ATE538144T1 - Wässriges verfahren zur herstellung einer stabilen fluorpolymer-dispersion - Google Patents

Wässriges verfahren zur herstellung einer stabilen fluorpolymer-dispersion

Info

Publication number
ATE538144T1
ATE538144T1 AT07864658T AT07864658T ATE538144T1 AT E538144 T1 ATE538144 T1 AT E538144T1 AT 07864658 T AT07864658 T AT 07864658T AT 07864658 T AT07864658 T AT 07864658T AT E538144 T1 ATE538144 T1 AT E538144T1
Authority
AT
Austria
Prior art keywords
fluorpolymer
dispersion
stable
producing
aqueous process
Prior art date
Application number
AT07864658T
Other languages
English (en)
Inventor
Ramin Amin-Sanayei
Christyn B Olmstead
Original Assignee
Arkema Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema Inc filed Critical Arkema Inc
Application granted granted Critical
Publication of ATE538144T1 publication Critical patent/ATE538144T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/14Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18Monomers containing fluorine
    • C08F14/22Vinylidene fluoride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/22Vinylidene fluoride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/06Ethers; Acetals; Ketals; Ortho-esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/16Homopolymers or copolymers or vinylidene fluoride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/10Homopolymers or copolymers of unsaturated ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02Polyalkylene oxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
AT07864658T 2006-12-08 2007-11-20 Wässriges verfahren zur herstellung einer stabilen fluorpolymer-dispersion ATE538144T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/635,873 US8338518B2 (en) 2005-06-10 2006-12-08 Aqueous process for making a stable fluoropolymer dispersion
PCT/US2007/085222 WO2008073685A1 (en) 2006-12-08 2007-11-20 Aqueous process for making a stable fluoropolymer dispersion

Publications (1)

Publication Number Publication Date
ATE538144T1 true ATE538144T1 (de) 2012-01-15

Family

ID=39512083

Family Applications (1)

Application Number Title Priority Date Filing Date
AT07864658T ATE538144T1 (de) 2006-12-08 2007-11-20 Wässriges verfahren zur herstellung einer stabilen fluorpolymer-dispersion

Country Status (7)

Country Link
US (2) US8338518B2 (de)
EP (1) EP2089462B1 (de)
JP (1) JP5410987B2 (de)
CN (1) CN101547966B (de)
AT (1) ATE538144T1 (de)
ES (1) ES2379295T3 (de)
WO (1) WO2008073685A1 (de)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7279522B2 (en) * 2001-09-05 2007-10-09 3M Innovative Properties Company Fluoropolymer dispersions containing no or little low molecular weight fluorinated surfactant
EP1570917B1 (de) * 2004-03-01 2009-06-10 3M Innovative Properties Company Verfahren zum Beschichten eines Gegenstands mit einer fluorhaltigen Kunststoffsdispersion
US8080621B2 (en) * 2005-06-10 2011-12-20 Arkema Inc. Aqueous process for making fluoropolymers
GB0514398D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
GB0525978D0 (en) * 2005-12-21 2006-02-01 3M Innovative Properties Co Fluorinated Surfactants For Making Fluoropolymers
US7795332B2 (en) * 2005-07-15 2010-09-14 3M Innovative Properties Company Method of removing fluorinated carboxylic acid from aqueous liquid
US20080015304A1 (en) * 2006-07-13 2008-01-17 Klaus Hintzer Aqueous emulsion polymerization process for producing fluoropolymers
GB0514387D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
GB0523853D0 (en) * 2005-11-24 2006-01-04 3M Innovative Properties Co Fluorinated surfactants for use in making a fluoropolymer
US7728087B2 (en) * 2005-12-23 2010-06-01 3M Innovative Properties Company Fluoropolymer dispersion and method for making the same
US20070276103A1 (en) * 2006-05-25 2007-11-29 3M Innovative Properties Company Fluorinated Surfactants
US7754795B2 (en) * 2006-05-25 2010-07-13 3M Innovative Properties Company Coating composition
US8119750B2 (en) * 2006-07-13 2012-02-21 3M Innovative Properties Company Explosion taming surfactants for the production of perfluoropolymers
EP2196479B9 (de) * 2007-10-11 2012-05-09 Kureha Corporation Vinylidenfluoridpolymerpulver und seine verwendung
WO2011017322A1 (en) * 2009-08-03 2011-02-10 Abbott Medical Optics Inc. Intraocular lens for providing accomodative vision
US9309329B2 (en) 2010-04-07 2016-04-12 Arkema Inc. Method for preparing pH-insensitive surfactant free polymer particle dispersion in aqueous medium
CN106188353B (zh) * 2010-11-09 2018-08-31 科慕埃弗西有限公司 使用烃表面活性剂的含氟单体的含水聚合
JP6201236B2 (ja) * 2010-11-09 2017-09-27 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー フルオロモノマーの水性重合における核形成
US9074025B2 (en) 2010-11-09 2015-07-07 The Chemours Company Fc, Llc Reducing the telogenic behavior of hydrocarbon-containing surfactants in aqueous dispersion fluoromonomer polymerization
US8735520B2 (en) 2010-11-09 2014-05-27 E.I. Du Pont De Nemours And Company Vinyl fluoride polymerization and aqueous dispersion of vinyl fluoride polymer
EP2508557B1 (de) * 2011-04-01 2016-08-17 Arkema Inc. Verfahren zur Herstellung eines pH-empfindlichen Tensids ohne Polymerteilchendispersion in einem wässrigen Medium
CN102493193B (zh) * 2011-12-14 2014-01-29 太仓中化环保化工有限公司 一种含氟拒水拒油剂及其制备方法
EP2803691B1 (de) * 2013-05-17 2016-04-20 3M Innovative Properties Company Fluorpolymerzusammensetzungen mit einem Polyhydroxytensid
JP6622209B2 (ja) 2013-11-26 2019-12-18 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー フルオロモノマーの水性重合において核を形成するためのポリアルキレンオキシドの使用
EP3145993B1 (de) 2014-05-19 2021-09-29 Arkema, Inc. Fluorpolymerzusammensetzung mit hohem schmelzfluss
KR20170091149A (ko) * 2014-12-05 2017-08-08 셀가드 엘엘씨 개선된 리튬 전지용 코팅 분리막 및 이와 관련된 방법
CN105823976B (zh) * 2015-01-09 2018-10-16 中芯国际集成电路制造(上海)有限公司 对芯片进行检测及对芯片测试结果进行验证的方法
EP3059265B1 (de) 2015-02-23 2020-10-07 3M Innovative Properties Company Peroxidhärtbare, durch Polymerisation mittels nichtfluorierter Emulgatoren erhältliche Fluorpolymere
USRE50063E1 (en) 2015-11-25 2024-07-30 Arkema Inc. Fluoropolymer compositions with improved mechanical dampening
JP6800999B2 (ja) 2016-04-01 2020-12-16 アーケマ・インコーポレイテッド 3dプリントフルオロポリマー構造体
WO2018011244A1 (en) * 2016-07-15 2018-01-18 Solvay Specialty Polymers Italy S.P.A. Fluorinated surfactant-free aqueous dispersion of a vinylidene fluoride copolymer comprising hydroxyl groups
FR3071500B1 (fr) * 2017-09-27 2020-05-15 Arkema France Synthese de latex de poly(fluorure de vinylidene) sans tensioactif par polymerisation en emulsion raft
EP3880719A4 (de) * 2018-11-12 2022-08-10 Arkema, Inc. Verfahren zur herstellung einer fluorpolymerdispersion
EP3950827B1 (de) * 2019-03-29 2023-07-26 Kureha Corporation Vinylidenfluoridbasierte polymerzusammensetzung, die unter verwendung von nichtfluoriertem tensid erhalten wird, und herstellungsverfahren dafür
JP7758683B2 (ja) * 2020-04-21 2025-10-22 サイエンスコ スペシャルティ ポリマーズ イタリー エス.ピー.エー. フッ化ビニリデンとトリフルオロエチレンとを含有するポリマーの水性分散液
CN116234794A (zh) 2020-10-01 2023-06-06 科慕埃弗西有限公司 含氟聚合物的水性聚合反应中的低反应性烃分散剂
JP2025539751A (ja) * 2022-11-14 2025-12-09 浙江省化工研究院有限公司 界面活性剤、その調製方法及び応用
EP4438632A1 (de) 2023-03-29 2024-10-02 Arkema France Polyvinylidenfluorid für anwendungen zur versorgung von hochreinem wasser
WO2025263074A1 (ja) * 2024-06-19 2025-12-26 Agc株式会社 水性分散液の製造方法
JP7827226B1 (ja) * 2024-06-19 2026-03-10 Agc株式会社 水性分散液の製造方法

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3178399A (en) * 1961-08-10 1965-04-13 Minnesota Mining & Mfg Fluorine-containing polymers and preparation thereof
US3475396A (en) 1966-07-06 1969-10-28 Diamond Shamrock Corp Process for polymerizing vinylidene fluoride
NL157322B (nl) * 1967-10-21 1978-07-17 Hoechst Ag Werkwijze voor het bereiden van polytetrafluoretheen-dispersies.
US3709856A (en) * 1970-05-21 1973-01-09 Pennwalt Corp Process for polymerizing fluoroolefins
US3714099A (en) * 1970-09-03 1973-01-30 Union Oil Co Self-crosslinking vinyl acetate-ethylene latexes
US3817951A (en) * 1972-11-20 1974-06-18 Pennwalt Corp Low-modulus thermoplastic ethylene-tetrafluoroethylene-hexafluoropropene terpolymers
FR2239501B1 (de) * 1973-07-10 1976-06-18 Solvay
US4057527A (en) * 1974-06-17 1977-11-08 Borden, Inc. Aqueous acrylate contact adhesive dispersions
US4406798A (en) * 1981-08-24 1983-09-27 Pfizer Inc. Surfactant enhanced injectivity of xanthan mobility control solutions for tertiary oil recovery
US4360652A (en) * 1981-08-31 1982-11-23 Pennwalt Corporation Method of preparing high quality vinylidene fluoride polymer in aqueous emulsion
JPS5834484B2 (ja) 1981-09-14 1983-07-27 ダイキン工業株式会社 ポリフツ化ビニリデン粉末の製造方法
US4569978A (en) * 1984-07-25 1986-02-11 Pennwalt Corporation Emulsion polymerization of vinylidene fluoride polymers in the presence of trichlorofluoromethane as chain transfer agent
DE3618517A1 (de) * 1985-06-04 1986-12-04 Lion Corp., Tokio/Tokyo Emulgiermittel zur emulsionspolymerisation
JPS63312836A (ja) * 1987-06-16 1988-12-21 Honny Chem Ind Co Ltd 炭化水素系ポリマ−を外層に形成してなるフロロカ−ボン系ポリマ−複合体及びその製造方法
US5349003A (en) * 1988-09-20 1994-09-20 Japan Synthetic Rubber Co., Ltd. Aqueous fluorine-containing polymer dispersion and aqueous dispersion containing fluorine-containing polymer and water-soluble resin and/or water dispersible resin
DE4192711T1 (de) * 1990-10-30 1992-12-10
JP3172983B2 (ja) 1993-09-20 2001-06-04 ダイキン工業株式会社 ビニリデンフルオライド系重合体の水性分散液およびその製法
US5955556A (en) * 1995-11-06 1999-09-21 Alliedsignal Inc. Method of manufacturing fluoropolymers
EP1359194B1 (de) * 1998-02-24 2006-10-11 Asahi Glass Company, Limited Wässrige Polytetrafluorethylen Dispersionszusammensetzung
US6720360B1 (en) * 2000-02-01 2004-04-13 3M Innovative Properties Company Ultra-clean fluoropolymers
US6593416B2 (en) * 2000-02-01 2003-07-15 3M Innovative Properties Company Fluoropolymers
US6794550B2 (en) * 2000-04-14 2004-09-21 3M Innovative Properties Company Method of making an aqueous dispersion of fluoropolymers
DE10018853C2 (de) 2000-04-14 2002-07-18 Dyneon Gmbh Herstellung wässriger Dispersionen von Fluorpolymeren
FR2811564B1 (fr) * 2000-07-13 2002-12-27 Oreal Nanoemulsion contenant des polymeres non ioniques, et ses utilisations notamment dans les domaines cosmetique, dermatologique, pharmaceutique et/ou ophtalmologique
US6512063B2 (en) * 2000-10-04 2003-01-28 Dupont Dow Elastomers L.L.C. Process for producing fluoroelastomers
WO2002064696A1 (en) * 2001-01-30 2002-08-22 Daikin Industries, Ltd. Water- and oil-repellent composition, process for producing the same and use thereof
DE10106145A1 (de) * 2001-02-10 2002-08-22 Clariant Gmbh Verwendung von neuen Alkyl- und Arylalkoxylaten als Emulgatoren in der Emulsionspolymerisation
CA2446016A1 (en) * 2001-05-02 2002-11-07 3M Innovative Properties Company Emulsifier free aqueous emulsion polymerization process for making fluoropolymers
US7045571B2 (en) * 2001-05-21 2006-05-16 3M Innovative Properties Company Emulsion polymerization of fluorinated monomers
JP4295098B2 (ja) * 2001-09-05 2009-07-15 スリーエム イノベイティブ プロパティズ カンパニー 低分子量フッ素化界面活性剤を全くまたは殆ど含まないフルオロポリマー分散
EP1512721B1 (de) * 2002-05-20 2011-03-30 Daikin Industries, Ltd. Wässrige fluorharzdispersionszusammensetzung und fluorierte beschichtungszusammensetzung auf wasserbasis
JP4206714B2 (ja) * 2002-09-10 2009-01-14 ダイキン工業株式会社 含フッ素樹脂水性分散体、含フッ素樹脂水性組成物、被覆物及び膜
US6734264B1 (en) * 2002-12-16 2004-05-11 Atofina Chemicals, Inc. Chain transfer agent
US6841616B2 (en) * 2003-03-28 2005-01-11 Arkema Inc. Polymerization of halogen-containing monomers using siloxane surfactant
DE10315182A1 (de) 2003-04-03 2004-10-14 Clariant Gmbh Verfahren zur Herstellung von stabilen Polymer-Konzentraten
JP4711633B2 (ja) 2003-06-17 2011-06-29 ローム アンド ハース カンパニー ポリマー組成物およびポリマーの調製法
EP1533325B1 (de) * 2003-11-17 2011-10-19 3M Innovative Properties Company Wässrige PTFE-Dispersionen mit einem niedrigen Gehalt an fluorierten Emulgatoren
JPWO2006035726A1 (ja) * 2004-09-27 2008-05-15 ダイキン工業株式会社 ポリテトラフルオロエチレン水性分散液組成物、ポリテトラフルオロエチレン樹脂フィルム及びポリテトラフルオロエチレン樹脂含浸体
US20060135716A1 (en) 2004-12-20 2006-06-22 Ming-Hong Hung Fluoroelastomers having low glass transition temperature
US8765890B2 (en) * 2005-06-10 2014-07-01 Arkema Inc. Aqueous process for making fluoropolymers
US20060281845A1 (en) * 2005-06-10 2006-12-14 Ramin Amin-Sanayei Aqueous process for making fluoropolymers
US7728087B2 (en) * 2005-12-23 2010-06-01 3M Innovative Properties Company Fluoropolymer dispersion and method for making the same

Also Published As

Publication number Publication date
JP5410987B2 (ja) 2014-02-05
ES2379295T3 (es) 2012-04-24
US20070082993A1 (en) 2007-04-12
JP2010512429A (ja) 2010-04-22
EP2089462A4 (de) 2010-01-27
CN101547966B (zh) 2013-07-10
US9068071B2 (en) 2015-06-30
US20130079461A1 (en) 2013-03-28
WO2008073685A1 (en) 2008-06-19
EP2089462B1 (de) 2011-12-21
EP2089462A1 (de) 2009-08-19
US8338518B2 (en) 2012-12-25
CN101547966A (zh) 2009-09-30

Similar Documents

Publication Publication Date Title
EP2089462A4 (de) Wässriges verfahren zur herstellung einer stabilen fluorpolymer-dispersion
ATE535553T1 (de) Wässriges verfahren zur herstellung von fluorpolymeren
DE60112420D1 (de) Verfahren zur herstellung einer wässrigen fluoropolymerdispersion
EA201390249A1 (ru) Связанные полимеры, применяемые для повышения стабильности микроэмульсионных жидкостей
ATE476451T1 (de) Verfahren zur herstellung polyvinylalkoholstabilisierter latices
ATE481362T1 (de) Verfahren zur herstellung von hydrophob modifizierten polymere
DE602007011472D1 (de) Verfahren zur Herstellung von Fluoralkohol, fluoriertes Monomer, Polymer, Resistzusammensetzung und Strukturierungsverfahren
ATE529451T1 (de) Wässrige ptfe-dispersionen mit einem niedrigen gehalt an fluorierten emulgatoren
DE60336400D1 (de) Wässrige Dispersionen von Polytetrafluorethylenteilchen
EP3023230A3 (de) Trennfolie/-schicht, system und verfahren zur verwendung derselben bei der zusatzstoffherstellung
DE602006003981D1 (de) Vinylester Polymerlatex Zusammensetzung und Verfahren zu dessen Herstellung
ATE541869T1 (de) Verfahren zur herstellung von fluorpolymeren
DE60203307D1 (de) Wässrige emulsionspolymerisation in gegenwart von ethern als kettenübertragungsmitteln zur herstellung von fluorpolymeren
ATE555847T1 (de) Verfahren zur herstellung von polyethylen- copolymeren
ATE441679T1 (de) Wässrige kunststoff dispersionen, verfahren zu deren herstellung sowie deren verwendung
MX2017003650A (es) Polimeros de emulsion acuosa finamente divididos y su uso para recubrimientos hidrofobos.
ATE522549T1 (de) Verfahren zur herstellung von polymeren nanopartikeln
ATE431368T1 (de) Blockcopolymere, verfahren zu deren herstellung und ihre verwendung in emulsionen
EP4039246A4 (de) Emulsionszusammensetzung, kosmetische zusammensetzung und verfahren zur herstellung einer emulsionszusammensetzung
ATE407156T1 (de) Verfahren zur herstellung von thermoplastischen fluoropolymeren mittels alkylsulfonate
ATE553254T1 (de) Verfahren zur herstellung von papier
DE60332354D1 (de) Verfahren zur beschichtung eines bautextils mit mindestens einer schicht eines siliconelastomers unter verwendung einer wässrigen siliconemulsion sowie bautextil mit einer derartigen beschichtung
SG11201806520XA (en) Amphiphilic diblock copolymer and use of same for producing polymeric filter membranes
EP4606850A3 (de) Verfahren zur herstellung von polyamid-werkstoffen mit verbesserten langzeitgebrauchseigenschaften
DE502005008386D1 (de) Verfahren zur herstellung von polymeren durch sprühpolymerisation