ATE504831T1 - Verfahren und vorrichtung für die messung von schwefelwasserstoff und thiolen in flüssigkeiten - Google Patents
Verfahren und vorrichtung für die messung von schwefelwasserstoff und thiolen in flüssigkeitenInfo
- Publication number
- ATE504831T1 ATE504831T1 AT03727719T AT03727719T ATE504831T1 AT E504831 T1 ATE504831 T1 AT E504831T1 AT 03727719 T AT03727719 T AT 03727719T AT 03727719 T AT03727719 T AT 03727719T AT E504831 T1 ATE504831 T1 AT E504831T1
- Authority
- AT
- Austria
- Prior art keywords
- thiols
- electrode
- hydrogen sulphide
- measuring
- flow path
- Prior art date
Links
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title abstract 4
- 150000003573 thiols Chemical class 0.000 title abstract 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 title 1
- 239000007788 liquid Substances 0.000 title 1
- 239000012530 fluid Substances 0.000 abstract 5
- 239000012528 membrane Substances 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000001419 dependent effect Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000005259 measurement Methods 0.000 abstract 1
- 238000006479 redox reaction Methods 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/404—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors
- G01N27/4045—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors for gases other than oxygen
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B47/00—Survey of boreholes or wells
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/2835—Specific substances contained in the oils or fuels
- G01N33/287—Sulfur content
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/18—Sulfur containing
- Y10T436/182—Organic or sulfhydryl containing [e.g., mercaptan, hydrogen, sulfide, etc.]
- Y10T436/184—Only hydrogen sulfide
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- General Physics & Mathematics (AREA)
- Mining & Mineral Resources (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Immunology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Pathology (AREA)
- Medicinal Chemistry (AREA)
- Molecular Biology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Fluid Mechanics (AREA)
- Environmental & Geological Engineering (AREA)
- Geophysics (AREA)
- Food Science & Technology (AREA)
- Electrochemistry (AREA)
- Sampling And Sample Adjustment (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Measuring Fluid Pressure (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0300812A GB2397651B (en) | 2003-01-15 | 2003-01-15 | Methods and apparatus for the measurement of hydrogen sulphide and thiols in fluids |
| PCT/GB2003/002345 WO2004063743A1 (en) | 2003-01-15 | 2003-05-28 | Methods and apparatus for the measurement of hydrogen sulphide and thiols in fluids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE504831T1 true ATE504831T1 (de) | 2011-04-15 |
Family
ID=9951127
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT03727719T ATE504831T1 (de) | 2003-01-15 | 2003-05-28 | Verfahren und vorrichtung für die messung von schwefelwasserstoff und thiolen in flüssigkeiten |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US7758734B2 (de) |
| EP (1) | EP1583962B1 (de) |
| AT (1) | ATE504831T1 (de) |
| AU (1) | AU2003234049A1 (de) |
| CA (1) | CA2512497C (de) |
| DE (1) | DE60336682D1 (de) |
| EA (1) | EA009570B1 (de) |
| GB (1) | GB2397651B (de) |
| MX (1) | MXPA05007540A (de) |
| NO (1) | NO338035B1 (de) |
| WO (1) | WO2004063743A1 (de) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2397651B (en) | 2003-01-15 | 2005-08-24 | Schlumberger Holdings | Methods and apparatus for the measurement of hydrogen sulphide and thiols in fluids |
| GB2404738B (en) | 2003-08-04 | 2005-09-28 | Schlumberger Holdings | System and method for sensing using diamond based microelectrodes |
| US8758593B2 (en) | 2004-01-08 | 2014-06-24 | Schlumberger Technology Corporation | Electrochemical sensor |
| US7664607B2 (en) | 2005-10-04 | 2010-02-16 | Teledyne Technologies Incorporated | Pre-calibrated gas sensor |
| US8907384B2 (en) * | 2006-01-26 | 2014-12-09 | Nanoselect, Inc. | CNT-based sensors: devices, processes and uses thereof |
| US20090278556A1 (en) * | 2006-01-26 | 2009-11-12 | Nanoselect, Inc. | Carbon Nanostructure Electrode Based Sensors: Devices, Processes and Uses Thereof |
| US20080135237A1 (en) * | 2006-06-01 | 2008-06-12 | Schlumberger Technology Corporation | Monitoring injected nonhydrocarbon and nonaqueous fluids through downhole fluid analysis |
| GB2444276B (en) | 2006-12-02 | 2009-06-03 | Schlumberger Holdings | System and method for qualitative and quantitative analysis of gaseous components of multiphase hydrocarbon mixtures |
| DE602007011061D1 (de) | 2007-08-23 | 2011-01-20 | Schlumberger Technology Bv | Vorrichtung und Verfahren zur Analyse leichter chemischer Verbindungen |
| US7520160B1 (en) | 2007-10-04 | 2009-04-21 | Schlumberger Technology Corporation | Electrochemical sensor |
| GB2476237B (en) * | 2009-12-15 | 2012-01-11 | Schlumberger Holdings | Calibration of electrochemical sensor |
| DE102010016103B4 (de) * | 2010-03-23 | 2012-01-26 | Andreas Hettich Gmbh & Co. Kg | Messvorrichtung mit Resonator |
| US8596354B2 (en) | 2010-04-02 | 2013-12-03 | Schlumberger Technology Corporation | Detection of tracers used in hydrocarbon wells |
| CN102822447B (zh) | 2010-05-21 | 2016-04-13 | 哈里伯顿能源服务公司 | 探测井下环境中二氧化碳和硫化氢的方法和井下工具装置 |
| GB201009136D0 (en) * | 2010-06-01 | 2010-07-14 | Isis Innovation | Electrochemical method |
| GB2493718A (en) | 2011-08-15 | 2013-02-20 | Schlumberger Holdings | Electrochemical sensor with surfactants |
| US9546959B2 (en) | 2011-09-16 | 2017-01-17 | Schlumberger Technology Corporation | Method and system for measurement of reservoir fluid properties |
| GB2497788B (en) | 2011-12-21 | 2020-12-30 | Schlumberger Holdings | Derivatization of carbon |
| GB2497791B (en) | 2011-12-21 | 2021-01-20 | Schlumberger Holdings | Derivatization of carbon |
| GB2497795B (en) | 2011-12-21 | 2020-04-08 | Schlumberger Holdings | Derivatization of carbon |
| GB2497972B (en) * | 2011-12-23 | 2016-03-16 | Schlumberger Holdings | Electrochemical sensors |
| US9212546B2 (en) | 2012-04-11 | 2015-12-15 | Baker Hughes Incorporated | Apparatuses and methods for obtaining at-bit measurements for an earth-boring drilling tool |
| US9605487B2 (en) | 2012-04-11 | 2017-03-28 | Baker Hughes Incorporated | Methods for forming instrumented cutting elements of an earth-boring drilling tool |
| US9394782B2 (en) | 2012-04-11 | 2016-07-19 | Baker Hughes Incorporated | Apparatuses and methods for at-bit resistivity measurements for an earth-boring drilling tool |
| GB2507042B (en) | 2012-10-16 | 2018-07-11 | Schlumberger Holdings | Electrochemical hydrogen sensor |
| HUE036145T2 (hu) * | 2013-03-28 | 2018-06-28 | Univ Louisiana State | Hidrogén-szulfid detektáló készülék |
| CN103291290B (zh) * | 2013-06-03 | 2016-04-06 | 西南石油大学 | 一种泥浆气体井下检测方法 |
| US10605068B2 (en) * | 2013-12-17 | 2020-03-31 | Schlumberger Technology Corporation | Downhole electrochemical fluid sensor and method of using same |
| WO2016144774A1 (en) | 2015-03-06 | 2016-09-15 | Shell Oil Company | Methods of measuring hydrogen sulfide concentrations in reservoir fluids |
| US10330587B2 (en) * | 2015-08-31 | 2019-06-25 | Exxonmobil Upstream Research Company | Smart electrochemical sensor for pipeline corrosion measurement |
| US9562430B1 (en) | 2015-10-05 | 2017-02-07 | Baker Hughes Incorporated | Chemiresistive sensors for downhole tools |
| US10025000B2 (en) | 2016-01-21 | 2018-07-17 | Baker Hughes Incorporated | Optical sensors for downhole tools and related systems and methods |
| US10120097B2 (en) | 2016-04-05 | 2018-11-06 | Baker Hughes Incorporated | Methods and apparatus for measuring hydrogen sulfide in downhole fluids |
| WO2018071036A1 (en) * | 2016-10-14 | 2018-04-19 | Halliburton Energy Services, Inc. | In situ treatment of chemical sensors |
| US10584581B2 (en) | 2018-07-03 | 2020-03-10 | Baker Hughes, A Ge Company, Llc | Apparatuses and method for attaching an instrumented cutting element to an earth-boring drilling tool |
| US11180989B2 (en) | 2018-07-03 | 2021-11-23 | Baker Hughes Holdings Llc | Apparatuses and methods for forming an instrumented cutting for an earth-boring drilling tool |
| EP4090957A1 (de) * | 2020-01-13 | 2022-11-23 | Beckman Coulter, Inc. | Ionenselektive festkörperelektroden |
| JP7573620B2 (ja) | 2020-01-13 | 2024-10-25 | ベックマン コールター, インコーポレイテッド | 固体イオン選択電極 |
| CN114717533B (zh) * | 2022-02-25 | 2023-03-10 | 中国地质大学(北京) | 一种利用仿生结构制备传感器电极保护薄膜的方法和应用 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE275924C (de) | ||||
| US3780575A (en) | 1972-12-08 | 1973-12-25 | Schlumberger Technology Corp | Formation-testing tool for obtaining multiple measurements and fluid samples |
| US3988233A (en) * | 1973-01-05 | 1976-10-26 | Bbc Brown Boveri & Company Limited | Apparatus for measuring dissolved gases in a fluid medium |
| US3915831A (en) * | 1973-04-09 | 1975-10-28 | Orion Research | Hydrogen sulfide sensing cell |
| US3859851A (en) | 1973-12-12 | 1975-01-14 | Schlumberger Technology Corp | Methods and apparatus for testing earth formations |
| US4490234A (en) * | 1982-02-22 | 1984-12-25 | Beckman Instruments, Inc. | Method for measuring ionic concentration utilizing an ion-sensing electrode |
| JPS6028826A (ja) * | 1983-07-26 | 1985-02-14 | Hiroshi Suzuki | かご型ゼオライト薄膜表層を有する複合膜及びその製造法 |
| US4994671A (en) | 1987-12-23 | 1991-02-19 | Schlumberger Technology Corporation | Apparatus and method for analyzing the composition of formation fluids |
| DD275924A1 (de) * | 1988-10-03 | 1990-02-07 | Junkalor Dessau | Amperometrische messzelle zur bestimmung von schwefelwasserstoff in gasen und fluessigkeiten |
| DE4319573A1 (de) * | 1993-06-14 | 1994-12-15 | Mannesmann Ag | Elektrochemischer Gasdetektor |
| US5480808A (en) * | 1994-01-31 | 1996-01-02 | The Unversity Of Dayton | Voltammetric method for measuring peroxide concentration in hydrocarbon fuels |
| GB2292805B (en) * | 1994-08-26 | 1998-09-09 | Mil Ram Techn Inc | Method and apparatus for the detection of toxic gases |
| US5499528A (en) * | 1994-09-26 | 1996-03-19 | W. L. Gore & Associates, Inc. | Apparatus for measuring hot gas content |
| US5667558A (en) * | 1995-07-13 | 1997-09-16 | Adapco, Inc. | Apparatus and associated method for reducing an undesired constituent of gas associated with wastewater |
| GB2359631B (en) * | 2000-02-26 | 2002-03-06 | Schlumberger Holdings | Hydrogen sulphide detection method and apparatus |
| US6629444B2 (en) * | 2001-08-08 | 2003-10-07 | Industrial Scientific Corporation | Method and apparatus for diagnosing gas sensors |
| DE10144862B4 (de) * | 2001-09-12 | 2006-06-29 | Drägerwerk AG | Elektrochemischer Gassensor mit Diamantelektrode |
| GB2391314B (en) | 2002-07-25 | 2005-08-10 | Schlumberger Holdings | Methods and apparatus for the measurement of hydrogen sulphide and thiols in fluids |
| GB2397651B (en) | 2003-01-15 | 2005-08-24 | Schlumberger Holdings | Methods and apparatus for the measurement of hydrogen sulphide and thiols in fluids |
| GB2404738B (en) * | 2003-08-04 | 2005-09-28 | Schlumberger Holdings | System and method for sensing using diamond based microelectrodes |
| US7520160B1 (en) * | 2007-10-04 | 2009-04-21 | Schlumberger Technology Corporation | Electrochemical sensor |
-
2003
- 2003-01-15 GB GB0300812A patent/GB2397651B/en not_active Expired - Fee Related
- 2003-05-28 MX MXPA05007540A patent/MXPA05007540A/es active IP Right Grant
- 2003-05-28 EA EA200501127A patent/EA009570B1/ru not_active IP Right Cessation
- 2003-05-28 CA CA2512497A patent/CA2512497C/en not_active Expired - Fee Related
- 2003-05-28 AT AT03727719T patent/ATE504831T1/de not_active IP Right Cessation
- 2003-05-28 DE DE60336682T patent/DE60336682D1/de not_active Expired - Lifetime
- 2003-05-28 EP EP03727719A patent/EP1583962B1/de not_active Expired - Lifetime
- 2003-05-28 AU AU2003234049A patent/AU2003234049A1/en not_active Abandoned
- 2003-05-28 US US10/541,568 patent/US7758734B2/en active Active
- 2003-05-28 WO PCT/GB2003/002345 patent/WO2004063743A1/en not_active Ceased
-
2005
- 2005-07-06 NO NO20053314A patent/NO338035B1/no not_active IP Right Cessation
-
2010
- 2010-06-09 US US12/797,148 patent/US8268146B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA2512497A1 (en) | 2004-07-29 |
| US20100243480A1 (en) | 2010-09-30 |
| US8268146B2 (en) | 2012-09-18 |
| MXPA05007540A (es) | 2005-09-21 |
| WO2004063743A1 (en) | 2004-07-29 |
| NO20053314D0 (no) | 2005-07-06 |
| DE60336682D1 (de) | 2011-05-19 |
| GB2397651A (en) | 2004-07-28 |
| GB0300812D0 (en) | 2003-02-12 |
| EA200501127A1 (ru) | 2006-02-24 |
| EP1583962B1 (de) | 2011-04-06 |
| NO338035B1 (no) | 2016-07-25 |
| AU2003234049A1 (en) | 2004-08-10 |
| US7758734B2 (en) | 2010-07-20 |
| AU2003234049A8 (en) | 2004-08-10 |
| NO20053314L (no) | 2005-10-14 |
| US20060243603A1 (en) | 2006-11-02 |
| EP1583962A1 (de) | 2005-10-12 |
| EA009570B1 (ru) | 2008-02-28 |
| GB2397651B (en) | 2005-08-24 |
| CA2512497C (en) | 2012-11-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |