ATE509963T1 - Verfahren und vorrichtung zur regulierung von statischer aufladung in polyolefinreaktoren - Google Patents
Verfahren und vorrichtung zur regulierung von statischer aufladung in polyolefinreaktorenInfo
- Publication number
- ATE509963T1 ATE509963T1 AT07796859T AT07796859T ATE509963T1 AT E509963 T1 ATE509963 T1 AT E509963T1 AT 07796859 T AT07796859 T AT 07796859T AT 07796859 T AT07796859 T AT 07796859T AT E509963 T1 ATE509963 T1 AT E509963T1
- Authority
- AT
- Austria
- Prior art keywords
- static
- static charge
- polyolefin
- regulating static
- polyolefin reactors
- Prior art date
Links
- 230000003068 static effect Effects 0.000 title abstract 6
- 229920000098 polyolefin Polymers 0.000 title abstract 2
- 230000001105 regulatory effect Effects 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000012968 metallocene catalyst Substances 0.000 abstract 1
- 239000000523 sample Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1809—Controlling processes
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05F—STATIC ELECTRICITY; NATURALLY-OCCURRING ELECTRICITY
- H05F3/00—Carrying-off electrostatic charges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00734—Controlling static charge
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00193—Sensing a parameter
- B01J2219/00195—Sensing a parameter of the reaction system
- B01J2219/002—Sensing a parameter of the reaction system inside the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00211—Control algorithm comparing a sensed parameter with a pre-set value
- B01J2219/00213—Fixed parameter value
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00222—Control algorithm taking actions
- B01J2219/00227—Control algorithm taking actions modifying the operating conditions
- B01J2219/00229—Control algorithm taking actions modifying the operating conditions of the reaction system
- B01J2219/00231—Control algorithm taking actions modifying the operating conditions of the reaction system at the reactor inlet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00245—Avoiding undesirable reactions or side-effects
- B01J2219/00254—Formation of unwanted polymer, such as "pop-corn"
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2400/00—Characteristics for processes of polymerization
- C08F2400/02—Control or adjustment of polymerization parameters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/02—Anti-static agent incorporated into the catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US83439506P | 2006-07-31 | 2006-07-31 | |
| PCT/US2007/016048 WO2008016478A2 (en) | 2006-07-31 | 2007-07-13 | Method and apparatus for controlling static charge in polyolefin reactors |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE509963T1 true ATE509963T1 (de) | 2011-06-15 |
Family
ID=37591830
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT07796859T ATE509963T1 (de) | 2006-07-31 | 2007-07-13 | Verfahren und vorrichtung zur regulierung von statischer aufladung in polyolefinreaktoren |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7799876B2 (de) |
| EP (1) | EP2084194B1 (de) |
| JP (1) | JP2009545647A (de) |
| KR (1) | KR20090035665A (de) |
| CN (1) | CN101627060B (de) |
| AT (1) | ATE509963T1 (de) |
| AU (1) | AU2007279379A1 (de) |
| BR (1) | BRPI0713950B1 (de) |
| CA (1) | CA2654433A1 (de) |
| MX (1) | MX2008016200A (de) |
| RU (1) | RU2441027C2 (de) |
| WO (1) | WO2008016478A2 (de) |
| ZA (1) | ZA200810176B (de) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102015090B (zh) * | 2008-04-22 | 2014-03-12 | 尤尼威蒂恩技术有限公司 | 反应器系统和使用该反应器系统的方法 |
| RU2527945C2 (ru) | 2009-01-08 | 2014-09-10 | Юнивейшн Текнолоджиз, Ллк | Добавка для процессов полимеризации полиолефинов |
| WO2010080871A1 (en) | 2009-01-08 | 2010-07-15 | Univation Technologies, Llc | Additive for gas phase polymerization processes |
| US8441250B2 (en) * | 2009-05-18 | 2013-05-14 | Univation Technologies, Llc | Method and apparatus for monitoring electrical properties of polymerization reactor wall film |
| RU2549541C2 (ru) | 2009-07-28 | 2015-04-27 | Юнивейшн Текнолоджиз, Ллк | Способ полимеризации с использованием нанесенного катализатора с затрудненной геометрией |
| BR112012005542B1 (pt) * | 2009-09-11 | 2019-08-20 | Basell Poliolefine Italia S.R.L | Processo para polimerização em fase gasosa de olefinas |
| WO2011071900A2 (en) * | 2009-12-07 | 2011-06-16 | Univation Technologies, Llc | Methods for reducing static charge of a catalyst and methods for using the catalyst to produce polyolefins |
| BR112012020762B1 (pt) | 2010-02-18 | 2020-04-07 | Univation Tech Llc | método para inativar um reator de polimerização de fase gasosa |
| EP2576042B1 (de) * | 2010-05-28 | 2014-10-15 | Univation Technologies, LLC | Verfahren und vorrichtung zur überwachung und wiederherstellung der elektrischen eigenschaften eines polymerisationsreaktorwandfilms |
| EP2593217B1 (de) * | 2010-07-16 | 2014-07-02 | Univation Technologies, LLC | Systeme und verfahren zur messung der partikelakkumulation auf reaktorflächen |
| WO2012009215A1 (en) * | 2010-07-16 | 2012-01-19 | Univation Technologies, Llc | Systems and methods for measuring static charge on particulates |
| US8703884B2 (en) | 2010-12-22 | 2014-04-22 | Univation Technologies, Llc | Additive for polyolefin polymerization processes |
| US9360453B2 (en) | 2012-12-28 | 2016-06-07 | Exxonmobil Research And Engineering Company | Instruments for monitoring electrostatic phenomena in reactors |
| WO2014106078A2 (en) * | 2012-12-28 | 2014-07-03 | Exxonmobil Research And Engineering Company | Instruments for monitoring electrostatic phenomena in reactors |
| US9328177B2 (en) | 2012-12-28 | 2016-05-03 | Exxonmobil Research And Engineering Company | Methods for processing and interpreting signals from static and acoustic probes in fluidized bed reactor systems |
| US9433914B2 (en) | 2013-12-20 | 2016-09-06 | Chevron Phillips Chemical Company, Lp | Polyolefin reactor system having a gas phase reactor |
| CN104159385B (zh) * | 2014-07-04 | 2016-07-27 | 中国石油化工股份有限公司 | 一种聚乙烯反应器的静电消除方法 |
| ES2719407T3 (es) | 2015-04-08 | 2019-07-10 | Univation Tech Llc | Transiciones en reactor cerrado entre catalizadores de metaloceno |
| KR102495590B1 (ko) * | 2019-05-10 | 2023-02-06 | 웰이앤씨 주식회사 | 공정반응기의 정전기 제거장치 |
| WO2020231109A1 (ko) * | 2019-05-10 | 2020-11-19 | 웰이앤씨 주식회사 | 공정반응기의 정전기 제거장치 |
| KR102513518B1 (ko) | 2020-12-23 | 2023-03-22 | 디엘케미칼 주식회사 | 메탈로센 올레핀 중합 공정용 대전방지제를 이용한 올레핀 중합 방법 |
| CN115576288B (zh) * | 2022-10-28 | 2023-08-08 | 苏州米果新材料科技有限公司 | 一种过滤材料的生产控制方法和系统 |
| WO2025111109A1 (en) | 2023-11-21 | 2025-05-30 | ExxonMobil Technology and Engineering Company | Gas phase fluidized bed reactor product discharge system |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3015587A1 (de) | 1980-04-23 | 1981-10-29 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von acylcyaniden |
| US4532311A (en) | 1981-03-26 | 1985-07-30 | Union Carbide Corporation | Process for reducing sheeting during polymerization of alpha-olefins |
| US4855370A (en) | 1986-10-01 | 1989-08-08 | Union Carbide Corporation | Method for reducing sheeting during polymerization of alpha-olefins |
| US4803251A (en) | 1987-11-04 | 1989-02-07 | Union Carbide Corporation | Method for reducing sheeting during polymerization of alpha-olefins |
| US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| EP0604990B1 (de) | 1992-12-29 | 1997-06-11 | Nippon Petrochemicals Co., Ltd. | Verfahren zur Alpha-Olefin-Polymerisation in der Dampfphase |
| JP3077940B2 (ja) | 1993-04-26 | 2000-08-21 | エクソン・ケミカル・パテンツ・インク | 流動層重合法のための安定な操作条件を決定する方法 |
| US5391657A (en) | 1993-09-27 | 1995-02-21 | Union Carbide Chemicals & Plastics Technology Corporaton | Method for reducing sheeting and static charges during polymerization of ethylene polymers |
| CZ170897A3 (en) * | 1996-06-06 | 1997-12-17 | Union Carbide Chem Plastic | Control of static charge in the course of polymerization process during which metallocene catalyst is used |
| US6008662A (en) | 1996-10-31 | 1999-12-28 | Oxford Instruments America, Inc. | Apparatus and method for measuring conditions in fluidized beds |
| DE69907667T2 (de) | 1998-05-28 | 2003-11-06 | Bp Chemicals Ltd., London | Verfahren zur frühzeitigen erkennung von reaktorverschmutzung bei der gasphasenpolymerisation |
| TW475934B (en) * | 1998-06-27 | 2002-02-11 | Basell Technology Co Bv | Process for the production of Α-olefin polymer |
| US6414093B1 (en) | 1999-12-10 | 2002-07-02 | Sumitomo Chemical Company, Limited | Method and Apparatus for detecting agglomerates |
| US6482903B1 (en) | 1999-12-15 | 2002-11-19 | Univation Technologies, Llc | Method for preparing a supported catalyst system and its use in a polymerization process |
| US6548610B2 (en) | 2000-10-06 | 2003-04-15 | Univation Technologies, Llc | Method and apparatus for reducing static charges during polymerization of olefin polymers |
| US6914027B2 (en) | 2000-12-01 | 2005-07-05 | Univation Technologies, Llc | Polymerization reactor operability using static charge modifier agents |
| US20050148742A1 (en) * | 2004-01-02 | 2005-07-07 | Hagerty Robert O. | Method for controlling sheeting in gas phase reactors |
-
2007
- 2007-07-13 EP EP07796859A patent/EP2084194B1/de active Active
- 2007-07-13 CN CN2007800219360A patent/CN101627060B/zh active Active
- 2007-07-13 AT AT07796859T patent/ATE509963T1/de not_active IP Right Cessation
- 2007-07-13 KR KR1020087031877A patent/KR20090035665A/ko not_active Withdrawn
- 2007-07-13 US US11/827,685 patent/US7799876B2/en active Active
- 2007-07-13 MX MX2008016200A patent/MX2008016200A/es unknown
- 2007-07-13 RU RU2008152781/04A patent/RU2441027C2/ru active
- 2007-07-13 JP JP2009522770A patent/JP2009545647A/ja active Pending
- 2007-07-13 AU AU2007279379A patent/AU2007279379A1/en not_active Abandoned
- 2007-07-13 BR BRPI0713950A patent/BRPI0713950B1/pt active IP Right Grant
- 2007-07-13 WO PCT/US2007/016048 patent/WO2008016478A2/en not_active Ceased
- 2007-07-13 CA CA002654433A patent/CA2654433A1/en not_active Abandoned
-
2008
- 2008-11-28 ZA ZA200810176A patent/ZA200810176B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN101627060A (zh) | 2010-01-13 |
| AU2007279379A1 (en) | 2008-02-07 |
| BRPI0713950A2 (pt) | 2012-12-04 |
| WO2008016478A2 (en) | 2008-02-07 |
| CN101627060B (zh) | 2011-11-30 |
| US20080027185A1 (en) | 2008-01-31 |
| BRPI0713950B1 (pt) | 2018-05-08 |
| KR20090035665A (ko) | 2009-04-10 |
| RU2441027C2 (ru) | 2012-01-27 |
| MX2008016200A (es) | 2009-01-20 |
| US7799876B2 (en) | 2010-09-21 |
| CA2654433A1 (en) | 2008-02-07 |
| RU2008152781A (ru) | 2010-07-10 |
| ZA200810176B (en) | 2009-11-25 |
| EP2084194B1 (de) | 2011-05-18 |
| WO2008016478A3 (en) | 2009-07-23 |
| EP2084194A2 (de) | 2009-08-05 |
| JP2009545647A (ja) | 2009-12-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |