KR101353883B1 (ko) * | 2005-12-21 | 2014-02-18 | 알베마를 코포레이션 | 브롬화 음이온성 스티렌계 중합체 및 이의 제조 |
| CA2657939C (en) * | 2006-07-20 | 2015-10-27 | Albemarle Corporation | Process technology for recovering brominated styrenic polymers from reaction mixtures in which they are formed and/or converting such mixtures into pellets or into granules or pastilles |
| KR20090093962A (ko) * | 2006-11-28 | 2009-09-02 | 알베마를 코포레이션 | 브롬화 음이온성 스티렌계 중합체를 저장, 수송, 및 사용하기 위해 경질이고 큰 형태로 전환하는 방법 |
| PL2158233T3 (pl) | 2007-06-07 | 2019-04-30 | Albemarle Corp | Addukty, addukty i oligomery lub addukty, oligomery i polimery o małym ciężarze cząsteczkowym oraz ich wytwarzanie |
| US8993684B2 (en) | 2008-06-06 | 2015-03-31 | Albemarle Corporation | Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations |
| CN102224122B (zh) | 2008-12-02 | 2014-09-03 | 雅宝公司 | 甲苯和苯乙烯衍生的调聚物分布物及由其制备的溴化阻燃剂 |
| KR20110100216A (ko) | 2008-12-02 | 2011-09-09 | 알베마를 코포레이션 | 분지형 또는 별모양 분지형 스티렌 폴리머, 텔로머, 및 부가물, 그의 합성, 그의 브롬화, 및 그의 용도 |
| JO3423B1 (ar) * | 2008-12-02 | 2019-10-20 | Albemarle Corp | مؤخرات لهب معالجة بالبروم و مواد مشتقه منها |
| WO2010065464A1 (en) | 2008-12-02 | 2010-06-10 | Albemarle Corporation | Bromination of telomer mixtures derived from toluene and styrene |
| JO3059B1 (ar) | 2009-05-01 | 2017-03-15 | Albemarle Corp | معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض |
| US8753554B2 (en) | 2009-05-01 | 2014-06-17 | Albemarle Corporation | Pelletized low molecular weight brominated aromatic polymer compositions |
| CN101555302B (zh) * | 2009-05-13 | 2010-12-01 | 重庆工商大学 | 利用废旧聚苯乙烯泡沫塑料制备溴化聚苯乙烯的方法 |
| KR102621597B1 (ko) * | 2018-09-10 | 2024-01-08 | 에스케이이노베이션 주식회사 | 난연제 및 이를 포함하는 난연성 수지 조성물 |
| CN109988309B (zh) * | 2019-03-26 | 2022-02-01 | 浙江置正有机硅有限公司 | 一种烷氧基抗结构剂的制备方法及其设备 |
| CN121426997A (zh) * | 2025-12-29 | 2026-01-30 | 潍坊鑫洋化工有限公司 | 一种全流程连续化制备溴化聚苯乙烯的方法及装置 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1890772A (en) * | 1930-01-28 | 1932-12-13 | Du Pont | Chlorination of meta styrene |
| US3050476A (en) * | 1958-12-08 | 1962-08-21 | Koppers Co Inc | Method of making a self extinguishing expandable polymer of styrene by bromination |
| NL128916C (de) * | 1965-02-18 | 1900-01-01 | ||
| US3845146A (en) * | 1969-10-06 | 1974-10-29 | Dow Chemical Co | Bromination with bromine chloride under pressure |
| CH584731A5 (de) * | 1973-12-17 | 1977-02-15 | Ciba Geigy Ag | |
| DE2515473C3 (de) * | 1975-04-09 | 1987-01-22 | Basf Ag, 6700 Ludwigshafen | Flammwidrige, lineare Polyester |
| US4074033A (en) * | 1976-07-09 | 1978-02-14 | Pratt & Lambert | Chemical milling of neoprene rubber |
| DE2645711C3 (de) * | 1976-10-09 | 1979-06-07 | Basf Ag, 6700 Ludwigshafen | Halogenhaltige Flammschutzmittel enthaltende Fasern und Fäden aus linearen, thermoplastischen Polyestern |
| DE2651435C3 (de) * | 1976-11-11 | 1980-11-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von bromierten Polymerisationsprodukten des Styrols |
| DE2703419B1 (de) * | 1977-01-28 | 1978-02-02 | Basf Ag | Flammwidrig ausgeruestete polyamid- formmassen |
| DE2727483A1 (de) * | 1977-06-18 | 1979-01-11 | Basf Ag | Selbstverloeschende thermoplastische formmassen |
| FR2413409A1 (fr) * | 1978-01-02 | 1979-07-27 | Huels Chemische Werke Ag | Procede pour preparer des polystyrenes resistant a la chaleur, bromes sur le noyau |
| US4352909A (en) * | 1980-08-20 | 1982-10-05 | Ferro Corporation | Process for the bromination of polystyrenes |
| US4683084A (en) * | 1983-04-28 | 1987-07-28 | Atlantic Richfield Company | Composition comprising a matrix resin, a flame retarding synergist, and an alternating copolymer of brominated styrene and N-brominated phenyl maleimide |
| EP0201411A3 (de) * | 1985-05-03 | 1989-02-08 | The Dow Chemical Company | Bromierte Polymere aus alkenylaromatischen Verbindungen |
| IL80021A (en) * | 1985-11-13 | 1993-04-04 | Bromine Compounds Ltd | Granular flame retardant agents, process for their preparation and articles obtained thereby |
| DE3779747T2 (de) * | 1987-01-28 | 1993-01-07 | Great Lakes Chemical Corp | Aromatische bromierung von polystyrol mit einer bromverbindung als reaktionsloesungsmittel. |
| US5112897A (en) * | 1989-06-06 | 1992-05-12 | Ferro Corporation | High impact polystyrene containing low molecular weight brominated polystyrene |
| US5112898A (en) * | 1989-06-06 | 1992-05-12 | Ferro Corporation | High impact polystyrene containing low molecular weight brominated polystyrene |
| JP2854948B2 (ja) * | 1990-09-13 | 1999-02-10 | マナック株式会社 | 難燃性熱硬化性樹脂組成物 |
| US5693714A (en) * | 1992-02-27 | 1997-12-02 | Composite Particles, Inc. | Higher modulus compositions incorporating particulate rubber |
| US5304618A (en) * | 1993-07-22 | 1994-04-19 | Great Lakes Chemical Corporation | Polymers of brominated styrene |
| EP0819155B1 (de) * | 1995-04-06 | 1999-09-22 | Ferro Corporation | Bromierte syndiotaktische styrolpolymere und verfahren zu ihrer herstellung und verwendung |
| US5532322B1 (en) * | 1995-09-26 | 1999-12-07 | Manac Inc | Process for preparing brominated polystyrene |
-
1996
- 1996-06-14 US US08/663,657 patent/US5723549A/en not_active Expired - Lifetime
-
1997
- 1997-11-18 WO PCT/US1997/021240 patent/WO1999025746A1/en not_active Ceased
- 1997-11-18 AT AT97948425T patent/ATE425994T1/de active
- 1997-11-18 ES ES97948425T patent/ES2324564T3/es not_active Expired - Lifetime
- 1997-11-18 EP EP97948425A patent/EP1032602B9/de not_active Revoked
- 1997-11-18 KR KR10-2000-7005338A patent/KR100506019B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US5723549A (en) | 1998-03-03 |
| EP1032602B9 (de) | 2009-10-21 |
| KR20010032151A (ko) | 2001-04-16 |
| WO1999025746A1 (en) | 1999-05-27 |
| KR100506019B1 (ko) | 2005-08-05 |
| EP1032602B1 (de) | 2009-03-18 |
| EP1032602A4 (de) | 2004-08-25 |
| EP1032602A1 (de) | 2000-09-06 |
| ES2324564T3 (es) | 2009-08-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| UEP | Publication of translation of european patent specification |
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