ATE429458T1 - METHOD FOR PRODUCING POLYALKLYENE CARBONATES - Google Patents
METHOD FOR PRODUCING POLYALKLYENE CARBONATESInfo
- Publication number
- ATE429458T1 ATE429458T1 AT03809306T AT03809306T ATE429458T1 AT E429458 T1 ATE429458 T1 AT E429458T1 AT 03809306 T AT03809306 T AT 03809306T AT 03809306 T AT03809306 T AT 03809306T AT E429458 T1 ATE429458 T1 AT E429458T1
- Authority
- AT
- Austria
- Prior art keywords
- polyalklyene
- carbonates
- producing
- organic compound
- framework material
- Prior art date
Links
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 3
- 150000001336 alkenes Chemical class 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 229910021645 metal ion Inorganic materials 0.000 abstract 2
- 150000002894 organic compounds Chemical class 0.000 abstract 2
- 229920005603 alternating copolymer Polymers 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002090 carbon oxide Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000012621 metal-organic framework Substances 0.000 abstract 1
- 229920001281 polyalkylene Polymers 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 238000007142 ring opening reaction Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/32—General preparatory processes using carbon dioxide
- C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
- B01J2531/16—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
- B01J2531/22—Magnesium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
- B01J2531/26—Zinc
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
- B01J2531/27—Cadmium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/38—Lanthanides other than lanthanum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/44—Lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
- B01J2531/72—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyesters Or Polycarbonates (AREA)
- Catalysts (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Steroid Compounds (AREA)
Abstract
A polyalkylene carbonate, an alternating copolymer, may be prepared by the ring opening of an alkene oxide or an alkene oxide precursor in the presence of carbon dioxide or any substance delivering carbon oxide, in the presence of at least one catalyst comprising a metal-organic framework material, wherein said framework material comprises pores and a metal ion and an at least bidentate organic compound, said bidentate organic compound being coordinately bound to the metal ion.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/279,940 US6617467B1 (en) | 2002-10-25 | 2002-10-25 | Process for producing polyalkylene carbonates |
| PCT/EP2003/011704 WO2004037895A1 (en) | 2002-10-25 | 2003-10-22 | Process for producing polyalkylene carbonates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE429458T1 true ATE429458T1 (en) | 2009-05-15 |
Family
ID=27788852
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT03809306T ATE429458T1 (en) | 2002-10-25 | 2003-10-22 | METHOD FOR PRODUCING POLYALKLYENE CARBONATES |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6617467B1 (en) |
| EP (1) | EP1558665B1 (en) |
| JP (1) | JP2006503946A (en) |
| CN (1) | CN1322026C (en) |
| AT (1) | ATE429458T1 (en) |
| AU (1) | AU2003276143A1 (en) |
| DE (1) | DE60327351D1 (en) |
| ES (1) | ES2324470T3 (en) |
| MY (1) | MY139209A (en) |
| TW (1) | TWI288148B (en) |
| WO (1) | WO2004037895A1 (en) |
Families Citing this family (89)
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|---|---|---|---|---|
| ES2269761T3 (en) * | 2001-04-30 | 2007-04-01 | The Regents Of The University Of Michigan | ISORRETICULAR ORGANOMETAL STRUCTURES, PROCEDURE FOR THEIR FORMATION, AND SYSTEMATIC DESIGN OF THE PITTER CALIBER AND FUNCTIONALITY OF THE SAME, WITH APPLICATION FOR THE STORAGE OF GASES. |
| US6929679B2 (en) * | 2002-02-01 | 2005-08-16 | Basf Aktiengesellschaft | Method of storing, uptaking, releasing of gases by novel framework materials |
| US7008607B2 (en) * | 2002-10-25 | 2006-03-07 | Basf Aktiengesellschaft | Process for preparing hydrogen peroxide from the elements |
| US6617467B1 (en) * | 2002-10-25 | 2003-09-09 | Basf Aktiengesellschaft | Process for producing polyalkylene carbonates |
| CA2524903A1 (en) * | 2003-05-09 | 2004-11-25 | The Regents Of The University Of Michigan | Implementation of a strategy for achieving extraordinary levels of surface and porosity in crystals |
| US7309380B2 (en) * | 2003-06-30 | 2007-12-18 | Basf Aktiengesellschaft | Gas storage system |
| US20050004404A1 (en) | 2003-07-03 | 2005-01-06 | Basf Akiengesellschaft | Process for the alkoxylation of monools in the presence of metallo-organic framework materials |
| DE10355087A1 (en) * | 2003-11-24 | 2005-06-09 | Basf Ag | Process for the electrochemical preparation of a crystalline porous organometallic framework |
| WO2006028479A1 (en) * | 2003-12-05 | 2006-03-16 | The Regents Of The University Of Michigan | Metal-organic polyhedra |
| US7411081B2 (en) * | 2004-01-13 | 2008-08-12 | Basf Aktiengesellschaft | Process for preparing and organometallic framework material |
| MX2007004679A (en) | 2004-10-22 | 2007-10-03 | Univ Michigan | Covalently linked organic frameworks and polyhedra. |
| US7524444B2 (en) * | 2004-11-09 | 2009-04-28 | Basf Aktiengesellschaft | Shaped bodies containing metal-organic frameworks |
| DE502005007676D1 (en) * | 2004-12-10 | 2009-08-20 | Basf Se | Preparation and Use of Ultra-Molecular Polycarbonate |
| MX2007012388A (en) * | 2005-04-07 | 2008-03-11 | Univ Michigan | High gas adsorption in a microporous metal-organic framework with open-metal sites. |
| DE102005035762A1 (en) * | 2005-07-29 | 2007-02-01 | Süd-Chemie AG | Producing highly porous layers comprises providing a substrate with a surface; modifying substrate surface section to produce surface-modified sections; and applying methyl orthoformate on the surface-modified sections of the substrate |
| DE102005037893A1 (en) * | 2005-08-10 | 2007-02-15 | Süd-Chemie AG | Process for the preparation of highly active metal / metal oxide catalysts |
| WO2007038508A2 (en) * | 2005-09-26 | 2007-04-05 | The Regents Of The University Of Michigan | Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature |
| US8314245B2 (en) * | 2006-02-28 | 2012-11-20 | The Regents Of The University Of Michigan | Preparation of functionalized zeolitic frameworks |
| EP2010315A2 (en) | 2006-04-18 | 2009-01-07 | Basf Se | Organometallic aluminum fumarate backbone material |
| GB0616350D0 (en) | 2006-08-17 | 2006-09-27 | Univ St Andrews | Adsorption and release of nitric oxide in metal organic frameworks |
| US9017584B2 (en) * | 2006-10-30 | 2015-04-28 | Alan M. Gilbert | Flame-retardant materials and systems |
| RU2009120403A (en) | 2006-10-30 | 2010-12-10 | Басф Се (De) | ALUMINUM NAPHTHALINDICARBOXYLATE AS A POROUS METALLORGANIC MATERIAL WITH A SKELETON STRUCTURE |
| US20080111114A1 (en) * | 2006-10-30 | 2008-05-15 | Gilbert Alan M | Flame-retardant materials and systems |
| US9719019B1 (en) | 2006-10-30 | 2017-08-01 | Alan M. Gilbert | Flame-retardant materials and systems |
| US7985868B1 (en) | 2006-11-01 | 2011-07-26 | Sandia Corporation | Hybrid metal organic scintillator materials system and particle detector |
| EP2114560A4 (en) * | 2007-01-24 | 2012-02-15 | Univ California | CRYSTALLINE 3D AND 2D COVALENT ORGANIC FRAMES |
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| ES2397231T3 (en) | 2007-04-24 | 2013-03-05 | Basf Se | Organometallic structural materials, with a hexagonal and trigonal structure, based on aluminum, iron or chromium, as well as a dicarboxylic acid |
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| CN111068786A (en) * | 2019-12-24 | 2020-04-28 | 新疆大学 | A basic functionalized F-Mn-MOF-74 nanocatalytic material for efficient catalysis of carbon dioxide cycloaddition reaction |
| CN114425450B (en) * | 2020-10-13 | 2023-08-29 | 中国石油化工股份有限公司 | Catalyst for preparing unsaturated carbonate, preparation method and application thereof |
| US12195576B2 (en) | 2021-06-23 | 2025-01-14 | Saudi Aramco Technologies Company | Polyol compositions and methods |
| GB2642304A (en) * | 2024-07-01 | 2026-01-07 | Viridico2 Ltd | Methods of preparing polymers using CO2 |
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|---|---|---|---|---|
| DE68927577T2 (en) * | 1988-08-09 | 1997-06-05 | Mitsui Petrochemical Ind | Process for producing a zinc-containing solid catalyst and process for producing polyalkylene carbonate |
| US5648508A (en) * | 1995-11-22 | 1997-07-15 | Nalco Chemical Company | Crystalline metal-organic microporous materials |
| US6617467B1 (en) * | 2002-10-25 | 2003-09-09 | Basf Aktiengesellschaft | Process for producing polyalkylene carbonates |
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2002
- 2002-10-25 US US10/279,940 patent/US6617467B1/en not_active Expired - Fee Related
-
2003
- 2003-10-22 ES ES03809306T patent/ES2324470T3/en not_active Expired - Lifetime
- 2003-10-22 AU AU2003276143A patent/AU2003276143A1/en not_active Abandoned
- 2003-10-22 DE DE60327351T patent/DE60327351D1/en not_active Expired - Lifetime
- 2003-10-22 WO PCT/EP2003/011704 patent/WO2004037895A1/en not_active Ceased
- 2003-10-22 AT AT03809306T patent/ATE429458T1/en not_active IP Right Cessation
- 2003-10-22 CN CNB2003801020233A patent/CN1322026C/en not_active Expired - Fee Related
- 2003-10-22 EP EP03809306A patent/EP1558665B1/en not_active Expired - Lifetime
- 2003-10-22 JP JP2004545938A patent/JP2006503946A/en not_active Ceased
- 2003-10-23 MY MYPI20034043A patent/MY139209A/en unknown
- 2003-10-24 TW TW092129604A patent/TWI288148B/en active
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| US6617467B1 (en) | 2003-09-09 |
| AU2003276143A1 (en) | 2004-05-13 |
| WO2004037895A1 (en) | 2004-05-06 |
| CN1322026C (en) | 2007-06-20 |
| EP1558665A1 (en) | 2005-08-03 |
| AU2003276143A8 (en) | 2004-05-13 |
| JP2006503946A (en) | 2006-02-02 |
| CN1708534A (en) | 2005-12-14 |
| TWI288148B (en) | 2007-10-11 |
| DE60327351D1 (en) | 2009-06-04 |
| EP1558665B1 (en) | 2009-04-22 |
| MY139209A (en) | 2009-08-28 |
| TW200415176A (en) | 2004-08-16 |
| ES2324470T3 (en) | 2009-08-07 |
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