ATE433509T1 - FLAME-RESISTANT FIBER COMPOSITE AND TEXTILE STRUCTURE MADE THEREOF - Google Patents

FLAME-RESISTANT FIBER COMPOSITE AND TEXTILE STRUCTURE MADE THEREOF

Info

Publication number
ATE433509T1
ATE433509T1 AT04728234T AT04728234T ATE433509T1 AT E433509 T1 ATE433509 T1 AT E433509T1 AT 04728234 T AT04728234 T AT 04728234T AT 04728234 T AT04728234 T AT 04728234T AT E433509 T1 ATE433509 T1 AT E433509T1
Authority
AT
Austria
Prior art keywords
weight
flame
fiber
resistant fiber
fiber composite
Prior art date
Application number
AT04728234T
Other languages
German (de)
Inventor
Wataru Mio
Susumu Iwade
Shigeru Maruyama
Hiroyasu Hagi
Original Assignee
Kaneka Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kaneka Corp filed Critical Kaneka Corp
Application granted granted Critical
Publication of ATE433509T1 publication Critical patent/ATE433509T1/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/443—Heat-resistant, fireproof or flame-retardant yarns or threads
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282—Addition polymers
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425—Cellulose series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4266—Natural fibres not provided for in group D04H1/425
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282—Addition polymers
    • D04H1/43—Acrylonitrile series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326—Condensation or reaction polymers
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326—Condensation or reaction polymers
    • D04H1/4334—Polyamides
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326—Condensation or reaction polymers
    • D04H1/4334—Polyamides
    • D04H1/4342—Aromatic polyamides
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • D04H1/43835—Mixed fibres, e.g. at least two chemically different fibres or fibre blends
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/696—Including strand or fiber material which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous compositions, water solubility, heat shrinkability, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/697—Containing at least two chemically different strand or fiber materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/697—Containing at least two chemically different strand or fiber materials
    • Y10T442/698—Containing polymeric and natural strand or fiber materials

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Artificial Filaments (AREA)
  • Woven Fabrics (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Absorbent Articles And Supports Therefor (AREA)

Abstract

The present invention relates to a flame resistant fiber composite obtained by compounding: 20 to 85% by weight of a fiber (A) containing 0.5 to 50 parts by weight of an Sb compound to 100 parts by weight of a polymer containing halogen atom of not less than 17% by weight; 5 to 80% by weight of a heat-resistant fiber (B); 0 to 40% by weight of a cellulosic fiber (C); and 0 to 40% by weight of an inflammable fiber (D). Use of the composite in furniture, beddings, etc. in house increasingly improves flame resistance of materials, enabling use in fields requiring advanced flame resistance.
AT04728234T 2003-04-28 2004-04-19 FLAME-RESISTANT FIBER COMPOSITE AND TEXTILE STRUCTURE MADE THEREOF ATE433509T1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2003123269 2003-04-28
JP2003125162 2003-04-30
JP2003125161 2003-04-30
PCT/JP2004/005583 WO2004097088A1 (en) 2003-04-28 2004-04-19 Flame-retardant fiber composite and fabric produced therefrom

Publications (1)

Publication Number Publication Date
ATE433509T1 true ATE433509T1 (en) 2009-06-15

Family

ID=33424782

Family Applications (1)

Application Number Title Priority Date Filing Date
AT04728234T ATE433509T1 (en) 2003-04-28 2004-04-19 FLAME-RESISTANT FIBER COMPOSITE AND TEXTILE STRUCTURE MADE THEREOF

Country Status (11)

Country Link
US (1) US20060234592A1 (en)
EP (1) EP1619278B1 (en)
JP (1) JP4308820B2 (en)
KR (1) KR20060007032A (en)
CN (1) CN1806071B (en)
AT (1) ATE433509T1 (en)
CA (1) CA2523378A1 (en)
DE (1) DE602004021484D1 (en)
ES (1) ES2326170T3 (en)
MX (1) MXPA05011334A (en)
WO (1) WO2004097088A1 (en)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7858542B2 (en) * 2004-10-22 2010-12-28 Kaneka Corporation Flame-retardant mattress
JP4757543B2 (en) * 2005-06-14 2011-08-24 株式会社カネカ Flame retardant nonwoven fabric and flame retardant mattress using the same
JP2007105403A (en) * 2005-10-17 2007-04-26 Kaneka Corp Fire-retardant nonwoven-fabric and fire retardant mattress using the same
DE602006010431D1 (en) * 2005-12-16 2009-12-24 Du Pont THERMAL PERFORMANCE CLOTHING ACCESSORIES WITH PIPE AND ARAMID FIBER OUTSIDE
KR100756557B1 (en) * 2006-04-27 2007-09-11 (주)리디아 Flame retardant nonwoven fabric and fabric using flame retardant rayon yarn
ITFI20070003A1 (en) * 2007-01-10 2008-07-11 Marco Cavallaro A THERMOMODELABLE MATERIAL, AND ITS IMPLEMENTATION PROCEDURE.
US7786031B2 (en) * 2007-01-26 2010-08-31 Milliken & Company Flame resistant textile
IT1390963B1 (en) * 2008-07-24 2011-10-27 Roberto Fantino LAYERED PRODUCT WITH HIGH CAPACITY OF THERMAL INSULATION AND SELF-EXTINGUISHING.
US7816287B1 (en) * 2009-07-10 2010-10-19 Polymer Group, Inc. Flame retardant nonwoven fabric and bedding articles
US20110212658A1 (en) * 2010-03-01 2011-09-01 Bekaert Textiles Usa, Inc. Fire retardant fabric
CN101787599B (en) * 2010-04-02 2012-05-23 绍兴文理学院 Production technology for T/R/H multielement functional fiber high textual quality yarn
CN103261500B (en) * 2010-12-09 2015-04-15 株式会社钟化 Fabrics containing acrylic fibers and overalls for arc protection
US20130029151A1 (en) * 2011-03-18 2013-01-31 E. I. Du Pont De Nemours And Company Flame-resistant finish for inherently flame resistant polymer yarns and process for making same
EP2729552B1 (en) 2011-07-06 2018-03-21 National Research Council of Canada Fire-resistant cellulosic material
US9091000B2 (en) 2011-09-26 2015-07-28 Kaneka Corporation Flameproof spun yarn, fabric, clothes and flameproof work clothes
KR101280553B1 (en) * 2012-01-03 2013-07-01 남택욱 Quasi-noncombustible spun yarn containing rayon staple fiber and corbon fiber, fabric using the same
US20140187113A1 (en) * 2012-04-04 2014-07-03 Drifire, Llc Fiber blends for dual hazard and comfort properties
CN102677290A (en) * 2012-05-29 2012-09-19 蔡紫林 Shell fabric
TWI616568B (en) * 2012-06-08 2018-03-01 Kaneka Corporation Protective clothing and arc-resistant protective clothing
KR101442720B1 (en) * 2013-03-22 2014-09-19 한국니트산업연구원 Flame-retardant yarn and menufacturing method thereby
CN105495750B (en) * 2014-09-22 2018-06-05 株式会社钟化 Flame-retardant fabric and the protective garment containing the cloth and silk
CN108882763B (en) * 2016-03-25 2021-07-27 株式会社钟化 Acrylic fiber for artificial hair, method for producing the same, and headgear product containing the same
CN108882760A (en) * 2016-04-05 2018-11-23 帝人株式会社 Cloth and silk, multilayered structure cloth and silk and fibre
MX2019009581A (en) * 2017-02-09 2019-12-09 Tuft & Needle Llc Flame retardant cover.
CN107313168A (en) * 2017-08-31 2017-11-03 苏州英得福机电科技有限公司 A kind of environment-friendly composite inflaming retarding fabric
CN110042565A (en) * 2019-04-26 2019-07-23 中科国联劳动防护技术研究院(北京)有限公司 A kind of fire-retardant arc protection blend based on fire extinguishing type fire-retardant regenerated cellulose fiber
CN110067037A (en) * 2019-04-26 2019-07-30 中科国联劳动防护技术研究院(北京)有限公司 A kind of regenerated celulose fibre
CN110079889A (en) * 2019-04-26 2019-08-02 中科国联劳动防护技术研究院(北京)有限公司 A kind of fire extinguishing type regeneration cellulose fiber mixing object
JP7263527B2 (en) * 2019-09-10 2023-04-24 株式会社カネカ Flame-retardant fiber composite and flame-retardant work clothes
KR102634294B1 (en) 2019-09-27 2024-02-07 주식회사 엘지화학 Method for producing flame retardant aid and flame retardant composition comprising the flame retardant aid produced by the method
KR102205344B1 (en) * 2020-03-10 2021-01-21 주식회사 디아이티그린 manufacturing method of a cloth for mattress
JP2024102391A (en) * 2021-06-04 2024-07-31 株式会社カネカ Flame retardant fabric and working wear using the same
WO2023171288A1 (en) 2022-03-09 2023-09-14 株式会社カネカ Flame-retardant acrylic fiber, method for manufacturing same, and flame-retardant fiber aggregate and flame-retardant work clothing including same

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EP0183014B1 (en) * 1984-10-05 1994-02-02 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Flame-retarded fiber blend
US4865906A (en) * 1988-01-22 1989-09-12 Smith Novis W Jr Flame retardant yard blend
FI91778C (en) * 1991-12-31 1994-08-10 Kemira Fibres Oy Silica - containing product and method for its preparation
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JP3477991B2 (en) * 1996-05-13 2003-12-10 鐘淵化学工業株式会社 Flame retardant fabric with improved heat resistance
DE69715849T2 (en) * 1996-05-13 2003-09-04 Kaneka Corp., Osaka FLAME RETARDANT FABRIC
JP4420554B2 (en) * 2000-11-22 2010-02-24 株式会社カネカ Flame retardant non-woven fabric
US7150059B2 (en) * 2003-05-05 2006-12-19 Precision Fabrics Group, Inc. Heat and flame-resistant materials and upholstered articles incorporating same
CN100396835C (en) * 2001-09-12 2008-06-25 巴索菲尔纤维有限责任公司 Nonwoven High Loft Flame Shield

Also Published As

Publication number Publication date
JPWO2004097088A1 (en) 2006-07-13
US20060234592A1 (en) 2006-10-19
CA2523378A1 (en) 2004-11-11
JP4308820B2 (en) 2009-08-05
EP1619278A1 (en) 2006-01-25
EP1619278A4 (en) 2006-09-20
MXPA05011334A (en) 2006-01-30
KR20060007032A (en) 2006-01-23
CN1806071B (en) 2011-08-31
CN1806071A (en) 2006-07-19
EP1619278B1 (en) 2009-06-10
ES2326170T3 (en) 2009-10-02
DE602004021484D1 (en) 2009-07-23
WO2004097088A1 (en) 2004-11-11

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