ATE500876T1 - Durchführung und optimierung eines druckwechseladsorptionsverfahrens - Google Patents
Durchführung und optimierung eines druckwechseladsorptionsverfahrensInfo
- Publication number
- ATE500876T1 ATE500876T1 AT03014498T AT03014498T ATE500876T1 AT E500876 T1 ATE500876 T1 AT E500876T1 AT 03014498 T AT03014498 T AT 03014498T AT 03014498 T AT03014498 T AT 03014498T AT E500876 T1 ATE500876 T1 AT E500876T1
- Authority
- AT
- Austria
- Prior art keywords
- adsorbable component
- strongly adsorbable
- adsorption process
- adsorber vessel
- optimization
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 238000001179 sorption measurement Methods 0.000 title abstract 2
- 238000005457 optimization Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 2
- 239000003463 adsorbent Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/104—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/25—Coated, impregnated or composite adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/302—Dimensions
- B01D2253/304—Linear dimensions, e.g. particle shape, diameter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/12—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/16—Hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/102—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/502—Carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/80—Water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40007—Controlling pressure or temperature swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
- B01D2259/40062—Four
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/414—Further details for adsorption processes and devices using different types of adsorbents
- B01D2259/4141—Further details for adsorption processes and devices using different types of adsorbents within a single bed
- B01D2259/4145—Further details for adsorption processes and devices using different types of adsorbents within a single bed arranged in series
- B01D2259/4146—Contiguous multilayered adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/261—Drying gases or vapours by adsorption
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Of Gases By Adsorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Auxiliary Devices For And Details Of Packaging Control (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/192,360 US6605136B1 (en) | 2002-07-10 | 2002-07-10 | Pressure swing adsorption process operation and optimization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE500876T1 true ATE500876T1 (de) | 2011-03-15 |
Family
ID=27662667
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT03014498T ATE500876T1 (de) | 2002-07-10 | 2003-07-03 | Durchführung und optimierung eines druckwechseladsorptionsverfahrens |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6605136B1 (de) |
| EP (1) | EP1380336B2 (de) |
| JP (1) | JP4028447B2 (de) |
| CN (1) | CN1306988C (de) |
| AT (1) | ATE500876T1 (de) |
| DE (1) | DE60336287D1 (de) |
| ES (1) | ES2359687T5 (de) |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7954490B2 (en) | 2005-02-09 | 2011-06-07 | Vbox, Incorporated | Method of providing ambulatory oxygen |
| US7404846B2 (en) * | 2005-04-26 | 2008-07-29 | Air Products And Chemicals, Inc. | Adsorbents for rapid cycle pressure swing adsorption processes |
| US7390350B2 (en) * | 2005-04-26 | 2008-06-24 | Air Products And Chemicals, Inc. | Design and operation methods for pressure swing adsorption systems |
| US7651549B2 (en) | 2006-06-13 | 2010-01-26 | Air Products And Chemicals, Inc. | Pressure swing adsorption process with improved recovery of high-purity product |
| US20080028933A1 (en) * | 2006-08-07 | 2008-02-07 | Ross David A | Radial sieve module |
| TW200833603A (en) * | 2006-10-20 | 2008-08-16 | Sumitomo Seika Chemicals | Method and apparatus for separating hydrogen gas |
| US7828878B2 (en) * | 2006-12-15 | 2010-11-09 | Praxair Technology, Inc. | High frequency PSA process for gas separation |
| FR2913969B1 (fr) * | 2007-03-22 | 2010-02-19 | Air Liquide | Ecretement des pics d'impurete |
| US20090065007A1 (en) | 2007-09-06 | 2009-03-12 | Wilkinson William R | Oxygen concentrator apparatus and method |
| MY154251A (en) | 2007-11-12 | 2015-05-29 | Exxonmobil Upstream Res Co | Methods of generating and utility gas |
| AU2009241530C1 (en) * | 2008-04-30 | 2016-12-01 | Exxonmobil Upstream Research Company | Method and apparatus for removal of oil from utility gas stream |
| US9974918B2 (en) | 2010-04-07 | 2018-05-22 | Caire Inc. | Portable oxygen delivery device |
| MY162263A (en) | 2010-05-28 | 2017-05-31 | Exxonmobil Upstream Res Co | Integrated adsorber head and valve design and swing adsorption methods related thereto |
| US8603228B2 (en) | 2010-09-07 | 2013-12-10 | Inova Labs, Inc. | Power management systems and methods for use in an oxygen concentrator |
| US8616207B2 (en) | 2010-09-07 | 2013-12-31 | Inova Labs, Inc. | Oxygen concentrator heat management system and method |
| US8535414B2 (en) | 2010-09-30 | 2013-09-17 | Air Products And Chemicals, Inc. | Recovering of xenon by adsorption process |
| US8734570B2 (en) | 2010-10-13 | 2014-05-27 | Wintek Corporation | Pressure and vacuum swing adsorption separation processes |
| TWI495501B (zh) | 2010-11-15 | 2015-08-11 | Exxonmobil Upstream Res Co | 動力分餾器及用於氣體混合物之分餾的循環法 |
| WO2012118757A1 (en) | 2011-03-01 | 2012-09-07 | Exxonmobil Upstream Research Company | Apparatus and systems having a reciprocating valve head assembly and swing adsorption processes related thereto |
| CA2990793C (en) | 2011-03-01 | 2019-04-09 | Exxonmobil Upstream Research Company | Methods of removing contaminants from a hydrocarbon stream by swing adsorption and related apparatus and systems |
| CA2842928A1 (en) | 2011-03-01 | 2012-11-29 | Exxonmobil Upstream Research Company | Apparatus and systems having a rotary valve assembly and swing adsorption processes related thereto |
| EA201391249A1 (ru) | 2011-03-01 | 2014-02-28 | Эксонмобил Апстрим Рисерч Компани | Устройства и системы, имеющие узел поворотного клапана, и связанные с этим циклические адсорбционные процессы |
| MX336393B (es) | 2011-03-01 | 2016-01-18 | Exxonmobil Upstream Res Co | Aparatos y sistemas que tienen un contactor adsorbente encerrado y procesos de adsorcion oscilante relacionados con los mismos. |
| BR112013017837A2 (pt) | 2011-03-01 | 2016-10-11 | Exxonmobil Upstream Res Co | aparelho e sistemas tendo múltiplos leitos de adsorção oscilante de configuração compacta e métodos relacionados com eles |
| WO2012161826A1 (en) | 2011-03-01 | 2012-11-29 | Exxonmobil Upstream Research Company | Methods of removing contaminants from a hydrocarbon stream by swing adsorption and related apparatus and systems |
| US9034078B2 (en) | 2012-09-05 | 2015-05-19 | Exxonmobil Upstream Research Company | Apparatus and systems having an adsorbent contactor and swing adsorption processes related thereto |
| JP6336991B2 (ja) | 2012-10-12 | 2018-06-06 | イノヴァ ラボ,インコーポレイテッド | 酸素濃縮器二重化システムおよび方法 |
| AU2013328912B2 (en) | 2012-10-12 | 2017-10-12 | Inova Labs, Inc. | Method and systems for the delivery of oxygen enriched gas |
| WO2014059409A1 (en) | 2012-10-12 | 2014-04-17 | Inova Labs, Inc. | Oxygen concentrator systems and methods |
| US9440179B2 (en) | 2014-02-14 | 2016-09-13 | InovaLabs, LLC | Oxygen concentrator pump systems and methods |
| US9675925B2 (en) | 2014-07-25 | 2017-06-13 | Exxonmobil Upstream Research Company | Apparatus and system having a valve assembly and swing adsorption processes related thereto |
| SG11201702212VA (en) | 2014-11-11 | 2017-05-30 | Exxonmobil Upstream Res Co | High capacity structures and monoliths via paste imprinting |
| SG11201703809RA (en) | 2014-12-10 | 2017-06-29 | Exxonmobil Res & Eng Co | Adsorbent-incorporated polymer fibers in packed bed and fabric contactors, and methods and devices using same |
| RU2666849C1 (ru) | 2014-12-23 | 2018-09-12 | Эксонмобил Апстрим Рисерч Компани | Структурированный слой адсорбента, способы его получения и его применение |
| SG11201707065PA (en) | 2015-05-15 | 2017-11-29 | Exxonmobil Upstream Res Co | Apparatus and system for swing adsorption processes related thereto |
| AU2016265109B2 (en) | 2015-05-15 | 2019-03-07 | Exxonmobil Upstream Research Company | Apparatus and system for swing adsorption processes related thereto comprising mid-bed purge systems |
| US10220345B2 (en) | 2015-09-02 | 2019-03-05 | Exxonmobil Upstream Research Company | Apparatus and system for swing adsorption processes related thereto |
| US10124286B2 (en) | 2015-09-02 | 2018-11-13 | Exxonmobil Upstream Research Company | Apparatus and system for swing adsorption processes related thereto |
| CA3001336A1 (en) | 2015-10-27 | 2017-05-04 | Exxonmobil Upstream Research Company | Apparatus and system for swing adsorption processes related thereto having a plurality of valves |
| AU2016346798B2 (en) | 2015-10-27 | 2019-11-07 | Exxonmobil Upstream Research Company | Apparatus and system for swing adsorption processes related thereto having actively-controlled feed poppet valves and passively controlled product valves |
| CN108348836B (zh) | 2015-10-27 | 2021-01-26 | 埃克森美孚上游研究公司 | 具有多个阀门的变化吸附方法相关的设备和系统 |
| KR20180083911A (ko) | 2015-11-16 | 2018-07-23 | 엑손모빌 업스트림 리서치 캄파니 | 흡착재 및 이산화탄소의 흡착 방법 |
| EP3429727B1 (de) | 2016-03-18 | 2025-02-12 | ExxonMobil Technology and Engineering Company | Vorrichtung und verfahren für wechseladsorptionsprozesse |
| WO2017192660A1 (en) | 2016-05-03 | 2017-11-09 | Inova Labs, Inc. | Method and systems for the delivery of oxygen enriched gas |
| CA3025615A1 (en) | 2016-05-31 | 2017-12-07 | Exxonmobil Upstream Research Company | Apparatus and system for swing adsorption processes |
| BR112018074420A2 (pt) | 2016-05-31 | 2019-03-06 | Exxonmobil Upstream Research Company | aparelho e sistema para processos de adsorção por variação |
| US10434458B2 (en) | 2016-08-31 | 2019-10-08 | Exxonmobil Upstream Research Company | Apparatus and system for swing adsorption processes related thereto |
| CA3033235C (en) | 2016-09-01 | 2022-04-19 | Exxonmobil Upstream Research Company | Swing adsorption processes for removing water using 3a zeolite structures |
| US10328382B2 (en) | 2016-09-29 | 2019-06-25 | Exxonmobil Upstream Research Company | Apparatus and system for testing swing adsorption processes |
| US10710053B2 (en) | 2016-12-21 | 2020-07-14 | Exxonmobil Upstream Research Company | Self-supporting structures having active materials |
| US10549230B2 (en) | 2016-12-21 | 2020-02-04 | Exxonmobil Upstream Research Company | Self-supporting structures having active materials |
| CN109248541B (zh) * | 2017-07-12 | 2021-03-05 | 中国石油化工股份有限公司 | 氢气回收系统协同优化方法及系统 |
| US11571651B2 (en) | 2017-12-22 | 2023-02-07 | Praxair Technology, Inc. | Core-shell composite adsorbent for use in hydrogen and helium PSA processes |
| US11331620B2 (en) | 2018-01-24 | 2022-05-17 | Exxonmobil Upstream Research Company | Apparatus and system for swing adsorption processes |
| US11413567B2 (en) | 2018-02-28 | 2022-08-16 | Exxonmobil Upstream Research Company | Apparatus and system for swing adsorption processes |
| US10835856B2 (en) * | 2018-08-14 | 2020-11-17 | Air Products And Chemicals, Inc. | Carbon molecular sieve adsorbent |
| US11318410B2 (en) | 2018-12-21 | 2022-05-03 | Exxonmobil Upstream Research Company | Flow modulation systems, apparatus, and methods for cyclical swing adsorption |
| CN111375288B (zh) * | 2018-12-27 | 2022-04-05 | 中国石油化工股份有限公司 | 存储器、变压吸附装置的优化方法、装置及设备 |
| WO2020222932A1 (en) | 2019-04-30 | 2020-11-05 | Exxonmobil Upstream Research Company | Rapid cycle adsorbent bed |
| US11642486B2 (en) | 2019-05-17 | 2023-05-09 | Breathe Technologies, Inc. | Portable oxygen concentrator retrofit system and method |
| US11607519B2 (en) | 2019-05-22 | 2023-03-21 | Breathe Technologies, Inc. | O2 concentrator with sieve bed bypass and control method thereof |
| WO2021071755A1 (en) | 2019-10-07 | 2021-04-15 | Exxonmobil Upstream Research Company | Adsorption processes and systems utilizing step lift control of hydraulically actuated poppet valves |
| EP4045173A1 (de) | 2019-10-16 | 2022-08-24 | Exxonmobil Upstream Research Company (EMHC-N1-4A-607) | Verfahren zur entwässerung mit kationischem zeolith rho |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3430418A (en) * | 1967-08-09 | 1969-03-04 | Union Carbide Corp | Selective adsorption process |
| US4194891A (en) * | 1978-12-27 | 1980-03-25 | Union Carbide Corporation | Multiple bed rapid pressure swing adsorption for oxygen |
| US5240474A (en) * | 1991-01-23 | 1993-08-31 | Air Products And Chemicals, Inc. | Air separation by pressure swing adsorption with a high capacity carbon molecular sieve |
| US5226933A (en) * | 1992-03-31 | 1993-07-13 | Ohio State University | Pressure swing adsorption system to purify oxygen |
| FR2731918B1 (fr) * | 1995-03-24 | 1997-05-23 | Air Liquide | Procede de separation d'azote de composes moins polaires |
| FR2743507B1 (fr) | 1996-01-16 | 1998-03-06 | Air Liquide | Procede pour la separation de melanges d'oxygene et d'azote utilisant un adsorbant a porosite amelioree |
| FR2758739B1 (fr) * | 1997-01-24 | 1999-02-26 | Ceca Sa | Perfectionnement dans les procedes psa de purification de l'hydrogene |
| FR2765491B1 (fr) * | 1997-07-07 | 1999-08-06 | Air Liquide | Procede de separation d'un flux gazeux par un procede psa |
| FR2767717B1 (fr) | 1997-08-28 | 1999-10-01 | Air Liquide | Granulometrie et epaisseur de lit d'une unite psa |
| FR2771656B1 (fr) * | 1997-12-01 | 2000-01-07 | Air Liquide | Procede psa mettant en oeuvre un adsorbant a proprietes de capacite et/ou de selectivite heterogenes |
| KR100582914B1 (ko) | 1998-02-27 | 2006-05-24 | 프랙스에어 테크놀로지, 인코포레이티드 | 흡착제 물질을 사용한 vpsa 방법 |
| EP1085935B1 (de) * | 1998-02-27 | 2012-09-12 | Praxair Technology, Inc. | Beschleunigte gastrennung |
| US6500234B1 (en) * | 1998-02-27 | 2002-12-31 | Praxair Technology, Inc. | Rate-enhanced gas separation |
| CA2321550A1 (en) | 1998-02-27 | 1999-09-02 | Steven J. Pontonio | Advanced adsorbent for psa |
| US6156101A (en) | 1999-02-09 | 2000-12-05 | Air Products And Chemicals, Inc. | Single bed pressure swing adsorption process and system |
| FR2792220B1 (fr) * | 1999-04-19 | 2001-06-15 | Air Liquide | Procede psa mettant en oeuvre un adsorbant a resistance intrinseque favorable a la cinetique d'adsorption |
| FR2799991B1 (fr) * | 1999-10-26 | 2002-10-11 | Air Liquide | Procede de production d'hydrogene utilisant un adsorbant carbone a parametres de dubinin selectionnes |
| US6302943B1 (en) * | 1999-11-02 | 2001-10-16 | Air Products And Chemicals, Inc. | Optimum adsorbents for H2 recovery by pressure and vacuum swing absorption |
| CA2357276A1 (en) * | 2000-09-15 | 2002-03-15 | James Smolarek | Pressure swing adsorption using mixed adsorbent layer |
| US6468328B2 (en) * | 2000-12-18 | 2002-10-22 | Air Products And Chemicals, Inc. | Oxygen production by adsorption |
| US6790260B2 (en) * | 2000-12-20 | 2004-09-14 | Praxair Technology, Inc. | Enhanced rate PSA process |
| US6551384B1 (en) * | 2001-07-05 | 2003-04-22 | Praxair Technology, Inc. | Medical oxygen concentrator |
-
2002
- 2002-07-10 US US10/192,360 patent/US6605136B1/en not_active Expired - Lifetime
-
2003
- 2003-07-03 ES ES03014498.4T patent/ES2359687T5/es not_active Expired - Lifetime
- 2003-07-03 AT AT03014498T patent/ATE500876T1/de not_active IP Right Cessation
- 2003-07-03 EP EP03014498.4A patent/EP1380336B2/de not_active Expired - Lifetime
- 2003-07-03 DE DE60336287T patent/DE60336287D1/de not_active Expired - Lifetime
- 2003-07-09 JP JP2003194365A patent/JP4028447B2/ja not_active Expired - Lifetime
- 2003-07-10 CN CNB031476201A patent/CN1306988C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE60336287D1 (de) | 2011-04-21 |
| ES2359687T5 (es) | 2014-11-11 |
| US6605136B1 (en) | 2003-08-12 |
| EP1380336A1 (de) | 2004-01-14 |
| EP1380336B2 (de) | 2014-10-01 |
| CN1306988C (zh) | 2007-03-28 |
| JP2004058056A (ja) | 2004-02-26 |
| CN1478584A (zh) | 2004-03-03 |
| ES2359687T3 (es) | 2011-05-25 |
| EP1380336B1 (de) | 2011-03-09 |
| JP4028447B2 (ja) | 2007-12-26 |
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