ATE507187T1 - Verfahren und vorrichtung zur abscheidung von nanoröhren oder stickstoffdotierten kohlenstoffnanoröhren mittels pyrolyse - Google Patents

Verfahren und vorrichtung zur abscheidung von nanoröhren oder stickstoffdotierten kohlenstoffnanoröhren mittels pyrolyse

Info

Publication number
ATE507187T1
ATE507187T1 AT03760783T AT03760783T ATE507187T1 AT E507187 T1 ATE507187 T1 AT E507187T1 AT 03760783 T AT03760783 T AT 03760783T AT 03760783 T AT03760783 T AT 03760783T AT E507187 T1 ATE507187 T1 AT E507187T1
Authority
AT
Austria
Prior art keywords
nitrogen
liquid
carbon nanotubes
carbon
atoms
Prior art date
Application number
AT03760783T
Other languages
English (en)
Inventor
Martine Mayne
Dominique Porterat
Frederic Schuster
Original Assignee
Commissariat Energie Atomique
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat Energie Atomique filed Critical Commissariat Energie Atomique
Application granted granted Critical
Publication of ATE507187T1 publication Critical patent/ATE507187T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/158Carbon nanotubes
    • C01B32/16Preparation
    • C01B32/162Preparation characterised by catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00Structure or properties of carbon nanotubes
    • C01B2202/08Aligned nanotubes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00Structure or properties of carbon nanotubes
    • C01B2202/20Nanotubes characterized by their properties
    • C01B2202/34Length

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Materials Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Catalysts (AREA)
  • Inorganic Fibers (AREA)
AT03760783T 2002-06-24 2003-06-24 Verfahren und vorrichtung zur abscheidung von nanoröhren oder stickstoffdotierten kohlenstoffnanoröhren mittels pyrolyse ATE507187T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0207785A FR2841233B1 (fr) 2002-06-24 2002-06-24 Procede et dispositif de depot par pyrolyse de nanotubes de carbone
PCT/FR2003/001944 WO2004000727A2 (fr) 2002-06-24 2003-06-24 Procede et dispositif de depot par pyrolyse de nanotubes de carbone ou de nanotubes de carbone dopes a l'azote

Publications (1)

Publication Number Publication Date
ATE507187T1 true ATE507187T1 (de) 2011-05-15

Family

ID=29719989

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03760783T ATE507187T1 (de) 2002-06-24 2003-06-24 Verfahren und vorrichtung zur abscheidung von nanoröhren oder stickstoffdotierten kohlenstoffnanoröhren mittels pyrolyse

Country Status (10)

Country Link
US (1) US7879300B2 (de)
EP (1) EP1515911B1 (de)
JP (1) JP4781674B2 (de)
CN (1) CN1678523A (de)
AT (1) ATE507187T1 (de)
AU (1) AU2003253078A1 (de)
DE (1) DE60336899D1 (de)
ES (1) ES2365705T3 (de)
FR (1) FR2841233B1 (de)
WO (1) WO2004000727A2 (de)

Families Citing this family (84)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7160531B1 (en) * 2001-05-08 2007-01-09 University Of Kentucky Research Foundation Process for the continuous production of aligned carbon nanotubes
FR2858465A1 (fr) * 2003-07-29 2005-02-04 Commissariat Energie Atomique Structures poreuses utilisables en tant que plaques bipolaires et procedes de preparation de telles structures poreuses
CN101023027B (zh) * 2004-09-22 2012-07-18 昭和电工株式会社 气相法碳纳米管的制造方法
WO2006067959A1 (ja) * 2004-12-21 2006-06-29 Shinshu University 医療機器
US8133465B2 (en) * 2005-09-12 2012-03-13 University Of Dayton Polymer-carbon nanotube composite for use as a sensor
GR1005374B (el) * 2006-01-09 2006-12-14 Μιχαλης Ιωαννη Σολωμακακης Κουνουποβελονα
JP4871177B2 (ja) * 2006-03-28 2012-02-08 コリア インスティチュート オブ エナジー リサーチ 超音波振動方式を用いたカーボンナノチューブ合成方法とその装置
US8207658B2 (en) 2006-08-25 2012-06-26 Rensselaer Polytechnic Institute Carbon nanotube growth on metallic substrate using vapor phase catalyst delivery
US8158217B2 (en) 2007-01-03 2012-04-17 Applied Nanostructured Solutions, Llc CNT-infused fiber and method therefor
US8951631B2 (en) 2007-01-03 2015-02-10 Applied Nanostructured Solutions, Llc CNT-infused metal fiber materials and process therefor
US8951632B2 (en) 2007-01-03 2015-02-10 Applied Nanostructured Solutions, Llc CNT-infused carbon fiber materials and process therefor
US9005755B2 (en) 2007-01-03 2015-04-14 Applied Nanostructured Solutions, Llc CNS-infused carbon nanomaterials and process therefor
US8628746B2 (en) * 2007-04-12 2014-01-14 Raytheon Company System and method for dispersing nanostructures in a composite material
CN101116817B (zh) * 2007-05-10 2011-04-06 南京大学 碳氮纳米管负载铂钌纳米粒子电极催化剂的制备方法
US8636972B1 (en) 2007-07-31 2014-01-28 Raytheon Company Making a nanomaterial composite
US8491292B1 (en) 2007-07-31 2013-07-23 Raytheon Company Aligning nanomaterial in a nanomaterial composite
FR2927619B1 (fr) * 2008-02-20 2011-01-14 Commissariat Energie Atomique Croissance de nanotubes de carbone sur substrats de carbone ou metalliques.
CN101671442A (zh) * 2008-09-12 2010-03-17 清华大学 碳纳米管阵列复合材料的制备方法
FR2936604B1 (fr) 2008-09-29 2010-11-05 Commissariat Energie Atomique Capteurs chimiques a base de nanotubes de carbone, procede de preparation et utilisations
BRPI0806065B1 (pt) * 2008-10-16 2021-05-18 Petroleo Brasileiro S. A. - Petrobras método para a produção de nanoesferas de carbono
KR101265847B1 (ko) * 2008-12-22 2013-05-20 도요타지도샤가부시키가이샤 복합형 탄소 및 그 제조방법
JP5577356B2 (ja) 2009-02-17 2014-08-20 アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニー カーボン・ナノチューブを繊維上に含んで構成された複合材料
CN102333906B (zh) 2009-02-27 2015-03-11 应用纳米结构方案公司 使用气体预热法的低温cnt生长
US20100227134A1 (en) 2009-03-03 2010-09-09 Lockheed Martin Corporation Method for the prevention of nanoparticle agglomeration at high temperatures
US9111658B2 (en) 2009-04-24 2015-08-18 Applied Nanostructured Solutions, Llc CNS-shielded wires
AU2010259173B2 (en) 2009-04-24 2015-03-19 Applied Nanostructured Solutions Llc CNT-based signature control material
BRPI1014711A2 (pt) 2009-04-27 2016-04-12 Applied Nanostrctured Solutions Llc aquecimento de resistência com base em cnt para descongelar estruturas de compósito
WO2011017200A1 (en) 2009-08-03 2011-02-10 Lockheed Martin Corporation Incorporation of nanoparticles in composite fibers
FR2952631B1 (fr) * 2009-11-13 2012-01-13 Commissariat Energie Atomique Procede d'elaboration de nanotubes de carbone sur un substrat
EP2504164A4 (de) 2009-11-23 2013-07-17 Applied Nanostructured Sols Keramikverbundmaterialien mit kohlenstoffnanoröhreninfundierten fasermaterialien sowie herstellungsverfahren dafür
CN102596715A (zh) 2009-11-23 2012-07-18 应用纳米结构方案公司 Cnt特制复合材料地面基结构
KR20120104600A (ko) 2009-12-14 2012-09-21 어플라이드 나노스트럭처드 솔루션스, 엘엘씨. 탄소 나노튜브 주입된 섬유 물질을 포함하는 방염 복합재 물질 및 물품
US9167736B2 (en) 2010-01-15 2015-10-20 Applied Nanostructured Solutions, Llc CNT-infused fiber as a self shielding wire for enhanced power transmission line
AU2011256789A1 (en) 2010-02-02 2012-07-12 Applied Nanostructured Solutions, Llc Fiber containing parallel-aligned carbon nanotubes
KR101818640B1 (ko) 2010-03-02 2018-01-15 어플라이드 나노스트럭처드 솔루션스, 엘엘씨. 카본 나노튜브 주입된 섬유를 포함하는 전기 장치 및 그의 제조 방법
CN101817522A (zh) * 2010-06-04 2010-09-01 温州大学 以可溶性金属盐为催化剂制备碳纳米管的方法
US8780526B2 (en) 2010-06-15 2014-07-15 Applied Nanostructured Solutions, Llc Electrical devices containing carbon nanotube-infused fibers and methods for production thereof
JP5390483B2 (ja) * 2010-07-16 2014-01-15 日本電信電話株式会社 ナノチューブの形成方法
US9017854B2 (en) 2010-08-30 2015-04-28 Applied Nanostructured Solutions, Llc Structural energy storage assemblies and methods for production thereof
BR112013005802A2 (pt) 2010-09-14 2016-05-10 Applied Nanostructured Sols substratos de vidro com nanotubos de carbono crescidos sobre os mesmos e métodos para sua produção
AU2011305809A1 (en) 2010-09-22 2013-02-28 Applied Nanostructured Solutions, Llc Carbon fiber substrates having carbon nanotubes grown thereon and processes for production thereof
EP2629595A2 (de) 2010-09-23 2013-08-21 Applied NanoStructured Solutions, LLC CNT-infundierte Faser als selbstabschirmendes Kabel für eine Übertragungsleitung mit erhöhter Leistung
CN102060284A (zh) * 2010-10-29 2011-05-18 华南理工大学 一种氮磷共掺杂多壁碳纳米管的制备方法
EP2506276A1 (de) * 2011-03-31 2012-10-03 Bayer MaterialScience AG Farbstoffsensibilisierte Solarzelle mit stickstoffdotierten Kohlenstoffnanoröhren
KR101236232B1 (ko) 2011-04-21 2013-02-22 한국과학기술연구원 에어로졸 공정기술을 이용한 금속 나노입자와 탄소나노튜브의 복합 나노구조체 제조장치 및 방법
CN102409433B (zh) * 2011-08-01 2013-04-17 复旦大学 一种基于碳纳米管的核壳结构复合纤维及其制备方法和应用
JP5839571B2 (ja) * 2012-02-27 2016-01-06 積水ナノコートテクノロジー株式会社 窒素原子がドープされたグラフェンフィルムを製造する方法
US9085464B2 (en) 2012-03-07 2015-07-21 Applied Nanostructured Solutions, Llc Resistance measurement system and method of using the same
US9475700B2 (en) * 2012-03-08 2016-10-25 Asahi Carbon Co., Ltd. Method for manufacturing carbon fiber, and carbon fiber
US8470285B1 (en) * 2012-04-04 2013-06-25 The United States Of America As Represented By The Secretary Of The Navy Method of liquid phase synthesis of carbon nanotubes in air
US9446951B2 (en) * 2012-04-19 2016-09-20 Alimorad Rashidi Highly-ordered nanostructure arrays and methods of preparation thereof
KR101389514B1 (ko) * 2012-05-09 2014-04-25 (주) 디에이치홀딩스 구조규칙성 중형다공성 탄소-탄소 나노튜브 나노 복합체 및 그 제조방법
WO2014039509A2 (en) 2012-09-04 2014-03-13 Ocv Intellectual Capital, Llc Dispersion of carbon enhanced reinforcement fibers in aqueous or non-aqueous media
US9595436B2 (en) 2012-10-25 2017-03-14 Applied Materials, Inc. Growing graphene on substrates
CN104016328B (zh) * 2013-02-28 2015-12-23 中国科学院大连化学物理研究所 一种含氮碳纳米管的制备方法
CN103466597B (zh) * 2013-09-02 2016-01-13 中国科学院金属研究所 氮在碳网格上的少量掺杂生长金属性单壁碳纳米管的方法
KR101568247B1 (ko) 2014-06-02 2015-11-12 한국에너지기술연구원 질소 도핑된 탄소 표면을 갖는 금속-탄소 하이브리드 복합체 및 그 제조방법
FI20145530A7 (fi) * 2014-06-09 2015-12-10 Canatu Oy Katalyyttihiukkanen ja menetelmä sen valmistamiseksi
CN104069885A (zh) * 2014-06-26 2014-10-01 上海第二工业大学 一种Fe-CNx纳米复合催化剂、制备方法及其应用
KR101598902B1 (ko) 2014-07-04 2016-03-02 재단법인대구경북과학기술원 전기방사를 이용한 질소가 도핑된 탄소 나노구조체의 제조방법 및 이를 통해 제조된 질소가 도핑된 탄소 나노구조체
US9957168B2 (en) 2014-07-09 2018-05-01 Honda Motor Co., Ltd. Method for synthesis of ruthenium nanoparticles with face-centered cubic and hexagonal close-packed structures
US10195668B2 (en) * 2014-07-09 2019-02-05 Honda Motor Co., Ltd. Method for continuous and controllable production of single walled carbon nanotubes
RU2625978C1 (ru) * 2016-01-12 2017-07-20 Акционерное общество "Уральский научно-исследовательский институт композиционных материалов" Способ получения углеродных нанотрубок методом газофазного химического осаждения
CN105776173B (zh) * 2016-02-04 2018-07-24 北京控制工程研究所 一种在基片上生长碳纳米管阵列的方法
US9670103B1 (en) * 2016-03-22 2017-06-06 King Fahd University Of Petroleum And Minerals Reactor and method for synthesizing metal oxide impregnated carbon nanotubes
CN108625159A (zh) * 2017-03-24 2018-10-09 山东大学 用于碳纤维布表面均匀生长碳纳米管的装置及方法
FR3068029B1 (fr) 2017-06-26 2022-12-16 Nawatechnologies Procede de fabrication de cables en nanotubes de carbone alignes
FR3068028B1 (fr) 2017-06-26 2021-06-11 Nawatechnologies Procede de fabrication de nanotubes de carbone fixes sur un substrat
FR3070381A1 (fr) 2017-08-29 2019-03-01 Nawatechnologies Procede de fabrication de nanotubes de carbone verticalement alignes, et supercondensateurs electrochimiques utilisant ces nanotubes comme electrodes
CN108313999A (zh) * 2018-01-31 2018-07-24 华南理工大学 一种氮、硫、磷杂原子掺杂碳材料的制备方法
CN108745395A (zh) * 2018-04-16 2018-11-06 浙江农林大学暨阳学院 一种掺氮纳米碳管材料的制备方法及催化应用
KR102543071B1 (ko) * 2018-11-13 2023-06-14 주식회사 엘지에너지솔루션 음극 활물질 및 이의 제조 방법
CA3124118A1 (en) * 2018-12-21 2020-06-25 Bio Industrial Technology, Incorporated In situ production and functionalization of carbon materials via gas-liquid mass transfer and uses thereof
CN111170402B (zh) * 2020-02-12 2021-07-02 东华大学 利用木质素基碳纳米管去除水体中全氟辛酸的方法
CN113249750B (zh) * 2020-05-06 2022-04-12 中国建材检验认证集团股份有限公司 一种利用不同曲率的氮掺杂碳纳米管电催化还原co2的方法
CN113003911B (zh) * 2021-03-11 2022-02-22 西安交通大学 一种低温碳化辅助两段式热解的污泥热化学处置系统及方法
CN113149115B (zh) * 2021-04-25 2022-09-30 中国海洋大学 一种光热海水淡化用的多级异质结构膜及制备方法
CN113941382B (zh) * 2021-09-13 2022-10-11 杭州电子科技大学 一种利用碳纤维束抓取与释放液滴的方法与装置
CN113788470A (zh) * 2021-09-29 2021-12-14 中北大学 一种杯叠结构掺氮碳纳米管的制备方法
CN114455572B (zh) * 2022-01-28 2024-05-03 中识物联网科技(东莞)有限公司 一种以废弃液态油类为碳源制备高长径比碳纳米管的方法
CN114887643B (zh) * 2022-05-13 2023-12-05 佛山仙湖实验室 一种氨热解制氢催化剂及其制备方法
EP4345062A1 (de) 2022-09-28 2024-04-03 Nawatechnologies Katalytische elektrode für brennstoffzelle oder elektrolysezelle und verfahren zur herstellung dieser elektrode
CN118324123B (zh) * 2024-05-11 2026-03-31 大连理工大学 一种氮掺杂碳微米管及其制备方法
CN119524735B (zh) * 2024-12-12 2025-06-24 江西铜业技术研究院有限公司 催化单壁纳米管生成的反应装置及其应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2707671B1 (fr) * 1993-07-12 1995-09-15 Centre Nat Rech Scient Procédé et dispositif d'introduction de précurseurs dans une enceinte de dépôt chimique en phase vapeur.
IT1276257B1 (it) * 1994-10-25 1997-10-28 Giuseppe Raoul Piccinini Carburatore miscelatore con condotto principale o diffusore venturi intercambiabile con sezione variabile per la strozzatura parziale o
CN1095065C (zh) * 1994-12-27 2002-11-27 Lg电子株式会社 热交换器的结构
AUPP976499A0 (en) 1999-04-16 1999-05-06 Commonwealth Scientific And Industrial Research Organisation Multilayer carbon nanotube films
US6495116B1 (en) * 2000-04-10 2002-12-17 Lockheed Martin Corporation Net shape manufacturing using carbon nanotubes
JP2001348215A (ja) * 2000-05-31 2001-12-18 Fuji Xerox Co Ltd カーボンナノチューブおよび/またはフラーレンの製造方法、並びにその製造装置
US6471457B2 (en) 2001-02-23 2002-10-29 Shimano, Inc. Screw retention device having a hook
JP4724929B2 (ja) * 2001-03-01 2011-07-13 ソニー株式会社 炭素質材料の製造方法及び製造装置
KR100432056B1 (ko) * 2001-07-20 2004-05-17 (주)케이에이치 케미컬 탄소나노튜브의 제조 방법
KR20020025101A (ko) * 2002-01-10 2002-04-03 (주) 나노텍 열분해를 이용한 탄소나노튜브의 대량 합성법
JP3818193B2 (ja) * 2002-03-27 2006-09-06 大阪瓦斯株式会社 カーボンナノチューブ含有炭素材料の製造方法

Also Published As

Publication number Publication date
US20050287064A1 (en) 2005-12-29
WO2004000727A2 (fr) 2003-12-31
JP4781674B2 (ja) 2011-09-28
EP1515911B1 (de) 2011-04-27
FR2841233A1 (fr) 2003-12-26
JP2005530671A (ja) 2005-10-13
EP1515911A2 (de) 2005-03-23
FR2841233B1 (fr) 2004-07-30
CN1678523A (zh) 2005-10-05
AU2003253078A1 (en) 2004-01-06
DE60336899D1 (de) 2011-06-09
US7879300B2 (en) 2011-02-01
ES2365705T3 (es) 2011-10-10
WO2004000727A3 (fr) 2004-05-06

Similar Documents

Publication Publication Date Title
ATE507187T1 (de) Verfahren und vorrichtung zur abscheidung von nanoröhren oder stickstoffdotierten kohlenstoffnanoröhren mittels pyrolyse
Plata et al. Multiple alkynes react with ethylene to enhance carbon nanotube synthesis, suggesting a polymerization-like formation mechanism
TWI318248B (en) Control of carbon nanotube diameter using cvd or pecvd growth
WO2008016390A3 (en) Catalyst for the growth of carbon single-walled nanotubes
WO2004048257A3 (en) Method for forming carbon nanotubes
WO2010068419A3 (en) Production of single crystal cvd diamond rapid growth rate
Fanelli et al. Ar/HMDSO/O2 Fed Atmospheric Pressure DBDs: Thin Film Deposition and GC‐MS Investigation of By‐Products
ATE413364T1 (de) Verfahren und vorrichtung zur herstellung von kohlenstoffnanoröhren
US8252713B1 (en) Combination catalysts based on iron for the substantial synthesis of multi-walled carbon nanotubes by chemical vapor deposition
DE69621503D1 (de) Verfahren zur Versorgung eines Rohres mit Koksanlagerung- und Kohlenmonoxidhemmenden Eigenschaften bei dem thermische Kracken von Kohlenwasserstoffen
FI2411322T3 (fi) Esikäsittelymenetelmä kivihiilestä ja hiilipitoisista hiilistä koostuvien hiilinanoputkien ja hiilinanorakenteiden synteesiä varten
KR20120106949A (ko) 기재 상에 탄소 나노튜브를 제조하는 방법
CN1288772A (zh) 含有硫化氢的气体组合物的处理方法
US9643847B2 (en) Method for growth of vertically aligned carbon nanotubes on diamond substrates
Neyts Atomistic simulations of plasma catalytic processes
KR20170089253A (ko) 분해 가스 오일을 이용한 수소 및 메탄 가스 생성 공정
WO2004048258A8 (en) Method for forming carbon nanotubes
TW200715375A (en) Low-temperature catalyzed formation of segmented nanowire of dielectric material
CA2556280A1 (en) Process for reforming hydrocarbons with carbon dioxide by the use of a selectively permeable membrane reactor
ATE438748T1 (de) Vorrichtung und verfahren zur kontinuierlichen gasphasenabscheidung unter atmosphärendruck und deren verwendung
Hübner et al. On the reduction of gas‐phase naphthalene using char–particles in a packed–bed atmospheric pressure plasma
JP2009511283A5 (de)
AR048578A1 (es) Procedimiento de transformacion de un gas de sintesis en hidrocarburos en presencia de sic-beta y efluente de este procedimiento
RU2290363C1 (ru) Способ непрерывного получения водорода
JP4617142B2 (ja) 薄膜製造方法

Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification

Ref document number: 1515911

Country of ref document: EP