ATE474809T1 - Katalytisches partialoxidationsverfahren zur herstellung von synthesegas - Google Patents

Katalytisches partialoxidationsverfahren zur herstellung von synthesegas

Info

Publication number
ATE474809T1
ATE474809T1 AT04765092T AT04765092T ATE474809T1 AT E474809 T1 ATE474809 T1 AT E474809T1 AT 04765092 T AT04765092 T AT 04765092T AT 04765092 T AT04765092 T AT 04765092T AT E474809 T1 ATE474809 T1 AT E474809T1
Authority
AT
Austria
Prior art keywords
reagents
oxidation process
partial oxidation
synthesis gas
temperatures ranging
Prior art date
Application number
AT04765092T
Other languages
English (en)
Inventor
Luca Basini
Andrea Bartolini
Giancarlo Lupi
Gabriele Clerici
Original Assignee
Eni Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eni Spa filed Critical Eni Spa
Application granted granted Critical
Publication of ATE474809T1 publication Critical patent/ATE474809T1/de

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0217—Pretreatment of the substrate before coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892—Nickel and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0278—Feeding reactive fluids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Fluid Mechanics (AREA)
  • Physics & Mathematics (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
AT04765092T 2003-09-11 2004-09-09 Katalytisches partialoxidationsverfahren zur herstellung von synthesegas ATE474809T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT001739A ITMI20031739A1 (it) 2003-09-11 2003-09-11 Procedimento di ossidazione parziale catalitica per
PCT/EP2004/010169 WO2005023710A2 (en) 2003-09-11 2004-09-09 Catalytic partial oxidation process for producing synthesis gas

Publications (1)

Publication Number Publication Date
ATE474809T1 true ATE474809T1 (de) 2010-08-15

Family

ID=34260019

Family Applications (1)

Application Number Title Priority Date Filing Date
AT04765092T ATE474809T1 (de) 2003-09-11 2004-09-09 Katalytisches partialoxidationsverfahren zur herstellung von synthesegas

Country Status (10)

Country Link
US (1) US7368482B2 (de)
EP (1) EP1663856B1 (de)
AT (1) ATE474809T1 (de)
CA (1) CA2538404C (de)
DE (1) DE602004028258D1 (de)
DK (1) DK1663856T3 (de)
ES (1) ES2349139T3 (de)
IT (1) ITMI20031739A1 (de)
PT (1) PT1663856E (de)
WO (1) WO2005023710A2 (de)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20021133A1 (it) * 2002-05-24 2003-11-24 Snam Progetti Procedimento per reazioni di ossidazione parziale catalitica
ITMI20072228A1 (it) * 2007-11-23 2009-05-24 Eni Spa Procedimento per produrre gas di sintesi e idrogeno a partire da idrocarburi liquidi e gassosi
EP2384240A1 (de) * 2008-12-30 2011-11-09 Basf Se Katalysator für die chlorwasserstoffoxidation enthaltend ruthenium und nickel
IT1398292B1 (it) * 2009-12-16 2013-02-22 Eni Spa Processo per la produzione di idrogeno a partire da idrocarburi liquidi, idrocarburi gassosi e/o composti ossigenati anche derivanti da biomasse
DK201000474A (en) * 2010-06-01 2011-12-02 Haldor Topsoe As Process for the preparation of synthesis gas
DE102011101077A1 (de) 2011-05-10 2012-11-15 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Verfahren und Reaktor zur autothermen Reformierung von Brennstoffen
AU2014346961B2 (en) 2013-11-06 2017-09-28 Watt Fuel Cell Corp. Reformer with perovskite as structural component thereof
AU2014346831B2 (en) 2013-11-06 2017-09-07 Watt Fuel Cell Corp. Liquid fuel CPOX reformers and methods of CPOX reforming
MX352226B (es) 2013-11-06 2017-11-15 WATT Fuel Cell Corp Sistemas de reformador cpox de combustible líquido y celdas de combustible, y métodos de producción de electricidad.
KR101832864B1 (ko) 2013-11-06 2018-02-27 와트 퓨얼 셀 코퍼레이션 기체 반응 매질 플로우 관리용 매니폴드를 가지는 화학 반응기
EP3065857B1 (de) 2013-11-06 2022-06-08 Watt Fuel Cell Corp. Integrierter cpox-reformer für brenngas und brennstoffzellensysteme sowie verfahren zur erzeugung von strom
WO2015069836A2 (en) 2013-11-06 2015-05-14 Watt Fuel Cell Corp. Gaseous fuel cpox reformers and methods of cpox reforming
WO2016016251A1 (en) 2014-07-29 2016-02-04 Eni S.P.A. Integrated sct-cpo/sr process for producing synthesis gas
WO2016016257A1 (en) 2014-07-29 2016-02-04 Eni S.P.A. Integrated sct-cpo/pox process for producing synthesis gas
RU191712U1 (ru) * 2018-10-08 2019-08-19 Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (Институт катализа СО РАН, ИК СО РАН) Устройство получения синтез-газа
IT202100011189A1 (it) 2021-05-03 2022-11-03 Nextchem S P A Processo a basso impatto ambientale per la riduzione di minerali ferrosi in altoforno impiegante gas di sintesi
IT202100012551A1 (it) 2021-05-14 2022-11-14 Rosetti Marino S P A Processo per la conversione della co2
IT202100015473A1 (it) * 2021-06-14 2022-12-14 Nextchem S P A Metodo di produzione di catalizzatori per processi chimici ad alta temperatura e catalizzatori cosi' ottenuti
WO2024165142A1 (en) 2023-02-07 2024-08-15 NextChem S.p.A. Process of direct reduction of iron ores by means of synthesis gas produced with catalytic partial oxidation
WO2024245540A1 (en) 2023-05-30 2024-12-05 Nextchem Tech S.P.A. Process for the production of carboxylic acids and carbonyl compounds by utilizing carbon dioxide-rich feedstock
WO2024245542A1 (en) 2023-05-30 2024-12-05 Nextchem Tech S.P.A. Process for the production of fuel and chemicals from waste materials by utilizing carbon dioxide-rich feedstock
WO2024245538A1 (en) 2023-05-30 2024-12-05 Nextchem Tech S.P.A. Process for the production of synthetic hydrocarbons compounds by utilizing carbon dioxide-rich feedstock
EP4750922A1 (de) 2023-07-26 2026-06-03 KT Tech S.p.A. Verbessertes verfahren zur schmelzreduktion von eisenerzen
WO2026008712A1 (en) 2024-07-04 2026-01-08 Kt Tech S.P.A. Process for the valorization of hydrocarbon mixtures and of secondary streams of industrial processes through partial oxidation reaction and co2 separation technologies

Family Cites Families (9)

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Publication number Priority date Publication date Assignee Title
US4394137A (en) 1980-12-03 1983-07-19 Texaco, Inc. Partial oxidation process
IT1272532B (it) 1993-08-27 1997-06-23 Snam Progetti Processo di ossidazione parziale catalitica del gas naturale per ottenere gas di sintesi e formaldeide
US5358696A (en) * 1993-12-01 1994-10-25 Texaco Inc. Production of H2 -rich gas
IT1283585B1 (it) 1996-04-11 1998-04-22 Snam Progetti Apparecchiatura per effettuare reazioni di ossidazione parziale
AR017317A1 (es) 1997-10-14 2001-09-05 Shell Int Research Proceso de oxidacion parcial catalitica, un metodo y disposicion para generar energia electrica por medio de dicho proceso, y medio de transporteprovisto con dicha disposicion
CZ20004900A3 (cs) 1998-06-30 2001-08-15 Shell Internationale Research Maatschappij B. V. Katalyzátor a způsob parciální katalytické oxidace dvěma katalyticky aktivními kovy
DE10002004A1 (de) * 2000-01-19 2001-08-09 Bosch Gmbh Robert Zerstäubungsvorrichtung
US6447745B1 (en) * 2000-08-01 2002-09-10 Exxonmobil Research And Engineering Company Catalytic oxidation process
ITMI20021133A1 (it) 2002-05-24 2003-11-24 Snam Progetti Procedimento per reazioni di ossidazione parziale catalitica

Also Published As

Publication number Publication date
WO2005023710A2 (en) 2005-03-17
DK1663856T3 (da) 2010-11-15
EP1663856B1 (de) 2010-07-21
PT1663856E (pt) 2010-10-22
DE602004028258D1 (de) 2010-09-02
EP1663856A2 (de) 2006-06-07
CA2538404A1 (en) 2005-03-17
WO2005023710A3 (en) 2005-05-26
ES2349139T3 (es) 2010-12-28
ITMI20031739A1 (it) 2005-03-12
US7368482B2 (en) 2008-05-06
US20070105962A1 (en) 2007-05-10
CA2538404C (en) 2012-08-07

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