ATE437854T1 - Katalytische carbonylierung von drei- und viergliedrigen heterocyklen - Google Patents

Katalytische carbonylierung von drei- und viergliedrigen heterocyklen

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Publication number
ATE437854T1
ATE437854T1 AT02804688T AT02804688T ATE437854T1 AT E437854 T1 ATE437854 T1 AT E437854T1 AT 02804688 T AT02804688 T AT 02804688T AT 02804688 T AT02804688 T AT 02804688T AT E437854 T1 ATE437854 T1 AT E437854T1
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Austria
Prior art keywords
ranges
membed
heterocycles
lewis acid
catalytic carbonylation
Prior art date
Application number
AT02804688T
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English (en)
Inventor
Geoffrey Coates
Yutan Getzler
Peter Wolczanski
Viswanath Mahadevan
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Cornell Res Foundation Inc
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Publication of ATE437854T1 publication Critical patent/ATE437854T1/de

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D205/00—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom
    • C07D205/02—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D205/06—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D205/08—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with one oxygen atom directly attached in position 2, e.g. beta-lactams
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D205/00—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom
    • C07D205/12—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D265/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom and one oxygen atom as the only ring hetero atoms
    • C07D265/04—1,3-Oxazines; Hydrogenated 1,3-oxazines
    • C07D265/06—1,3-Oxazines; Hydrogenated 1,3-oxazines not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D305/00—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
    • C07D305/02—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings
    • C07D305/10—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having one or more double bonds between ring members or between ring members and non-ring members
    • C07D305/12—Beta-lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D305/00—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
    • C07D305/14—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms condensed with carbocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32—Oxygen atoms
    • C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • C07F15/065—Cobalt compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0208—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38—Lanthanides other than lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Furan Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
AT02804688T 2001-12-06 2002-12-02 Katalytische carbonylierung von drei- und viergliedrigen heterocyklen ATE437854T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US33617001P 2001-12-06 2001-12-06
PCT/US2002/036140 WO2003050154A2 (en) 2001-12-06 2002-12-02 Catalytic carbonylation of three and four membered heterocycles

Publications (1)

Publication Number Publication Date
ATE437854T1 true ATE437854T1 (de) 2009-08-15

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AT02804688T ATE437854T1 (de) 2001-12-06 2002-12-02 Katalytische carbonylierung von drei- und viergliedrigen heterocyklen

Country Status (9)

Country Link
US (1) US6852865B2 (de)
EP (1) EP1461315B1 (de)
JP (2) JP5187929B2 (de)
AT (1) ATE437854T1 (de)
AU (1) AU2002356929A1 (de)
DE (1) DE60233163D1 (de)
DK (1) DK1461315T3 (de)
ES (1) ES2330930T3 (de)
WO (1) WO2003050154A2 (de)

Families Citing this family (82)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10235317A1 (de) 2002-08-01 2004-02-12 Basf Ag Katalysator und Verfahren zur Carbonylierung von Oxiranen
DE10235316A1 (de) * 2002-08-01 2004-02-12 Basf Ag Katalysator und Verfahren zur Carbonylierung von Oxiranen
US7950221B2 (en) 2003-04-25 2011-05-31 Catelectric Corp. Methods and apparatus for controlling catalytic processes, including catalyst regeneration and soot elimination
US7074822B2 (en) 2004-02-23 2006-07-11 Solvay Pharmaceuticals Gmbh Alkyl carbamate-substituted β-lactones, process for their preparation, and pharmaceutical compositions containing them
WO2006058681A2 (de) * 2004-11-30 2006-06-08 Basf Aktiengesellschaft Verfahren zur herstellung von enantiomerenangereicherten lactonen
US7569709B2 (en) * 2006-03-10 2009-08-04 Cornell Research Foundation, Inc. Low pressure carbonylation of heterocycles
US8481756B1 (en) 2007-09-04 2013-07-09 Cornell Research Foundation, Inc. Succinic anhydrides from epoxides
US7964084B2 (en) * 2007-09-20 2011-06-21 Catelectric Corp. Methods and apparatus for the synthesis of useful compounds
US20090101516A1 (en) * 2007-09-20 2009-04-23 The University Of Connecticut Methods and apparatus for the synthesis of useful compounds
WO2009139852A1 (en) * 2008-05-12 2009-11-19 Catelectric Corp. Methods and apparatus for controlling catalytic processes, including the deposition of carbon based particles
CA2736482C (en) 2008-09-08 2018-01-02 Novomer, Inc. Polycarbonate polyol compositions and methods
WO2010112569A1 (en) 2009-03-31 2010-10-07 Robert Zimmermann Modulation of adipose triglyceride lipase for prevention and treatment of cachexia, loss of weight and muscle atrophy and methods of screening therefor
EP2414830A2 (de) 2009-03-31 2012-02-08 Robert Zimmermann Atgl(adipose triglyceride lipase )-modulation zur vorbeugung und behandlung von kachexie, gewichtsverlust und muskelatrophie sowie screening-verfahren dafür
MY179719A (en) * 2009-04-08 2020-11-11 Novomer Inc Process for beta-lactone production
WO2011123558A1 (en) * 2010-04-01 2011-10-06 Novomer, Inc. Synthesis of metal complexes
WO2011163309A2 (en) * 2010-06-22 2011-12-29 Cornell University Carbonylative polymerization methods
WO2012030619A1 (en) 2010-08-28 2012-03-08 Novomer, Inc. Succinic anhydride from ethylene oxide
JP2014527456A (ja) * 2011-05-13 2014-10-16 ノボマー， インコーポレイテッド 触媒的カルボニル化用触媒および方法
CN103842082B (zh) 2011-08-08 2017-07-18 诺沃梅尔公司 聚合物合成的催化剂和方法
HUE039449T2 (hu) * 2011-10-26 2018-12-28 Novomer Inc Eljárás akrilátok elõállítására epoxidokból
CN102531918B (zh) * 2012-01-18 2013-10-02 安阳工学院 一种对映纯对称反式二烷基环己胺的合成方法
JP2015511947A (ja) * 2012-02-13 2015-04-23 ノボマー， インコーポレイテッド エポキシドから酸無水物を生成するためのプロセス
JP2015522091A (ja) * 2012-06-27 2015-08-03 ノボマー， インコーポレイテッド ポリエステル生成のための触媒および方法
CN110183402B (zh) * 2013-12-07 2024-04-02 诺沃梅尔公司 纳米过滤膜和使用方法
KR20160135300A (ko) 2014-03-14 2016-11-25 노보머, 인코포레이티드 에폭사이드 카보닐화용 촉매
US10858329B2 (en) 2014-05-05 2020-12-08 Novomer, Inc. Catalyst recycle methods
WO2015171791A1 (en) 2014-05-06 2015-11-12 Massachusetts Institute Of Technology Compositions and methods comprising conductive metal organic frameworks and uses thereof
US10597294B2 (en) 2014-05-30 2020-03-24 Novomer, Inc. Integrated methods for chemical synthesis
WO2016015019A1 (en) 2014-07-25 2016-01-28 Novomer, Inc. Synthesis of metal complexes and uses thereof
MA41508A (fr) 2015-02-13 2017-12-19 Novomer Inc Systèmes et procédés de production d'acide polyacrylique
MA41507A (fr) 2015-02-13 2017-12-19 Novomer Inc Systèmes et procédés de production de polymères
MA41514A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédés intégrés de synthèse chimique
US10221150B2 (en) 2015-02-13 2019-03-05 Novomer, Inc. Continuous carbonylation processes
KR20170134375A (ko) 2015-02-13 2017-12-06 노보머, 인코포레이티드 폴리프로피오락톤의 제조를 위한 방법 및 시스템
HK1245243A1 (zh) 2015-02-13 2018-08-24 诺沃梅尔公司 灵活的化学生产平台
MA41510A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédé de production d'acide acrylique
MA41513A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédé de distillation pour la production d'acide acrylique
CA2991202A1 (en) 2015-07-01 2017-01-05 Novomer, Inc. Methods for coproduction of terephthalic acid and styrene from ethylene oxide
CN107922303A (zh) 2015-07-01 2018-04-17 诺沃梅尔公司 由环氧乙烷制造对苯二甲酸的方法
CN105001164A (zh) * 2015-07-02 2015-10-28 齐鲁工业大学 含对甲苯磺酸的金属配位聚合物的合成及其催化活性
MX2018001404A (es) 2015-07-31 2018-08-15 Novomer Inc Sistema de produccion/proceso de producción para acido acrilico y sus precursores.
KR20190025574A (ko) * 2016-06-30 2019-03-11 제이엔씨 주식회사 에틸렌성 불포화기 함유 γ-부티로락톤 유도체의 제조 방법
JP2019532054A (ja) 2016-09-20 2019-11-07 グラクソスミスクライン、インテレクチュアル、プロパティー、（ナンバー２）、リミテッドＧｌａｘｏｓｍｉｔｈｋｌｉｎｅ Ｉｎｔｅｌｌｅｃｔｕａｌ Ｐｒｏｐｅｒｔｙ （Ｎｏ．２） Ｌｉｍｉｔｅｄ Ｔｒｐｖ４拮抗薬
TW201825458A (zh) 2016-09-20 2018-07-16 英商葛蘭素史克智慧財產（第二）有限公司 Ｔｒｐｖ４拮抗劑
RU2019110821A (ru) 2016-09-20 2020-10-22 Глэксосмитклайн Интеллекчуал Проперти (Но.2) Лимитед Антагонисты trpv4
US11179708B2 (en) * 2016-10-04 2021-11-23 Massachusetts Institute Of Technology Compositions and methods for selective carbonylation of heterocyclic compounds
US10144802B2 (en) 2016-12-05 2018-12-04 Novomer, Inc. Beta-propiolactone based copolymers containing biogenic carbon, methods for their production and uses thereof
US10065914B1 (en) 2017-04-24 2018-09-04 Novomer, Inc. Thermolysis of polypropiolactone to produce acrylic acid
US10676426B2 (en) 2017-06-30 2020-06-09 Novomer, Inc. Acrylonitrile derivatives from epoxide and carbon monoxide reagents
US10781156B2 (en) 2017-06-30 2020-09-22 Novomer, Inc. Compositions for improved production of acrylic acid
US10961209B2 (en) 2017-08-10 2021-03-30 Novomer, Inc. Processes for producing beta-lactone and beta-lactone derivatives with heterogenous catalysts
US10590099B1 (en) 2017-08-10 2020-03-17 Novomer, Inc. Processes for producing beta-lactone with heterogenous catalysts
US20190076835A1 (en) 2017-09-11 2019-03-14 Novomer, Inc. Processses using multifunctional catalysts
EP3691785A4 (de) 2017-10-05 2021-08-04 Novomer, Inc. Isocyanate, derivate und verfahren zu ihrer herstellung
ES2991139T3 (es) 2018-07-13 2024-12-02 Novomer Inc Espumas de polilactona y métodos de fabricación de las mismas
WO2020028606A1 (en) 2018-08-02 2020-02-06 Saudi Aramco Technologies Company Sustainable polymer compositions and methods
US20210403445A1 (en) * 2018-11-16 2021-12-30 Cornell University Systems and methods for regioselective carbonylation of 2,2-disubstituted epoxides
KR20210137037A (ko) 2019-03-08 2021-11-17 노보머, 인코포레이티드 아미드 및 니트릴 화합물을 생산하기 위한 통합 방법 및 시스템
US11851416B2 (en) * 2019-07-22 2023-12-26 Cornell University Systems and methods for regioselective carbonylation of 2,2-disubstituted epoxides for the production of alpha,alpha-disubstituted beta-lactones
EP4007755A1 (de) * 2019-08-01 2022-06-08 ExxonMobil Research and Engineering Company Verfahren und system zur herstellung substituierter lactone
US20220280928A1 (en) * 2019-08-02 2022-09-08 Novomer, Inc. Heterogeneous catalysts, and uses thereof
WO2021141508A1 (en) * 2020-01-10 2021-07-15 Uniwersytet Jagielloński Antiviral aromatic sulphonamides derivatives, their method of synthesis and use
CN111393394B (zh) * 2020-05-12 2023-03-31 上海朴颐化学科技有限公司 丁内酯类化合物的合成方法
JP2024507694A (ja) 2021-01-29 2024-02-21 ノボマー， インコーポレイテッド 気体反応物と液体反応物と反応させるための改良された反応器及び方法
KR20230150283A (ko) 2021-02-26 2023-10-30 노보머, 인코포레이티드 생분해성 폴리에스테르의 생성 방법
WO2022187010A1 (en) * 2021-03-02 2022-09-09 Novomer, Inc. Process for the recovery and/or regeneration of catalyst components
EP4319916B1 (de) 2021-04-06 2025-08-27 Novomer, Inc. Neue carbonylierungskatalysatoren und verfahren zu ihrer herstellung
JP2024513428A (ja) 2021-04-06 2024-03-25 ノボマー， インコーポレイテッド ポルフィリン組成物及びポルフィリン組成物を生成する方法
WO2022221086A1 (en) * 2021-04-16 2022-10-20 Novomer, Inc. Improved method of carbonylating an epoxide
EP4323425A1 (de) 2021-04-16 2024-02-21 Novomer, Inc. Polypropiolactone und verfahren zur herstellung
US12195576B2 (en) 2021-06-23 2025-01-14 Saudi Aramco Technologies Company Polyol compositions and methods
CN117615846A (zh) 2021-07-09 2024-02-27 诺沃梅尔公司 用于增强催化羰基化活性的空间改性席夫碱配体
WO2023003890A1 (en) 2021-07-21 2023-01-26 Novomer, Inc. Methods for beta-lactone copolymerization
EP4433210A1 (de) 2021-11-17 2024-09-25 Novomer, Inc. Synthese von carbonylierungskatalysatoren
CN114345414B (zh) * 2021-12-31 2023-03-07 厦门大学 一种有机金属催化剂及使用其制备3-羟基丙酸酯的方法
KR20250056908A (ko) 2022-09-02 2025-04-28 노보머, 인코포레이티드 베타-락톤 제조 공정
CN115710241B (zh) * 2022-09-30 2025-07-08 浙江大学 一种环内酯的合成方法
JP2026504450A (ja) 2023-02-02 2026-02-05 ノボマー， インコーポレイテッド ポリプロピオラクトン及びイオン性液体を使用した調製方法
JP2026505805A (ja) 2023-02-02 2026-02-18 ノボマー， インコーポレイテッド 極性プロトン性溶媒中のラクトンの重合
KR20260019652A (ko) 2023-06-16 2026-02-10 노보머, 인코포레이티드 코발트염으로부터 카보닐화 촉매의 합성
KR20260019653A (ko) 2023-06-16 2026-02-10 노보머, 인코포레이티드 알킬알루미늄 환원을 사용한 카보닐화 촉매의 합성
FR3151851A1 (fr) 2023-08-01 2025-02-07 Commissariat A L'energie Atomique Et Aux Energies Alternatives Procede de preparation d’anhydride cyclique a partir d’une lactone

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0577206B1 (de) * 1992-06-29 1998-08-26 Shell Internationale Researchmaatschappij B.V. Carbonylierung von Epoxyden
US5310948A (en) * 1992-06-29 1994-05-10 Shell Oil Company Carbonylation of epoxides
US5493017A (en) * 1992-08-14 1996-02-20 The Trustees Of The University Of Pennsylvania Ring-metalated porphyrins
US5371199B1 (en) * 1992-08-14 1995-12-26 Univ Pennsylvania Substituted porphyrins porphyrin-containing polymers and synthetic methods therefor
DE10137046A1 (de) 2001-07-31 2003-02-20 Basf Ag Verfahren zur Herstellung von thermoplastischen Poly(3-hydroxyalkanoaten)

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EP1461315A2 (de) 2004-09-29
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DE60233163D1 (de) 2009-09-10
WO2003050154A2 (en) 2003-06-19
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US20030162961A1 (en) 2003-08-28
WO2003050154A3 (en) 2003-11-20
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