ATE542836T1 - Verfahren zur herstellung von ethylenpolymeren unter verwendung einer reihe von hintereinander angeordneten reaktoren - Google Patents
Verfahren zur herstellung von ethylenpolymeren unter verwendung einer reihe von hintereinander angeordneten reaktorenInfo
- Publication number
- ATE542836T1 ATE542836T1 AT07727500T AT07727500T ATE542836T1 AT E542836 T1 ATE542836 T1 AT E542836T1 AT 07727500 T AT07727500 T AT 07727500T AT 07727500 T AT07727500 T AT 07727500T AT E542836 T1 ATE542836 T1 AT E542836T1
- Authority
- AT
- Austria
- Prior art keywords
- reactors
- arrange
- sequence
- series
- ethylene polymers
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 229920000573 polyethylene Polymers 0.000 title abstract 2
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- -1 polyethylene Polymers 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/14—Organic medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/22—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of chromium, molybdenum or tungsten
- C08F4/24—Oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06112030A EP1847554A1 (de) | 2006-03-30 | 2006-03-30 | Aufschlämmungsverfahren zum Polymerisieren von Ethylen in Gegenwart einer kleinen Menge von Abfangmittel |
| EP06121494A EP1905785A1 (de) | 2006-09-29 | 2006-09-29 | Verfahren zur Herstellung von Ethylenpolymeren unter Verwendung von einer Anzahl von Reaktoren in Serie |
| PCT/EP2007/053028 WO2007113208A1 (en) | 2006-03-30 | 2007-03-29 | Process for the preparation of ethylene polymers using a number of reactors arranged in series |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE542836T1 true ATE542836T1 (de) | 2012-02-15 |
Family
ID=38068682
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT07727500T ATE542836T1 (de) | 2006-03-30 | 2007-03-29 | Verfahren zur herstellung von ethylenpolymeren unter verwendung einer reihe von hintereinander angeordneten reaktoren |
Country Status (10)
| Country | Link |
|---|---|
| US (4) | US7847042B2 (de) |
| EP (2) | EP1999168B1 (de) |
| JP (2) | JP5237258B2 (de) |
| KR (3) | KR101319786B1 (de) |
| AT (1) | ATE542836T1 (de) |
| DK (2) | DK1999161T3 (de) |
| EA (2) | EA015891B1 (de) |
| ES (2) | ES2404288T3 (de) |
| PT (2) | PT1999161E (de) |
| WO (2) | WO2007113213A1 (de) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5237258B2 (ja) | 2006-03-30 | 2013-07-17 | トタル リサーチ アンド テクノロジー フエリユイ | 直列に配置された複数の反応装置を用いてエチレンのポリマーを製造する方法 |
| KR101084677B1 (ko) * | 2008-05-14 | 2011-11-22 | 주식회사 엘지화학 | 올레핀 중합체의 제조방법 |
| BR112013033155B1 (pt) * | 2011-06-24 | 2020-12-22 | Ineos Europe Ag | Processo de pasta fluida para a polimerização de etileno em um sistema de reator e uso de propano como um diluente e uma concentração de sólidos |
| US9102773B2 (en) * | 2013-02-06 | 2015-08-11 | Exxonmobil Chemical Patents Inc. | Process for controlling molecular weight of polyolefins prepared using pyridyl diamide catalyst systems |
| EP3180367B1 (de) | 2014-08-14 | 2018-04-18 | Basell Polyolefine GmbH | Multireaktoraufschlämmungspolymerisationsverfahren mit hochreinem ethylen |
| CA2868640C (en) * | 2014-10-21 | 2021-10-26 | Nova Chemicals Corporation | Solution polymerization process |
| US10882987B2 (en) | 2019-01-09 | 2021-01-05 | Nova Chemicals (International) S.A. | Ethylene interpolymer products having intermediate branching |
Family Cites Families (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3082195A (en) * | 1959-10-22 | 1963-03-19 | Standard Oil Co | Polymerization process |
| DE2810396A1 (de) * | 1978-03-10 | 1979-09-27 | Huels Chemische Werke Ag | Verfahren zur herstellung von copolymerisaten aus ethylen, mindestens einem anderen 1-monoolefin und gegebenenfalls einem nicht-konjugierten dien |
| DE3723526A1 (de) | 1987-07-16 | 1989-01-26 | Hoechst Ag | Verfahren zur herstellung eines polyolefins mit einer breiten molmassenverteilung |
| US5330947A (en) * | 1991-10-15 | 1994-07-19 | Fina Technology, Inc. | Boron alkyl as co-catalyst to improve polymerization yield and control polydispersity |
| US6545088B1 (en) * | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| BE1006439A3 (fr) | 1992-12-21 | 1994-08-30 | Solvay Societe Annonyme | Procede de preparation d'une composition de polymeres d'ethylene, composition de polymeres d'ethylene et son utilisation. |
| BR9405715A (pt) * | 1993-01-29 | 1995-11-28 | Dow Chemical Co | Processo para preparar um composição de interpolímero de etileno/a-olefina e composição de interpolímero de etileno/a-olefina |
| EP0700464A1 (de) * | 1993-05-25 | 1996-03-13 | Exxon Chemical Patents Inc. | Neue polyolefinfasern und daraus hergestellte flächengebilde |
| US5371145A (en) * | 1993-06-08 | 1994-12-06 | Union Carbide Chemicals & Plastics Technology Corporation | High density, high molecular weight polyethylene |
| BE1007653A3 (fr) * | 1993-10-26 | 1995-09-05 | Fina Research | Procede de production de polyethylene ayant une distribution large de poids moleculaire. |
| US5514455A (en) * | 1994-07-08 | 1996-05-07 | Union Carbide Chemicals & Plastics Technology Corporation | Film extruded from an in situ blend of ethylene copolymers |
| US5763543A (en) * | 1994-09-14 | 1998-06-09 | Exxon Chemical Patents Inc. | Olefin polymerization process with little or no scavenger present |
| FI96216C (fi) * | 1994-12-16 | 1996-05-27 | Borealis Polymers Oy | Prosessi polyeteenin valmistamiseksi |
| BE1011333A3 (fr) * | 1997-08-20 | 1999-07-06 | Solvay | Procede de fabrication d'une composition de polymeres d'ethylene. |
| SE513632C2 (sv) | 1998-07-06 | 2000-10-09 | Borealis Polymers Oy | Multimodal polyetenkomposition för rör |
| KR100430438B1 (ko) * | 1998-10-22 | 2004-07-19 | 대림산업 주식회사 | 담지메탈로센촉매,그제조방법및이를이용한폴리올레핀의중합방법 |
| EP1041090A1 (de) * | 1999-03-29 | 2000-10-04 | Fina Research S.A. | Herstellung von Polyethylen mit breiter Molekulargewichtsverteilung |
| EP1083183A1 (de) * | 1999-09-10 | 2001-03-14 | Fina Research S.A. | Verfahren zur Herstellung von Polyolefinen |
| WO2001032757A1 (en) | 1999-11-04 | 2001-05-10 | Exxonmobil Chemical Patents Inc. | Foamable polypropylene polymers and their use |
| US7041617B2 (en) * | 2004-01-09 | 2006-05-09 | Chevron Phillips Chemical Company, L.P. | Catalyst compositions and polyolefins for extrusion coating applications |
| EP1195388A1 (de) * | 2000-10-04 | 2002-04-10 | ATOFINA Research | Verfahren zur Herstellung von bimodalem Polyethylen |
| EP1201711A1 (de) | 2000-10-27 | 2002-05-02 | ATOFINA Research | Rohre aus Polyethylen und Verfahren zur Herstellung |
| JP2004143289A (ja) * | 2002-10-24 | 2004-05-20 | Asahi Kasei Chemicals Corp | オレフィン重合用触媒およびポリオレフィンの製造方法 |
| US6921804B2 (en) * | 2003-03-25 | 2005-07-26 | Equistar Chemicals L.P. | Cascaded polyolefin slurry polymerization employing disengagement vessel between reactors |
| US6903170B2 (en) | 2003-09-29 | 2005-06-07 | Equistar Chemicals, Lp | Olefin polymerization process using triisobutylaluminum as a scavenger |
| PT1660231E (pt) * | 2004-02-13 | 2007-06-12 | Total Petrochemicals Res Feluy | Método e aparelho para preparar e fornecer suspensão catalítica a um reactor de polimerização. |
| EP1713842B1 (de) * | 2004-02-13 | 2010-11-24 | Total Petrochemicals Research Feluy | Verfahren zur verbesserung der copolymerisation von ethylen und einem olefin-comonomer in einem schlaufenpolymerisationsreaktor |
| EP1563902A1 (de) * | 2004-02-13 | 2005-08-17 | Total Petrochemicals Research Feluy | Verfahren und Vorrichtung zur Herstellung und zur Zufuhr von einem Katalysatorschlamm für einen Polymerisationsreaktor |
| EP1564228A1 (de) * | 2004-02-13 | 2005-08-17 | Total Petrochemicals Research Feluy | Verfahren zur Polymerisation von Olefin mit sequentiellen Ausgabe |
| US8492489B2 (en) * | 2004-02-13 | 2013-07-23 | Total Petrochemicals Research Feluy | Double loop technology |
| ES2262131T3 (es) * | 2004-02-13 | 2006-11-16 | Total Petrochemicals Research Feluy | Tamaño de grano de catalizador. |
| US20050272891A1 (en) * | 2004-02-13 | 2005-12-08 | Atofina Research S.A. | Double loop technology |
| EP1630178A1 (de) * | 2004-08-10 | 2006-03-01 | Innovene Manufacturing Belgium NV | Polymerisationsverfahren |
| JP4705702B2 (ja) * | 2004-11-09 | 2011-06-22 | 日本ポリエチレン株式会社 | エチレン系共重合体の製造方法及びエチレン系共重合体並びに成形品 |
| BRPI0517210B1 (pt) * | 2004-12-17 | 2017-01-24 | Dow Global Technologies Inc | composição adequada para tubos, composição adequada para películas sopradas, composição adequada para artigos moldados soprados, tubo, película, artigo moldado por sopro e método para melhorar o comportamento de fluxo de fluência de uma resina |
| EP1905785A1 (de) | 2006-09-29 | 2008-04-02 | Total Petrochemicals Research Feluy | Verfahren zur Herstellung von Ethylenpolymeren unter Verwendung von einer Anzahl von Reaktoren in Serie |
| JP5237258B2 (ja) * | 2006-03-30 | 2013-07-17 | トタル リサーチ アンド テクノロジー フエリユイ | 直列に配置された複数の反応装置を用いてエチレンのポリマーを製造する方法 |
| EP1847554A1 (de) | 2006-03-30 | 2007-10-24 | Total Petrochemicals Research Feluy | Aufschlämmungsverfahren zum Polymerisieren von Ethylen in Gegenwart einer kleinen Menge von Abfangmittel |
| EP1842861A1 (de) * | 2006-04-03 | 2007-10-10 | Total Petrochemicals Research Feluy | Verfahren zur Verbesserung der Polymerisation von Ethen und einem oder mehreren optionalen Comonomer(en) in einem Schlaufenreaktor |
| EP2033976A1 (de) * | 2007-09-03 | 2009-03-11 | INEOS Manufacturing Belgium NV | Polymerisationsprozess in der Schlammphase |
| US20100125124A1 (en) * | 2008-11-17 | 2010-05-20 | Fina Technology, Inc. | Methods of catalyst activation |
| RU2522439C2 (ru) * | 2009-02-27 | 2014-07-10 | Базелль Полиолефине Гмбх | Многостадийный способ полимеризации этилена |
-
2007
- 2007-03-29 JP JP2009502090A patent/JP5237258B2/ja not_active Expired - Fee Related
- 2007-03-29 US US12/295,253 patent/US7847042B2/en active Active
- 2007-03-29 KR KR1020087023750A patent/KR101319786B1/ko active Active
- 2007-03-29 EA EA200802091A patent/EA015891B1/ru not_active IP Right Cessation
- 2007-03-29 DK DK07727516.2T patent/DK1999161T3/da active
- 2007-03-29 ES ES07727516T patent/ES2404288T3/es active Active
- 2007-03-29 EA EA200802092A patent/EA014355B1/ru not_active IP Right Cessation
- 2007-03-29 WO PCT/EP2007/053044 patent/WO2007113213A1/en not_active Ceased
- 2007-03-29 DK DK07727500.6T patent/DK1999168T3/da active
- 2007-03-29 PT PT77275162T patent/PT1999161E/pt unknown
- 2007-03-29 KR KR1020087022395A patent/KR101258102B1/ko active Active
- 2007-03-29 US US12/295,249 patent/US9447206B2/en active Active
- 2007-03-29 KR KR1020127032663A patent/KR20130008644A/ko not_active Ceased
- 2007-03-29 JP JP2009502096A patent/JP5296670B2/ja not_active Expired - Fee Related
- 2007-03-29 PT PT07727500T patent/PT1999168E/pt unknown
- 2007-03-29 EP EP07727500A patent/EP1999168B1/de not_active Revoked
- 2007-03-29 EP EP07727516A patent/EP1999161B1/de not_active Revoked
- 2007-03-29 AT AT07727500T patent/ATE542836T1/de active
- 2007-03-29 ES ES07727500T patent/ES2378784T3/es active Active
- 2007-03-29 WO PCT/EP2007/053028 patent/WO2007113208A1/en not_active Ceased
-
2016
- 2016-08-16 US US15/237,705 patent/US10259898B2/en active Active
-
2019
- 2019-03-04 US US16/291,354 patent/US10995168B2/en active Active
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