ATE551296T1 - Feinkristalliner zsm-5 zeolith und seine anwendung - Google Patents

Feinkristalliner zsm-5 zeolith und seine anwendung

Info

Publication number
ATE551296T1
ATE551296T1 AT99965748T AT99965748T ATE551296T1 AT E551296 T1 ATE551296 T1 AT E551296T1 AT 99965748 T AT99965748 T AT 99965748T AT 99965748 T AT99965748 T AT 99965748T AT E551296 T1 ATE551296 T1 AT E551296T1
Authority
AT
Austria
Prior art keywords
zeolite
application
fine crystalline
crystalline zsm
zsm
Prior art date
Application number
AT99965748T
Other languages
English (en)
Inventor
Jeffrey Beck
Carrie Kennedy
Wieslaw Roth
David Stern
Original Assignee
Exxonmobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Oil Corp filed Critical Exxonmobil Oil Corp
Application granted granted Critical
Publication of ATE551296T1 publication Critical patent/ATE551296T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
AT99965748T 1998-12-22 1999-11-04 Feinkristalliner zsm-5 zeolith und seine anwendung ATE551296T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/218,191 US6180550B1 (en) 1998-12-22 1998-12-22 Small crystal ZSM-5, its synthesis and use
PCT/US1999/025888 WO2000037398A1 (en) 1998-12-22 1999-11-04 Small crystal zsm-5, its synthesis and use

Publications (1)

Publication Number Publication Date
ATE551296T1 true ATE551296T1 (de) 2012-04-15

Family

ID=22814103

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99965748T ATE551296T1 (de) 1998-12-22 1999-11-04 Feinkristalliner zsm-5 zeolith und seine anwendung

Country Status (7)

Country Link
US (2) US6180550B1 (de)
EP (1) EP1140740B1 (de)
JP (1) JP4782285B2 (de)
AT (1) ATE551296T1 (de)
AU (1) AU2144800A (de)
WO (1) WO2000037398A1 (de)
ZA (1) ZA200105001B (de)

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US7132042B2 (en) * 2002-10-08 2006-11-07 Exxonmobil Research And Engineering Company Production of fuels and lube oils from fischer-tropsch wax
US20040065584A1 (en) * 2002-10-08 2004-04-08 Bishop Adeana Richelle Heavy lube oil from fischer- tropsch wax
US6846778B2 (en) * 2002-10-08 2005-01-25 Exxonmobil Research And Engineering Company Synthetic isoparaffinic premium heavy lubricant base stock
US7201838B2 (en) * 2002-10-08 2007-04-10 Exxonmobil Research And Engineering Company Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product
US7344631B2 (en) 2002-10-08 2008-03-18 Exxonmobil Research And Engineering Company Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product
AU2003286975A1 (en) * 2002-12-30 2004-07-22 Sk Corporation Method of preparing zsm-5 using variable temperature without organic template
US7411103B2 (en) * 2003-11-06 2008-08-12 Haldor Topsoe A/S Process for the catalytic isomerisation of aromatic compounds
US9221723B2 (en) * 2007-05-24 2015-12-29 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation-1
US8993468B2 (en) * 2007-05-24 2015-03-31 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolites
US9233884B2 (en) 2007-05-24 2016-01-12 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—bimetallic deposition
US8969232B2 (en) 2007-05-24 2015-03-03 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation 2
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JP5354976B2 (ja) * 2007-10-23 2013-11-27 出光興産株式会社 軽質オレフィン類製造用触媒及び軽質オレフィン類の製造方法
JP5723599B2 (ja) * 2008-02-22 2015-05-27 エクソンモービル・ケミカル・パテンツ・インク 金属高含有分子篩およびそれらの製造プロセス
SG188173A1 (en) 2008-02-22 2013-03-28 Exxonmobil Chem Patents Inc Large crystal molecular sieves and their manufacture
EP2300159A1 (de) * 2008-06-06 2011-03-30 Total Petrochemicals Research Feluy Verfahren zur herstellung von kristallinen metallosilicaten
US20110117007A1 (en) * 2009-11-13 2011-05-19 Chervon U.S.A. Inc. Method for making mfi-type molecular sieves
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US20110282122A1 (en) * 2010-05-14 2011-11-17 Uop, Llc Molecular sieve, catalyst, and/or a process relating thereto
US20130085311A1 (en) * 2011-09-29 2013-04-04 Honam Petrochemical Corporation Zsm-5 catalyst with micropores and mesopores, preparation method thereof and production method of light olefins through catalytic cracking of hydrocarbons using the catalyst
US9193645B2 (en) 2012-08-31 2015-11-24 Exxonmobil Chemical Patents Inc. Xylene isomerization process and catalyst therefor
EP2925710A4 (de) 2012-11-30 2016-05-11 Exxonmobil Chem Patents Inc Energieeffiziente verfahren zur xylenherstellung
US9309169B2 (en) 2012-11-30 2016-04-12 Exxonmobil Chemical Patents Inc. Process for the production of purified xylene isomers
CN104812703B (zh) * 2012-12-07 2018-05-29 埃克森美孚研究工程公司 具有改进形态的zsm-5晶体的合成
WO2014146128A1 (en) * 2013-03-15 2014-09-18 The Coca-Cola Company Mesoporous mfi-zeolite catalysts, methods of preparing the same and uses
CN105163851A (zh) * 2013-04-29 2015-12-16 沙特基础工业公司 石脑油转化成烯烃的催化方法
JP6398448B2 (ja) 2013-08-30 2018-10-03 東ソー株式会社 ペンタシル型ゼオライト及びその製造方法
CN104512908B (zh) * 2013-09-26 2017-02-08 天津神能科技有限公司 一种小晶粒zsm‑5沸石分子筛的合成方法
CN105636693B (zh) 2013-11-22 2019-12-13 沙特基础工业公司 用于轻石脑油芳构化的具有改善的活性/选择性的催化剂
FR3024662B1 (fr) * 2014-08-05 2016-12-09 Ifp Energies Now Procede de separation du meta-xylene utilisant un adsorbant zeolithique a haute surface externe
US10626019B2 (en) * 2014-12-30 2020-04-21 W. R. Grace & Co.-Conn. Methods for preparing zeolites with surfactant-templated mesoporosity and tunable aluminum content
US9688587B2 (en) 2015-03-03 2017-06-27 Uop Llc Process for oxygenate to olefin conversion using 2-D pentasil zeolite
US10336665B2 (en) 2015-03-03 2019-07-02 Uop Llc Yields in xylene isomerization using layer MFI zeolites
US9890094B2 (en) 2015-03-03 2018-02-13 Uop Llc High meso-surface area and high acid site density pentasil zeolite for use in xylene conversion
US9643897B2 (en) 2015-03-03 2017-05-09 Uop Llc Enhanced propylene production in OTO process with modified zeolites
US10010878B2 (en) 2015-03-03 2018-07-03 Uop Llc High meso-surface area, low Si/Al ratio pentasil zeolite
CN106629768A (zh) * 2015-11-02 2017-05-10 中国石油化工股份有限公司 均匀纳米zsm-5分子筛合成方法
WO2017180509A1 (en) 2016-04-14 2017-10-19 Uop Llc Liquid phase xylene isomerization in the absence of hydrogen
EP3872033A4 (de) * 2018-10-25 2022-08-17 Tosoh Corporation Pentasil-zeolith und herstellungsverfahren dafür
CN109721077B (zh) * 2018-12-24 2022-06-14 大连理工大学 一种薄片状Fe-ZSM-5沸石分子筛及其制备方法
US20220289645A1 (en) 2019-08-23 2022-09-15 Exxonmobil Chemical Patents Inc. Processes for Isomerizing C8 Aromatic Hydrocarbons Using Serial Reactors
KR102811928B1 (ko) 2019-08-23 2025-05-22 엑손모빌 케미칼 패턴츠 인코포레이티드 C8 방향족 탄화수소를 이성질체화하기 위한 방법
FR3104574B1 (fr) 2019-12-17 2021-12-31 Ifp Energies Now Dispositif et procédé de conversion de composés aromatiques par alkylation de toluène par du CO et de benzène par l’éthanol
FR3104577B1 (fr) 2019-12-17 2021-12-31 Ifp Energies Now Dispositif et procédé de conversion de composés aromatiques par alkylation de toluène par du CO
FR3104576B1 (fr) 2019-12-17 2021-12-31 Ifp Energies Now Dispositif et procédé de conversion de composés aromatiques par alkylation de benzène par l’éthanol
FR3104571B1 (fr) 2019-12-17 2021-12-31 Ifp Energies Now Dispositif et procédé de conversion de composés aromatiques par alkylation de toluène par du CO pour production de paratolualdéhyde
FR3104579B1 (fr) 2019-12-17 2021-12-31 Ifp Energies Now Dispositif et procédé de conversion de composés aromatiques par alkylation de benzène par de l’éthylène
FR3104572B1 (fr) 2019-12-17 2021-12-31 Ifp Energies Now Conversion de composés aromatiques par alkylation de toluène par du CO et de benzène par l’éthanol pour production de paratolualdéhyde
FR3104573B1 (fr) 2019-12-17 2021-12-31 Ifp Energies Now Dispositif et procédé de conversion de composés aromatiques par alkylation de toluène par du méthanol
FR3104575B1 (fr) 2019-12-17 2021-12-31 Ifp Energies Now Dispositif et procédé de conversion de composés aromatiques par alkylation de benzène par du CO
FR3112774B1 (fr) 2020-07-27 2023-06-02 Ifp Energies Now Dispositif et procédé de production d’aromatiques par pyrolyse de biomasse et conversion de gaz à l'eau inversée.
FR3112773B1 (fr) 2020-07-27 2023-06-02 Ifp Energies Now Dispositif et procédé de production d’aromatiques à partir d’un gaz de pyrolyse de biomasse
CN113184876B (zh) * 2021-07-05 2021-09-17 山东国瓷功能材料股份有限公司 用于吸音材料的zsm-5分子筛、其制备方法及所得产品
FR3126976A1 (fr) 2021-09-10 2023-03-17 IFP Energies Nouvelles Oxycombustion de composés hydrocarbonés riches en oxygène pour la production de xylènes.
FR3126977A1 (fr) 2021-09-10 2023-03-17 IFP Energies Nouvelles Combustion en boucle chimique de composés hydrocarbonés riches en oxygène pour la production de xylènes.
FR3130833B1 (fr) 2021-12-21 2024-10-11 Ifp Energies Now Unité de production et de séparation des aromatiques avec valorisation d’un extrait et/ou d’un raffinat provenant d’un procédé d’extraction liquide-liquide
FR3143029A1 (fr) 2022-12-13 2024-06-14 IFP Energies Nouvelles Procédé et dispositif de production d’aromatiques et de monoéthylène glycol à partir d’un gaz de pyrolyse de biomasse

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Also Published As

Publication number Publication date
JP4782285B2 (ja) 2011-09-28
ZA200105001B (en) 2002-07-19
WO2000037398A1 (en) 2000-06-29
EP1140740A1 (de) 2001-10-10
EP1140740A4 (de) 2008-04-09
US6180550B1 (en) 2001-01-30
EP1140740B1 (de) 2012-03-28
JP2002535222A (ja) 2002-10-22
US6504075B2 (en) 2003-01-07
AU2144800A (en) 2000-07-12
US20010024635A1 (en) 2001-09-27

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