ATE455804T1 - Verfahren zur gasphasenpolymerisation von olefinen - Google Patents

Verfahren zur gasphasenpolymerisation von olefinen

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Publication number
ATE455804T1
ATE455804T1 AT06763097T AT06763097T ATE455804T1 AT E455804 T1 ATE455804 T1 AT E455804T1 AT 06763097 T AT06763097 T AT 06763097T AT 06763097 T AT06763097 T AT 06763097T AT E455804 T1 ATE455804 T1 AT E455804T1
Authority
AT
Austria
Prior art keywords
riser
downcomer
phase polymerization
polymerization zones
leave
Prior art date
Application number
AT06763097T
Other languages
English (en)
Inventor
Gabriele Mei
Joachim T M Pater
Gerben Meier
Pietro Baita
Original Assignee
Basell Poliolefine Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Poliolefine Srl filed Critical Basell Poliolefine Srl
Application granted granted Critical
Publication of ATE455804T1 publication Critical patent/ATE455804T1/de

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2415Tubular reactors
    • B01J19/2435Loop-type reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1845Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised
    • B01J8/1863Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised followed by a downward movement outside the reactor and subsequently re-entering it
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/38Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it
    • B01J8/384Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only
    • B01J8/388Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only externally, i.e. the particles leaving the vessel and subsequently re-entering it
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00548Flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00548Flow
    • B01J2208/00557Flow controlling the residence time inside the reactor vessel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00164Controlling or regulating processes controlling the flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00164Controlling or regulating processes controlling the flow
    • B01J2219/00166Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901Monomer polymerized in vapor state in presence of transition metal containing catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT06763097T 2005-05-13 2006-05-09 Verfahren zur gasphasenpolymerisation von olefinen ATE455804T1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP05104036 2005-05-13
US68235205P 2005-05-18 2005-05-18
PCT/EP2006/062148 WO2006120187A1 (en) 2005-05-13 2006-05-09 Process for the gas-phase polymerization of olefins

Publications (1)

Publication Number Publication Date
ATE455804T1 true ATE455804T1 (de) 2010-02-15

Family

ID=39423605

Family Applications (1)

Application Number Title Priority Date Filing Date
AT06763097T ATE455804T1 (de) 2005-05-13 2006-05-09 Verfahren zur gasphasenpolymerisation von olefinen

Country Status (10)

Country Link
US (1) US7687588B2 (de)
EP (1) EP1896513B1 (de)
JP (1) JP5106386B2 (de)
KR (1) KR101328410B1 (de)
CN (1) CN101175775B (de)
AT (1) ATE455804T1 (de)
BR (1) BRPI0612432A2 (de)
CA (1) CA2608318A1 (de)
RU (1) RU2412207C2 (de)
WO (1) WO2006120187A1 (de)

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US20090029621A1 (en) * 2005-12-20 2009-01-29 Basell Poliolefine Italia S.R.L. Soft Non-Woven Fabrics
DE102007056533A1 (de) * 2007-11-23 2009-05-28 Clariant International Limited Wachsartige Ionomere
JP5308795B2 (ja) * 2007-12-11 2013-10-09 住友化学株式会社 ポリオレフィン製造方法、並びに、噴流層装置を備えたポリオレフィン製造システム
US8198383B2 (en) * 2007-12-21 2012-06-12 Basell Poliolefine Italia, s.r.l. Process for the gas-phase polymerization of olefins
WO2010026091A1 (en) * 2008-09-04 2010-03-11 Basell Poliolefine Italia S.R.L. Process for the gas-phase polymerization of olefins
ES2370689T3 (es) 2009-02-25 2011-12-21 Borealis Ag Polímero multimodal de polipropileno, composición que comprende el mismo y un procedimiento para producir el mismo.
EP2223944A1 (de) 2009-02-26 2010-09-01 Borealis AG Verfahren zur Herstellung von Semikristallin-Propylenpolymeren
CN102741301B (zh) 2009-09-11 2014-10-08 巴塞尔聚烯烃意大利有限责任公司 烯烃的气相聚合方法
CN102947356B (zh) * 2010-06-22 2015-09-09 巴塞尔聚烯烃意大利有限责任公司 烯烃气相聚合的方法
EP2452959B1 (de) 2010-11-12 2015-01-21 Borealis AG Verfahren zur Herstellung von statistischen Propylencopolymeren und deren Verwendung
EP2452960B1 (de) 2010-11-12 2015-01-07 Borealis AG Verfahren zur Herstellung von Propylencopolymeren mit einer extrem hohen Schmelzflussrate
EP2452976A1 (de) 2010-11-12 2012-05-16 Borealis AG Heterophasische Propylencopolymere mit verbesserten Steifheits-/Stoßfestigkeits-/Fließfähigkeitsverhältnis
EP2452957A1 (de) 2010-11-12 2012-05-16 Borealis AG Verbessertes Verfahren zur Herstellung heterophasischer Propylencopolymere
US8198384B1 (en) 2011-01-10 2012-06-12 Westlake Longview Corporation Method for preventing or reducing clogging of a fines ejector
ES2605429T3 (es) 2011-06-15 2017-03-14 Borealis Ag Mezcla del reactor in situ de un polipropileno nucleado catalizado por Ziegler-Natta y un polipropileno catalizado por metaloceno
MY187826A (en) 2016-11-10 2021-10-26 Basell Polyolefine Gmbh Olefin polymerization process in a gas-phase reactor comprising a riser unit and a downcomer
EP3321288A1 (de) 2016-11-10 2018-05-16 Basell Polyolefine GmbH Olefinpolymerisierungsverfahren in einem gasphasenreaktor mit einem steigrohr und einem fallrohr
EP3321295A1 (de) * 2016-11-10 2018-05-16 Basell Polyolefine GmbH Olefinpolymerisierungsverfahren in gasphasenreaktor mit drei oder mehr polymerisierungsbereichen
CN110392700B (zh) * 2017-03-27 2022-01-11 巴塞尔聚烯烃意大利有限公司 烯烃的气相聚合方法
EP3823999A1 (de) 2018-07-19 2021-05-26 Borealis AG Verfahren zur herstellung eines uhmwpe-homopolymers
US10781273B2 (en) 2018-12-27 2020-09-22 Chevron Phillips Chemical Company Lp Multiple reactor and multiple zone polyolefin polymerization
EP3999301A1 (de) * 2019-07-19 2022-05-25 SABIC Global Technologies, B.V. Polymerzusammensetzung und aus der polymerzusammensetzung hergestellte expandierte polypropylenperlen
US12435167B2 (en) 2019-09-05 2025-10-07 Exxonmobil Chemical Patents Inc. Processes for producing polyolefins and impact copolymers with broad molecular weight distribution and high stiffness
US20230056312A1 (en) 2020-01-24 2023-02-23 Exxonmobil Chemical Patents Inc. Methods for producing bimodal polyolefins and impact copolymers
CN115135681A (zh) 2020-02-17 2022-09-30 埃克森美孚化学专利公司 具有高分子量尾部的基于丙烯的聚合物组合物
US20260015443A1 (en) 2022-07-27 2026-01-15 Exxonmobil Chemical Patents Inc. Polyproplyene compositions with enhanced strain hardening and methods of producing the same

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DE3408464A1 (de) 1984-03-08 1985-09-12 VLT Gesellschaft für verfahrenstechnische Entwicklung mbH, 7000 Stuttgart Verfahren zur durchfuehrung von reaktionen und stoffaustauschprozessen in heterogenen fluiden systemen
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Also Published As

Publication number Publication date
KR20080008356A (ko) 2008-01-23
RU2007146451A (ru) 2009-06-20
EP1896513A1 (de) 2008-03-12
JP5106386B2 (ja) 2012-12-26
CN101175775A (zh) 2008-05-07
BRPI0612432A2 (pt) 2010-11-09
CA2608318A1 (en) 2006-11-16
EP1896513B1 (de) 2010-01-20
RU2412207C2 (ru) 2011-02-20
CN101175775B (zh) 2010-12-08
US7687588B2 (en) 2010-03-30
US20090036617A1 (en) 2009-02-05
WO2006120187A1 (en) 2006-11-16
KR101328410B1 (ko) 2013-11-13
JP2008540755A (ja) 2008-11-20

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