ATE618T1 - PROCESSES FOR THE PRODUCTION OF MODIFIED POLYAETHERPOLYOLS AND THEIR USE FOR THE PRODUCTION OF POLYURETHANE PLASTICS. - Google Patents
PROCESSES FOR THE PRODUCTION OF MODIFIED POLYAETHERPOLYOLS AND THEIR USE FOR THE PRODUCTION OF POLYURETHANE PLASTICS.Info
- Publication number
- ATE618T1 ATE618T1 AT79103005T AT79103005T ATE618T1 AT E618 T1 ATE618 T1 AT E618T1 AT 79103005 T AT79103005 T AT 79103005T AT 79103005 T AT79103005 T AT 79103005T AT E618 T1 ATE618 T1 AT E618T1
- Authority
- AT
- Austria
- Prior art keywords
- production
- weight
- modified
- polyaetherpolyols
- processes
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 229920003023 plastic Polymers 0.000 title 1
- 239000004033 plastic Substances 0.000 title 1
- 229920002635 polyurethane Polymers 0.000 title 1
- 239000004814 polyurethane Substances 0.000 title 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 229920000570 polyether Polymers 0.000 abstract 2
- 229920005862 polyol Polymers 0.000 abstract 2
- 150000003077 polyols Chemical class 0.000 abstract 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 229910052717 sulfur Chemical group 0.000 abstract 1
- 239000011593 sulfur Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
- C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Graft Or Block Polymers (AREA)
Abstract
The instant invention is directed to a process for the preparation of modified polyether polyols comprising polymerizing of from 1 to 50 parts by weight of a mixture of 20 to 100% by weight (based on the total quantity of monomers) of acrylonitrile and 0 to 80% by weight of styrene in 50 to 99 parts by weight of the polyether polyol in the presence of a polymerization initiator which yields radicals, wherein said polymerization is carried out in the presence of from 0.1 to 1.5% by weight, based on the total quantity of monomers put into the process, of a compound of the formula: A=CH-X-R wherein A represents a divalent group <IMAGE> R represents a C1-18 alkyl, C1-10 cycloalkyl, or substituted or unsubstituted benzyl group, R' represents C1-8 alkyl group, n represents 0, 1 or 2 and X represents oxygen or sulfur.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782837026 DE2837026A1 (en) | 1978-08-24 | 1978-08-24 | METHOD FOR PRODUCING MODIFIED POLYAETHERPOLYOLS |
| EP79103005A EP0008444B1 (en) | 1978-08-24 | 1979-08-17 | Process for preparing modified polyether polyols and their use for preparing polyurethane plastics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE618T1 true ATE618T1 (en) | 1982-02-15 |
Family
ID=6047846
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT79103005T ATE618T1 (en) | 1978-08-24 | 1979-08-17 | PROCESSES FOR THE PRODUCTION OF MODIFIED POLYAETHERPOLYOLS AND THEIR USE FOR THE PRODUCTION OF POLYURETHANE PLASTICS. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4230823A (en) |
| EP (1) | EP0008444B1 (en) |
| JP (1) | JPS5531880A (en) |
| AT (1) | ATE618T1 (en) |
| AU (1) | AU5023979A (en) |
| BR (1) | BR7905428A (en) |
| CA (1) | CA1121090A (en) |
| DE (2) | DE2837026A1 (en) |
| ES (1) | ES483584A1 (en) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3010374A1 (en) * | 1980-03-18 | 1981-10-08 | Bayer Ag, 5090 Leverkusen | METHOD FOR PRODUCING COPOLYMERS OF STYRENE AND / OR THEIR DERIVATIVES |
| DE3010373A1 (en) * | 1980-03-18 | 1981-10-01 | Bayer Ag, 5090 Leverkusen | METHOD FOR THE PRODUCTION OF METHACRYLIC ACID METHYL ESTER HOMO OR COPOLYMERS |
| JPS5880500U (en) * | 1981-11-20 | 1983-05-31 | 株式会社クボタ | anchor bolt |
| USRE33291E (en) * | 1982-04-01 | 1990-08-07 | Basf Corporation | Process for the preparation of white graft polymer dispersions and flame-retardant polyurethane foams |
| USRE32733E (en) * | 1982-05-18 | 1988-08-16 | Union Carbide Corporation | Polymer/polyol compositions having improved combustion resistance |
| US4463107A (en) * | 1982-05-18 | 1984-07-31 | Union Carbide Corporation | Polymer/polyol compositions having improved combustion resistance |
| JPS59168020A (en) * | 1983-03-15 | 1984-09-21 | Toyoda Gosei Co Ltd | Nonyellowing semirigid polyurethane foam |
| US4448903A (en) * | 1983-07-25 | 1984-05-15 | Mobay Chemical Corporation | Novel system for the production of polyurethanes |
| US4574137A (en) * | 1984-08-23 | 1986-03-04 | The Dow Chemical Company | Process for preparing copolymer polyols |
| US4652589A (en) * | 1985-02-08 | 1987-03-24 | Union Carbide Corporation | Polymer/polyols having improved combustion resistance and intrinsic viscosity, methods of making same and polyurethanes prepared therefrom |
| DE3701888A1 (en) * | 1987-01-23 | 1988-08-04 | Bayer Ag | ADHESIVES AND ITS USE FOR PRODUCING ADHESIVES |
| JPH0324720Y2 (en) * | 1987-10-22 | 1991-05-29 | ||
| JPH03244620A (en) * | 1990-02-23 | 1991-10-31 | Asahi Glass Co Ltd | Production of polyurethane foam |
| US5300535A (en) * | 1988-10-25 | 1994-04-05 | Asahi Glass Company Ltd. | Method for producing polyurethane flexible foam |
| US5223570A (en) * | 1990-02-07 | 1993-06-29 | Basf Corporation | Method for the preparation of graft polymer dispersions having broad particle size distribution without wildly fluctuating viscosities |
| EP0692507A1 (en) * | 1994-07-11 | 1996-01-17 | Basf Corporation | Flexible open-cell polyurethane foam |
| DE4431226A1 (en) * | 1994-09-02 | 1996-03-07 | Bayer Ag | Low-viscosity, stable agglomerate-free polymer polyols, a process for their preparation and their use in the production of polyurethane plastics |
| ES2164176T3 (en) * | 1995-03-10 | 2002-02-16 | Bayer Ag | LOW VISCOSITY POLYMER POLYOLS, A PROCEDURE FOR THEIR PREPARATION, AS WELL AS ITS USE FOR THE MANUFACTURE OF POLYURETHANE FOAMS. |
| US5554662A (en) * | 1995-03-10 | 1996-09-10 | Bayer Adtiengesellschaft | Low viscosity polymer polyols a process for their production as well as the manufacture of polyurethane from materials |
| DE10297477T5 (en) * | 2001-11-26 | 2004-11-25 | Urawa Kenkyusho Private Ltd. Co. | Guide wire and method of making the same |
| WO2003064534A1 (en) * | 2002-01-25 | 2003-08-07 | Sanyo Chemical Industries, Ltd. | Aqueous synthetic resin dispersion |
| US20050239968A1 (en) * | 2004-04-23 | 2005-10-27 | Heyman Duane A | Process for preparing graft polyols using enol ethers as reaction moderators |
| EP1921113B1 (en) | 2005-07-07 | 2020-01-08 | Sanyo Chemical Industries, Ltd. | Polyol composition containing fine particles dispersed therein, process for production of polymeric polyols, and process for production of polyurethane resins |
| US8772405B2 (en) * | 2007-09-28 | 2014-07-08 | Sanyo Chemical Industries, Ltd. | Polymer polyol, method for producing the same, and method for producing polyurethane resin |
| JP4851503B2 (en) * | 2007-10-10 | 2012-01-11 | 三洋化成工業株式会社 | Method for producing fine particle dispersed polyol and method for producing polyurethane resin |
| CN102471445B (en) | 2009-07-20 | 2014-05-28 | 巴斯夫欧洲公司 | Method for preparing viscoelastic polyurethane soft foam material |
| DE102011077213A1 (en) | 2011-06-08 | 2012-12-13 | Bayer Material Science Ag | Polyurethane polymers |
| DE102011077200A1 (en) | 2011-06-08 | 2012-12-13 | Bayer Materialscience Aktiengesellschaft | adhesives |
| KR101876936B1 (en) * | 2016-08-11 | 2018-08-09 | (주)동성화인텍 | Composition of high flame retarding polyurethane foam and insulator comprising the same |
| KR20230013239A (en) | 2020-05-14 | 2023-01-26 | 바스프 에스이 | Electrical dissipative polyurethane foam and its use in trench breakers or pipeline pillows |
| EP4168464B1 (en) | 2020-06-22 | 2025-08-06 | Basf Se | Viscoelastic elastomeric polyurethane foams, process for preparing them and use thereof |
| CN116134064A (en) | 2020-07-24 | 2023-05-16 | 巴斯夫欧洲公司 | Multilayer structure and process for preparing multilayer structure |
| WO2023036801A1 (en) | 2021-09-07 | 2023-03-16 | Basf Se | Ionic monomer- based polyurethane foams and use thereof in trench breakers or pipeline pillows or thermally insulative material |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3304273A (en) * | 1963-02-06 | 1967-02-14 | Stamberger Paul | Method of preparing polyurethanes from liquid, stable, reactive, filmforming polymer/polyol mixtures formed by polymerizing an ethylenically unsaturated monomer in a polyol |
| GB1022434A (en) * | 1961-11-28 | 1966-03-16 | Union Carbide Corp | Improvements in and relating to polymers |
| DE1152537B (en) | 1962-06-02 | 1963-08-08 | Bayer Ag | Process for the production of homogeneous plastics containing urethane groups |
| DE1693163C3 (en) * | 1967-07-27 | 1974-02-07 | Bayer Ag, 5090 Leverkusen | Cyclohexene (3) ylidene methyl ether |
| US3953393A (en) * | 1974-01-07 | 1976-04-27 | Basf Wyandotte Corporation | Low temperature process for the preparation of graft copolymer dispersions |
| US4014846A (en) * | 1974-04-29 | 1977-03-29 | Basf Wyandotte Corporation | Low-viscous, stable polymer dispersions and polyurethanes prepared therefrom |
| US4104236A (en) * | 1974-08-28 | 1978-08-01 | Union Carbide Corporation | Liquid polymer/polyols and polyurethane elastomers based thereon |
| US3966521A (en) * | 1974-10-10 | 1976-06-29 | Basf Wyandotte Corporation | Polyurethane foam composite |
| US4172825A (en) * | 1975-07-10 | 1979-10-30 | Union Carbide Corporation | Polymer/polyols and process for production thereof |
| US4021383A (en) * | 1975-12-22 | 1977-05-03 | Texaco Development Corporation | Infused polymer containing monohydric compounds and polyurethane compositions based thereon |
| US4021384A (en) * | 1975-12-22 | 1977-05-03 | Texaco Development Corporation | Infused polymer containing polyols and polyurethane compositions based thereon |
-
1978
- 1978-08-24 DE DE19782837026 patent/DE2837026A1/en not_active Withdrawn
-
1979
- 1979-08-03 CA CA000333333A patent/CA1121090A/en not_active Expired
- 1979-08-09 US US06/065,307 patent/US4230823A/en not_active Expired - Lifetime
- 1979-08-17 EP EP79103005A patent/EP0008444B1/en not_active Expired
- 1979-08-17 AT AT79103005T patent/ATE618T1/en not_active IP Right Cessation
- 1979-08-17 DE DE7979103005T patent/DE2961977D1/en not_active Expired
- 1979-08-22 JP JP10615679A patent/JPS5531880A/en active Pending
- 1979-08-23 AU AU50239/79A patent/AU5023979A/en not_active Withdrawn
- 1979-08-23 ES ES483584A patent/ES483584A1/en not_active Expired
- 1979-08-23 BR BR7905428A patent/BR7905428A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0008444B1 (en) | 1982-01-27 |
| CA1121090A (en) | 1982-03-30 |
| DE2961977D1 (en) | 1982-03-11 |
| AU5023979A (en) | 1980-02-28 |
| DE2837026A1 (en) | 1980-03-06 |
| US4230823A (en) | 1980-10-28 |
| EP0008444A2 (en) | 1980-03-05 |
| JPS5531880A (en) | 1980-03-06 |
| BR7905428A (en) | 1980-05-27 |
| ES483584A1 (en) | 1980-07-01 |
| EP0008444A3 (en) | 1980-04-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| REN | Ceased due to non-payment of the annual fee |