ATE489413T1 - Polyurethanheisschmelzkleber mit acrylkopolymeren und thermoplastharzen - Google Patents
Polyurethanheisschmelzkleber mit acrylkopolymeren und thermoplastharzenInfo
- Publication number
- ATE489413T1 ATE489413T1 AT01927206T AT01927206T ATE489413T1 AT E489413 T1 ATE489413 T1 AT E489413T1 AT 01927206 T AT01927206 T AT 01927206T AT 01927206 T AT01927206 T AT 01927206T AT E489413 T1 ATE489413 T1 AT E489413T1
- Authority
- AT
- Austria
- Prior art keywords
- hot melt
- melt adhesive
- thermoplastic resins
- acrylic copolymers
- polyurethane hot
- Prior art date
Links
- 229920002635 polyurethane Polymers 0.000 title abstract 5
- 239000004814 polyurethane Substances 0.000 title abstract 5
- 229920005992 thermoplastic resin Polymers 0.000 title abstract 3
- 239000004831 Hot glue Substances 0.000 title 1
- 229920006243 acrylic copolymer Polymers 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 4
- 239000000853 adhesive Substances 0.000 abstract 3
- 230000001070 adhesive effect Effects 0.000 abstract 3
- 239000000565 sealant Substances 0.000 abstract 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 abstract 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 abstract 1
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract 1
- 239000012943 hotmelt Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract 1
- 229920000058 polyacrylate Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K3/1006—Materials in mouldable or extrudable form for sealing or packing joints or covers characterised by the chemical nature of one of its constituents
- C09K3/1021—Polyurethanes or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/36—Hydroxylated esters of higher fatty acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4063—Mixtures of compounds of group C08G18/62 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/20—Compositions for hot melt adhesives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
- Polyurethanes Or Polyureas (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/556,721 US6482878B1 (en) | 2000-04-21 | 2000-04-21 | Polyurethane hotmelt adhesives with acrylic copolymers and thermoplastic resins |
| PCT/US2001/012719 WO2001081495A2 (en) | 2000-04-21 | 2001-04-18 | Polyurethane hotmelt adhesives with acrylic copolymers and thermoplastic resins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE489413T1 true ATE489413T1 (de) | 2010-12-15 |
Family
ID=24222564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT01927206T ATE489413T1 (de) | 2000-04-21 | 2001-04-18 | Polyurethanheisschmelzkleber mit acrylkopolymeren und thermoplastharzen |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6482878B1 (de) |
| EP (1) | EP1307495B1 (de) |
| JP (1) | JP2003531271A (de) |
| CN (1) | CN1244606C (de) |
| AT (1) | ATE489413T1 (de) |
| AU (1) | AU2001253681A1 (de) |
| DE (1) | DE60143528D1 (de) |
| ES (1) | ES2359048T3 (de) |
| WO (1) | WO2001081495A2 (de) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7005476B1 (en) * | 1999-02-11 | 2006-02-28 | Jowat Lobers Und Frank Gmbh & Co. Kg | Multicomponent coating and adhesive material |
| US6613836B2 (en) | 2001-06-15 | 2003-09-02 | National Starch And Chemical Investment Holding Corporation | Reactive hot melt adhesive |
| US20030004263A1 (en) * | 2001-06-15 | 2003-01-02 | Schmidt Robert C. | Reactive hot melt adhesive |
| US20030010443A1 (en) * | 2001-07-09 | 2003-01-16 | Rumack Daniel T. | Reactive hot melt adhesive |
| JP4767454B2 (ja) * | 2001-08-31 | 2011-09-07 | コニシ株式会社 | １液湿気硬化型ウレタン系接着剤組成物 |
| DE10149142A1 (de) * | 2001-10-05 | 2003-04-24 | Henkel Kgaa | Modifizierter reaktiver Schmelzklebstoff und dessen Verwendung |
| US7025853B2 (en) | 2002-07-03 | 2006-04-11 | Rohm And Haas Company | Reactive hot-melt adhesive compositions with improved green strength |
| US7037402B2 (en) * | 2002-10-15 | 2006-05-02 | National Starch & Chemical Investment Holding Corporation | Reactive hot melt adhesive with non-polymeric aromatic difunctionals |
| US8664330B2 (en) | 2003-04-04 | 2014-03-04 | Henkel US IP LLC | Reactive hot melt adhesive with improved hydrolysis resistance |
| JP4279155B2 (ja) * | 2003-05-13 | 2009-06-17 | ローム アンド ハース カンパニー | 湿分反応性ホットメルト接着剤 |
| US7829615B2 (en) * | 2003-06-09 | 2010-11-09 | Henkel Ag & Co. Kgaa | Reactive hot melt adhesives |
| JP3970860B2 (ja) * | 2003-11-03 | 2007-09-05 | ローム アンド ハース カンパニー | 水分反応性ホットメルト組成物 |
| US7332540B2 (en) | 2004-02-18 | 2008-02-19 | Eastman Chemical Company | Aromatic-acrylate tackifier resins |
| US7238732B2 (en) | 2004-02-18 | 2007-07-03 | Eastman Chemical Company | Radiation-curable adhesive compositions |
| US7262242B2 (en) | 2004-02-18 | 2007-08-28 | Eastman Chemical Company | Aromatic/acrylate tackifier resin and acrylic polymer blends |
| US7645831B2 (en) * | 2004-03-26 | 2010-01-12 | Henkel Ag & Co. Kgaa | Reactive hot melt adhesives |
| CN1325594C (zh) * | 2004-06-22 | 2007-07-11 | 姜堰鼎盛特种化工有限公司 | 聚氨酯胶粘剂 |
| US20060084755A1 (en) * | 2004-10-19 | 2006-04-20 | Good David J | Reactive hot melt adhesive with block acrylic copolymer |
| US7169852B2 (en) | 2004-11-12 | 2007-01-30 | Rohm And Haas Company | Moisture-reactive hot-melt compositions |
| EP1879975A1 (de) * | 2005-05-02 | 2008-01-23 | Cytec Surface Specialties, S.A. | Klebstoffzusammensetzung und verfahren |
| US20070155859A1 (en) * | 2006-01-04 | 2007-07-05 | Zhengzhe Song | Reactive polyurethane hot melt adhesive |
| DE102006020605A1 (de) * | 2006-05-02 | 2007-11-08 | Bayer Materialscience Ag | Feuchtigkeitshärtende Kleb- und Dichtstoffe |
| CL2007003131A1 (es) * | 2006-11-01 | 2008-07-04 | Lucite Int Inc | Metodo para fabricar un articulo que comprende formular composicion acrilica que tiene un agente de transferencia con grupo que reacciona con isocianato y luego unir a una composicion que contiene isocianato; articulo; metodo que mejora la eficiencia |
| KR100838005B1 (ko) | 2007-01-15 | 2008-06-12 | 주식회사 쌍 곰 | 난방바닥 타일 접착용 시멘트 접착강화제 |
| US7625963B2 (en) * | 2007-01-25 | 2009-12-01 | Henkel Ag & Co. Kgaa | Reactive hot melt adhesive with bituminous additive |
| KR20090128400A (ko) | 2007-02-28 | 2009-12-15 | 스미토모 베이클리트 컴퍼니 리미티드 | 반도체용 접착 필름 및 그것을 이용한 반도체 장치 |
| US8216682B2 (en) * | 2007-10-11 | 2012-07-10 | Illinois Tool Works, Inc. | Moisture curable isocyanate containing acrylic formulation |
| WO2009055990A1 (fr) * | 2007-10-30 | 2009-05-07 | Zhang, Bi | Gazon artificiel et son procédé de fabrication |
| CN101424068B (zh) * | 2007-11-02 | 2011-07-20 | 广州爱奇实业有限公司 | 新型人造草皮及其制造方法 |
| US9309348B2 (en) | 2009-03-24 | 2016-04-12 | Nippon Carbide Industries Co., Inc. | Adhesive composition |
| CN101638568B (zh) * | 2009-06-09 | 2012-03-14 | 虞建放 | 改性聚氨酯类防水密封胶 |
| EP2471885A4 (de) * | 2009-08-27 | 2014-05-14 | Asahi Glass Co Ltd | Schmelzhaftkleberzusammensetzung |
| CN101701143B (zh) * | 2009-09-23 | 2013-09-25 | 上海鼎道科技发展有限公司 | 一种紫外光固化粘合剂及其制备方法 |
| JP2011116817A (ja) * | 2009-12-01 | 2011-06-16 | Henkel Japan Ltd | 湿気硬化型ホットメルト接着剤 |
| JP5757707B2 (ja) * | 2010-08-26 | 2015-07-29 | ヘンケルジャパン株式会社 | 湿気硬化型ホットメルト接着剤 |
| CN101921564B (zh) * | 2010-09-29 | 2012-04-04 | 泰州五行消防水带有限公司 | 一种芳纶纤维编织层专用粘合剂及其制备方法 |
| CA2817916C (en) * | 2010-11-15 | 2019-02-12 | Cohera Medical, Inc. | Biodegradable compositions having pressure sensitive adhesive properties |
| MX352304B (es) * | 2011-11-07 | 2017-11-16 | Philip Morris Products Sa | Articulo para fumar con contenido visible. |
| WO2013148506A1 (en) * | 2012-03-30 | 2013-10-03 | 3M Innovative Properties Company | Urea-based and urethane-based pressure sensitive adhesive blends |
| CN102796485A (zh) * | 2012-09-11 | 2012-11-28 | 无锡市万力粘合材料有限公司 | 反应性聚氨酯热熔胶及其制备方法 |
| CN102977811A (zh) * | 2012-11-21 | 2013-03-20 | 深圳长园电子材料有限公司 | 一种双壁热缩套管用无卤复合热熔胶及其制备方法 |
| KR20140067366A (ko) * | 2012-11-26 | 2014-06-05 | 박희대 | 에폭시 접착용 핫멜트 필름의 조성물 |
| EP2948486A1 (de) * | 2013-01-28 | 2015-12-02 | Lucite International UK Limited | Schmelzhaftkleber |
| CN103087669B (zh) * | 2013-03-05 | 2014-11-12 | 河南省科学院化学研究所有限公司 | 一种用于复合板制造的湿固化聚氨酯热熔胶粘剂 |
| JP6400070B2 (ja) | 2013-03-14 | 2018-10-03 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | ホットメルト接着剤およびその形成方法 |
| JP2014177574A (ja) * | 2013-03-15 | 2014-09-25 | Dic Corp | 樹脂組成物、プライマー及び物品 |
| CN103215003B (zh) * | 2013-04-19 | 2014-12-10 | 厦门朝富人造革有限公司 | 热塑性聚氨酯发泡树脂粘胶、其制备方法、用途以及制品 |
| CN103333619A (zh) * | 2013-06-27 | 2013-10-02 | 苏州工业园区依利电子贸易有限公司 | 一种弹性粘胶剂 |
| WO2015016029A1 (ja) * | 2013-07-31 | 2015-02-05 | Dic株式会社 | 湿気硬化型ホットメルトウレタン組成物及び接着剤 |
| CN103709975B (zh) * | 2013-11-29 | 2016-07-06 | 中国科学院长春应用化学研究所 | 用于复合氟塑料薄膜的聚氨酯胶粘剂及其制备方法 |
| CN106536666A (zh) | 2014-07-02 | 2017-03-22 | 汉高股份有限及两合公司 | 可移除的聚氨酯热熔粘合剂及其用途 |
| KR101601447B1 (ko) * | 2014-07-04 | 2016-03-09 | 현대자동차주식회사 | 초경량 폴리우레탄 인조피혁 조성물 |
| US10240697B2 (en) | 2014-08-22 | 2019-03-26 | 5elem Material Scientific(Jiangsu) Co., LTD. | Fracturing liquid delivery hose for recovery of shale oil and gas, and manufacturing method thereof |
| JP6556050B2 (ja) * | 2015-12-25 | 2019-08-07 | ヘンケルジャパン株式会社 | 湿気硬化型ホットメルト接着剤 |
| CN110167985A (zh) * | 2017-01-12 | 2019-08-23 | 巴斯夫欧洲公司 | 聚氨酯的物理性能改进 |
| CN107011851A (zh) * | 2017-05-05 | 2017-08-04 | 广东泰强化工实业有限公司 | 3d打印用热熔胶及其制备方法 |
| PL3990510T3 (pl) * | 2019-06-25 | 2025-02-10 | H.B. Fuller Company | Utwardzalna wilgocią kompozycja poliuretanowego kleju topliwego o niskim poziomie monomeru diizocyjanianu |
| US20240240069A1 (en) | 2021-04-23 | 2024-07-18 | Follmann Gmbh & Co. Kg | Polymerization of a silane-modified polymer, which is produced by means of a radical chain polymerization, in a polyol or in a prepolymer with terminal isocyanate groups, and use thereof in polyurethane formulations |
| DE102021119133A1 (de) | 2021-07-23 | 2023-01-26 | Follmann Gmbh & Co. Kg | Polymerzusammensetzung sowie Verfahren zu deren Herstellung und deren Verwendung, feuchtigkeitshärtende Polyurethan-Schmelzklebstoffzusammensetzung sowie Verfahren zu deren Herstellung und deren Verwendung, 1K-Polyurethanklebstoff sowie Verfahren zu dessen Herstellung und dessen Verwendung |
| CN118355088A (zh) * | 2021-09-28 | 2024-07-16 | 汉高股份有限及两合公司 | 可湿固化的聚氨酯热熔粘合剂组合物 |
| DE102022127933A1 (de) | 2022-10-21 | 2024-05-02 | Follmann Gmbh & Co. Kg | Radikalische Polymerisation von UV-vernetzenden Silanacrylaten in einer Isocyanat-haltigen Polyurethan-Matrix |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5130898B2 (de) | 1973-01-11 | 1976-09-03 | ||
| JPS5321236A (en) * | 1976-08-10 | 1978-02-27 | Mitsubishi Petrochem Co Ltd | Reactive hot-melt adhesives |
| US4585819A (en) | 1984-08-14 | 1986-04-29 | H. B. Fuller Company | Fusion adhesive which can comprise an isocyanate prepolymer, a thermoplastic polymer and/or a lower molecular weight ketone resin |
| US4775719A (en) * | 1986-01-29 | 1988-10-04 | H. B. Fuller Company | Thermally stable hot melt moisture-cure polyurethane adhesive composition |
| EP0246473B1 (de) * | 1986-05-05 | 1990-04-18 | National Starch and Chemical Corporation | Acrylmodifzierte reaktive Urethan-Schmelz-Klebstoff-Zusammensetzungen |
| US5021507A (en) | 1986-05-05 | 1991-06-04 | National Starch And Chemical Investment Holding Corporation | Arcylic modified reactive urethane hot melt adhesive compositions |
| US4808255A (en) | 1987-05-07 | 1989-02-28 | H. B. Fuller Company | Thermally stable reactive hot melt urethane adhesive composition having a thermoplastic polymer, a compatible, curing urethane polyester polyol prepolymer and a tackifying agent |
| FR2641791B1 (fr) | 1989-01-19 | 1991-04-19 | Atochem | Composition adhesive thermofusible reticulable a l'humidite, son procede de fabrication |
| FR2698877B1 (fr) | 1992-12-04 | 1995-04-07 | Atochem Elf Sa | Composition adhésives thermofusibles réticulables à l'humidité. |
| JPH07197006A (ja) * | 1994-01-07 | 1995-08-01 | Sekisui Chem Co Ltd | 湿気硬化型ウレタン系ホットメルト接着剤の除去方法 |
| US5866656A (en) | 1995-06-07 | 1999-02-02 | National Starch And Chemical Investment Holding Corporation | Polyurethane hotmelt adhesives with reactive acrylic copolymers |
| EP0819711A1 (de) | 1996-07-16 | 1998-01-21 | Ato Findley S.A. | Einkomponentpolyurethanklebstoffe die erhöhte Anfangsfestigkeit aufweisen |
| CA2214311A1 (en) | 1996-09-06 | 1998-03-06 | Air Products And Chemicals, Inc. | Hot melt adhesives comprising low free monomer, low oligomer isocyanate prepolymers |
| US5939488A (en) * | 1997-10-15 | 1999-08-17 | National Starch And Chemical Investment Holding Corporation | Fast setting polyurethane hot melt adhesive composition comprising low hydroxyl number/high molecular weight polyester diols |
-
2000
- 2000-04-21 US US09/556,721 patent/US6482878B1/en not_active Expired - Lifetime
-
2001
- 2001-04-18 CN CNB018115373A patent/CN1244606C/zh not_active Expired - Fee Related
- 2001-04-18 WO PCT/US2001/012719 patent/WO2001081495A2/en not_active Ceased
- 2001-04-18 JP JP2001578571A patent/JP2003531271A/ja active Pending
- 2001-04-18 DE DE60143528T patent/DE60143528D1/de not_active Expired - Lifetime
- 2001-04-18 EP EP01927206A patent/EP1307495B1/de not_active Expired - Lifetime
- 2001-04-18 AT AT01927206T patent/ATE489413T1/de not_active IP Right Cessation
- 2001-04-18 ES ES01927206T patent/ES2359048T3/es not_active Expired - Lifetime
- 2001-04-18 AU AU2001253681A patent/AU2001253681A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO2001081495A3 (en) | 2002-02-21 |
| AU2001253681A1 (en) | 2001-11-07 |
| DE60143528D1 (de) | 2011-01-05 |
| EP1307495B1 (de) | 2010-11-24 |
| EP1307495A2 (de) | 2003-05-07 |
| WO2001081495A2 (en) | 2001-11-01 |
| ES2359048T3 (es) | 2011-05-18 |
| CN1437623A (zh) | 2003-08-20 |
| US6482878B1 (en) | 2002-11-19 |
| CN1244606C (zh) | 2006-03-08 |
| JP2003531271A (ja) | 2003-10-21 |
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