ATE497992T1 - MULTIMODAL POLYETHYLENE COMPOSITION, MIXED CATALYSAOTR AND METHOD FOR PREPARING THE COMPOSITION - Google Patents
MULTIMODAL POLYETHYLENE COMPOSITION, MIXED CATALYSAOTR AND METHOD FOR PREPARING THE COMPOSITIONInfo
- Publication number
- ATE497992T1 ATE497992T1 AT07856840T AT07856840T ATE497992T1 AT E497992 T1 ATE497992 T1 AT E497992T1 AT 07856840 T AT07856840 T AT 07856840T AT 07856840 T AT07856840 T AT 07856840T AT E497992 T1 ATE497992 T1 AT E497992T1
- Authority
- AT
- Austria
- Prior art keywords
- ethylene polymer
- composition
- molecular weight
- polymer fraction
- comonomer content
- Prior art date
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
A multimodal polyethylene composition, in particular suitable for the preparation of films, but also textile articles, blow molded articles and injection molded articles is described. The polyethylene composition of the invention comprises at least three ethylene polymer fractions having distinct molecular weights or comonomer contents, said at least three ethylene polymer fractions comprising at least one first ethylene polymer fraction having a first molecular weight, a first comonomer content lower than a predetermined value and a first density; at least one second ethylene polymer fraction having a second molecular weight higher than said first molecular weight, a second comonomer content higher than said first comonomer content, and a second density; and at least one third ethylene polymer fraction having a third molecular weight higher than said first molecular weight, a third comonomer content lower than a predetermined value, and a third density; wherein said at least one first ethylene polymer fraction and said at least third ethylene polymer fraction are prepared by the use of a first and, respectively, third catalyst and said at least one second ethylene polymer fraction is prepared by the use of a second catalyst of the single site type. The films prepared from the composition of the invention have improved water vapor barrier properties. Furthermore, a mixed catalyst system comprising at least three catalyst components and a process particularly suitable to prepare the composition of the invention are described.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06026752 | 2006-12-22 | ||
| US92136607P | 2007-04-02 | 2007-04-02 | |
| PCT/EP2007/011113 WO2008077530A2 (en) | 2006-12-22 | 2007-12-18 | Multimodal polyethylene composition, mixed catalyst and process for preparing the composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE497992T1 true ATE497992T1 (en) | 2011-02-15 |
Family
ID=43568382
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT07856840T ATE497992T1 (en) | 2006-12-22 | 2007-12-18 | MULTIMODAL POLYETHYLENE COMPOSITION, MIXED CATALYSAOTR AND METHOD FOR PREPARING THE COMPOSITION |
Country Status (4)
| Country | Link |
|---|---|
| CN (1) | CN102083902B (en) |
| AT (1) | ATE497992T1 (en) |
| DE (1) | DE602007012474D1 (en) |
| TW (1) | TW200838913A (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2011822A1 (en) * | 2007-07-04 | 2009-01-07 | Borealis Technology Oy | Multimodal polyethylene co-polymer resin composition, a preparation process therefore and a polymeric product comprising the same |
| EP2592111A1 (en) * | 2011-11-11 | 2013-05-15 | Basell Poliolefine Italia S.r.l. | Polymer composition for bumpers and interiors and polyethylene-based resin precursor |
| JP5840743B2 (en) * | 2013-09-05 | 2016-01-06 | 旭化成ケミカルズ株式会社 | Polyethylene resin composition, microporous film and method for producing the same, and battery separator |
| EP3464457B2 (en) * | 2016-05-31 | 2025-04-09 | Borealis AG | Polymer composition and a process for production of the polymer composition |
| KR102073252B1 (en) | 2016-12-05 | 2020-02-04 | 주식회사 엘지화학 | Catalyst composition for polymerizing olefin copolymer and preparation method of olefin copolymer |
| EP3592780B1 (en) * | 2017-03-09 | 2025-07-23 | ExxonMobil Chemical Patents Inc. | Process for producing polyethylene |
| EP3732215B8 (en) | 2017-12-26 | 2022-04-27 | Dow Global Technologies LLC | Dual reactor solution process for the production of multimodal ethylene-based polymer |
| KR102647144B1 (en) * | 2017-12-26 | 2024-03-15 | 다우 글로벌 테크놀로지스 엘엘씨 | Composition comprising multimodal ethylene-based polymer and low-density polyethylene (LDPE) |
| ES2946586T3 (en) | 2017-12-26 | 2023-07-21 | Dow Global Technologies Llc | Procedure for the production of multimodal ethylene-based polymers |
| BR112020012842B1 (en) | 2017-12-26 | 2024-01-02 | Dow Global Technologies Llc | METHOD FOR PRODUCING A TRIMODAL POLYMER IN A SOLUTION POLYMERIZATION PROCESS |
| JP7278286B2 (en) | 2017-12-26 | 2023-05-19 | ダウ グローバル テクノロジーズ エルエルシー | Multimodal ethylene-based polymer composition with improved toughness |
| CN116355305B (en) * | 2021-12-28 | 2025-11-21 | 中国石油天然气股份有限公司 | Polyethylene base resin composition for film and preparation method thereof |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR940008983B1 (en) * | 1988-06-23 | 1994-09-28 | 도오소오 가부시끼가이샤 | Process for the preparation of polyethylene |
| WO2000032643A1 (en) * | 1998-12-02 | 2000-06-08 | Idemitsu Petrochemical Co., Ltd. | Catalyst for olefin polymerization and process for producing olefin polymer with the catalyst |
| US6218472B1 (en) * | 1999-09-24 | 2001-04-17 | Fina Research, S.A. | Production of multimodal polyethylene |
| DE10259491A1 (en) * | 2002-12-19 | 2004-07-01 | Basell Polyolefine Gmbh | Polyethylene moulding material for production of blow-moulded containers comprises low-mol. wt. ethylene homopolymer, high-mol. wt. copolymer of ethylene and 4-8C olefin, and ultrahigh-mol. wt. ethylene copolymer |
| DE10261064A1 (en) * | 2002-12-24 | 2004-07-08 | Basell Polyolefine Gmbh | Polyethylene molding composition with multimodal molecular weight distribution, used for making large blow-molded L-ring containers, contains low-molecular homopolyethylene and high- and ultrahigh-molecular copolyethylenes |
| DE10261065A1 (en) * | 2002-12-24 | 2004-07-08 | Basell Polyolefine Gmbh | Polyethylene molding composition with multimodal molecular weight distribution, used for making large blow-molded containers, contains low-molecular homo polyethylene and high- and ultrahigh-molecular co polyethylenes |
| DE10261066A1 (en) * | 2002-12-24 | 2004-07-08 | Basell Polyolefine Gmbh | Polyethylene molding composition with multimodal molecular weight distribution, used for making blow-molded cans, contains low-molecular homo polyethylene and high- and ultrahigh-molecular co polyethylenes |
| DE102005009895A1 (en) * | 2005-03-01 | 2006-09-07 | Basell Polyolefine Gmbh | Polyethylene molding compound for producing blown films with improved mechanical properties |
| DE102005009916A1 (en) * | 2005-03-01 | 2006-09-07 | Basell Polyolefine Gmbh | Polyethylene molding compound for producing blown films with improved mechanical properties |
| DE102005009896A1 (en) * | 2005-03-01 | 2006-09-07 | Basell Polyolefine Gmbh | Polyethylene molding compound for producing blown films with improved mechanical properties |
-
2007
- 2007-12-18 AT AT07856840T patent/ATE497992T1/en not_active IP Right Cessation
- 2007-12-18 CN CN200780051713.9A patent/CN102083902B/en not_active Expired - Fee Related
- 2007-12-18 DE DE602007012474T patent/DE602007012474D1/en active Active
- 2007-12-21 TW TW96149595A patent/TW200838913A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE602007012474D1 (en) | 2011-03-24 |
| CN102083902A (en) | 2011-06-01 |
| CN102083902B (en) | 2014-08-13 |
| TW200838913A (en) | 2008-10-01 |
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| Date | Code | Title | Description |
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| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |