ATE551296T1 - Feinkristalliner zsm-5 zeolith und seine anwendung - Google Patents
Feinkristalliner zsm-5 zeolith und seine anwendungInfo
- Publication number
- ATE551296T1 ATE551296T1 AT99965748T AT99965748T ATE551296T1 AT E551296 T1 ATE551296 T1 AT E551296T1 AT 99965748 T AT99965748 T AT 99965748T AT 99965748 T AT99965748 T AT 99965748T AT E551296 T1 ATE551296 T1 AT E551296T1
- Authority
- AT
- Austria
- Prior art keywords
- zeolite
- application
- fine crystalline
- crystalline zsm
- zsm
- Prior art date
Links
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000002178 crystalline material Substances 0.000 abstract 1
- 238000006317 isomerization reaction Methods 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 238000002429 nitrogen sorption measurement Methods 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C01B39/38—Type ZSM-5
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C01B39/38—Type ZSM-5
- C01B39/40—Type ZSM-5 using at least one organic template directing agent
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
- C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
- C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/218,191 US6180550B1 (en) | 1998-12-22 | 1998-12-22 | Small crystal ZSM-5, its synthesis and use |
| PCT/US1999/025888 WO2000037398A1 (en) | 1998-12-22 | 1999-11-04 | Small crystal zsm-5, its synthesis and use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE551296T1 true ATE551296T1 (de) | 2012-04-15 |
Family
ID=22814103
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT99965748T ATE551296T1 (de) | 1998-12-22 | 1999-11-04 | Feinkristalliner zsm-5 zeolith und seine anwendung |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US6180550B1 (de) |
| EP (1) | EP1140740B1 (de) |
| JP (1) | JP4782285B2 (de) |
| AT (1) | ATE551296T1 (de) |
| AU (1) | AU2144800A (de) |
| WO (1) | WO2000037398A1 (de) |
| ZA (1) | ZA200105001B (de) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6180550B1 (en) * | 1998-12-22 | 2001-01-30 | Mobile Oil Corporation | Small crystal ZSM-5, its synthesis and use |
| US6667023B2 (en) | 2002-03-01 | 2003-12-23 | Akzo Nobel N.V. | Preparation of MFI type crystalline zeolitic aluminosilicate |
| US7132042B2 (en) * | 2002-10-08 | 2006-11-07 | Exxonmobil Research And Engineering Company | Production of fuels and lube oils from fischer-tropsch wax |
| US7344631B2 (en) | 2002-10-08 | 2008-03-18 | Exxonmobil Research And Engineering Company | Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product |
| US20040065584A1 (en) * | 2002-10-08 | 2004-04-08 | Bishop Adeana Richelle | Heavy lube oil from fischer- tropsch wax |
| US7201838B2 (en) * | 2002-10-08 | 2007-04-10 | Exxonmobil Research And Engineering Company | Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product |
| US6846778B2 (en) * | 2002-10-08 | 2005-01-25 | Exxonmobil Research And Engineering Company | Synthetic isoparaffinic premium heavy lubricant base stock |
| WO2004058643A1 (en) * | 2002-12-30 | 2004-07-15 | Sk Corporation | Method of preparing zsm-5 using variable temperature without organic template |
| US7411103B2 (en) * | 2003-11-06 | 2008-08-12 | Haldor Topsoe A/S | Process for the catalytic isomerisation of aromatic compounds |
| US8993468B2 (en) * | 2007-05-24 | 2015-03-31 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolites |
| US9221723B2 (en) * | 2007-05-24 | 2015-12-29 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation-1 |
| WO2008153759A2 (en) | 2007-05-24 | 2008-12-18 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof-bimetallic deposition |
| US8969232B2 (en) * | 2007-05-24 | 2015-03-03 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation 2 |
| JP5354976B2 (ja) * | 2007-10-23 | 2013-11-27 | 出光興産株式会社 | 軽質オレフィン類製造用触媒及び軽質オレフィン類の製造方法 |
| WO2009054306A1 (ja) * | 2007-10-23 | 2009-04-30 | Idemitsu Kosan Co., Ltd. | 軽質オレフィン類製造用触媒及び軽質オレフィン類の製造方法 |
| SG188172A1 (en) * | 2008-02-22 | 2013-03-28 | Exxonmobil Chem Patents Inc | High metal content molecular sieves and their manufacture |
| SG188173A1 (en) * | 2008-02-22 | 2013-03-28 | Exxonmobil Chem Patents Inc | Large crystal molecular sieves and their manufacture |
| JP5588972B2 (ja) * | 2008-06-06 | 2014-09-10 | トタル リサーチ アンド テクノロジー フエリユイ | 結晶質メタロシリケートの製造方法 |
| US20110117007A1 (en) * | 2009-11-13 | 2011-05-19 | Chervon U.S.A. Inc. | Method for making mfi-type molecular sieves |
| CN102791375B (zh) | 2010-03-08 | 2014-12-24 | 陶氏环球技术有限责任公司 | 用于将乙醇直接转化为丙烯的催化剂组合物 |
| US8575055B2 (en) | 2010-03-30 | 2013-11-05 | Uop Llc | Surface-modified zeolites and methods for preparing the same |
| WO2011133326A2 (en) * | 2010-04-21 | 2011-10-27 | Exxonmobil Chemical Patents Inc. | Xylenes isomerization process and catalyst therefor |
| US20110282122A1 (en) * | 2010-05-14 | 2011-11-17 | Uop, Llc | Molecular sieve, catalyst, and/or a process relating thereto |
| US20130085311A1 (en) * | 2011-09-29 | 2013-04-04 | Honam Petrochemical Corporation | Zsm-5 catalyst with micropores and mesopores, preparation method thereof and production method of light olefins through catalytic cracking of hydrocarbons using the catalyst |
| US9193645B2 (en) | 2012-08-31 | 2015-11-24 | Exxonmobil Chemical Patents Inc. | Xylene isomerization process and catalyst therefor |
| US9309169B2 (en) | 2012-11-30 | 2016-04-12 | Exxonmobil Chemical Patents Inc. | Process for the production of purified xylene isomers |
| EP2925710A4 (de) | 2012-11-30 | 2016-05-11 | Exxonmobil Chem Patents Inc | Energieeffiziente verfahren zur xylenherstellung |
| CA2891025C (en) * | 2012-12-07 | 2019-07-30 | Exxonmobil Research And Engineering Company | Synthesis of zsm-5 crystals with improved morphology |
| WO2014146128A1 (en) * | 2013-03-15 | 2014-09-18 | The Coca-Cola Company | Mesoporous mfi-zeolite catalysts, methods of preparing the same and uses |
| CN112264086A (zh) * | 2013-04-29 | 2021-01-26 | 沙特基础工业公司 | 石脑油转化成烯烃的催化方法 |
| JP6398448B2 (ja) | 2013-08-30 | 2018-10-03 | 東ソー株式会社 | ペンタシル型ゼオライト及びその製造方法 |
| CN104512908B (zh) * | 2013-09-26 | 2017-02-08 | 天津神能科技有限公司 | 一种小晶粒zsm‑5沸石分子筛的合成方法 |
| EP3071326B1 (de) | 2013-11-22 | 2022-08-24 | Saudi Basic Industries Corporation | Katalysator mit verbesserter/aktivität selektivität für aromatisierung von leichtem naphtha |
| FR3024662B1 (fr) * | 2014-08-05 | 2016-12-09 | Ifp Energies Now | Procede de separation du meta-xylene utilisant un adsorbant zeolithique a haute surface externe |
| US10626019B2 (en) * | 2014-12-30 | 2020-04-21 | W. R. Grace & Co.-Conn. | Methods for preparing zeolites with surfactant-templated mesoporosity and tunable aluminum content |
| US9688587B2 (en) | 2015-03-03 | 2017-06-27 | Uop Llc | Process for oxygenate to olefin conversion using 2-D pentasil zeolite |
| US9890094B2 (en) | 2015-03-03 | 2018-02-13 | Uop Llc | High meso-surface area and high acid site density pentasil zeolite for use in xylene conversion |
| US10010878B2 (en) | 2015-03-03 | 2018-07-03 | Uop Llc | High meso-surface area, low Si/Al ratio pentasil zeolite |
| US9643897B2 (en) | 2015-03-03 | 2017-05-09 | Uop Llc | Enhanced propylene production in OTO process with modified zeolites |
| US10336665B2 (en) | 2015-03-03 | 2019-07-02 | Uop Llc | Yields in xylene isomerization using layer MFI zeolites |
| CN106629768A (zh) * | 2015-11-02 | 2017-05-10 | 中国石油化工股份有限公司 | 均匀纳米zsm-5分子筛合成方法 |
| SG11201805226QA (en) | 2016-04-14 | 2018-07-30 | Uop Llc | Liquid phase xylene isomerization in the absence of hydrogen |
| CN112930323B (zh) | 2018-10-25 | 2023-12-15 | 东曹株式会社 | Pentasil型沸石和其制造方法 |
| CN109721077B (zh) * | 2018-12-24 | 2022-06-14 | 大连理工大学 | 一种薄片状Fe-ZSM-5沸石分子筛及其制备方法 |
| CN114286808B (zh) | 2019-08-23 | 2025-04-01 | 埃克森美孚化学专利公司 | 异构化c8芳族烃的方法 |
| US20220289645A1 (en) | 2019-08-23 | 2022-09-15 | Exxonmobil Chemical Patents Inc. | Processes for Isomerizing C8 Aromatic Hydrocarbons Using Serial Reactors |
| FR3104577B1 (fr) | 2019-12-17 | 2021-12-31 | Ifp Energies Now | Dispositif et procédé de conversion de composés aromatiques par alkylation de toluène par du CO |
| FR3104573B1 (fr) | 2019-12-17 | 2021-12-31 | Ifp Energies Now | Dispositif et procédé de conversion de composés aromatiques par alkylation de toluène par du méthanol |
| FR3104571B1 (fr) | 2019-12-17 | 2021-12-31 | Ifp Energies Now | Dispositif et procédé de conversion de composés aromatiques par alkylation de toluène par du CO pour production de paratolualdéhyde |
| FR3104572B1 (fr) | 2019-12-17 | 2021-12-31 | Ifp Energies Now | Conversion de composés aromatiques par alkylation de toluène par du CO et de benzène par l’éthanol pour production de paratolualdéhyde |
| FR3104579B1 (fr) | 2019-12-17 | 2021-12-31 | Ifp Energies Now | Dispositif et procédé de conversion de composés aromatiques par alkylation de benzène par de l’éthylène |
| FR3104576B1 (fr) | 2019-12-17 | 2021-12-31 | Ifp Energies Now | Dispositif et procédé de conversion de composés aromatiques par alkylation de benzène par l’éthanol |
| FR3104574B1 (fr) | 2019-12-17 | 2021-12-31 | Ifp Energies Now | Dispositif et procédé de conversion de composés aromatiques par alkylation de toluène par du CO et de benzène par l’éthanol |
| FR3104575B1 (fr) | 2019-12-17 | 2021-12-31 | Ifp Energies Now | Dispositif et procédé de conversion de composés aromatiques par alkylation de benzène par du CO |
| FR3112774B1 (fr) | 2020-07-27 | 2023-06-02 | Ifp Energies Now | Dispositif et procédé de production d’aromatiques par pyrolyse de biomasse et conversion de gaz à l'eau inversée. |
| FR3112773B1 (fr) | 2020-07-27 | 2023-06-02 | Ifp Energies Now | Dispositif et procédé de production d’aromatiques à partir d’un gaz de pyrolyse de biomasse |
| CN113184876B (zh) * | 2021-07-05 | 2021-09-17 | 山东国瓷功能材料股份有限公司 | 用于吸音材料的zsm-5分子筛、其制备方法及所得产品 |
| FR3126977A1 (fr) | 2021-09-10 | 2023-03-17 | IFP Energies Nouvelles | Combustion en boucle chimique de composés hydrocarbonés riches en oxygène pour la production de xylènes. |
| FR3126976A1 (fr) | 2021-09-10 | 2023-03-17 | IFP Energies Nouvelles | Oxycombustion de composés hydrocarbonés riches en oxygène pour la production de xylènes. |
| FR3130833B1 (fr) | 2021-12-21 | 2024-10-11 | Ifp Energies Now | Unité de production et de séparation des aromatiques avec valorisation d’un extrait et/ou d’un raffinat provenant d’un procédé d’extraction liquide-liquide |
| FR3143029A1 (fr) | 2022-12-13 | 2024-06-14 | IFP Energies Nouvelles | Procédé et dispositif de production d’aromatiques et de monoéthylène glycol à partir d’un gaz de pyrolyse de biomasse |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3702886A (en) | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
| US3926782A (en) | 1973-02-09 | 1975-12-16 | Mobil Oil Corp | Hydrocarbon conversion |
| US3968024A (en) * | 1973-07-06 | 1976-07-06 | Mobil Oil Corporation | Catalytic hydrodewaxing |
| CA1040187A (en) | 1973-09-07 | 1978-10-10 | Mobil Oil Corporation | Method of preparing a crystalline aluminosilicate zeolite |
| US4060568A (en) * | 1976-03-31 | 1977-11-29 | Mobil Oil Corporation | Silica-modified zeolite catalyst and conversion therewith |
| US4526879A (en) * | 1978-11-13 | 1985-07-02 | Mobil Oil Corporation | Synthesis of zeolite ZSM-5 |
| US4379027A (en) * | 1981-12-24 | 1983-04-05 | Mobil Oil Corporation | Selective hydrogenation of vinyltoluene |
| JPS58145616A (ja) * | 1982-02-22 | 1983-08-30 | Teijin Yuka Kk | 新規結晶性アルミノシリケ−トゼオライト及びその製造法 |
| DK164097C (da) | 1982-09-20 | 1992-10-05 | Tosoh Corp | Fremgangsmaade til fremstilling af zeoliter |
| EP0106652B1 (de) | 1982-10-13 | 1988-01-27 | Sumitomo Pharmaceuticals Company, Limited | Beta-Lactam-Verbindungen und ihre Herstellung |
| US4845063A (en) * | 1982-10-15 | 1989-07-04 | Mobil Oil Corporation | Zeolite catalyst of improved hydrothermal stability |
| US4678766A (en) * | 1983-10-19 | 1987-07-07 | Mobil Oil Corporation | Enhancement of shape selectivity of zeolites |
| JPS60248630A (ja) * | 1984-05-24 | 1985-12-09 | Agency Of Ind Science & Technol | 低級オレフインの製造方法 |
| US4899011A (en) * | 1986-01-15 | 1990-02-06 | Mobil Oil Corporation | Xylene isomerization process to exhaustively convert ethylbenzene and non-aromatics |
| US4773987A (en) * | 1986-06-13 | 1988-09-27 | Mobil Oil Corporation | Shape-selective conversion of organic feedstock using clathrate group tectosilicates |
| US4754096A (en) * | 1987-07-13 | 1988-06-28 | Mobil Oil Corporation | Production of high viscosity index lubricating oils from lower olefins |
| NZ225813A (en) | 1987-09-02 | 1990-11-27 | Mobil Oil Corp | Zsm-5 in crystal form having specific dimensions, and preparation thereof |
| US5240892A (en) * | 1987-09-02 | 1993-08-31 | Mobil Oil Corporation | Small crystal ZSM-5, as a catalyst |
| DE3868194D1 (de) * | 1987-09-02 | 1992-03-12 | Mobil Oil Corp | Verfahren zur transalkylierung von (polyalkyl)aromatischen kohlenwasserstoffen. |
| US4851604A (en) * | 1987-09-02 | 1989-07-25 | Mobil Oil Corp. | Toluene disproportionation |
| US5271920A (en) * | 1988-11-21 | 1993-12-21 | Mobil Oil Corporation | Activation of zeolites |
| US5369071A (en) | 1992-12-11 | 1994-11-29 | Mobil Oil Corporation | Manufacture of improved catalyst |
| US5365003A (en) * | 1993-02-25 | 1994-11-15 | Mobil Oil Corp. | Shape selective conversion of hydrocarbons over extrusion-modified molecular sieve |
| US5705726A (en) * | 1994-11-18 | 1998-01-06 | Mobil Oil Corporation | Xylene isomerization on separate reactors |
| US5888378A (en) * | 1997-03-18 | 1999-03-30 | Mobile Oil Corporation | Catalytic cracking process |
| US6180550B1 (en) * | 1998-12-22 | 2001-01-30 | Mobile Oil Corporation | Small crystal ZSM-5, its synthesis and use |
-
1998
- 1998-12-22 US US09/218,191 patent/US6180550B1/en not_active Expired - Lifetime
-
1999
- 1999-11-04 AU AU21448/00A patent/AU2144800A/en not_active Abandoned
- 1999-11-04 AT AT99965748T patent/ATE551296T1/de active
- 1999-11-04 EP EP99965748A patent/EP1140740B1/de not_active Expired - Lifetime
- 1999-11-04 WO PCT/US1999/025888 patent/WO2000037398A1/en not_active Ceased
- 1999-11-04 JP JP2000589472A patent/JP4782285B2/ja not_active Expired - Lifetime
-
2001
- 2001-01-22 US US09/767,183 patent/US6504075B2/en not_active Expired - Lifetime
- 2001-06-19 ZA ZA200105001A patent/ZA200105001B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2002535222A (ja) | 2002-10-22 |
| EP1140740A1 (de) | 2001-10-10 |
| AU2144800A (en) | 2000-07-12 |
| ZA200105001B (en) | 2002-07-19 |
| JP4782285B2 (ja) | 2011-09-28 |
| US6180550B1 (en) | 2001-01-30 |
| WO2000037398A1 (en) | 2000-06-29 |
| EP1140740A4 (de) | 2008-04-09 |
| US20010024635A1 (en) | 2001-09-27 |
| US6504075B2 (en) | 2003-01-07 |
| EP1140740B1 (de) | 2012-03-28 |
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