ATE474870T1 - Herstellungsverfahren für einen polyisocyanuratverbund - Google Patents
Herstellungsverfahren für einen polyisocyanuratverbundInfo
- Publication number
- ATE474870T1 ATE474870T1 AT07703950T AT07703950T ATE474870T1 AT E474870 T1 ATE474870 T1 AT E474870T1 AT 07703950 T AT07703950 T AT 07703950T AT 07703950 T AT07703950 T AT 07703950T AT E474870 T1 ATE474870 T1 AT E474870T1
- Authority
- AT
- Austria
- Prior art keywords
- amount
- reactive
- composite
- polyol
- weight
- Prior art date
Links
- 239000002131 composite material Substances 0.000 title abstract 7
- 229920000582 polyisocyanurate Polymers 0.000 title abstract 2
- 239000011495 polyisocyanurate Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920005862 polyol Polymers 0.000 abstract 4
- 150000003077 polyols Chemical class 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- 239000011230 binding agent Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229920001228 polyisocyanate Polymers 0.000 abstract 2
- 239000005056 polyisocyanate Substances 0.000 abstract 2
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000006353 oxyethylene group Chemical group 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 238000005829 trimerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
- C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06110206 | 2006-02-21 | ||
| PCT/EP2007/050453 WO2007096216A1 (en) | 2006-02-21 | 2007-01-17 | Process for making a polyisocyanurate composite |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE474870T1 true ATE474870T1 (de) | 2010-08-15 |
Family
ID=36704189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT07703950T ATE474870T1 (de) | 2006-02-21 | 2007-01-17 | Herstellungsverfahren für einen polyisocyanuratverbund |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20090005517A1 (de) |
| EP (1) | EP1989242B1 (de) |
| JP (1) | JP5159640B2 (de) |
| KR (1) | KR101360637B1 (de) |
| CN (1) | CN101389675B (de) |
| AT (1) | ATE474870T1 (de) |
| AU (1) | AU2007217657B2 (de) |
| BR (1) | BRPI0707479B1 (de) |
| CA (1) | CA2636621C (de) |
| DE (1) | DE602007007903D1 (de) |
| RU (1) | RU2434027C2 (de) |
| WO (1) | WO2007096216A1 (de) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4818104B2 (ja) * | 2003-06-12 | 2011-11-16 | ハンツマン・インターナショナル・エルエルシー | ポリイソシアヌレートポリウレタン材料の製造プロセス |
| EP1940899B1 (de) | 2005-10-13 | 2009-08-05 | Huntsman International Llc | Verfahren zur herstellung von polyisocyanat-polyurethan-material |
| CN101466517B (zh) * | 2006-06-14 | 2012-02-22 | 亨茨曼国际有限公司 | 复合面板 |
| US9314947B2 (en) * | 2007-05-23 | 2016-04-19 | Huntsman International Llc | Adhesives, reaction systems, and processes for production of lignocellulosic composites |
| CN101945910B (zh) * | 2008-02-14 | 2013-09-18 | 亨茨曼国际有限公司 | 具有高的硬嵌段含量的弹性体材料和制备它们的方法 |
| US8349908B2 (en) * | 2008-03-07 | 2013-01-08 | Huntsman International Llc | Foamed materials comprising a matrix having a high highblock content and process for preparing them |
| EP2342252B1 (de) * | 2008-08-28 | 2017-04-26 | Huntsman International LLC | Durch die reaktion von polyol und anhydrid gewonnene mischung und deren verwendung bei polyisocyanaten zur herstellung von polyisocyanuraten |
| CN102405244B (zh) | 2009-04-21 | 2016-10-05 | 亨茨曼国际有限公司 | 多异氰酸酯组合物 |
| WO2012062796A1 (en) | 2010-11-09 | 2012-05-18 | Rockwool International A/S | Method for manufacturing an aerogel-containing composite and composite produced by said method |
| EP2637982B1 (de) * | 2010-11-09 | 2021-01-06 | Rockwool International A/S | Mineralfaserprodukt mit verringerter wärmeleitfähigkeit |
| US9127163B2 (en) | 2010-11-29 | 2015-09-08 | Huntsman International Llc | Polyisocyanate-based binder |
| CN102115525B (zh) * | 2010-12-30 | 2012-09-26 | 山东东大一诺威聚氨酯有限公司 | 一种聚异氰脲酸酯聚氨酯涂料固化剂及其制备方法 |
| BR112013016686B1 (pt) | 2011-01-31 | 2020-07-07 | Huntsman International Llc | composição de resina epóxi, processo para a preparação de uma composição, composição curável, material de poliisocianurato-poliuretano, processo para fabricar um material de poliisocianurato- poliuretano, e, uso de um composto |
| BR112014011154B1 (pt) | 2011-11-22 | 2022-05-10 | Huntsman International Llc | Composição curável, processos para a preparação de uma composição curável e de poliisocianurato, e, poliisocianurato |
| JP2015504110A (ja) | 2011-12-28 | 2015-02-05 | ハンツマン・インターナショナル・エルエルシー | ポリイソシアネート組成物を含む硬化性組成物 |
| EP2644270A1 (de) | 2012-03-29 | 2013-10-02 | Huntsman International Llc | Polyisocyanat-Trimerisationskatalysatorzusammensetzung |
| JP5696735B2 (ja) | 2013-03-25 | 2015-04-08 | 日油株式会社 | ウレタン硬化性組成物 |
| EP2805976A1 (de) | 2013-05-24 | 2014-11-26 | Huntsman International Llc | Aldehyd enthaltende Zusammensetzungen, die zur Herstellung von härtbaren Polyisocyanatzusammensetzungen geeignet sind |
| MX2016000046A (es) * | 2013-07-11 | 2016-03-09 | Dow Global Technologies Llc | Proceso para producir uretano-isocianuratos. |
| JP6678386B2 (ja) * | 2014-11-21 | 2020-04-08 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | 耐火性物品およびその製造方法 |
| DE102014226838A1 (de) | 2014-12-22 | 2016-06-23 | Henkel Ag & Co. Kgaa | Oxazolidinon- und Isocyanurat-vernetzte Matrix für faserverstärktes Material |
| DE102014226842A1 (de) | 2014-12-22 | 2016-06-23 | Henkel Ag & Co. Kgaa | Katalysator-Zusammensetzung zur Härtung von Epoxidgruppen-haltigen Harzen |
| EP3452528B1 (de) * | 2016-05-04 | 2025-07-30 | Covestro Deutschland AG | Verfahren zur herstellung eines polyisocyanurat-kompositwerkstoffs |
| CA3019657A1 (en) | 2016-05-04 | 2017-11-09 | Covestro Deutschland Ag | Method for producing a polyisocyanurate composite material |
| CN114800727B (zh) * | 2022-03-25 | 2023-01-13 | 万华化学集团股份有限公司 | 一种单板类人造板的制备方法 |
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| US3206352A (en) * | 1962-03-23 | 1965-09-14 | Monsanto Res Corp | Polymeric polyisocyanurate laminating resin prepared from a diaryl dhsocyanate and acocatalyst system |
| US3940517A (en) * | 1973-01-11 | 1976-02-24 | The Celotex Corporation | Polyisocyanurate foam, catalyst composition and process for producing such |
| US3817939A (en) * | 1973-02-21 | 1974-06-18 | Minnesota Mining & Mfg | Organic carbonate salts as isocyanate trimerization catalysts |
| DE2607380C3 (de) * | 1976-02-24 | 1981-07-23 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von warmformbaren Polyisocyanuratschaumstoffen |
| US4066580A (en) * | 1976-06-07 | 1978-01-03 | Basf Wyandotte Corporation | Process for the manufacture of polyisocyanurate foams |
| US4126742A (en) * | 1978-05-15 | 1978-11-21 | The Upjohn Company | High-modulus polyisocyanurate elastomers |
| US4126741A (en) * | 1978-05-15 | 1978-11-21 | The Upjohn Company | High-modulus polyisocyanurate elastomers |
| US4247656A (en) * | 1979-03-14 | 1981-01-27 | Minnesota Mining And Manufacturing Company | Poly(urethane-isocyanurate) foams |
| DE2921162A1 (de) * | 1979-05-25 | 1980-12-04 | Bayer Ag | Hitzehaertbare formmassen und verfahren zur herstellung von formkoerpern |
| US4424288A (en) * | 1981-12-24 | 1984-01-03 | Basf Wyandotte Corporation | Carbodiimide-modified polymethylene polyphenylene polyisocyanates for use in the preparation of polyisocyanurate-polyurethane foams |
| US4661533A (en) * | 1985-10-28 | 1987-04-28 | The Dow Chemical Company | Rigid polyurethane modified polyisocyanurate containing fly ash as an inorganic filler |
| IT1190432B (it) * | 1985-12-10 | 1988-02-16 | Montedison Spa | Compositi ad alta densita' a base essenzialmente poliisocianurica |
| US4871612A (en) * | 1986-09-05 | 1989-10-03 | Inoue Mtp Kabushiki Kaisha | Interior member for vehicles and method for its manufacture |
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| JPS63309510A (ja) * | 1987-06-12 | 1988-12-16 | Nippon Polyurethan Kogyo Kk | ポリイソシアヌレ−ト複合体の製造法 |
| US4800058A (en) * | 1987-08-24 | 1989-01-24 | Arco Chemical Company | Method for the preparation of rigid cast or transfer molded thermoset polyurethane modified polyisocyanurate compositions |
| US4900776A (en) * | 1988-12-01 | 1990-02-13 | Georgia-Pacific Resins, Inc. | Potassium catalyst system for preparing polyurethane based plywood-patch compositions |
| US5286759A (en) * | 1991-03-08 | 1994-02-15 | The Dow Chemical Company | Foaming system for rigid urethane and isocyanurate foams |
| US5137929A (en) * | 1991-06-21 | 1992-08-11 | Allied-Signal Inc. | Additives which stabilize hydrohalocarbon blowing agent in polyurethane and polyisocyanurate foam formulations during polymerization |
| US5260344A (en) * | 1992-03-13 | 1993-11-09 | Asahi Glass Company, Ltd. | Open cell rigid isocyanurate foams and method for producing the same and vacuum heat insulating layer by use of the same |
| BE1005821A3 (nl) * | 1992-05-18 | 1994-02-08 | Recticel | Werkwijze voor het vervaardigen van zelfdragende kunststof garnituuronderdelen en aldus vervaardigd garnituuronderdeel. |
| US5232957A (en) * | 1992-09-11 | 1993-08-03 | Davidson Textron Inc. | RIM molded energy absorbing polyurethane foam |
| US5418261A (en) * | 1993-01-25 | 1995-05-23 | Imperial Chemical Industries Plc | Polyurethane foams |
| US5556934A (en) * | 1993-09-03 | 1996-09-17 | H. B. Fuller Licensing & Financing Inc. | Isocyanurate embedment compound |
| DE4421817A1 (de) * | 1994-06-22 | 1996-01-04 | Bayer Ag | Verfahren zur Isolierung von Rohren |
| SE9500342D0 (sv) * | 1995-01-31 | 1995-01-31 | Marek Kwiatkowski | Novel chain terminators, the use thereof for nucleic acid sequencing and synthesis and a method of their preparation |
| US5900442A (en) * | 1995-05-12 | 1999-05-04 | Imperial Chemical Industries Plc | Flexible polyurethane foams |
| US5928772A (en) * | 1996-06-13 | 1999-07-27 | Dainippon Ink And Chemicals, Inc. | Panel material and method of manufacturing the same |
| AU725188B2 (en) * | 1996-06-27 | 2000-10-05 | Huntsman Ici Chemicals Llc | Microcellular elastomeric polyurethane foams |
| DE19838167A1 (de) * | 1998-08-21 | 2000-02-24 | Basf Ag | Mischung enthaltend Isocyanate sowie organische und/oder anorganische Säureanhydride |
| HK1042313A1 (zh) * | 1998-11-16 | 2002-08-09 | 亨茨曼国际有限公司 | 聚异氰脲酸酯组合物及复合材料 |
| DE19918726C2 (de) * | 1999-04-24 | 2002-04-11 | Bayer Ag | Offenzellige Polyurethanhartschaumstoffe |
| US6509392B1 (en) * | 2000-01-25 | 2003-01-21 | H.A. International Llc | Foundry binder and process |
| WO2001068565A2 (en) * | 2000-03-16 | 2001-09-20 | The Regents Of The University Of California | Chemoselective ligation by use of a phosphine |
| EP1167414A1 (de) * | 2000-06-29 | 2002-01-02 | Huntsman International Llc | Verfahren zur Herstellung von Polyurethanhartschaumstoffen mit hoher Haftung |
| EP1172387A1 (de) * | 2000-07-14 | 2002-01-16 | Huntsman International Llc | Verfahren zum Herstellen eines Elastomers |
| EP1178063A1 (de) * | 2000-08-01 | 2002-02-06 | Huntsman International Llc | Verfahren zur Herstellung eines Polyurethanmaterials |
| FR2812653A1 (fr) * | 2000-08-03 | 2002-02-08 | Michelin Soc Tech | Colle pour compositions de caoutchouc, son procede de preparation et articles comportant cette colle |
| CN1447832A (zh) * | 2000-08-18 | 2003-10-08 | 亨茨曼国际有限公司 | 单组分热固性聚氨酯体系 |
| IT1319215B1 (it) * | 2000-10-16 | 2003-09-26 | Industrialesud Spa | Prodotto multistrato, suo uso per la realizzazione di articolileggeri, fonoassorbenti, autoportanti e articoli ottenibili con detto |
| US6773756B2 (en) * | 2002-03-20 | 2004-08-10 | Bayer Polymers Llc | Process to manufacture three dimensionally shaped substrate for sound abatement |
| ES2566761T3 (es) * | 2002-05-30 | 2016-04-15 | The Scripps Research Institute | Ligación de azidas y acetilenos catalizada por cobre |
| US20040069971A1 (en) * | 2002-10-15 | 2004-04-15 | Witteveen Martijn M. | Polyol compositions and rigid polyisocyanurate foams prepared therefrom |
| US20040249078A1 (en) * | 2003-06-04 | 2004-12-09 | Honeywell International, Inc. | Foam catalyst systems |
| JP4818104B2 (ja) * | 2003-06-12 | 2011-11-16 | ハンツマン・インターナショナル・エルエルシー | ポリイソシアヌレートポリウレタン材料の製造プロセス |
| US7763341B2 (en) * | 2004-01-23 | 2010-07-27 | Century-Board Usa, Llc | Filled polymer composite and synthetic building material compositions |
| ITRM20040375A1 (it) * | 2004-07-23 | 2004-10-23 | Tekno Garden S R L | Materiali compositi a base di resine leganti, procedimenti per la loro preparazione e usi. |
| EP1940899B1 (de) * | 2005-10-13 | 2009-08-05 | Huntsman International Llc | Verfahren zur herstellung von polyisocyanat-polyurethan-material |
| DE602006018974D1 (de) * | 2005-10-13 | 2011-01-27 | Huntsman Int Llc | Verfahren zur herstellung eines polyisocyanuratpolyurethanmaterials |
-
2007
- 2007-01-17 AT AT07703950T patent/ATE474870T1/de not_active IP Right Cessation
- 2007-01-17 US US12/279,903 patent/US20090005517A1/en not_active Abandoned
- 2007-01-17 EP EP07703950A patent/EP1989242B1/de active Active
- 2007-01-17 KR KR1020087020313A patent/KR101360637B1/ko active Active
- 2007-01-17 DE DE602007007903T patent/DE602007007903D1/de active Active
- 2007-01-17 WO PCT/EP2007/050453 patent/WO2007096216A1/en not_active Ceased
- 2007-01-17 CA CA2636621A patent/CA2636621C/en active Active
- 2007-01-17 RU RU2008137599/04A patent/RU2434027C2/ru active
- 2007-01-17 CN CN2007800061446A patent/CN101389675B/zh active Active
- 2007-01-17 BR BRPI0707479-4A patent/BRPI0707479B1/pt not_active IP Right Cessation
- 2007-01-17 JP JP2008554713A patent/JP5159640B2/ja not_active Expired - Fee Related
- 2007-01-17 AU AU2007217657A patent/AU2007217657B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| JP2009527585A (ja) | 2009-07-30 |
| JP5159640B2 (ja) | 2013-03-06 |
| EP1989242B1 (de) | 2010-07-21 |
| RU2008137599A (ru) | 2010-03-27 |
| DE602007007903D1 (de) | 2010-09-02 |
| BRPI0707479A2 (pt) | 2011-05-03 |
| RU2434027C2 (ru) | 2011-11-20 |
| EP1989242A1 (de) | 2008-11-12 |
| CA2636621C (en) | 2013-06-25 |
| AU2007217657B2 (en) | 2011-08-04 |
| KR20080106521A (ko) | 2008-12-08 |
| CA2636621A1 (en) | 2007-08-30 |
| CN101389675A (zh) | 2009-03-18 |
| AU2007217657A1 (en) | 2007-08-30 |
| US20090005517A1 (en) | 2009-01-01 |
| KR101360637B1 (ko) | 2014-02-07 |
| CN101389675B (zh) | 2012-06-20 |
| WO2007096216A1 (en) | 2007-08-30 |
| BRPI0707479B1 (pt) | 2018-06-05 |
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