ATE521649T1 - Verfahren zur herstellung von mikrogelpartikeln durch gesteuerte radikale polymerisierung in einer wässrigen dispersion mit nitroxid- steuerungsmitteln - Google Patents

Verfahren zur herstellung von mikrogelpartikeln durch gesteuerte radikale polymerisierung in einer wässrigen dispersion mit nitroxid- steuerungsmitteln

Info

Publication number
ATE521649T1
ATE521649T1 AT08708293T AT08708293T ATE521649T1 AT E521649 T1 ATE521649 T1 AT E521649T1 AT 08708293 T AT08708293 T AT 08708293T AT 08708293 T AT08708293 T AT 08708293T AT E521649 T1 ATE521649 T1 AT E521649T1
Authority
AT
Austria
Prior art keywords
monomers
microgel particles
preparation
ammonium
nitroxide
Prior art date
Application number
AT08708293T
Other languages
English (en)
Inventor
Stephanie Magnet
Bernadette Charleux
Guillaume Delaittre
Maud Save
Original Assignee
Arkema France
Centre Nat Rech Scient
Univ Paris Curie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France, Centre Nat Rech Scient, Univ Paris Curie filed Critical Arkema France
Application granted granted Critical
Publication of ATE521649T1 publication Critical patent/ATE521649T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11—Encapsulated compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/90—Block copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04—Acids, Metal salts or ammonium salts thereof
    • C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F20/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F20/56—Acrylamide; Methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/04—Polymers provided for in subclasses C08C or C08F
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
AT08708293T 2007-01-29 2008-01-28 Verfahren zur herstellung von mikrogelpartikeln durch gesteuerte radikale polymerisierung in einer wässrigen dispersion mit nitroxid- steuerungsmitteln ATE521649T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0752941A FR2911877B1 (fr) 2007-01-29 2007-01-29 Procede de preparation de particules de microgel par polymerisation radicalaire controlee en dispersion aqueuse mettant en oeuvre des agents de controle nitroxydes
PCT/EP2008/050975 WO2008095814A1 (fr) 2007-01-29 2008-01-28 Procede de preparation de particules de microgel par polymerisation radicalaire controlee en dispersion aqueuse mettant en œuvre des agents de contrôle nitroxydes.

Publications (1)

Publication Number Publication Date
ATE521649T1 true ATE521649T1 (de) 2011-09-15

Family

ID=38535599

Family Applications (1)

Application Number Title Priority Date Filing Date
AT08708293T ATE521649T1 (de) 2007-01-29 2008-01-28 Verfahren zur herstellung von mikrogelpartikeln durch gesteuerte radikale polymerisierung in einer wässrigen dispersion mit nitroxid- steuerungsmitteln

Country Status (6)

Country Link
US (1) US20100137534A1 (de)
EP (1) EP2125921B1 (de)
JP (1) JP5367585B2 (de)
AT (1) ATE521649T1 (de)
FR (1) FR2911877B1 (de)
WO (1) WO2008095814A1 (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5321299B2 (ja) * 2009-07-07 2013-10-23 東亞合成株式会社 接着剤組成物
FR2969619B1 (fr) * 2010-12-23 2013-01-04 Arkema France Particules polymeriques filamenteuses et procede de preparation desdites particules par polymerisation radicalaire controlee en emulsion.
JP6843047B2 (ja) 2014-12-05 2021-03-17 ユニバーシティ オブ フロリダ リサーチ ファンデーション インコーポレーティッド 支持体として相変化物質を用いた３ｄ印刷
US11007705B2 (en) 2015-02-13 2021-05-18 University Of Florida Research Foundation, Inc. High speed 3D printing system for wound and tissue replacement
US9650480B2 (en) 2015-04-15 2017-05-16 Ppg Industries Ohio, Inc. Curable film-forming compositions containing encapsulated catalyst components
US11390835B2 (en) 2015-05-08 2022-07-19 University Of Florida Research Foundation, Inc. Growth media for three-dimensional cell culture
WO2017040981A1 (en) 2015-09-03 2017-03-09 University Of Florida Research Foundation, Inc. Valve incorporating temporary phase change material
WO2017096263A1 (en) 2015-12-04 2017-06-08 University Of Florida Research Foundation, Incorporated Crosslinkable or functionalizable polymers for 3d printing of soft materials
US11124644B2 (en) * 2016-09-01 2021-09-21 University Of Florida Research Foundation, Inc. Organic microgel system for 3D printing of silicone structures

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AUPO460797A0 (en) * 1997-01-15 1997-02-06 University Of Melbourne, The Polymerisation process
DE69835678T2 (de) * 1997-07-28 2007-08-30 Kaneka Corp. Polymere und verfahren zur herstellung von polymeren
US6720395B2 (en) * 1997-07-28 2004-04-13 Kaneka Corporation Method for producing a stellar polymer
AUPP337298A0 (en) * 1998-05-07 1998-05-28 University Of Melbourne, The Process for microgel preparation
AUPQ679400A0 (en) * 2000-04-07 2000-05-11 Commonwealth Scientific And Industrial Research Organisation Microgel synthesis
CN1446833A (zh) * 2003-02-08 2003-10-08 复旦大学 一种温敏性可降解微凝胶及其制备方法
FR2861394B1 (fr) * 2003-10-24 2006-01-20 Arkema Procede de preparation de polyalcoaxymines utilisables comme amorceurs pour la polymerisation radicalaire de (co)polymeres vivants polyfonctionnels
FR2866026B1 (fr) * 2004-02-06 2008-05-23 Arkema Procede de polymerisation radicalaire en emulsion mettant en oeuvre des alcoxyamines hydrosolubles
US20080104393A1 (en) * 2006-09-28 2008-05-01 Microsoft Corporation Cloud-based access control list
US8418222B2 (en) * 2008-03-05 2013-04-09 Microsoft Corporation Flexible scalable application authorization for cloud computing environments
US7886038B2 (en) * 2008-05-27 2011-02-08 Red Hat, Inc. Methods and systems for user identity management in cloud-based networks
US8943551B2 (en) * 2008-08-14 2015-01-27 Microsoft Corporation Cloud-based device information storage
US8271974B2 (en) * 2008-10-08 2012-09-18 Kaavo Inc. Cloud computing lifecycle management for N-tier applications
US8984505B2 (en) * 2008-11-26 2015-03-17 Red Hat, Inc. Providing access control to user-controlled resources in a cloud computing environment
US9210173B2 (en) * 2008-11-26 2015-12-08 Red Hat, Inc. Securing appliances for use in a cloud computing environment
US8370835B2 (en) * 2009-03-12 2013-02-05 Arend Erich Dittmer Method for dynamically generating a configuration for a virtual machine with a virtual hard disk in an external storage device
US8190569B2 (en) * 2009-04-03 2012-05-29 Wishlist Holdings Limited System and method for site cloning
US8966017B2 (en) * 2009-07-09 2015-02-24 Novell, Inc. Techniques for cloud control and management
US8490150B2 (en) * 2009-09-23 2013-07-16 Ca, Inc. System, method, and software for enforcing access control policy rules on utility computing virtualization in cloud computing systems
US20110072487A1 (en) * 2009-09-23 2011-03-24 Computer Associates Think, Inc. System, Method, and Software for Providing Access Control Enforcement Capabilities in Cloud Computing Systems
US20110137947A1 (en) * 2009-12-03 2011-06-09 International Business Machines Corporation Dynamic access control for documents in electronic communications within a cloud computing environment
US8452957B2 (en) * 2010-04-27 2013-05-28 Telefonaktiebolaget L M Ericsson (Publ) Method and nodes for providing secure access to cloud computing for mobile users
EP2583211B1 (de) * 2010-06-15 2020-04-15 Oracle International Corporation Virtuelle berechnungsinfrastruktur
US9323561B2 (en) * 2010-08-13 2016-04-26 International Business Machines Corporation Calibrating cloud computing environments
US8468352B2 (en) * 2010-09-17 2013-06-18 Microsoft Corporation Retrieving and using cloud based storage credentials
US8775626B2 (en) * 2010-09-17 2014-07-08 Microsoft Corporation Using templates to configure cloud resources
US8713163B2 (en) * 2010-09-17 2014-04-29 Microsoft Corporation Monitoring cloud-runtime operations

Also Published As

Publication number Publication date
US20100137534A1 (en) 2010-06-03
FR2911877A1 (fr) 2008-08-01
WO2008095814A1 (fr) 2008-08-14
FR2911877B1 (fr) 2009-04-10
JP5367585B2 (ja) 2013-12-11
JP2010516849A (ja) 2010-05-20
EP2125921A1 (de) 2009-12-02
EP2125921B1 (de) 2011-08-24

Similar Documents

Publication Publication Date Title
ATE521649T1 (de) Verfahren zur herstellung von mikrogelpartikeln durch gesteuerte radikale polymerisierung in einer wässrigen dispersion mit nitroxid- steuerungsmitteln
MX2010002022A (es) Monomeros y polimeros entrelazables y el uso de los mismos.
JP3289700B2 (ja) 水性塗料用樹脂組成物
DE60012981D1 (de) Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit xanthaten
DE602005023566D1 (de) Verfahren zur Herstellung von Hydrophob modifizierten Polymere
ATE356834T1 (de) Verfahren zur herstellung von latices durch verwendung von block copolymere als tensid
JP2011225893A (ja) 水性ポリマー分散液の製造方法
RU2010129835A (ru) Водные полимерные дисперсии, способ их получения и их применение
TW200744747A (en) Nanogel contrast agents for optical molecular imaging
DE60118007D1 (de) Verfahren zur herstellung von blockcopolymeren durch eine kontrollierte radikalpolymerisation in gegenwart von einer disulfidverbindung
ATE460438T1 (de) Verfahren zur herstellung von vinylester- (meth)acrylsäureester-mischpolymerisaten
ATE393172T1 (de) Verfahren zur radikalischen emulsionspolymerisation unter verwendung von wasserlöslichen alkoxyaminen
CN103509419A (zh) 木材保护油漆
ATE441679T1 (de) Wässrige kunststoff dispersionen, verfahren zu deren herstellung sowie deren verwendung
ATE326490T1 (de) Verfahren zur herstellung von wässrigen dispersionen kationischer homo- und copolymere unter verwendung von amphoteren schutzkolloiden
DE59806774D1 (de) Verfahren zur Herstellung von wässrigen Dispersionen als Grundierung für Heisssiegelkleber
DE502005008386D1 (de) Verfahren zur herstellung von polymeren durch sprühpolymerisation
AU2016433599B2 (en) Aqueous polymer composition
CN108350304A (zh) 水性胶乳基涂料组合物
ATE365178T1 (de) Hagelbeständiges verbund-acrylglas und verfahren zu seiner herstellung
US20140323608A1 (en) Polymer dispersions
ATE384754T1 (de) Verfahren zur herstellung von hochverzweigten polyamiden
JP2016505679A (ja) 熱増粘性ポリマーを製造する新規な方法及び新規な櫛型コポリマー
CN109265625A (zh) 一种真石漆专用丙烯酸乳液及其制备方法和应用
ATE304529T1 (de) Verfahren zur herstellung von hydroxy- peroxyestern

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties