ATE547484T2 - Verfahren zur herstellung von hochfesten suspensionen aus mineralmaterialien - Google Patents

Verfahren zur herstellung von hochfesten suspensionen aus mineralmaterialien Download PDF

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Publication number
ATE547484T2
ATE547484T2 AT10164211T AT10164211T ATE547484T2 AT E547484 T2 ATE547484 T2 AT E547484T2 AT 10164211 T AT10164211 T AT 10164211T AT 10164211 T AT10164211 T AT 10164211T AT E547484 T2 ATE547484 T2 AT E547484T2
Authority
AT
Austria
Prior art keywords
mineral materials
aqueous suspension
producing high
suspensions
mineral
Prior art date
Application number
AT10164211T
Other languages
English (en)
Inventor
Matthias Buri
Patrick A C Gane
Original Assignee
Omya Development Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=42752435&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE547484(T2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Omya Development Ag filed Critical Omya Development Ag
Application granted granted Critical
Publication of ATE547484T2 publication Critical patent/ATE547484T2/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/45—Anti-settling agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/02—Compounds of alkaline earth metals or magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/02—Compounds of alkaline earth metals or magnesium
    • C09C1/021—Calcium carbonates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/02—Compounds of alkaline earth metals or magnesium
    • C09C1/028—Compounds containing only magnesium as metal
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/40—Compounds of aluminium
    • C09C1/42—Clays
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/04—Physical treatment, e.g. grinding or treatment with ultrasonic vibrations
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Paper (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Paints Or Removers (AREA)
  • Physical Water Treatments (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Disintegrating Or Milling (AREA)
  • Fertilizers (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
AT10164211T 2010-05-28 2010-05-28 Verfahren zur herstellung von hochfesten suspensionen aus mineralmaterialien ATE547484T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP10164211.4A EP2390284B2 (de) 2010-05-28 2010-05-28 Verfahren zur Herstellung von hochfesten Suspensionen aus Mineralmaterialien

Publications (1)

Publication Number Publication Date
ATE547484T2 true ATE547484T2 (de) 2012-03-15

Family

ID=42752435

Family Applications (1)

Application Number Title Priority Date Filing Date
AT10164211T ATE547484T2 (de) 2010-05-28 2010-05-28 Verfahren zur herstellung von hochfesten suspensionen aus mineralmaterialien

Country Status (24)

Country Link
US (2) US8721838B2 (de)
EP (2) EP2390284B2 (de)
JP (1) JP6085556B2 (de)
KR (1) KR101856794B1 (de)
CN (1) CN102985495B (de)
AT (1) ATE547484T2 (de)
AU (1) AU2011257220B2 (de)
BR (1) BR112012030165B1 (de)
CA (1) CA2799646C (de)
CL (1) CL2012003312A1 (de)
DK (1) DK2390284T4 (de)
ES (2) ES2383589T5 (de)
HR (2) HRP20180932T1 (de)
IL (1) IL223132A (de)
MX (1) MX2012013588A (de)
NZ (1) NZ603706A (de)
PL (1) PL2390284T5 (de)
PT (1) PT2390284E (de)
RU (1) RU2572976C2 (de)
SI (3) SI2390284T2 (de)
TR (1) TR201808780T4 (de)
TW (1) TWI554574B (de)
WO (1) WO2011147922A1 (de)
ZA (1) ZA201208714B (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101740419B1 (ko) 2008-07-18 2017-05-26 지알티, 인코포레이티드 천연 가스를 액체 탄화수소로 변환시키는 연속 공정
EP2390284B2 (de) 2010-05-28 2017-03-15 Omya International AG Verfahren zur Herstellung von hochfesten Suspensionen aus Mineralmaterialien
SI2623467T1 (sl) * 2012-02-03 2016-08-31 Omya International Ag Postopek za pripravo vodne raztopine, ki vsebuje vsaj en zemeljsko alkalijski hidrogenkarbonat in njegova uporaba
ES2550854T3 (es) 2012-06-28 2015-11-12 Omya International Ag Suspensión acuosa con alto contenido en sólidos de pigmentos y/o material de relleno y/o minerales en un entorno de pH acídico
BR112015000173B1 (pt) 2012-07-12 2021-07-27 Akzo Nobel Chemicals International B.V. Processo de cristalização evaporativa para obter composições do sal cloreto de sódio
FI126260B (en) * 2013-05-20 2016-09-15 Kemira Oyj Antifouling mixture and its use
CN103525130A (zh) * 2013-10-16 2014-01-22 上海东升新材料有限公司 窄粒径重钙的制备方法
US10647143B2 (en) 2014-05-26 2020-05-12 Omya International Ag Calcium carbonate for rotogravure printing medium
RS55981B1 (sr) 2014-05-26 2017-09-29 Omya Int Ag Postupak za pripremu mrvica koje sadrže kalcijum karbonat
EP3002318A1 (de) * 2014-09-30 2016-04-06 Omya International AG Verfahren zur Verbesserung der Partikelgrößenverteilung von calciumcarbonathaltigem Material
ES2672208T3 (es) * 2014-11-07 2018-06-13 Omya International Ag Método de fabricación de una suspensión que comprende un material que comprende carbonato de calcio
CN105821703B (zh) * 2016-03-28 2017-12-19 东升新材料（山东）有限公司 一种特种纸专用复合填料的制备方法
FR3073219B1 (fr) * 2017-11-09 2021-11-12 Coatex Sas Preparation d'une suspension aqueuse de materiau phosphate
CN112982014A (zh) * 2021-04-26 2021-06-18 刘小建 滤纸用抗菌填料及其制备方法
WO2023052516A1 (en) * 2021-09-30 2023-04-06 Omya International Ag Process for preparing a wet ground mineral material

Family Cites Families (32)

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FR2488814A1 (fr) 1980-08-21 1982-02-26 Coatex Sa Agent de broyage pour suspension aqueuse de materiaux mineraux en vue d'applications pigmentaires
FR2531444A1 (fr) 1982-08-06 1984-02-10 Coatex Sa Agent de broyage a base de polymeres et/ou copolymeres acryliques pour suspension aqueuse de materiaux mineraux grossiers en vue d'applications pigmentaires
FR2539137A1 (fr) 1982-08-06 1984-07-13 Coatex Sa Agent de broyage a base de polymeres et/ou copolymeres acryliques neutralises pour suspension aqueuse de materiaux mineraux grossiers en vue d'applications pigmentaires
DE3275717D1 (en) 1982-11-10 1987-04-23 Allied Colloids Ltd Calcium carbonate dispersions
DE3479223D1 (en) 1983-05-20 1989-09-07 Allied Colloids Ltd Water soluble polymers and dispersions containing them
US4738718A (en) * 1985-10-28 1988-04-19 Freeport Minerals Company Method for the recovery of gold using autoclaving
FR2603042B1 (fr) 1986-08-22 1988-11-10 Coatex Sa Compositions pigmentaires complexes pour l'enduction du papier
DE4004953C3 (de) 1990-02-19 1998-01-29 Stockhausen Chem Fab Gmbh Verfahren zur Herstellung von neutralisierten Polyacrylsäuren und ihre Verwendung als Mahl- und Dispergierhilfsmittel
DK0548086T3 (de) 1990-06-29 1997-03-10 Ecc Int Inc
CA2080961C (fr) 1991-11-12 2002-04-02 Jean-Bernard Egraz Agent de broyage et/ou de dispersion a base de polymeres et/ou copolymeres neutralises en partie par du magnesium pour suspensions aqueuses de materiaux mineraux en vue d'applications pigmentaires
ES2113933T3 (es) 1991-11-12 1998-05-16 Coatex Sa Agente de trituracion y/o dispersion a base de polimeros y/o copolimeros neutralizados parcialmente por magnesio para suspensiones acuosas de materiales minerales para la aplicacion de pigmentos.
GB2275876B (en) * 1993-03-12 1996-07-17 Ecc Int Ltd Grinding alkaline earth metal pigments
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FR2728182B1 (fr) 1994-12-16 1997-01-24 Coatex Sa Procede d'obtention d'agents de broyage et/ou de dispersion par separation physico-chimique, agents obtenus et leurs utilisations
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GB9627002D0 (en) 1996-12-27 1997-02-12 Ecc Int Ltd Dispersed aqueous suspensions
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GB0221632D0 (en) * 2002-09-17 2002-10-30 Imerys Minerals Ltd Grinding method
JP4328521B2 (ja) * 2002-12-10 2009-09-09 奥多摩工業株式会社 炭酸カルシウム高濃度スラリーの製造方法
DE10311617A1 (de) * 2003-03-14 2004-09-23 Basf Ag Verwendung von Polyacrylsäuren als Mahlhilfsmittel für Calciumcarbonat
EP1752499A1 (de) * 2005-07-25 2007-02-14 Omya Development AG Verfahren zur Dispergieren und oder Zerkleinern und oder Konzentrieren von Calcium Carbonat in wässrigem Medium, mittels einer wässrigen Lösung enthaltend Zirkonienverbindungen.
FR2894846B1 (fr) 2005-12-20 2008-02-01 Coatex Sas Utilisation de dispersants pour concentrer des matieres minerales dans l'eau, dispersions obtenues et leurs utilisations.
PT1993515E (pt) 2006-03-10 2009-11-05 Laboswiss Ag Um método para solubilização, dispersão e estabilização de compostos, produtos obtidos por esse método, assim como a sua utilização
FR2903618B1 (fr) 2006-07-12 2008-10-31 Coatex Sas Agent de dispersion et/ou d'aide au broyage pour dispersion et suspension aqueuse de matieres minerales, dispersion et suspension obtenues et leurs utilisations.
JP5113784B2 (ja) 2008-03-31 2013-01-09 ローム アンド ハース カンパニー （メタ）アクリル酸のホモポリマーおよび／またはコポリマーを含む分散剤を使用して水性分散物中で鉱物を粉砕する方法
PT2143688T (pt) * 2008-07-07 2016-12-09 Omya Int Ag Processo de fabrico de suspensões aquosas de carbonato de cálcio e suspensões obtidas assim como as suas utilizações
EP2194103A1 (de) * 2008-12-04 2010-06-09 Omya Development Ag Verfahren zur Herstellung von Calciumcarbonatmaterialien mit einer Teilchenoberfläche mit verbesserten Adsorptionseigenschaften
EP2390284B2 (de) 2010-05-28 2017-03-15 Omya International AG Verfahren zur Herstellung von hochfesten Suspensionen aus Mineralmaterialien

Also Published As

Publication number Publication date
WO2011147922A1 (en) 2011-12-01
TW201141963A (en) 2011-12-01
JP6085556B2 (ja) 2017-02-22
CA2799646C (en) 2018-01-16
EP2390284B2 (de) 2017-03-15
JP2013528240A (ja) 2013-07-08
KR101856794B1 (ko) 2018-05-10
EP2390284A1 (de) 2011-11-30
US9243121B2 (en) 2016-01-26
RU2012157778A (ru) 2014-07-10
AU2011257220A1 (en) 2012-12-13
CN102985495A (zh) 2013-03-20
EP2576704A1 (de) 2013-04-10
ES2383589T3 (es) 2012-06-22
EP2576704B1 (de) 2018-04-18
DK2390284T3 (da) 2012-06-18
US20140213711A1 (en) 2014-07-31
PL2390284T3 (pl) 2012-08-31
HRP20120435T4 (hr) 2017-06-16
EP2390284B1 (de) 2012-02-29
BR112012030165B1 (pt) 2021-01-19
BR112012030165A8 (pt) 2018-01-02
US20130174994A1 (en) 2013-07-11
SI2390284T2 (sl) 2017-07-31
AU2011257220B2 (en) 2015-01-22
CN102985495B (zh) 2016-05-11
IL223132A0 (en) 2013-02-03
SI2576704T1 (en) 2018-08-31
RU2572976C2 (ru) 2016-01-20
CA2799646A1 (en) 2011-12-01
NZ603706A (en) 2015-02-27
HRP20180932T1 (hr) 2018-08-24
MX2012013588A (es) 2012-12-17
BR112012030165A2 (pt) 2016-09-06
ES2383589T5 (es) 2017-08-28
IL223132A (en) 2017-02-28
HRP20120435T1 (en) 2012-06-30
ES2673723T3 (es) 2018-06-25
US8721838B2 (en) 2014-05-13
ZA201208714B (en) 2014-01-29
TWI554574B (zh) 2016-10-21
SI2390284T1 (sl) 2012-07-31
PL2390284T5 (pl) 2017-10-31
TR201808780T4 (tr) 2018-07-23
DK2390284T4 (en) 2017-06-19
CL2012003312A1 (es) 2013-06-28
KR20130083394A (ko) 2013-07-22
PT2390284E (pt) 2012-06-01

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