ATE527234T1 - Verfahren zur nitrierung von benzol in der gasphase unter verwendung von salpetersäure über einem molybdänsilikat enthaltenden katalysator - Google Patents
Verfahren zur nitrierung von benzol in der gasphase unter verwendung von salpetersäure über einem molybdänsilikat enthaltenden katalysatorInfo
- Publication number
- ATE527234T1 ATE527234T1 AT03253422T AT03253422T ATE527234T1 AT E527234 T1 ATE527234 T1 AT E527234T1 AT 03253422 T AT03253422 T AT 03253422T AT 03253422 T AT03253422 T AT 03253422T AT E527234 T1 ATE527234 T1 AT E527234T1
- Authority
- AT
- Austria
- Prior art keywords
- benzene
- nitration
- nitric acid
- molybdenus
- silicate
- Prior art date
Links
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title abstract 12
- 238000000034 method Methods 0.000 title abstract 5
- 238000006396 nitration reaction Methods 0.000 title abstract 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 title abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title abstract 3
- 229910017604 nitric acid Inorganic materials 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title abstract 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 abstract 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 5
- 238000006243 chemical reaction Methods 0.000 abstract 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
- 230000000802 nitrating effect Effects 0.000 abstract 1
- 239000010815 organic waste Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000011973 solid acid Substances 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/06—Preparation of nitro compounds
- C07C201/08—Preparation of nitro compounds by substitution of hydrogen atoms by nitro groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN798DE2002 | 2002-07-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE527234T1 true ATE527234T1 (de) | 2011-10-15 |
Family
ID=30012267
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT03253422T ATE527234T1 (de) | 2002-07-31 | 2003-05-30 | Verfahren zur nitrierung von benzol in der gasphase unter verwendung von salpetersäure über einem molybdänsilikat enthaltenden katalysator |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US6791000B2 (de) |
| EP (1) | EP1386907B1 (de) |
| AT (1) | ATE527234T1 (de) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101538203B (zh) * | 2009-04-08 | 2012-05-30 | 聊城大学 | 一种二氧化硅负载杂多酸铵催化合成一硝基苯的方法 |
| US8314045B1 (en) | 2009-10-27 | 2012-11-20 | Entreprises Sinoncelli S.A.R.L. | Solid acid catalyst |
| US9409854B2 (en) | 2013-06-03 | 2016-08-09 | Council Of Scientific & Industrial Research | Liquid phase nitration of aromatics using solid acid catalyst |
| CN104230716A (zh) * | 2014-08-28 | 2014-12-24 | 厦门大学 | 一种提高2,5-二氯硝基苯硝化反应速率的方法 |
| CN104892426B (zh) * | 2015-05-29 | 2018-01-30 | 江苏亚邦染料股份有限公司 | 一种以吡咯烷酮类离子液体为催化剂制备1‑硝基蒽醌的方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2431585A (en) * | 1944-06-29 | 1947-11-25 | Ici Ltd | Nitration of aromatic hydrocarbons |
| DE2632234C3 (de) * | 1976-07-17 | 1978-12-21 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Nitrotoluolgemischen mit einem überwiegenden Gehalt an Nitrotoluol |
| JPS58180460A (ja) * | 1982-04-16 | 1983-10-21 | Sumitomo Chem Co Ltd | ニトロ化方法 |
| JPS6239548A (ja) * | 1985-08-16 | 1987-02-20 | Mitsui Toatsu Chem Inc | アミノ化合物の製法 |
| CH683918A5 (de) * | 1991-12-04 | 1994-06-15 | Uetikon Chemie Ag | Verfahren zur Herstellung von Nitrobenzol. |
-
2003
- 2003-05-30 AT AT03253422T patent/ATE527234T1/de not_active IP Right Cessation
- 2003-05-30 EP EP03253422A patent/EP1386907B1/de not_active Expired - Lifetime
- 2003-05-30 US US10/449,718 patent/US6791000B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP1386907A2 (de) | 2004-02-04 |
| US20040024267A1 (en) | 2004-02-05 |
| EP1386907A3 (de) | 2004-10-13 |
| EP1386907B1 (de) | 2011-10-05 |
| US6791000B2 (en) | 2004-09-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Dallinger et al. | The concept of chemical generators: on-site on-demand production of hazardous reagents in continuous flow | |
| Yan et al. | Recent advances in the synthesis of aromatic nitro compounds | |
| Smith et al. | A novel method for the nitration of simple aromatic compounds | |
| Badgujar et al. | Review on greener and safer synthesis of nitro compounds | |
| Smith et al. | Superior methodology for the nitration of simple aromatic compounds | |
| DE502007001946D1 (de) | Verfahren zur Herstellung von Dinitrotoluol | |
| Dove et al. | Vanadium (V) oxytrinitrate, VO (NO 3) 3. A powerful reagent for the nitration of aromatic compounds at room temperature under non-acidic conditions | |
| Peng et al. | Regioselective double Kyodai nitration of toluene and chlorobenzene over zeolites. High preference for the 2, 4-dinitro isomer at the second nitration stage | |
| Khazaei et al. | An Efficient Method for the Nitration of Phenols with NaNO^ sub 2^ in the Presence of 3-Methyl-1-Sulfonic Acid Imidazolium Chloride | |
| Carmeli et al. | Oxidation of Azides by the HOF⊙ CH3CN: A Novel Synthesis of Nitro Compounds | |
| ATE527234T1 (de) | Verfahren zur nitrierung von benzol in der gasphase unter verwendung von salpetersäure über einem molybdänsilikat enthaltenden katalysator | |
| Vekariya et al. | Alumina sulfuric acid (ASA), tungstate sulfuric acid (TSA), molybdate sulfuric acid (MSA) and xanthan sulfuric acid (XSA) as solid and heterogeneous catalysts in green organic synthesis: a review. | |
| Ma et al. | Selective nitration of aromatic compounds catalyzed by Hβ zeolite using N2O5 | |
| KR20170015484A (ko) | 니트로화로부터의 폐가스에서 질소 산화물을 제거하기 위한 방법 및 장치 | |
| DE69815399D1 (de) | Verfahren zur nitrierung von aromatischen verbindungen mit hilfe eines nichtsauren nitrierungsprozesses | |
| Kamal et al. | An efficient and facile nitration of phenols with nitric acid/zinc chloride under ultrasonic conditions | |
| US5977418A (en) | Regioselective nitration of aromatic compounds by dinitrogen pentoxide and the reaction products thereof | |
| DE602006002403D1 (de) | Herstellungsverfahren von Dinitrotoluol | |
| Zhu et al. | First application of bismuth triflate as an efficient, non-transition metallic and reusable catalyst for aromatic nitration | |
| Crampton et al. | The nitration of arenes in perfluorocarbon solvents | |
| CZ20013995A3 (cs) | Způsob kontinuální isotermní výroby mononitrotoluenů | |
| Muppidi et al. | Hydro peroxides/NaNO2/KHSO4 mediated synthesis, kinetics and mechanistic study of nitration of aromatic compounds in aqueous acetonitrile | |
| Menand et al. | TMAF-Catalyzed conjugate addition of oxazolidinone and thiols | |
| KR0164447B1 (ko) | 방향족 화합물의 니트로화 방법 | |
| WO1992004313A1 (fr) | Procede non polluant de production d'un compose nitro aromatique sans usage d'acide mineral |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |